Chemistry:Gold triiodide

From HandWiki
Gold triiodide
Names
Systematic IUPAC name
Gold(III) iodide
Other names
Auric iodide
Gold iodide
Digold hexaiodide
Identifiers
3D model (JSmol)
ChemSpider
Properties
AuI3
Molar mass 577.67998 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Gold iodide (AuI3) is the chemical compound with the formula AuI3. Although Au2I6 is predicted to be stable,[1] gold(III) iodide remains an example of a nonexistent or unstable compound.[2] Attempts to isolate pure samples result in the formation of gold(I) iodide and iodine:

AuI3AuI + I2[citation needed]

References

  1. Tilo Söhnel, Reuben Brown, Lars Kloo Peter Schwerdtfeger "The Stability of Gold Iodides in the Gas Phase and the Solid State" Chemistry - A European Journal 2001, volume 7, 3167–3173. doi:10.1002/1521-3765(20010716)7:14<3167::AID-CHEM3167>3.0.CO;2-G
  2. Schulz, A., & Hargittai, M. (2001), "Structural variations and bonding in gold halides: A quantum chemical study of monomeric and dimeric gold monohalide and gold trihalide molecules, AuX, Au2X2, AuX3, and Au2X6 (X = F, Cl, Br, I)", Chemistry - A European Journal 7 (17), doi:10.1002/1521-3765(20010903)7:17<3657::aid-chem3657>3.0.co;2-q ; also see cover picture description