Chemistry:Ovalene

From HandWiki
Ovalene
Structural formula of ovalene
Ball-and-stick model of the ovalene molecule
Names
Preferred IUPAC name
Ovalene[1]
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
EC Number
  • 205-880-1
UNII
Properties
C32H14
Molar mass 398.45 g/mol
Density 1.496 g/cm3[2]
Melting point 473 °C (883 °F; 746 K)[2]
-353.8·10−6 cm3/mol[3]
Structure[2]
monoclinic, P21/a
a = 1.947(5) nm, b = 0.470(1) nm, c = 1.012(4) nm
α = 90°, β = 105.0(3)°, γ = 90°
2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is ☑Y☒N ?)
Infobox references

Ovalene is a polycyclic aromatic hydrocarbon with the formula C32H14, which consists of ten peri-fused six-membered rings. It is very similar to coronene.

Ovalene is a reddish-orange compound. It is sparingly soluble in solvents such as benzene, toluene, and dichloromethane. Its solutions have a green fluorescence under UV light.

Ovalene has been shown to form in deep-sea hydrothermal vent areas and in the hydrocracking process of petroleum refining.

References

  1. Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 205. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4. 
  2. 2.0 2.1 2.2 Donaldson, D. M.; Robertson, J. M. (1953). "The crystal and molecular structure of ovalene a quantitative X-ray investigation". Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences 220 (1141): 157–170. doi:10.1098/rspa.1953.0179. Bibcode1953RSPSA.220..157D. 
  3. Akamatu, Hideo; Inokuchi, Hiroo; Handa, Takashi (1951). "Electrical Conductivity and Magnetic Susceptibility of Ovalene". Nature 168 (4273): 520–521. doi:10.1038/168520b0. Bibcode1951Natur.168..520A. 

External links