Chemistry:Diruthenium phosphide
From HandWiki
| Identifiers | |
|---|---|
3D model (JSmol)
|
|
| |
| |
| Properties | |
| PRu2 | |
| Molar mass | 233.11 g·mol−1 |
| Appearance | crystals |
| insoluble | |
| Related compounds | |
Related compounds
|
Molybdenum monophosphide, Molybdenum diphosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Diruthenium phosphide is a binary inorganic compound of ruthenium metal and phosphorus with the chemical formula Ru
2P.[1]
Preparation
Diruthenium phosphide can be prepared by heating both elements in vacuum at above 1000 °C:[2][3]
- 8 Ru + P
4 → 4Ru
2P
Properties
Diruthenium phosphide forms crystals of rhombic crystal system; the structure of the lead dichloride type.
Uses
Diruthenium phosphide can be used as a catalyst.[4][5]
References
- ↑ Macintyre, Jane E. (5 December 1996) (in en). Dictionary of Inorganic Compounds, Supplement 4. CRC Press. p. 496. ISBN 978-0-412-75020-5. https://books.google.com/books?id=VvDoE5oN09wC&dq=Ruthenium+phosphide+Ru2P&pg=PA496. Retrieved 11 March 2024.
- ↑ Macintyre, Jane E. (15 July 1993) (in en). Dictionary of Inorganic Compounds, Supplement 1. CRC Press. p. 328. ISBN 978-0-412-49090-3. https://books.google.com/books?id=SJepeRehoTIC&dq=Ruthenium+phosphide+Ru2P&pg=PA328. Retrieved 11 March 2024.
- ↑ Teller, Hanan; Krichevski, Olga; Gur, Meital; Gedanken, Aharon; Schechter, Alex (2 July 2015). "Ruthenium Phosphide Synthesis and Electroactivity toward Oxygen Reduction in Acid Solutions" (in en). ACS Catalysis 5 (7): 4260–4267. doi:10.1021/acscatal.5b00880. ISSN 2155-5435. https://pubs.acs.org/doi/10.1021/acscatal.5b00880. Retrieved 11 March 2024.
- ↑ Acres, Gary J. K.; Swars, Kurt (29 June 2013) (in en). Pt Platinum: Supplement Volume A 1 Technology of Platinum-Group Metals. Springer Science & Business Media. p. 242. ISBN 978-3-662-10278-7. https://books.google.com/books?id=kW_mCAAAQBAJ&dq=Ruthenium+phosphide+Ru2P&pg=PA242. Retrieved 11 March 2024.
- ↑ Liu, Tingting; Wang, Jianmei; Zhong, Changyin; Lu, Shiyu; Yang, Wenrong; Liu, Jian; Hu, Weihua; Li, Chang Ming (12 June 2019). "Benchmarking Three Ruthenium Phosphide Phases for Electrocatalysis of the Hydrogen Evolution Reaction: Experimental and Theoretical Insights" (in en). Chemistry – A European Journal 25 (33): 7826–7830. doi:10.1002/chem.201901215. ISSN 0947-6539. PMID 30990231. https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201901215. Retrieved 11 March 2024.
 |  |
