Chemistry:Iron(IV) oxytetrafluoroborate
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_oxytetrafluoroborate.svg)
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3D model (JSmol)
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| FeO(BF4)2 | |
| Molar mass | 245.456 g/mol |
| Soluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Iron(IV) oxytetrafluoroborate is a chemical compound with the rare Fe(IV) ion. It was first reported in 1998 but was not confirmed. Then in 2006, a more reliable production was reported. It was created by reacting iron(II) tetrafluoroborate with ozone. The compound is very unstable, some of the product was quickly decomposed with the leftover Fe(II) to create iron(III) tetrafluoroborate and Fe(IV) complexes. It is also decomposed by various oxygen acceptors such as sulfur which creates sulfur monoxide and iron(II) tetrafluoroborate.[1]
References
- ↑ Ames Laboratory, Iowa State University (2006). "Aqueous Ferryl(IV) Ion: Kinetics of Oxygen Atom Transfer To Substrates and Oxo Exchange with Solvent Water" (in English). Inorganic Chemistry (U.S. Department of Energy) 45 (2): 814–820. doi:10.1021/ic051868z. PMID 16411719. https://pubs.acs.org/doi/full/10.1021/ic051868z. Retrieved 17 May 2021.
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