Chemistry:Ferrugine
From HandWiki
Ferrugine (2α-benzoyltropane) is a tropane alkaloid discovered in the basic extract of the Australian rainforest tree Darlingia ferruginea where it occurs in the leaves and stems. The structure has been determined through spectroscopic analysis[1][2] and confirmed by chemical synthesis.[3][4][5]
(+)-Ferrugine is the natural enantiomer, with a reported specific rotation of ° (CHCl3).[2]
See also
- Ferruginine
References
- ↑ "Ferrugine. Novel tropane alkaloid". Chemistry & Industry (London, United Kingdom) (18): 794. 1975..
- ↑ 2.0 2.1 "Alkaloids of Darlingia ferruginea". Australian Journal of Chemistry 32 (11): 2537. 1979. doi:10.1071/CH9792537.
- ↑ "Thermal elimination of diethyldithiocarbamates and application in the synthesis of (+/-)-ferrugine". The Journal of Organic Chemistry 73 (20): 8116–8119. October 2008. doi:10.1021/jo801652x. PMID 18785775.
- ↑ Ahmed S (August 2009). Total synthesis of ferrugine and synthetic studies towards ferrugine and stemofoline (Ph.D. thesis). University of Birmingham.
- ↑ "Approaches to the enantioselective synthesis of ferrugine and its analogues.". Tetrahedron 68 (39): 8236–8244. September 2012. doi:10.1016/j.tet.2012.07.061.
 |  |
