Chemistry:Lutetium phosphide
From HandWiki
| Names | |
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| Other names
Phosphanylidynelutetium
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| Identifiers | |
3D model (JSmol)
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| EC Number |
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PubChem CID
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| Properties | |
| LuP | |
| Molar mass | 205.94[2] |
| Appearance | Dark crystals |
| Density | 8,1 |
| Insoluble | |
| Structure | |
| cubic | |
| Related compounds | |
Other anions
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Lutetium nitride Lutetium arsenide Lutetium antimonide Lutetium bismuthide |
Other cations
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Ytterbium phosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP.[3][4] The compound forms dark crystals, does not dissolve in water.
Synthesis
Heating powdered lutetium and red phosphorus in an inert atmosphere or vacuum:
- [math]\ce{ 4Lu + P4 -> 4LuP }[/math]
It can also be formed in the reaction of lutetium and phosphine.
Physical properties
Lutetium phosphide forms dark cubic crystals, space group Fm3m, cell parameters a = 0.5533 nm, Z = 4.[5]
Stable in air, does not dissolve in water and reacts actively with nitric acid.
Uses
The compound is a semiconductor used in high power, high-frequency applications, and in laser diodes.[6]
Also used in gamma radiation detectors due to its ability to absorb radiation.
References
- ↑ (in en) EINECS: European Inventory of Existing Commercial Chemical Substances. Office for Official Publications of the European Communities. 1987. p. 591. ISBN 978-92-825-7507-9. https://books.google.com/books?id=U_slAQAAMAAJ&q=lutetium+phosphide+LuP. Retrieved 12 December 2021.
- ↑ "Landolt-Börnstein Substance / Property Index". lb.chemie.uni-hamburg.de. https://lb.chemie.uni-hamburg.de/static/MF/3_Lu_Lu1_Lu1P.php?content=591/GW4ckRAlW.
- ↑ (in en) Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. United States Environmental Protection Agency. Office of Toxic Substances. 1980. p. 176. https://books.google.com/books?id=fkkJPwbY93gC&dq=lutetium+phosphide+LuP&pg=RA4-PA176. Retrieved 12 December 2021.
- ↑ "Lutetium Phosphide" (in en). American Elements. https://www.americanelements.com/lutetium-phosphide-12032-05-2.
- ↑ Singh, Sanjay Kumar (2019). High Pressure Properties of Lutetium Monopnictides (LuX, X = N, P, As) Theoretical Study at High Pressure : Phase Transition, Electronic and Thermal Properties of LuN, LuP and LuAs Compounds (1. Auflage ed.). Saarbrücken: Scholar's Press. ISBN 9786138913924. https://www.booklooker.de/B%C3%BCcher/Sanjay-Kumar-VERMA-Singh+High-Pressure-Properties-of-Lutetium-Monopnictides-LuX-X-N-P-As/id/A02uT9cn01ZZG. Retrieved 12 December 2021.
- ↑ "CAS 12032-05-2 Lutetium Phosphide - Alfa Chemistry". alfa-chemistry.com. https://www.alfa-chemistry.com/product/lutetium-phosphide-cas-12032-05-2-46940.html.
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