Physics:Kepert model

The Kepert model is a modification of VSEPR theory used to predict the 3-dimensional structures of transitional metal complexes. In the Kepert model, the ligands attached to the metal are considered to repel each other the same way that point charges repel each other in VSEPR theory. Unlike VSEPR theory, the Kepert model does not account for non-bonding electrons. Therefore, the geometry of the coordination complex is independent of the electronic configuration of the metal center. Thus [ML_n]^m+ has the same coordination geometry as [ML_n]^m−. The Kepert model cannot explain the formation of square planar complexes or distorted structures.

The Kepert model predicts the following geometries for coordination numbers of 2 through 9:

2. Linear
3. Trigonal planar
4. Tetrahedral
5. Trigonal bipyramidal or Square pyramidal
6. Octahedral
7. Pentagonal bipyramidal, Capped octahedral or Capped trigonal prismatic
8. Square antiprismatic, Dodecahedral or Bicapped trigonal prismatic
9. Tricapped trigonal prismatic or Capped square antiprismatic

References

Housecroft, C. E.; Sharpe, A. G. (2004). Inorganic Chemistry (2nd ed.). Prentice Hall. pp. 541-542. ISBN 978-0-13-039913-7.