Chemistry:Nitrate selenite

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The nitrate selenites are mixed anion compounds containing distinct nitrate (NO3−)and selenite (SO32−) groups. The compounds are colourless unless coloured by cations.

List

formula formula weight crystal system space group unit cell Å volume density comment reference
[Cu(HSeO3)2(NO3)2]2−•2NH4+•NH4NO3 orthorhombic Pnma a=8.8813 b=24.01 c=7.2195 [1]
(RbNO3)2[Cu(HSeO3)2] monoclinic P21/c a=9.2833 b=7.1193 c=9.0315 β=91.643° [2]
Ag5Cu2(NO3)(SeO3)4 1326.26 triclinic P1 a=5.148 b=7.050 c=10.540 α=73.09° β=89.08° γ=88.50° 365.85 5.61 [3]
Cd(HSeO3)NO3 302.38 orthorhombic Pbca a=6.359 b=8.945 c=16.648 Z=8 949.1 4.23 [4]
(CsNO3)[Cu(HSeO3)2] orthorhombic Pnma a=8.891 b=13.859 c=7.249 [2]
Gd(NO3)(Se2O5)•3H2O orthorhombic P212121 a=6.2509 b=7.0944 c=20.747 SHG 0.2 × KDP [5]
Lu(SeO3)(NO3)(H2O) 381.96 orthorhombic Pbcn a=16.151 b=11.854 c=6.795 Z=8 1300.9 3.900 colourless [6]
(TlNO3)[Cu(HSeO3)2] orthorhombic Pnma a=8.7788 b=13.668 c=7.2056 [2]
Pb2(SeO3)(NO3)2 orthorhombic Pmn21 a = 5.4669 b = 10.3277 c = 7.2610 Z = 4 409.96 [7][8]
Pb2(NO2)(NO3)(SeO3) orthorhombic Pmn21 a=5.529 b=10.357 c=6.811 Z=2 [9]
PbCu3(OH)(NO3)(SeO3)3•0.5H2O triclinic P1 a=7.761 b=9.478 c=9.514 α=66.94° β=69.83° γ=81.83° Z=2 [3][10]
Pb2Cu3O2(NO3)2(SeO3)2 orthorhombic Cmc21 a=5.884 b=12.186 c=19.371 Z=4 [3][10]
Pb(OF)Cu3(SeO3)2(NO3) 748.74 R3m a=6.6973 c=18.5548 Z=3 720.75 5.175 dark brown [11]
PbCdF(SeO3)(NO3) orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 Z=4 621.9 5.634 SHG 2.6×KDP band gap 4.42 eV [12]
Bi(SeO3)(NO3) monoclinic C2/c a=15.352 b=4.9112 c=14.101 β=110.79° [13]
(Bi3O2)(SeO3)2(NO3) monoclinic P21/c a=9.9403 b=9.6857 c=10.6864 β=93.115° Z=4 [14]
((CH3)4N)[UO2(NO3)(SeO3)] monoclinic C2/m a = 21.888 b = 6.9501 c = 8.349 β = 97.618° Z = 4 1259.0 2.813 yellow-green [15]
(H2en)[(UO2)(SeO3)(HSeO3)](NO3)·0.5H2O 1316.19 orthorhombic Pbca a = 13.170 b = 11.055 c = 18.009 Z = 4 2621.8 3.334 [16]

References

  1. ↑ Lafront, A.M.; Trombe, J.C. (June 1995). "'Layered hydrogenselenite' I. Synthesis, structure redetermination of [Cu(HSeO3)2(H2O)2 and determination of [Cu(HSeO3)2(NO3)2]2−·2NH4+,NH4NO3. Structural relationships of these complexes with [Cu(HSeO3)2]"] (in en). Inorganica Chimica Acta 234 (1–2): 19–25. doi:10.1016/0020-1693(95)04500-9. https://linkinghub.elsevier.com/retrieve/pii/0020169395045009. 
  2. ↑ 2.0 2.1 2.2 Markovski, Mishel R.; Charkin, Dmitri O.; Siidra, Oleg I.; Nekrasova, Diana O. (2019-12-18). "Copper hydroselenite nitrates ( A + NO 3 ) n [Cu(HSeO 3 ) 2 ( A =Rb + , Cs + and Tl + , n =1, 2) related to Ruddlesden – Popper phases"] (in en). Zeitschrift für Kristallographie - Crystalline Materials 234 (11–12): 749–756. doi:10.1515/zkri-2019-0036. ISSN 2196-7105. https://www.degruyter.com/document/doi/10.1515/zkri-2019-0036/html. 
  3. ↑ 3.0 3.1 3.2 Effenberger, H. (1991-12-15). "Structure of pentasilver(I) dicopper(II) mononitrate tetraselenite(IV)". Acta Crystallographica Section C Crystal Structure Communications 47 (12): 2522–2525. doi:10.1107/S0108270191006935. Bibcode: 1991AcCrC..47.2522E. https://scripts.iucr.org/cgi-bin/paper?S0108270191006935. 
  4. ↑ Leskela, Markku; Valkonen, Jussi; Leskela, Tuula (1984). "The crystal structure, thermal behaviour and IR spectrum of cadmium hydrogenselenite nitrate". Acta Chemica Scandinavica A 38: 233–239. doi:10.3891/acta.chem.scand.38a-0233. http://actachemscand.org/pdf/acta_vol_38a_p0233-0239.pdf. 
  5. ↑ Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020). "Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge". Dalton Transactions 49 (10): 3253–3259. doi:10.1039/D0DT00116C. PMID 32096527. 
  6. ↑ Wu, Chao; Li, Longhua; Lin, Lin; Huang, Zhipeng; Humphrey, Mark G.; Zhang, Chi (2020-04-14). "Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution" (in en). Chemistry of Materials 32 (7): 3043–3053. doi:10.1021/acs.chemmater.0c00034. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.0c00034. 
  7. ↑ Meng, Chang-Yu; Geng, Lei; Chen, Wen-Ting; Wei, Ming-Fang; Dai, Kai; Lu, Hong-Yan; Cheng, Wen-Dan (August 2015). "Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2". Journal of Alloys and Compounds 640: 39–44. doi:10.1016/j.jallcom.2015.04.021. 
  8. ↑ Meng, Chang-Yu; Geng, Lei; Chen, Wen-Ting; Wei, Ming-Fang; Dai, Kai; Lu, Hong-Yan; Cheng, Wen-Dan (August 2015). "Syntheses, structures, and characterizations of a new second-order nonlinear optical material: Pb2(SeO3)(NO3)2" (in en). Journal of Alloys and Compounds 640: 39–44. doi:10.1016/j.jallcom.2015.04.021. https://linkinghub.elsevier.com/retrieve/pii/S0925838815009627. 
  9. ↑ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)" (in de). Monatshefte für Chemie Chemical Monthly 118 (2): 211–216. doi:10.1007/BF00810054. ISSN 0026-9247. http://link.springer.com/10.1007/BF00810054. 
  10. ↑ 10.0 10.1 Effenberger, Herta (October 1986). "PbCu3(OH)(NO3)(SeO3)3·1/2H2O und Pb2Cu3O2(NO3)2(SeO3)2: Synthese und Kristallstrukturuntersuchung" (in de). Monatshefte für Chemie - Chemical Monthly 117 (10): 1099–1106. doi:10.1007/BF00811322. ISSN 0026-9247. http://link.springer.com/10.1007/BF00811322. 
  11. ↑ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice" (in en). Chemical Communications 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. http://xlink.rsc.org/?DOI=D0CC03684F. 
  12. ↑ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units" (in en). Inorganic Chemistry 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. 
  13. ↑ Song, Jun-Ling; Qian, Cheng (February 2017). "Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite-Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 -OH)(TeO 3 ) 3 (NO 3 ) 2" (in en). ChemistrySelect 2 (4): 1681–1685. doi:10.1002/slct.201601967. ISSN 2365-6549. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.201601967. 
  14. ↑ Meng, Chang-Yu; Wei, Ming-Fang; Geng, Lei; Hu, Pei-Qing; Yu, Meng-Xia; Cheng, Wen-Dan (July 2016). "Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2(NO3) and [Bi(TeO3)](NO3)"] (in en). Journal of Solid State Chemistry 239: 46–52. doi:10.1016/j.jssc.2016.04.013. https://linkinghub.elsevier.com/retrieve/pii/S0022459616301360. 
  15. ↑ Liu, Dong-Sheng; Huang, Gan-Sheng; Luo, Qiu-Yan; Xu, Ya-Ping; Li, Xin-Fa (2006-07-01). "Poly[tetramethylammonium [nitratouranyl-μ 3 -selenito]]". Acta Crystallographica Section e Structure Reports Online 62 (7): m1584–m1585. doi:10.1107/S1600536806022045. ISSN 1600-5368. https://scripts.iucr.org/cgi-bin/paper?S1600536806022045. 
  16. ↑ Liu, Dong-Sheng; Kuang, Han-Mao; Chen, Wen-Tong; Luo, Qiu-Yan; Sui, Yan (September 2015). "Synthesis, Structure, and Photoluminescence Properties of an Organically-Templated Uranyl Selenite" (in en). Zeitschrift für anorganische und allgemeine Chemie 641 (11): 2009–2013. doi:10.1002/zaac.201500277. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201500277. 
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 C NO−3,
NH4NO3 		O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2 		Co(NO3)2,
Co(NO3)3 		Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2 		Tl(NO3)3,
TlNO3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4 		Pr Nd(NO3)3 Pm Sm Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr



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