Chemistry:Moissanite

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Short description: Silicon carbide mineral
Moissanite
Moissanite-USGS-20-1001d-14x-.jpg
General
CategoryMineral species
Formula
(repeating unit)		SiC
Strunz classification1.DA.05
Crystal system6H polytype, most common: hexagonal
Crystal class6H polytype: dihexagonal pyramidal (6mm)
H-M symbol: (6mm)
Space group6H polytype: P63mc
Identification
ColorColorless, green, yellow
Crystal habitGenerally found as inclusions in other minerals
Cleavage(0001) indistinct
FractureConchoidal – fractures developed in brittle materials characterized by smoothly curving surfaces, e.g., quartz
Mohs scale hardness9.25
|re|er}}Adamantine to metallic
StreakGreenish gray
DiaphaneityTransparent
Specific gravity3.218–3.22
Refractive indexnω = 2.654 nε = 2.967
Birefringence0.313 (6H form)
Dispersion0.104
Ultraviolet fluorescenceOrange-red
Melting point2730 °C (decomposes)
SolubilityNone
Other characteristicsNot radioactive, non-magnetic
References[1][2][3]

Moissanite (/ˈmɔɪsəˌnaɪt/)[5] is naturally occurring silicon carbide and its various crystalline polymorphs. It has the chemical formula SiC and is a rare mineral, discovered by the French chemist Henri Moissan in 1893. Silicon carbide is useful for commercial and industrial applications due to its hardness, optical properties and thermal conductivity.

Background

The mineral moissanite was discovered by Henri Moissan while examining rock samples from a meteor crater located in Canyon Diablo, Arizona, in 1893. At first, he mistakenly identified the crystals as diamonds, but in 1904 he identified the crystals as silicon carbide.[6][7] Artificial silicon carbide had been synthesized in the lab by Edward G. Acheson in 1891, just two years before Moissan's discovery.[8]

The mineral form of silicon carbide was named in honor of Moissan later on in his life.

Geological occurrence

In its natural form, moissanite remains very rare. Until the 1950s, no other source for moissanite other than as presolar grains in carbonaceous chondrite meteorites[9] had been encountered. Then, in 1958, moissanite was found in the upper mantle Green River Formation in Wyoming and, the following year, as inclusions in the ultramafic rock kimberlite from a diamond mine in Yakutia in the Russian Far East.[10] Yet the existence of moissanite in nature was questioned as late as 1986 by the American geologist Charles Milton.[11]

Discoveries show that it occurs naturally as inclusions in diamonds, xenoliths, and such other ultramafic rock such as lamproite.[12]

Meteorites

Analysis of silicon carbide grains found in the Murchison meteorite has revealed anomalous isotopic ratios of carbon and silicon, indicating an extraterrestrial origin from outside the Solar System.[13] 99% of these silicon carbide grains originate around carbon-rich asymptotic giant branch stars. Silicon carbide is commonly found around these stars, as deduced from their infrared spectra.[14] The discovery of silicon carbide in the Canyon Diablo meteorite and other places was delayed for a long time as carborundum (SiC) contamination had occurred from man-made abrasive tools.[12]

Physical properties

The crystalline structure is held together with strong covalent bonding similar to diamonds,[6] that allows moissanite to withstand high pressures up to 52.1 gigapascals.[6][15] Colors vary widely and are graded from D to K range on the diamond color grading scale.[16]

Sources

All applications of silicon carbide today use synthetic material, as the natural material is very scarce.

The idea that a silicon-carbon bond might in fact exist in nature was first proposed by the Swedish chemist Jöns Jacob Berzelius as early as 1824 (Berzelius 1824).[17] In 1891, Edward Goodrich Acheson produced viable minerals that could substitute for diamond as an abrasive and cutting material.[18] This was possible, as moissanite is one of the hardest substances known, with a hardness just below that of diamond and comparable with those of cubic boron nitride and boron. Pure synthetic moissanite can also be made from thermal decomposition of the preceramic polymer poly(methylsilyne), requiring no binding matrix, e.g., cobalt metal powder.

Single-crystalline silicon carbide, in certain forms, has been used for the fabrication of high-performance semiconductor devices. As natural sources of silicon carbide are rare, and only certain atomic arrangements are useful for gemological applications, North Carolina–based Cree Research, Inc., founded in 1987, developed a commercial process for producing large single crystals of silicon carbide. Cree is the world leader in the growth of single crystal silicon carbide, mostly for electronics use.[19]

In 1995 C3 Inc., a company helmed by Charles Eric Hunter, formed Charles & Colvard to market gem quality moissanite. Charles & Colvard was the first company to produce and sell synthetic moissanite under U.S. patent US5723391 A, first filed by C3 Inc. in North Carolina.[20]

Applications

A moissanite engagement ring
Moissanite: emerald cut

Moissanite was introduced to the jewelry market as a diamond alternative in 1998 after Charles & Colvard (formerly known as C3 Inc.) received patents to create and market lab-grown silicon carbide gemstones, becoming the first firm to do so. By 2018 all patents on the original process world-wide had expired.[21][22][23] Charles & Colvard currently makes and distributes moissanite jewelry and loose gems under the trademarks Forever One, Forever Brilliant, and Forever Classic.[24] Other manufacturers market silicon carbide gemstones under trademarked names such as Amora.

On the Mohs scale of mineral hardness (with diamond as the upper extreme, 10) moissanite is rated as 9.25.[3] As a diamond alternative Moissanite has some optical properties exceeding those of diamond. It is marketed as a lower price alternative to diamond that does not involve the expensive mining practices used for the extraction of natural diamonds. As some of its properties are quite similar to diamond, moissanite may be used as counterfeit diamond. Testing equipment based on measuring thermal conductivity in particular may give results similar to diamond. In contrast to diamond, moissanite exhibits a thermochromism, such that heating it gradually will cause it to temporarily change color, starting at around 65 °C (150 °F). A more practical test is a measurement of electrical conductivity, which will show higher values for moissanite. Moissanite is birefringent (i.e., light sent through the material splits into separate beams that depend on the source polarization), which can be easily seen, and diamond is not.[25]

Because of its hardness, it can be used in high-pressure experiments, as a replacement for diamond (see diamond anvil cell).[6] Since large diamonds are usually too expensive to be used as anvils, moissanite is more often used in large-volume experiments. Synthetic moissanite is also interesting for electronic and thermal applications because its thermal conductivity is similar to that of diamonds.[15] High power silicon carbide electronic devices are expected to find use in the design of protection circuits used for motors, actuators, and energy storage or pulse power systems.[26] It also exhibits thermoluminescence,[27] making it useful in radiation dosimetry.[28]

See also

References

  1. ↑ Moissanite. Webmineral
  2. ↑ Moissanite. Mindat
  3. ↑ 3.0 3.1 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W. and Nichols, Monte C. (eds.) "Moissanite". Handbook of Mineralogy. Mineralogical Society of America
  4. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. 
  5. ↑ Moissanite (3rd ed.), Oxford University Press, September 2005, http://oed.com/search?searchType=dictionary&q=Moissanite  (Subscription or UK public library membership required.)
  6. ↑ 6.0 6.1 6.2 6.3 Xu J.; Mao H. (2000). "Moissanite: A window for high-pressure experiments". Science 290 (5492): 783–787. doi:10.1126/science.290.5492.783. PMID 11052937. Bibcode: 2000Sci...290..783X. 
  7. ↑ Moissan, Henri (1904). "Nouvelles recherches sur la météorité de Cañon Diablo". Comptes rendus 139: 773–786. http://gallica.bnf.fr/ark:/12148/bpt6k30930/f773.table. 
  8. ↑ Smith, Kady. "History and Applications of Silicon Carbide". Moissanite & Co. http://blog.moissaniteco.com/history-and-applications-of-silicon-carbide/. 
  9. ↑ Yokoyama, T.; Rai, V. K.; Alexander, C. M. O’D.; Lewis, R. S.; Carlson, R. W.; Shirey, S. B.; Thiemens, M. H.; Walker, R. J. (March 2007). "Nucleosynthetic Os Isotopic Anomalies in Carbonaceous Chondrites". 38th Lunar and Planetary Science Conference (1338): 1151. Bibcode: 2007LPI....38.1151Y. http://www.lpi.usra.edu/meetings/lpsc2007/pdf/1151.pdf. 
  10. ↑ Bauer, J.; Fiala, J.; Hřichová, R. (1963). "Natural α–Silicon Carbide". American Mineralogist 48: 620–634. http://www.minsocam.org/msa/collectors_corner/arc/moissanite.htm. 
  11. ↑ Belkin, H. E.; Dwornik, E. J. (1994). "Memorial of Charles Milton April 25, 1896 – October 1990". American Mineralogist 79: 190–192. http://www.minsocam.org/ammin/AM79/AM79_190.pdf. 
  12. ↑ 12.0 12.1 Di Pierro S.; Gnos E.; Grobety B.H.; Armbruster T. et al. (2003). "Rock-forming moissanite (natural α-silicon carbide)". American Mineralogist 88 (11–12): 1817–1821. doi:10.2138/am-2003-11-1223. Bibcode: 2003AmMin..88.1817D. http://www.geoscienceworld.org/cgi/georef/2004018181. 
  13. ↑ Kelly, Jim. The Astrophysical Nature of Silicon Carbide. chem.ucl.ac.uk
  14. ↑ Greene, Dave. "Will Moissanite Pass a Diamond Tester? | Best Test Options". Retrieved 21 September 2019.
  15. ↑ 15.0 15.1 Zhang J.; Wang L.; Weidner D.J.; Uchida T. et al. (2002). "The strength of moissanite". American Mineralogist 87 (7): 1005–1008. doi:10.2138/am-2002-0725. Bibcode: 2002AmMin..87.1005Z. http://www.minsocam.org/msa/AmMin/toc/Abstracts/2002_Abstracts/July02_Abstracts/Zhang_p1005_02.pdf. 
  16. ↑ Read P. (2005). Gemmology. Massachusetts: Elsevier Butterworth-Heinemann. ISBN 978-0-7506-6449-3. https://books.google.com/books?id=t-OQO3Wk-JsC. 
  17. ↑ "Silicon Carbide – Older than the Stars". http://img.chem.ucl.ac.uk/www/kelly/history.htm. 
  18. ↑ "Silicon carbide | chemical compound". https://www.britannica.com/science/silicon-carbide. 
  19. ↑ "Moissanite History". https://www.moissanitejewelry.com/history.htm. 
  20. ↑ "Silicon carbide gemstones". https://patents.google.com/patent/US5723391. 
  21. ↑ Hunter, Charles Eric & Dirk Verbiest, "Single crystal gems hardness, refractive index, polishing, and crystallization", US patent 5762896
  22. ↑ Hunter, Charles Eric & Dirk Verbiest, "Silicon carbide gemstones", US patent expired 5723391
  23. ↑ "Moissanite gem patent restrictions by country and year of expiration". http://betterthandiamond.com/pages/Moissanite-Gem-Patent-restrictions-by-country-and-year-of-expiration.html. 
  24. ↑ "Moissanite Rights". Professional Jeweler Magazine. May 1998. http://www.professionaljeweler.com/archives/articles/1998/may98/0598press1.html. Retrieved 24 October 2012. 
  25. ↑ "Diamond look-alike comparison chart". International Gem Society. http://www.gemsociety.org/article/diamond-look-alike-comparison-chart/. 
  26. ↑ Bhatnagar, M.; Baliga, B.J. (1993). "Comparison of 6H-SiC, 3C-SiC, and Si for power devices". IEEE Transactions on Electron Devices 40 (3): 645–655. doi:10.1109/16.199372. Bibcode: 1993ITED...40..645B. 
  27. ↑ Godfrey-Smith, D.I. (Aug 1, 2006). "Applicability of moissanite, a monocrystalline form of silicon carbide,to retrospective and forensic dosimetry". Radiation Measurements 41 (7): 976–981. doi:10.1016/j.radmeas.2006.05.025. Bibcode: 2006RadM...41..976G. https://www.deepdyve.com/lp/elsevier/applicability-of-moissanite-a-monocrystalline-form-of-silicon-carbide-Uaw0AcXWN0. Retrieved 23 December 2017. 
  28. ↑ Bruzzia, M.; Navab, F.; Piniac, S.; Russoc, S. (12 December 2001). "High quality SiC applications in radiation dosimetry". Applied Surface Science 184 (1–4): 425–430. doi:10.1016/S0169-4332(01)00528-1. Bibcode: 2001ApSS..184..425B. 

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