Chemistry:Tricarbonate
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Names | |
---|---|
IUPAC name
Tricarbonate
| |
Properties | |
C 3O2− 7 | |
Molar mass | 148.026 g·mol−1 |
Structure | |
Trigonal planar at carbon atoms | |
Related compounds | |
Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
In organic chemistry, a tricarbonate is a compound containing the divalent –O–C(=O)–O–C(=O)–O–C(=O)–O– functional group, which consists of three carbonate groups linked in a chain by sharing of oxygen oxygen atoms. These compounds can be viewed as derivatives of a hypothetical tricarbonic acid, HO–C(=O)–O–C(=O)–O–C(=O)–OH. An important example is di-tert-butyl tricarbonate (H
3C–)
3C–C
3O
7–C(–CH
3)
3, an intermediate in the synthesis of di-tert-butyl dicarbonate.[1]
The term tricarbonate is sometimes used for salts that contain three carbonate dianions in their covalent structure or stoichiometric formula, such as cerium tricarbonate Ce
2(CO
3)
3.
See also
References
- ↑ Barry M. Pope, Yutaka Yamamoto, and D. Stanley Tarbell (1977), "Di-tert-Butyl Dicarbonate". Organic Syntheses, Vol. 57, p.45; Coll. Vol. 6 (1988) p.418
Original source: https://en.wikipedia.org/wiki/Tricarbonate.
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