Chemistry:Gallium(III) cyanide
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3D model (JSmol)
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PubChem CID
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| Properties | |
| Ga(CN)3 | |
| Molar mass | 147.78 g/mol |
| Appearance | White solid |
| Melting point | 450 °C (842 °F; 723 K)[1] (decomposes) |
| Reacts[1] | |
| Solubility | Soluble in THF and DMF, insoluble in hexane[1] |
| Structure[2] | |
| Cubic | |
| Pm3m | |
a = 5.295 Å α = 90°, β = 90°, γ = 90°
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Gallium(III) cyanide is a chemical compound of gallium with the formula Ga(CN)3. It is an air-sensitive white solid that decomposes at 450 °C.[1]
Production and reactions
Gallium(III) cyanide is produced by the reaction of gallium(III) chloride and trimethylsilyl cyanide at 75 °C:[1]
- 3 Me3SiCN + GaCl3 → 3 Me3SiCl + Ga(CN)3
The tetracyanogallate(III) ion can be produced by the reaction of Ga(CN)3 and LiCN or CuCN. It also forms adducts with pyridine to produce Ga(CN)3(NC5H5)2.[1][3]
References
- ↑ 1.0 1.1 1.2 1.3 1.4 1.5 Louis C. Brousseau; Darrick Williams; J. Kouvetakis; M. O'Keeffe (1997). "Synthetic Routes to Ga(CN)3 and MGa(CN)4 (M = Li, Cu) Framework Structures" (in en). Journal of the American Chemical Society 119 (27): 6292–6296. doi:10.1021/ja9702024.
- ↑ D.J. Williams; D.E. Partin; F.J. Lincoln; J. Kouvetakis; M. O'Keeffe (1997). "The Disordered Crystal Structures of Zn(CN)2and Ga(CN)3" (in en). Journal of Solid State Chemistry 134 (1): 164–169. doi:10.1006/jssc.1997.7571. Bibcode: 1997JSSCh.134..164W.
- ↑ A. V. G. Chizmeshya; C. J. Ritter; T. L. Groy; J. B. Tice; J. Kouvetakis (2007). "Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues" (in en). Chemistry of Materials 19 (24): 5890–5901. doi:10.1021/cm071275h.
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