Chemistry:Hafnium phosphide
From HandWiki
| Names | |
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| IUPAC name
Phosphanylidynehafnium
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Other names
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| EC Number |
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| Properties | |
| HfP | |
| Molar mass | 209.464 g/mol[1] |
| Appearance | Crystalline solid |
| Density | 9.78 g/cm3[2] |
| log P | 0.30[3] |
| Structure | |
| Hexagonal | |
| Related compounds | |
Related compounds
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Hafnium(III) phosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Hafnium phosphide (HfP) is a binary inorganic compound of hafnium metal and phosphorus.
Preparation
It can be obtained by heating together hafnium powder and red phosphorus in sealed quartz tube under vacuum at high temperatures.[4]
Uses
The compound is a semiconductor used in high power, high frequency applications and in laser diodes.[5]
Silica-supported hafnium phosphide (HfP/SiO2) was used as a solid acid catalyst to drive furfural production from xylan.[6][7]
References
- ↑ "CompTox Chemicals Dashboard". https://comptox.epa.gov/dashboard/chemical/details/DTXSID301314087.
- ↑ McColm, Ian J. (1994), McColm, Ian J., ed., "H" (in en), Dictionary of Ceramic Science and Engineering (Boston, MA: Springer US): pp. 153–163, doi:10.1007/978-1-4757-2321-2_8, ISBN 978-1-4757-2321-2
- ↑ "SureChEMBL". https://www.surechembl.org/chemical/SCHEMBL2953072.
- ↑ Mandot, Vivek (March 1998). "Hyperfine interaction study of electric field gradient in hafnium phosphide using181Ta probe". Pramana Journal of Physics 50 (3): 227–230. https://www.ias.ac.in/describe/article/pram/050/03/0227-0230.
- ↑ Elements, American. "Hafnium Phosphide" (in en). https://www.americanelements.com/hafnium-phosphide-12325-59-6.
- ↑ Xu, Siquan; Wu, Ningxin; Yuan, Hui; Chen, Yuan; Pan, Donghui; Wu, Yuanfeng; Fan, Jingdeng; Gao, Lijing et al. (2020-04-01). "An Effective and Stable HfP/SiO2 Catalyst for the Production of Furfural from Xylan" (in en). Catalysis Letters 150 (4): 1121–1127. doi:10.1007/s10562-019-02994-2. ISSN 1572-879X.
- ↑ Cousin, Elsa; Namhaed, Kritsana; Pérès, Yolande; Cognet, Patrick; Delmas, Michel; Hermansyah, Heri; Gozan, Misri; Alaba, Peter Adeniyi et al. (November 2022). "Towards efficient and greener processes for furfural production from biomass: A review of the recent trends". Science of the Total Environment 847. doi:10.1016/j.scitotenv.2022.157599. ISSN 0048-9697.
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