Chemistry:Rhodium(III) hydroxide
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| Properties | |
| H3O3Rh | |
| Molar mass | 153.926 g·mol−1 |
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| GHS Signal word | Warning |
| H302, H312, H315, H319, H332, H335, H413 | |
| P261, P264, P270, P271, P273, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P321, P322, P330, P332+313, P337+313, P362, P363, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Rhodium(III) hydroxide is a chemical compound with the formula Rh(OH)3.
Various compounds of rhodium(III) with hydroxide ligands are known.[1]
Some double hydroxides called rhodium(III) hydrogarnets are known to exist. They include BaNaRh(OH)6, Ca3Rh2(OH)12, Sr3Rh2(OH)12.[2] and Ba3[Rh(OH)6]2 ⋅ H2O.[3]
Ga[Rh(OH)6(Mo6O18)](H2O)16 is a complex molybdate hydroxide.[4]
References
- ↑ Spiccia, Leone (July 2004). "Homopolynuclear and heteropolynuclear Rh(III) aqua ions – a review" (in en). Inorganica Chimica Acta 357 (10): 2799–2817. doi:10.1016/j.ica.2003.12.036. https://linkinghub.elsevier.com/retrieve/pii/S0020169303007837.
- ↑ Cook, Daniel S.; Clarkson, Guy J.; Dawson, Daniel M.; Ashbrook, Sharon E.; Fisher, Janet M.; Thompsett, David; Pickup, David M.; Chadwick, Alan V. et al. (2018-09-04). "Alkaline-Earth Rhodium Hydroxides: Synthesis, Structures, and Thermal Decomposition to Complex Oxides" (in en). Inorganic Chemistry 57 (17): 11217–11224. doi:10.1021/acs.inorgchem.8b01797. ISSN 0020-1669. PMID 30106569. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b01797.
- ↑ Albrecht, Ralf; Bretschneider, Vincent; Doert, Thomas; Ruck, Michael (2021-04-08). "Ba 3 [Rh(OH) 6 ] 2 ⋅ H 2 O – a Precursor to Barium Oxorhodates with One‐dimensional Hydrogen Bonding Systems". Zeitschrift für anorganische und allgemeine Chemie 647 (18): 1702–1708. doi:10.1002/zaac.202100016.
- ↑ Kaziev, G. Z.; Osminkina, I. V.; Kin'ones, Saul' O.; Bel'skij, V. K.; Zavodnik, V. E. (2002). "Synthesis, thermal analysis, IR spectra, and crystal structure of gallium hexamolybdorhodate(3)" (in Russian). Zhurnal Neorganicheskoj Khimii 47 (1): 18–22. ISSN 0044-457X. http://inis.iaea.org/Search/search.aspx?orig_q=RN:34012515.
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