Chemistry:Selenide borate
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Selenide borates, officially known as borate selenides, are chemical mixed anion compounds that contain any kind of borate and selenide ions. They are distinct from selenoborates in which selenium atoms replace oxygen in borates. There are also analogous borate sulfides, with sulfur ions instead of selenium.
List
| name | chem | mw | crystal system | space group | unit cell | volume | density | comments | references |
|---|---|---|---|---|---|---|---|---|---|
| Zn8Se2[BO2]12 | I43m | a=7.6749 b=7.6749 c=7.6749 | band gap 4.42 eV SHG 0.14xKDP | [1][2] | |||||
| YSeBO2 | 210.68 | orthorhombic | Cmc21 | a=5.6617 b=16.5858 c=1.441 Z=4 | 389.15 | 3.596 | band gap 3.45 eV | [3] | |
| Sm6Ta2MgSeB8O26 | 1869.75 | trigonal | P3 | a=8.089 c=8.6765 Z=1 | 491.70 | 6.314 | [4] | ||
| Eu6Ta2MgSeB8O26 | 1879.41 | trigonal | P3 | a=8.0717 c=8.6491 Z=1 | 488.01 | 6.395 | [4] | ||
| Gd6Ta2MgSeB8O26 | 1911.15 | trigonal | P3 | a=8.0536 c=8.6296 Z=1 | 484.73 | 6.547 | [4] |
References
- ↑ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (2020) (in en), CSD 1999764: Experimental Crystal Structure Determination, FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, doi:10.5517/ccdc.csd.cc253xjr, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc253xjr&sid=DataCite, retrieved 2021-03-13
- ↑ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (October 2020). "Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis" (in en). Journal of Solid State Chemistry 290: 121572. doi:10.1016/j.jssc.2020.121572. Bibcode: 2020JSSCh.29021572Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459620304023.
- ↑ Lu, Zhen-Tao; Fan, Wen-Jing; Wang, Zhi-Qian; Gu, Ning; Yue, Zeng-Hao; Xue, Huai-Guo; Guo, Sheng-Ping (2020-06-15). "Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO 2 : Featuring a [YSeBO 2 n Planar Belt"] (in en). Inorganic Chemistry 59 (12): 7905–7909. doi:10.1021/acs.inorgchem.0c00753. ISSN 0020-1669. PMID 32469211. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00753.
- ↑ 4.0 4.1 4.2 Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE 6 Ta 2 MgQB 8 O 26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B 4 O 10 Cluster" (in en). Inorganic Chemistry 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00086.
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