Chemistry:Caesium perchlorate
From HandWiki
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| Names | |
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| IUPAC name
Caesium perchlorate
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| Other names
Cesium perchlorate
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| CsClO4 | |
| Molar mass | 232.36 g/mol |
| Appearance | Colorless crystals |
| Density | 3.327 g/cm3 |
| Melting point | 250 °C (482 °F; 523 K) (decomposes) |
| 1.974 g/100 ml (25 °C) | |
Solubility product (Ksp)
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3.95×10−3[3] |
Refractive index (nD)
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1.4887 |
| Structure | |
| orthorhombic (<219 °C) cubic (>219 °C, a = 798 pm) | |
| Pnma (<219 °C) F43m (>219 °C) | |
a = 982 pm, b = 600 pm, c = 779 pm (orthorhombic, <219 °C)
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| Hazards | |
| Safety data sheet | External MSDS |
| GHS pictograms |  
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| GHS Signal word | Danger |
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| Flash point | Non-flammable |
| Related compounds | |
Other anions
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Caesium chloride Caesium chlorate |
Other cations
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Lithium perchlorate Sodium perchlorate Potassium perchlorate Rubidium perchlorate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
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| Infobox references | |
Tracking categories (test):
Caesium perchlorate or cesium perchlorate (CsClO4), is a perchlorate of caesium. It forms white crystals, which are sparingly soluble in cold water and ethanol. It dissolves more easily in hot water.
CsClO4 is the second least soluble of the alkali metal perchlorates (after Fr, followed by Rb, K, Li, and Na), a property which may be used for separatory purposes and even for gravimetric analysis.[5] This low solubility played an important role in the characterization of francium as an alkali metal, as francium perchlorate coprecipitates with caesium perchlorate.[6]
| Temperature (°C) | 0 | 8.5 | 14 | 25 | 40 | 50 | 60 | 70 | 99 |
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| Solubility (g / 100 ml) | 0.8 | 0.91 | 1.91 | 1.974 | 3.694 | 5.47 | 7.30 | 9.79 | 28.57 |
When heated, CsClO4 decomposes to caesium chloride above 250 °C. Like all perchlorates, it is a strong oxidant and may react violently with reducing agents and organic materials, especially at elevated temperatures.
References
- ↑ 1.0 1.1 Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press.
- ↑ 2.0 2.1 Brezina, F.; Mollin, J.; Pastorek, R.; Sindelar, Z. (1986), Chemicke tabulky anorganickych sloucenin, SNTL.
- ↑ John Rumble (June 18, 2018) (in English). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–188. ISBN 978-1138561632.
- ↑ PubChem. "Cesium perchlorate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/123309.
- ↑ Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 1017. ISBN 978-0-08-022057-4. https://books.google.com/books?id=OezvAAAAMAAJ&q=0-08-022057-6&dq=0-08-022057-6&source=bl&ots=m4tIRxdwSk&sig=XQTTjw5EN9n5z62JB3d0vaUEn0Y&hl=en&sa=X&ei=UoAWUN7-EM6ziQfyxIDoCQ&ved=0CD8Q6AEwBA..
- ↑ Hyde, E. K. (1952), "Radiochemical Methods for the Isolation of Element 87 (Francium)", J. Am. Chem. Soc. 74 (16): 4181–84, doi:10.1021/ja01136a066
Compounds containing perchlorate group
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| HClO4 | He | ||||||||||||||||||
| LiClO4 | Be(ClO4)2 | B(ClO4)−4 B(ClO4)3 |
ROClO3 | N(ClO4)3 NH4ClO4 NOClO4 |
O | FClO4 | Ne | ||||||||||||
| NaClO4 | Mg(ClO4)2 | Al(ClO4)3 | Si | P | S | ClO−4 ClOClO3 Cl2O7 |
Ar | ||||||||||||
| KClO4 | Ca(ClO4)2 | Sc(ClO4)3 | Ti(ClO4)4 | VO(ClO4)3 VO2(ClO4) |
Cr(ClO4)3 | Mn(ClO4)2 | Fe(ClO4)3 | Co(ClO4)2, Co(ClO4)3 |
Ni(ClO4)2 | Cu(ClO4)2 | Zn(ClO4)2 | Ga(ClO4)3 | Ge | As | Se | Br | Kr | ||
| RbClO4 | Sr(ClO4)2 | Y(ClO4)3 | Zr(ClO4)4 | Nb(ClO5)4 | Mo | Tc | Ru | Rh(ClO4)3 | Pd(ClO4)2 | AgClO4 | Cd(ClO4)2 | In(ClO4)3 | Sn(ClO4)4 | Sb | TeO(ClO4)2 | I | Xe | ||
| CsClO4 | Ba(ClO4)2 | Hf(ClO4)4 | Ta(ClO5)5 | W | Re | Os | Ir | Pt | Au | Hg2(ClO4)2, Hg(ClO4)2 |
Tl(ClO4)3 | Pb(ClO4)2 | Bi(ClO4)3 | Po | At | Rn | |||
| FrClO4 | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La | Ce(ClO4)x | Pr | Nd | Pm | Sm(ClO4)3 | Eu(ClO4)3 | Gd(ClO4)3 | Tb(ClO4)3 | Dy(ClO4)3 | Ho(ClO4)3 | Er(ClO4)3 | Tm(ClO4)3 | Yb(ClO4)3 | Lu(ClO4)3 | |||||
| Ac | Th(ClO4)4 | Pa | UO2(ClO4)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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