Chemistry:Thallium(I) nitrate
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| Names | |
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| IUPAC name
thallium(I) nitrate
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| Other names
thallous nitrate
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
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PubChem CID
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| Properties | |
| TlNO3 | |
| Molar mass | 266.39 g/mol |
| Appearance | colorless solid |
| Density | 5.55 g/cm3 |
| Melting point | 206 °C (403 °F; 479 K) |
| Boiling point | 430 °C (806 °F; 703 K) |
| 95 g/L (20 °C) | |
| Hazards | |
| GHS pictograms |    
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| GHS Signal word | Danger |
| H272, H300+330Script error: No such module "Preview warning".Category:GHS errors, H373, H411 | |
| P210, P260, P273, P301+310+330Script error: No such module "Preview warning".Category:GHS errors, P304+340+310, P403+233 | |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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15 mg/kg (mouse, oral) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Thallium(I) nitrate, also known as thallous nitrate, is a thallium compound with the formula TlNO3. It is a colorless and highly toxic salt.
Preparation
Thallium(I) nitrate can be produced by reacting thallium(I) iodide with nitric acid.[1]
However, the production is simpler starting from the metal, its hydroxide or the carbonate: [2]
- [math]\displaystyle{ \mathrm{TlOH + HNO_3 \longrightarrow \ TlNO_3 + H_2O} }[/math]
- [math]\displaystyle{ \mathrm{Tl_2CO_3 + 2 \ HNO_3 \longrightarrow \ 2 \ TlNO_3 + CO_2 + H_2O} }[/math]
Toxicity
Thallium(I) nitrate is extremely toxic, like many other thallium compounds. It is highly toxic by ingestion but can also be absorbed through skin due to its solubility in water.[3]
See also
References
- ↑ R. Pribil, V. Veselý, K. Kratochvíl (1961), "Contributions to the basic problems of complexometry--IV : Determination of thallium" (in German), Talanta 8 (1): pp. 52–54, doi:10.1016/0039-9140(61)80037-4
- ↑ Heinrich Remy: Lehrbuch der Anorganischen Chemie Band I + II, Leipzig 1973.
- ↑ National Center for Biotechnology Information (2023). PubChem Compound Summary for CID 24937, Thallium nitrate. Retrieved March 20, 2023 from https://pubchem.ncbi.nlm.nih.gov/compound/Thallium-nitrate.
Salts and covalent derivatives of the nitrate ion
| HNO3 | He | ||||||||||||||||
| LiNO3 | Be(NO3)2 | B(NO3)−4 | C | NO−3, NH4NO3 |
O | FNO3 | Ne | ||||||||||
| NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | ||||||||||
| KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3, Fe(NO3)2 |
Co(NO3)2, Co(NO3)3 |
Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | Br | Kr |
| RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb | Mo | Tc | Ru | Rh | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In | Sn | Sb(NO3)3 | Te | I | Xe(NO3)2 |
| CsNO3 | Ba(NO3)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2(NO3)2, Hg(NO3)2 |
Tl(NO3)3, TlNO3 |
Pb(NO3)2 | Bi(NO3)3 BiO(NO3) |
Po | At | Rn | |
| FrNO3 | Ra(NO3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La(NO3)3 | Ce(NO3)3, Ce(NO3)4 |
Pr | Nd(NO3)3 | Pm | Sm | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac(NO3)3 | Th(NO3)4 | Pa | UO2(NO3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
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