Chemistry:Asulam

From HandWiki
Asulam
Skeletal formula
Ball-and-stick model
Names
Preferred IUPAC name
Methyl (4-aminobenzene-1-sulfonyl)carbamate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
KEGG
UNII
Properties
C8H10N2O4S
Molar mass 230.241 g/mol
Density 1.419 g/mL
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Tracking categories (test):

Asulam is a herbicide invented by May & Baker Ltd , internally called M&B9057,[1] that is used in horticulture and agriculture to kill bracken[2][3] and docks.[4] It is also used as an antiviral agent. It is currently marketed, by United Phosphorus Ltd - UPL, as "Asulox" which contains 400 g/L of asulam sodium salt.

Asulam was declared not approved by the Commission Implementing Regulation (EU) No 1045/2011 of 19 October 2011 concerning the non-approval of the active substance asulam. Concerns included: lack of evidence concerning the fate of the toxic metabolite sulfanilamide and other metabolites; the poorly characterised nature of the impurities potentially present in the technical-grade product; toxicity to birds. This decision is given in with Regulation (EC) No 1107/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market, and amending Commission Decision 2008/934/EC (http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2011:275:0023:0024:EN:PDF).

References

  1. "ChemSpider – Asulam – C8H10N2O4S". http://www.chemspider.com/Chemical-Structure.17707.html?rid=5a4054d2-3aa3-4364-942b-6e3bfa42cd9c. Retrieved 30 September 2011. 
  2. R. J. Pakemana, M. G. Le Ducb and R. H. Marrs (1998). "An assessment of aerially applied asulam as a method of long-term bracken control". Journal of Environmental Management 53 (3): 255–262. doi:10.1006/jema.1998.0207. 
  3. C. S. R. Snow and R. H. Marrs (1997). "Restoration of Calluna heathland on a bracken Pteridium-infested site in north west England". Biological Conservation 81 (1–2): 35–42. doi:10.1016/S0006-3207(96)00147-4. 
  4. R. I. Speight and J. B. Whittaker (1987). "Interactions Between the Chrysomelid Beetle Gastrophysa viridula, the Weed Rumex obtusifolius and the Herbicide Asulam". The Journal of Applied Ecology 24 (1): 119–129. doi:10.2307/2403791. 

Further reading

  • Asulam in the Pesticide Properties DataBase (PPDB)