Chemistry:Rhodochrosite
| Rhodochrosite | |
|---|---|
 | |
| General | |
| Category | Carbonate minerals |
| Formula (repeating unit) | MnCO3 |
| Strunz classification | 5.AB.05 |
| Crystal system | Trigonal |
| Crystal class | Hexagonal scalenohedral (3m) H-M symbol: (3 2/m) |
| Space group | R3c |
| Unit cell | a = 4.777, c = 15.67 [Å]; Z = 6 |
| Identification | |
| Formula mass | 114.95 g/mol |
| Color | Pink, rose, rose-red, red, cherry-red, yellow, yellowish grey, grey, cinnamon-brown, white, may be banded; colourless to pale rose in transmitted light. |
| Crystal habit | Rhombohedral and scalenohedral crystals; also commonly bladed, columnar, stalactitic, botryoidal, granular or massive |
| Twinning | On {1012} as contact and lamellar |
| Cleavage | On {1011} perfect; parting on {1012} |
| Fracture | Uneven, conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 3.5–4 |
| Vitreous to pearly|re|er}} | Vitreous to pearly |
| Streak | White |
| Diaphaneity | Transparent to translucent |
| Specific gravity | 3.7 |
| Optical properties | Uniaxial (−) |
| Refractive index | nω = 1.814–1.816 nε = 1.596–1.598 |
| Birefringence | δ = 0.218 |
| Pleochroism | weak |
| Ultraviolet fluorescence | None |
| References | [1][2][3] |
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour,[5] but it can also be shades of pink to pale brown. It streaks white,[6] and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6.[7] The crystal system of rhodochrosite is trigonal, with a lattice structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−3) are arranged in a triangular planar configuration, and the manganese ions (Mn2–) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer.[8] Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa , China , and the Americas.[6] It is one of the national symbols of Argentina.
Rhodochrosite forms a complete solid solution series with iron carbonate (siderite). Calcium (as well as magnesium and zinc, to a limited extent) frequently substitutes for manganese in the structure, leading to lighter shades of red and pink, depending on the degree of substitution. This is the reason for the pink color of rhodochrosite.
Occurrence and discovery
Rhodochrosite occurs as a hydrothermal vein mineral along with other manganese minerals in low temperature ore deposits as in the silver mines of Romania where it was first found. Banded rhodochrosite is mined in Capillitas, Argentina .
It was first described in 1813 in reference to a sample from Cavnic, Maramureş, present-day Romania. The name is derived from the combination of Greek words ροδόν (rodon, meaning rose) and χρωσις (chrosis, meaning coloring).[1]
Use
Rhodochrosite is mainly used as an ore of manganese, which is a key component of low-cost stainless steel formulations and certain aluminium alloys.[9] Quality banded specimens are often used for decorative stones and jewellery. Due to its softness and perfect cleavage it is rarely found faceted in jewellery.[10]
Manganese carbonate is extremely destructive to the amalgamation process historically used in the concentration of silver ores, and were often discarded on the mine dump.
Culture
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| Small Rhodochrosite specimen featured in a mineral kit, from Wuton mine, Guangxi, China. |
Rhodochrosite is Argentina's "national gemstone".[11][12] Colorado officially named rhodochrosite as its state mineral in 2002.[13]
It is sometimes called "Rosa del Inca", "Inca Rose" or Rosinca.[14]
Gallery
"The Searchlight," a large red rhodochrosite from Sweet Home Mine, Alma, Colorado, U.S.
Rhodochrosite with fluorite, tetrahedrite and quartz.
Rhodochrosite from Silverton, Colorado, U.S.
The Alma King is the largest known rhodochrosite crystal; it was found in the Sweet Home Mine near Alma, Colorado and donated to the Denver Museum of Nature and Science.
Exhibit in La Plata Museum, Argentina.
The Alma Rose specimen from the Sweet Home Mine. On display at the Rice Northwest Museum of Rocks and Minerals in Hillsboro, Oregon, U.S.
See also
References
- ↑ 1.0 1.1 "Rhodochrosite" (PDF). Handbook of Mineralogy. V (Borates, Carbonates, Sulfates). Chantilly, VA, US: Mineralogical Society of America. 2003. ISBN 0962209740. http://rruff.geo.arizona.edu/doclib/hom/rhodochrosite.pdf.
- ↑ Rhodochrosite. Mindat.org
- ↑ Rhodochrosite. Webmineral
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. https://www.cambridge.org/core/journals/mineralogical-magazine/article/imacnmnc-approved-mineral-symbols/62311F45ED37831D78603C6E6B25EE0A.
- ↑ Deer, William Alexander (1998). Rock-forming Minerals: Non-Silicates. 5B. Geological Society of London. pp. 150–152. ISBN 9781897799901. https://books.google.com/books?id=Rz0kukaagQsC&pg=PA150.
- ↑ 6.0 6.1 Cairncross, Bruce (2015). Understanding Minerals & Crystals. Penguin Random House South Africa. p. 180. ISBN 9781775843344. https://books.google.com/books?id=9w1bDwAAQBAJ&pg=PA180.
- ↑ Ridgway, Robert Henderson (1933). Manganese: General Information. U.S. Department of the Interior, Bureau of Mines. p. 3. https://books.google.com/books?id=-XSAML4RhPsC&pg=PA3.
- ↑ Rhodonite. Mindat.org
- ↑ Emsley, John (2001). "Manganese". Nature's Building Blocks: An A-Z Guide to the Elements. Oxford, UK: Oxford University Press. p. 251. ISBN 978-0-19-850340-8.
- ↑ Matlins, Antoinette Leonard (2005). Colored gemstones : the Antoinette Matlins buying guide : how to select, buy, care for & enjoy sapphires, emeralds, rubies, and other colored gems with confidence and knowledge. Woodstock, Vt.: GemStone Press. p. 143. ISBN 978-0-943763-45-3. OCLC 60374175.
- ↑ "Piedra nacional: la Rodocrosita" (in es). Embassy of the Argentine Republic in the Colombian Republic. http://www.ecolo.mrecic.gov.ar/content/piedra-nacional-la-rodocrosita.
- ↑ Moreno, María (9 November 2002). "La piedra argentina" (in es). Página/12. http://www.pagina12.com.ar/diario/placer/16-12298-2002-11-09.html.
- ↑ "Colorado State Archives; Symbols & Emblems". http://www.colorado.gov/dpa/doit/archives/history/symbemb.htm#Mineral.
- ↑ Dietrich, R. V. (16 July 2005). "Rhodochrosite". Central Michigan University. http://stoneplus.cst.cmich.edu/Rhodochrosite.htm.
- Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., ISBN:0-471-80580-7.
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