Chemistry:Neodymium bismuthide

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Neodymium bismuthide
NaCl polyhedra.svg
Names
Other names
Neodymium(III) bismuthide
Identifiers
3D model (JSmol)
ChemSpider
Properties
BiNd
Molar mass 352.22 g/mol
Density 8.8 g/cm3
Melting point 1775°C;[1] 1900°C[2]
Critical point (T, P) -111 kJ/mol[3]
Structure
cubic
Fm3m
a = 6.4222 Å
4
Related compounds
Other anions
Neodymium(III) nitride
Neodymium(III) arsenide
Neodymium(III) phosphide
Neodymium(III) antimonide
Neodymium(III) oxide
Other cations
PrBi
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Neodymium bismuthide or Bismuth-Neodymium[4] is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

Preparation

Neodymium bismuthide can be prepared by reacting a stoichiometric amount of neodymium and bismuth at 1900°C:[citation needed]

Nd + Bi → NdBi

Physical properties

Neodymium bismuthide forms cubic crystals of the space group Fm3m, with cell parameters a = 0.64222 nm, Z = 4 with a structure like sodium chloride.[5] The compound melts at 1900°C.[2] At a temperature of 24 K, an antiferromagnetic transition occurs in the compound.[6]

References

  1. Abulkhaev V.D. (2001). "Phase digram of the neodymium-bismuth system". Zhurnal Neorganicheskoj Khimii 46 (4): 659-662. ISSN 0044-457X. https://inis.iaea.org/search/search.aspx?orig_q=RN:33016098. 
  2. 2.0 2.1 Alloy Phase Diagrams. 3. 1992. ISBN 0-87170-381-5. 
  3. A. Borsese; R. Capelli; S. Delfino; R. Ferro (1974). "The heat of formation of neodymium-bismuth alloys". Thermochimica Acta 8 (4): 393-397. doi:10.1016/0040-6031(74)85107-5. 
  4. Okamoto, H. (2002-03-01). "Bi-Nd (Bismuth-Neodymium)" (in en). Journal of Phase Equilibria 23 (2): 191. doi:10.1361/1054971023604224. ISSN 1054-9714. https://doi.org/10.1361/1054971023604224. 
  5. Ed. N. P. Lyakisheva (1996). State Diagrams of Binary Metal Systems. 1. Engineering. p. 992. ISBN 5-217-02688-X. 
  6. P. Schobinger-Papamantellos, P. Fischer, O. Vogt, E. Kaldis (1973). "Magnetic ordering of neodymium monopnictides determined by neutron diffraction". J. Phys. C: Solid State Phys. 6 (4): 725-737. doi:10.1088/0022-3719/6/4/020. Bibcode1973JPhC....6..725S.