Chemistry:Lazulite

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Lazulite
Lazulite specimen found near Rapid Creek, Yukon, Canada
General
CategoryPhosphate mineral
Formula
(repeating unit)
(Mg,Fe2+)Al
2
(PO
4
)
2
(OH)
2
Strunz classification8.BB.40
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H–M symbol)
Space groupP21/c
Unit cella = 7.144(1), b = 7.278(1)
c = 7.228(1) [Å]; β = 120.5(1)°; Z = 2
Identification
ColorAzure, sky blue, bluish white, yellow-green, blue-green, rarely green
Crystal habitTabular, acute to stubby bipyramidal crystals; granular, massive
TwinningCommon by several twin laws
CleavagePoor to good on {110}, indistinct on {101}
FractureUneven, splintery
TenacityBrittle
Mohs scale hardness5.5–6.0
|re|er}}Vitreous
StreakWhite
DiaphaneityTransparent to translucent to nearly opaque
Specific gravity3.122–3.240
Optical propertiesBiaxial (−)
Refractive indexnα = 1.604–1.626
nβ = 1.626–1.654
nγ = 1.637–1.663
Birefringenceδ = 0.033–0.037
PleochroismStrong: X = colorless, Y = blue, Z = darker blue
2V angleMeasured: 61–70°
FusibilityInfusible
SolubilityInsoluble
References[1][2][3][4]

Lazulite or Azure spar[6]: 14  is a transparent to semi-opaque, blue mineral that is a phosphate of magnesium, iron, and aluminium, with the chemical formula (Mg,Fe2+)Al
2
(PO
4
)
2
(OH)
2
.[2] Lazulite forms one endmember of a solid solution series with the darker, iron-rich scorzalite.[2][4]

Lazulite crystallizes in the monoclinic system. Its crystal habits include steep bipyramidal or wedge-shaped crystals.[7] Lazulite has a Mohs hardness of 5.5–6.0 and a specific gravity of 3.0–3.1. It is infusible and insoluble.[4]

Occurrence and discovery

Lazulite from Laila,(Village Dasso) Kutwal Valley Haramosh Gilgit District, Gilgit-Baltistan, Pakistan. Size: 2.4 cm × 1.7 cm × 0.8 cm (0.94 in × 0.67 in × 0.31 in).

Lazulite forms by high-grade metamorphism of silica-rich rocks and in pegmatites. It occurs in association with quartz, andalusite, rutile, kyanite, corundum, muscovite, pyrophyllite, dumortierite, wagnerite, svanbergite, trolleite, and berlinite in metamorphic terrains; and with albite, quartz, muscovite, tourmaline and beryl in pegmatites.[1] It may be confused with lazurite, lapis lazuli or azurite.

The type locality is in Freßnitzgraben in Krieglach, it's also found in Salzburg, Austria; Zermatt, Switzerland; Minas Gerais, Brazil; Lincoln County, Georgia; Inyo County, California; the Yukon in Canada; and elsewhere.

It was first described in 1795 for deposits in Styria, Austria.[2] Its name comes from the German lazurstein, for 'blue stone'[1] or from the Arabic for heaven.[2][4]

References

  1. 1.0 1.1 1.2 "Lazulite". Handbook of Mineralogy. RRUFF. http://rruff.geo.arizona.edu/doclib/hom/lazulite.pdf. 
  2. 2.0 2.1 2.2 2.3 2.4 Lazulite, MinDat.org, http://www.mindat.org/show.php?id=2356 
  3. Lazulite Mineral Data, WebMineral.com, https://webmineral.com/data/Lazulite.shtml 
  4. 4.0 4.1 4.2 4.3 Hurlbut, Cornelius S.; Klein, Cornelius (1985). Manual of Mineralogy (20th ed.). Wiley. ISBN 0-471-80580-7. 
  5. Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine (Mineralogical Society of Great Britain and Ireland) 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  6. Krivovichev V. G. Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. (in Russian)
  7. "Lazulite". Minerals.net. https://minerals.net/mineral/lazulite.aspx.