Chemistry:Diethylmercury

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Diethylmercury
Diethylmercury Structural Formula V2.svg
Names
IUPAC name
diethylmercury
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 211-000-7
MeSH C007378
UNII
Properties
C4H10Hg
(C2H5)2Hg
Molar mass 258.71 g/mol
Appearance Colorless liquid
Odor Sweet
Density 2.446 g/ml
Melting point −45 °C (−49 °F; 228 K)
Boiling point 156 to 157 °C (313 to 315 °F; 429 to 430 K)
Insoluble
Solubility Ethers, hydrocarbons, THF
Hazards
Main hazards Flammable, extremely toxic
GHS pictograms GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
GHS Signal word Danger
H225, H300+310+330Script error: No such module "Preview warning".Category:GHS errors, H373, H410
P260, P262, P264, P270, P271, P273, P280, P284, P301+310, P302+350, P304+340, P310, P314, P320, P321, P322, P330, P361, P363, P391, P403+233, P405, P501
Flash point N/A
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Diethylmercury is a flammable, colorless liquid, and one of the strongest known neurotoxins. This organomercury compound is described as having a slightly sweet smell, though inhaling enough fumes to notice this would be hazardous.[1] This chemical can cross the blood–brain barrier, causing permanent brain damage. It is, however, considerably less toxic than dimethylmercury.

Synthesis

Diethylmercury can be obtained from the reaction between ethylmagnesium bromide and mercury(II) chloride.[2]

2 C2H5MgBr + HgCl2 → Hg(C2H5)2 + MgBr2 + MgCl2

Other methods are also known.[3]

See also

References