Biology:Eugenol synthase

From HandWiki
Eugenol synthase
Identifiers
EC number1.1.1.318
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum

Eugenol synthase (EC 1.1.1.318, LtCES1, EGS1, EGS2) is an enzyme with systematic name eugenol:NADP+ oxidoreductase (coniferyl ester reducing).[1][2][3][4][5][6] This enzyme catalyses the following chemical reaction: eugenol + a carboxylate + NADP+ [math]\displaystyle{ \rightleftharpoons }[/math] a coniferyl ester + NADPH + H+

The enzyme acts in the reverse direction.

References

  1. "Eugenol and isoeugenol, characteristic aromatic constituents of spices, are biosynthesized via reduction of a coniferyl alcohol ester". Proceedings of the National Academy of Sciences of the United States of America 103 (26): 10128–33. June 2006. doi:10.1073/pnas.0603732103. PMID 16782809. 
  2. "A pinoresinol-lariciresinol reductase homologue from the creosote bush (Larrea tridentata) catalyzes the efficient in vitro conversion of p-coumaryl/coniferyl alcohol esters into the allylphenols chavicol/eugenol, but not the propenylphenols p-anol/isoeugenol". Archives of Biochemistry and Biophysics 465 (1): 209–18. September 2007. doi:10.1016/j.abb.2007.06.002. PMID 17624297. 
  3. "Structure and reaction mechanism of basil eugenol synthase". PLOS ONE 2 (10): e993. October 2007. doi:10.1371/journal.pone.0000993. PMID 17912370. Bibcode2007PLoSO...2..993L.  open access
  4. "The multiple phenylpropene synthases in both Clarkia breweri and Petunia hybrida represent two distinct protein lineages". The Plant Journal 54 (3): 362–74. May 2008. doi:10.1111/j.1365-313X.2008.03412.x. PMID 18208524. 
  5. "Biosynthesis of t-anethole in anise: characterization of t-anol/isoeugenol synthase and an O-methyltransferase specific for a C7-C8 propenyl side chain". Plant Physiology 149 (1): 384–94. January 2009. doi:10.1104/pp.108.128066. PMID 18987218. 
  6. "Eugenol synthase genes in floral scent variation in Gymnadenia species". Functional & Integrative Genomics 14 (4): 779–88. December 2014. doi:10.1007/s10142-014-0397-9. PMID 25239559. https://www.zora.uzh.ch/id/eprint/104915/8/ZORA_NL_104915.pdf. 

External links