Chemistry:Scandium phosphide
From HandWiki
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| Names | |
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| Other names
Scandium monophosphide,[1] phosphanylidynescandium
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| EC Number |
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PubChem CID
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| Properties | |
| PSc | |
| Molar mass | 75.93 |
| Structure[2] | |
| Rock salt structure | |
| Fm3m | |
a = 0.5312 nm
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Formula units (Z)
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4 |
| Octahedral at Sc3+, Octahedral at P3- | |
| Related compounds | |
Other anions
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Scandium arsenide Scandium antimonide |
Other cations
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Yttrium phosphide Lutetium phosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.[3][4][5]
Synthesis
ScP can be obtained by the reaction of scandium and phosphorus at 1000 °C.[2]
- [math]\ce{ 4Sc + P4 -> 4ScP }[/math]
Physical properties
This compound is calculated to be a semiconductor used in high power, high frequency applications and in laser diodes.[6][7]
Chemical properties
ScP can be smelted with cobalt or nickel through electric arc to obtain ScCoP and ScNiP.[8]
References
- ↑ Gschneidner (Jr.), Karl A.; Eyring, LeRoy (1978) (in en). Handbook on the Physics and Chemistry of Rare Earths: without special title. North-Holland Publishing Company. p. 287. ISBN 978-0-444-82507-0. https://books.google.com/books?id=ROzvAAAAMAAJ&q=Scandium+phosphide+ScP. Retrieved 10 December 2021.
- ↑ 2.0 2.1 Parthé, E. (10 January 1963). "Note on the structure of ScP and YP" (in en). Acta Crystallographica 16 (1): 71. doi:10.1107/S0365110X63000141. Bibcode: 1963AcCry..16...71P. http://scripts.iucr.org/cgi-bin/paper?S0365110X63000141. Retrieved 12 December 2021.
- ↑ "Scandium Phosphide" (in en). American Elements. https://www.americanelements.com/scandium-phosphide-12202-43-6.
- ↑ "scandium phosphide" (in en). National Institute of Standards and Technology. https://webbook.nist.gov/cgi/formula?ID=C12202436.
- ↑ (in en) Toxic Substances Control Act (TSCA) Chemical Substance Inventory. U.S. Government Printing Office. 1979. p. 79. https://books.google.com/books?id=EwXoYmUt_B0C&dq=Scandium+phosphide&pg=RA2-PA49. Retrieved 10 December 2021.
- ↑ Karil, Poornima; Karma, Nikita; Choudhary, K. K.; Kaurav, Netram (29 May 2020). "Effect of pressure on structural and elastic properties of Scandium phosphide". AIP Conference Proceedings. Emerging Interfaces of Physical Sciences and Technology 2019: Eipt2019 2224 (1): 030001. doi:10.1063/5.0000475. Bibcode: 2020AIPC.2224c0001K. https://aip.scitation.org/doi/abs/10.1063/5.0000475?journalCode=apc#:~:text=Scandium%20Phosphide%20is%20a%20semiconductor,under%20the%20influence%20of%20pressure.. Retrieved 10 December 2021.
- ↑ Perkins, Peter G.; Marwaha, Ashok K.; Stewart, James J. P. (1 November 1981). "The band structures and magnetic properties of some transition-metal monophosphides I. Scandium phosphide" (in en). Theoretica Chimica Acta 59 (6): 555–568. doi:10.1007/BF00552849. https://link.springer.com/article/10.1007/BF00552849. Retrieved 10 December 2021.
- ↑ Kleinke, Holger; Franzen, Hugo F. (1 May 1998). "Sc–Sc Bonding in the New Ternary Phosphide ScNiP" (in en). Journal of Solid State Chemistry 137 (2): 218–222. doi:10.1006/jssc.1997.7704. Bibcode: 1998JSSCh.137..218K. https://www.sciencedirect.com/science/article/abs/pii/S0022459697977045. Retrieved 12 December 2021.
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