Chemistry:Triplite

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Triplite
Triplite-t5105a.jpg
Triplite from Alchuri, Shigar Valley, Baltistan, Pakistan (1.2 × 1 × 0.9 cm)
General
CategoryPhosphate minerals
Formula
(repeating unit)
(Mn,Fe)2(PO4)(F,OH)
Strunz classification8.BB.10
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupI2/a (no. 15)
Unit cella = 11.97 Å, b = 6.52 Å
c = 10.09 Å; β = 105.62°; Z = 8
Identification
ColorChestnut to reddish brown, flesh-red, salmon-pink
Crystal habitPrismatic, massive to nodular
CleavageGood on {001}, fair on {010}, poor on {100}
FractureUneven to subconchoidal
Mohs scale hardness5 to 5.5
|re|er}}Vitreous to resinous
StreakWhite to brown
DiaphaneityTranslucent to opaque
Specific gravity3.5 – 3.9
Optical propertiesBiaxial (+)
Refractive indexnα=1.643–1.684, nβ=1.647–1.693, nγ=1.668–1.703
PleochroismDistinct; yellow-brown to reddish brown
2V angle25 – 76°
Dispersionr > v, moderate to strong
Alters toAlters to brownish black
References[1][2][3][4]

Triplite is a rare phosphate mineral with formula: (Mn, Fe)
2
PO
4
(F, OH)
. It occurs in phosphate-rich granitic pegmatites typically as irregular brown opaque masses. Triplite was first described in 1813 for an occurrence in Chanteloube, Limousin, France .[6] The name is from the Greek triplos for triple, in reference to the three cleavage directions.[2] In color and appearance, it is very similar to rhodocrosite, another manganese bearing mineral. Chemically, it is also quite similar to triploidite the difference being that triplite is fluorine dominant while triploidite is hydroxide dominant.

Occurrence

Triplite from Colorado

Triplite is a rare fluoro-hydroxide phosphate mineral that forms in phosphate rich granite pegmatites and high temperature hydrothermal veins. It has been found in the United States in California , Nevada, Arizona, Colorado, South Dakota, Virginia, Connecticut, and Maine. Other occurrences include the Shigar Valley, Pakistan ; China ; Bavaria, Germany ; Kimito, Finland and Karibib, Namibia.[2]

References

  1. Handbook of Mineralogy
  2. 2.0 2.1 2.2 Mindat.org
  3. Webmineral data
  4. Vignola, Pietro; Gatta, G. Diego; Hatert, Frédéric; Guastoni, Alessandro; Bersani, Danilo (April 2014). "ON THE CRYSTAL-CHEMISTRY OF A NEAR-ENDMEMBER TRIPLITE, Mn 2+ 2 (PO 4 )F, FROM THE CODERA VALLEY (SONDRIO PROVINCE, CENTRAL ALPS, ITALY)". The Canadian Mineralogist 52 (2): 235–245. doi:10.3749/canmin.52.2.235. 
  5. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  6. Triplite Crystals from Colorado, C. W. Wolf and E. Wm. Heinrich, American Mineralogist, Volume 32, pages 518–526, 1947

External links