Chemistry:Zirconium monophosphide
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| IUPAC name
Phosphinidinzirconium
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| Properties | |
| PZr | |
| Molar mass | 122.198 g·mol−1 |
| Appearance | solid |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP.[1][2][3]
Preparation
Zirconium monophosphide can be prepared from direct reaction of zirconium powders with red phosphorus:[4]
- 4 Zr + P
4 → 4 ZrP
Physical properties
The α-form of zirconium monophosphide has a NaCl crystal structure.[5] The β-form structure is hexagonal. The α-form is a superconductor if cooled below 5K.[6]
References
- ↑ "Zirconium Phosphide" (in en). American Elements. https://www.americanelements.com/zirconium-phosphide-12037-72-8.
- ↑ Irani, K. S.; Gingerich, K. A. (1 October 1963). "Structural transformation of zirconium phosphide". Journal of Physics and Chemistry of Solids 24 (10): 1153–1158. doi:10.1016/0022-3697(63)90231-2. ISSN 0022-3697. https://www.sciencedirect.com/science/article/abs/pii/0022369763902312. Retrieved 7 March 2024.
- ↑ O'Bannon, Loran (6 December 2012) (in en). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 283. ISBN 978-1-4613-2655-7. https://books.google.com/books?id=pM_gBwAAQBAJ&dq=%22zirconium+phosphide+ZrP%22&pg=PA283. Retrieved 7 March 2024.
- ↑ Li, Zhen; Chen, Ning; Wang, Jigang; Li, Peishen; Guo, Ming; Wang, Qiang; Li, Chunhong; Wang, Changzheng et al. (12 October 2017). "Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method". Scientific Reports 7 (1): 13044. doi:10.1038/s41598-017-13616-5. PMID 29026175. PMC 5638856. https://bpb-us-e1.wpmucdn.com/sites.ucsc.edu/dist/7/1409/files/2022/06/QW-ZrP.pdf.
- ↑ Swanson, Howard Eugene (1962) (in en). Standard X-ray Diffraction Powder Patterns: Data for 46 substances. National Bureau of Standards. p. 75. https://books.google.com/books?id=c065QK_BMSkC&dq=%22zirconium+phosphide+ZrP%22&pg=RA5-PA75. Retrieved 7 March 2024.
- ↑ Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3769. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=%22zirconium+phosphide+ZrP%22&pg=PA3769. Retrieved 7 March 2024.
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