Chemistry:Selenidostannate

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Selenidostannates are chemical compounds which contain anionic units of selenium connected to tin. They can be considered as stannates where selenium substitutes for oxygen. Similar compounds include the selenogermanates and thiostannates. They are in the category of chalcogenidotetrelates or more broadly chalcogenometallates.

Formation

Some selenidostannates can be made by treating tin diselenide (SnSe2) with an alkali selenide dissolved in water.[1] Other possible solvents include  choline chloride with 1,8-diaminooctane,[2]

Properties

Most selenidostannates are semiconductors. Their resistance drops on exposure to light. Also selenidostannates are often coloured, most often orange, red or yellow.

Many are unstable in humid air, as the water reacts with the selenidostannate to form hydrogen selenide (H2Se).

Use

Selenidostannates are primarily of research interest. They are under investigation as photoelectric materials.

List

name chem mw crystal system space group unit cell Å volume density comment references
tris(μ2-1,2-Diaminoethane)-1,2-diaminoethane-di-lithium triselenido-tin(iv) Li4Sn2Se6 · 8en monoclinic C2/c a=22.660 b=9.449 c=20.336 β=101.24° [3]
diammonium [NH4]2Sn4Se9 orthorhombic Pnma a =13.2274 b=12.4270 c=12.6102 supertetrahedra Sn4Se10 arranged in layers [4]
bis(dimethylammonium) heptakis(μ-selenido)-tri-tin dimethylamine solvate [NH2(CH3)2]2Sn3Se7·0.5NH(CH3)2 monoclinic C2/c a=23.5939 b=13.6409 c=15.0372, β=102.177° chains of Sn3Se8 [4]
tetrakis(ethylammonium) tetradecakis(μ-selenido)-hexa-tin [NH3C2H5]2Sn3Se7 orthorhombic Cmca a=13.5561 b=24.0194 c=27.0184 [4]
bis(Ethylenediammonium) ethylenediamine bis((μ2-selenido)-diseleno-tin(iv)) [enH2]2[Sn2Se6] · en triclinic P1 a =8.636 b =11.044 c =6.613, α =104.48° β =110.76° γ =79.43° twin edge-bridged SnSe4 tetrahedra [5]
tetrakis(2-Aminoethylammonium) bis(μ2-selenido)-tetraselenido-di-tin(iv) 1,2-diaminoethane [enH]4[SnIV2Se6] · en triclinic P1 a=11.212 b=11.631 c=13.097, α=79.40° β=76.82° γ=64.82° [6]
catena(Ethylenediammonium hemiethylenediamine (μ3-selenido)-hexakis(μ2-selenido)-tri-tin(iv)) [enH2][Sn3Se7]·0.5en orthorhombic Fdd2 a=23.597 b=27.563 c=13.877 [4][5]
catena-(tetrakis(μ2-Seleno)-ethylenediamine-di-tin(iv)) [2 SnSe2·en] orthorhombic Pca21 a 1=3.724 b =11.866 c =13.647 [5]
[(C2H5)3NH]2Sn3Se7 P212121 2.12 eV [4]
[(C2H5)3NH]2Sn3Se7·0.25H2O monoclinic P21/n 2.1 eV [4]
(Et4N)2Sn3Se7 monoclinic P21/m a=10.140 b=13.858 c=12.071, β=100.649° [7]
[NEt4]4[Sn4Se10] cubic P43n a = 22.170 10897 [8]
bis(tetrapropylammonium) nonaselenidotetrastannate(IV) ([C3H7]4N)2[Sn4Se9] monoclinic P21/n a = 15.328, b = 19.058, c = 15.398, β = 97.947°, Z = 4 4454.7 orange [9]
(C7N4OH16)2Sn3Se7·H2 orthorhombic Pbca [4]
(NH3(CH2)8NH3)Sn3Se7 triclinic P1 [4]
Octane-1,8-diammonium (μ3-selena)-hexakis(μ2-selena)-tri-tin (NH3(CH2)8NH3)Sn3Se7 triclinic P1 a=8.4419 b=11.6441 c=13.1857 α=66.636° β=77.989° γ=83.919° [10]
Decane-1,10-diammonium (μ3-selena)-hexakis(μ2-selena)-tri-tin (NH3(CH2)10NH3)Sn3Se7 monoclinic C2/c a=23.726 b=13.910 c=15.954 β=111.915° [10]
(NH3(CH2)10NH3)Sn3Se7 monoclinic C2/c [4]
tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ3-selenido)-octadecakis(μ2-selenido)-nona-tin monoclinic P21/c a =18.652 b=20.353 c=20.196 β=105.244° [11]
tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) dodecakis(μ2-selenido)-diselenido-hexa-tin [Mmpmim]4Sn6Se14 monoclinic P21/c a=14.270 b=15.549 c=14.377 β=92.749° [11]
bis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) (μ3-selenido)-hexakis(μ2-selenido)-tri-tin [Mmpmim]2Sn3Se7 trigonal P3221 a=13.9470 b=13.9470 c=27.8553 [11]
octakis(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) tetrakis(μ3-selenido)-docosakis(μ2-selenido)-diselenido-dodeca-tin [Mmpmim]8Sn12Se26 monoclinic P21/c a=24.538 b=13.961 c=19.434 β=94.539° [11]
tetra(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) bis(μ3-selenido)-dodecakis(μ2-selenido)-hexa-tin [Mmbmim]4Sn6Se14 trigonal P3221 a=13.9381 c=27.774 [11]
[prmmim]2[Sn3Se7] P3221 [4]
Bmmim=1-butyl-2,3-dimethylimidazolium [bmmim]2[Sn3Se7] P3221 band gap 2.2 eV [4]
Bzmim = 1-benzyl-3-methylimidazolium

bis(1-benzyl-3-methylimidazolium) heptakis(μ-selenido)-tri-tin

[Bzmim]2[Sn3Se7] orthorhombic Pbca a=14.297 b=13.8808 c=16.8855 β=99.817° [12]
Emim = 1-ethyl-3-methylimidazolium

pentakis(1-ethyl-3-methylimidazolium) bis(heptakis(μ-selenido)-tri-tin) chloride unknown solvate

[Emim]5[Sn3Se7]2Cl hexagonal P63/mmc a=13.8331 c=18.4649 [12]
[DBNH]2[Sn3Se7]·PEG monoclinic C2/c band gap 2.13 eV [4]
[DBNH]3[NH4][Sn6Se14] trigonal R3 band gap 2.02 eV [4]
(H+-DBN)2[Sn3Se7] Cmc21 band gap 2.02 eV [4]
(CH3)3N(CH2)2OH]2[Sn3Se7] orthorhombic Pbca band gap 2.35 eV [4]
catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate] (CH3)3N(CH2)2OH]2[Sn3Se7]∙H2O monoclinic P21/n a=9.8365 b=13.5796 c=20.7384 β=92.727° Z=4 2893.0 2.606 orange; [4][13]
catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin] (CH3)3N(CH2)2CH3]2[Sn3Se7] orthorhombic Pbca a =17.534 b =13.7273 c =24.1221 Z=8 5806.2 2.547 orange [14]
bis(N,N,N-trimethylbutanaminium) poly[heptaselenidotristannate(IV)] (Bu(CH3)3N)2[Sn3Se7] monoclinic C2/c a = 23.950, b = 13.760, c = 20.011, β = 114.565°, Z = 8 5998 orange [4][15]
AEPP = N-aminoethylpiperazine [AEPPH2]2[Sn5Se12] triclinic P1 a = 10.6351, b = 10.6850, c = 10.7771, α = 61.344°, β = 62.442°, γ = 67.468 [16]
phen=1,10-Phenanthroline (CH3NH3)4(Sn2Se6)·6phen triclinic P1 a 10.594 b 12.225 c 14.945 α 83.589° β 83.133° γ 86.604° [17]
Im=imidazolium

catena-(pentakis(3-n-butyl-1-methylimidazolium) dodecakis(μ-selenido)-nona-tin tetrafluoroborate)

(C4C1C1Im)5[Sn9Se20][BF4] monoclinic P21/n a=13.878 b=20.365 c=31.026 β =91.326° Z=4 8766 2.652 orange [18]
DMMP=2,6-dimethylmorpholine (DMMPH)4[Sn2Se6] monoclinic P21/n a=6.158 b=22.381 c=14.642 β=93.57° Z=2 2014.1 1.926 yellow [18]
catena-(bis(1-ethyl-3-methylimidazolium) bis(2,6-dimethylmorpholin-4-ium) tetradecakis(μ-selenido)-hexa-tin) (C2C1Im)2(DMMPH)2[Sn6Se14] monoclinic P21/n a=20.616 b=13.857 c=19.629 β=107.40° Z=4 5351 2.821 orange [18]
catena-[tetrakis(3-n-Butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(μ3-selenido)-undecakis(μ2-selenido)-selenido-hexa-tin(iv)] [BMMIm]4[Sn6Se14] monoclinic P21/c a 24.2744 b 13.8901 c 19.1763 β 94.083° Z=4 6449.3 2.503 orange [19]
catena-(hexadecakis(1-butyl-2,3-dimethylimidazolium) octakis(μ3-selenido)-octatetracontakis(μ2-selenido)-tetracosa-tin) [BMMIm]16[Sn24Se56] trigonal P32 a=27.8622 c=28.0566 Z=3 18862.4 2.568 red [19]
catena-(tris(3-Butyl-1,2-dimethylimidazolium) 2,6-dimethylmorpholin-4-ium (μ3-selenido)-dodecakis(μ2-selenido)-selenido-hexa-tin) [BMMIm]3[DMMPH][Sn6Se14] triclinic P1 a 11.1358 b 12.6745 c 23.362, α 89.690° β 88.473° γ 72.098° Z=2 3136.6 2.534 orange or yellow (low temp) [19]
1-butyl-3-methyl-inidazolinium [BMIm]4[Sn9Se20] monoclinic Cc a=19.901 b=26.494 c=14.447 β=105.34 Z=4 7361 2.892 red [20]
catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate] [HOCH2CH2N(CH3)3]2Sn3Se7·H2O monoclinic P21/n a 9.8365 b 13.5796 c 20.7384 β 92.727° orange (high temp) or yellow [21]
catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin] [CH3CH2CH2N(CH3)3]2Sn3Se7 orthorhombic Pbca a 17.403 b 13.7025 c 23.9113 2.852 yellow [21]
tetrakis(piperidinium) bis(μ-selenido)-tetraselenido-di-tin {[Sn2Se6]·4(C5NH12)} monoclinic P21/n a 10.3277 b 10.2808 c 15.7823 β 96.725° 2.0110 red [22]
catena-[bis(3,6,7,8-tetrahydro-2H-pyrrolo[1,2-a]pyrimidin-5-ium) tetrakis(μ-selenido)-hexa-tin] {[Sn3Se7]·2(HDBN)} DBN = 1,5-diazabicyclo[4.3.0]non-5-ene orthorhombic Cmc21 a 13.4435 b 24.4817 c 14.4494 red [22]
[dabcoH]2[(CH3)2NH2]2[Sn2Se6] monoclinic C2/m a=20.172 b=11.674 c=6.476 β=103.15 Z=2 1485.2 2.303 yellow [23]
(N2H4)3(N2H5)4Sn2Se6 triclinic P1 a = 6.6475, b = 9.5474, c = 9.883, α = 94.110°, β = 99.429°, γ = 104.141°, Z = 1 [24]
bis(1-Aminoethylammonium) bis(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane-potassium) bis(μ2-seleno)-tetraseleno-di-tin(iv) (enH)2(2,2,2-crypt-K)2Sn2Se6 monoclinic P21/n a=8.442 b=25.877 c=14.821 β=104.19°
(MeSn)4Se6 triclinic P1 a = 9.147, b =10.495 c =10.508, α = 85.60, β = 89.83 γ =65.71° Z=2 916 adamantane structure [25]
Na4SnS4 tetragonal I41acd [26]
Na4SnS4 tetragonal P421c a=7.84679 c=6.95798, Z=2 428.42 yellow [26]
Na4SnSe4·14H2O [26]
Na4SnSe4·16H2O monoclinic P21/m a = 8.673, b = 16.563, c = 8.647, β = 92.10°, Z = 2 tetrahedra; Sn-Se bond length 2.504−2.527 Å [27][1]
Na4Sn2S6·5H2O [28]
Na4Sn2Se6·13H2O triclinic P1 a = 7.106, b = 10.330, c = 19.009, α = 78.60, β = 85.66, γ = 72.85° Z = 2 (at −130 °C) orange-red; tetrahedral edge-shared pairs [27][29]
Na4Ge2Se6 · 16 H2O monoclinic P21/c a = 9.894, b = 11.781, c = 12.225, β = 92.90°, Z = 2 [30]
Na4Sn3Se8 trigonal bipyramid + tetrahedron [27]
Na6Sn4Se11 · 22 H2O monoclinic C2/c a 15.325 b 11.634 c 26.739 β 95.81° yellow-orange [31]
Na6Sn2Se7·16H2O red [29]
catena-(tris(1-Amino-2-ammonioethane) octakis(μ3-selenido)-hexakis(μ2-selenido)-sodium-hexa-tin sesquikis(dimethylamine) sesquihydrate) (enH)3Na[Sn3Se7]2·1.5Me2NH·1.5H2O R32 a=13.8647 c=18.962 Na+ ion conductor [32]
bis((μ4-Selenido)-(μ3-selenido)-bis(μ2-ethylene-1,2-diamine))-tetra-sodium-tin [Na4(en)4][SnSe4] orthorhombic P41212 a=13.090 b=13.090 c=14.548 [33]
Li2MgNaSe4 orthorhombic Pmn21 a = 8.40 b = 7.18 c = 6.73 Z=2 405.9 3.867 yellow; moisture absorbing [34]
SnPSe3 monoclinic Pn a=6.8161 b=7.7264 c=9.6437 β=91.073° [35]
K4SnSe4 orthorhombic Pnma a=14.714 b=10.323 c=8.248 Z=4 yellow [36]
2D-K2Sn2Se5 orthorhombic Pbca a=13.0246 b=12.186 c=14.135 Z=8 [37]
K4Sn2Se6 tetrahedral edge-shared pairs [27]
K4Sn3Se8 orthorhombic Ccca a 8.214 b 27.795 c 8.2136 [38]
K0.5[Sn3Se7] hexagonal P6522 a=13.8325 c 43.295 Z=12 7174.1 2.579 red [18]
K6Sn4Se11 . 8H2O monoclinic C2/c a =28.004 b =9 c =15.192, β 113.8° [7]
K6[SnIII2Se6] [6]
K4Sn4Se10·4.5H2O trigonal R3 a=15.32 c=21.019 [39]
tetrakis(Tetramethylammonium) (hexakis(μ2-seleno)-di-tin(iv)-potassium) K(N(CH3)4)3Sn2Se6 triclinic P1 a 9.587 b 10.005 c 15.996 α 95.15° β 92.81° γ 106.96° [40]
(μ2-Ethylene-1,2-diamine-N,N')-bis(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium (μ2-ethylene-1,2-diamine-N,N')-(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium hexakis(μ2-selenido)-(tetraselenoxy)-tetra-tin(iv) [18-crown-6-K]4[Sn4Se10]·5en monoclinic P21/n a=22.003 b=18.966 c=24.392 β=97.548° [41]
dipotassium(+) bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)potassium(+)] hexaselenodistannate(4-) tetrakis(ethylenediamine) solvate (18-crown-6) K2[K(C12H24O6)]2[Sn2Se6].4C2H8N2 monoclinic P21/n a=15.634 b=8.479 c=23.404 β=108.60° [42]
bis((4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium) tris(tetraselenido)-tin(iv) [K-(2,2,2-crypt)]2Sn(Se4)3 triclinic P1 a=10.7088 b=12.9986 c=21.7865 α=86.299° β=81.598° γ=87.258° [43]
Ca(en)4Ca(en)3[Sn2Se6] triclinic P1 a = 10.2708, b = 12.2739, c = 16.3103, α = 93.576°, β = 90.609°, γ = 109.269°, Z = 1 1936.09 [44]
[VII(dien)2]2[Sn2Se6] monoclinic P21/n a 9.7686 b 15.094 c 12.517 β 91.007° band gap 2.11 eV [45]
catena-(tetraethylenepentaminedi-ium octakis(μ-selenido)-bis(tetraethylenepentamine)-tetraselenolato-tetra-tin(iv)-di-vanadium(iii)) [H2tepa]0.5[VIII(tepa)(μ-Sn2Se6)] orthorhombic Abm2 a=7.808 b=41.97 c=16.982 Z=8 5565 2.496 [46]
tepa = tetraethylenepentamine

bis(Hydroxy-tetraethylenepentamine-chromium) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) monohydrate

[Cr(tepa)(OH)]2Sn2Se6·H2O orthorhombic Pbcn a=16.767 b=14.552 c=14.859 2.08 eV [47]
peha = pentaethylenehexamide

bis(Pentaethylenehexamine-chromium) dichloride 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)

[Cr(peha)]2(Sn2Se6)Cl2 monoclinic P21/n a=9.636 b=14.361 c=15.357 β=106.50° 2.19 eV [47]
en = ethylenediamine, pip = piperazine

pentakis(tris(ethylenediamine)-chromium(iii)) bis(tetrakis(selenyl)-tin(iv)) heptakis(chloride) piperazine solvate

[Cr(en)3]2.5[SnSe4]·Cl3.5·(pip)0.5·1.5H2O trigonal R3c a=15.4035 c =61.487 band gap 2.23 eV;SnSe4 tetrahedron [2]
catena-[(μ3-Selenido)-(μ2-selenido)-bis(1,2-diaminoethane)-selenido-manganese-tin] SnSe3Mn(en)2 monoclinic P21/n a =9.4565 b =11.2896 c =12.7937 β =103.765° Z=4 2.657 red [48]
catena-[(μ3-Selenido)-bis(μ2-selenido)-(1,2-diaminoethane)-manganese-tin] SnSe3Mn(en) orthorhombic Pbca a=13.9290 b=7.5261 c=19.2572 Z=8 2018.7 3.097 red [48]
catena-[bis(μ3-Selenido)-bis(μ2-selenido)-bis(1,2-diaminoethane)-di-manganese-tin] MnSnSe4Mn(en)2 orthorhombic Pnma a=13.1101 b=14.8267 c=7.9466 Z=4 1544.66 2.858 yellow [48]
pentaehtylenehexaamine [Mn(peha)][Sn3Se7] monoclinic P21/n [4]
[Mn(dien)2]Sn3Se7·0.5H2O monoclinic P21/n band gap 1.89 eV [4]
[Mn(en)2.5(en-Me)0.5][Sn3Se7] monoclinic P21/c [4]
catena-[tris(ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin] [Mn(en)3][Sn3Se7] monoclinic P21/n a=12.2277 b=13.1904 c=15.9272 β=100.174° red [4][49]
catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin monohydrate] [Mn(dien)2][Sn3Se7]∙H2O monoclinic P21/n a=12.3987 b=13.3150 c=16.6672 β=96.378° red; band gap 2.04 eV [4][49]
[Mn(dien)2]Sn3Se7·0.5H2O monoclinic P21/n a 12.322 b 13.300 c 16.706 β 96.331° [50]
bis(bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) bis(μ-selenido)-tetrakis(selenido)-di-tin [Mn(dien)2]2Sn2Se6 monoclinic P21/n a 12.677 b 9.585 c 15.595 β 102.49(3)° [50]
[Mn(dien)2]MnSnSe4 orthorhombic C2221 a=9.002 b=17.761 c=12.967 band gap 2.25 eV [51]
catena-[tris(ethane-1,2-diamine)-manganese(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] [Mn(en)3]Sn3Se6(Se2) monoclinic P21/n a 11.974 b 14.046 c 15.893, β 99.78° [52]
catena-((bis(diethylenetriamine)-manganese(ii)) bis(μ-selenido)-manganese) [Mn(en)3][Sn(Se4)3] triclinic P1 a 10.222 b 12.175 c 12.394, α 89.37° β 74.97° γ 75.66° [52]
en = ethylenediamine, hda = N-(2-hydroxyethyl)ethylenediamine)

bis(bis(ethylenediamine)-(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii)) bis(μ-selenido)-tetrakis(selenido)-di-tin

[Mn(en)2(hda)]2[Sn2Se6] monoclinic P21/n a 9.1189 b 12.3968 c 17.515 β 97.010° [53]
catena-[bis(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin] [Mn(hda)2][SnMnSe4] monoclinic C2/c a 9.4497 b 17.6025 c 13.1121 β 103.617° [53]
dien = diethylenetriamine

catena-[bis(diethylenetriamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin]

[Mn(dien)2][SnMnSe4] orthorhombic C2221 a 9.0169 b 17.740 c 12.9543 [53]
heptakis(μ2-selenido)-(tetraethylenepentamine)-manganese(ii)-tri-tin(iv) Mn(tepa)·Sn3Se7 orthorhombic P212121 a=12.533 b=13.709 c=13.989 [54]
tetrakis(μ2-selenido)-bis(seleno)-bis(tetraethylenepentamine)-di-manganese(ii)-di-tin(iv) [Mn(tepa)]2(μ2-Sn2Se6) tetragonal I41/a a=26.483 b=26.483 c=10.1423 [54]
hexakis(μ2-selenido)-tetrakis(1,10-phenanthroline)-di-manganese-di-tin dihydrate {[Mn(phen)2]2(μ2-Sn2Se6)}·H2O monoclinic P21/n a 11.061 b 10.061 c 25.21 β 90.081° [17]
catena-((μ3-selenido)-bis(μ2-selenido)-(1,10-phenanthroline)-manganese-tin) [Mn(phen)]2(μ4-Sn2Se6) triclinic P1 a 9.721 b 10.257 c 10.346, α 118.24° β 112.53° γ 95.75° [17]
hexakis(μ-2-aminoethan-1-olato)-octakis(μ-selenido)-hepta-manganese-di-tin Mn7(ea)6(SnSe4)2 orthorhombic Pccn a=14.886 b=19.354 c=12.4314 Z=4 3581.5 2.993 orange [55]
catena-(pentakis(μ2-selenido)-bis(1,10-phenanthroline)-manganese-di-tin) [Mn(phen)2](Sn2Se5) monoclinic C2/c a 16.639 b 12.961 c 14.088β 117.91° [17]
catena-[tris(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(tris(ethane-1,2-diamine)-manganese) icosakis(μ-selenido)-selenido-nona-tin chloride] (Bmmim)3[Mn(en)3]2[Sn9Se21]Cl monoclinic P21/c a=19.4488 b=19.5108 c=26.6148 β=109.587° red [49]
catena-[hexakis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) bis((N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) tetratriacontakis(selenido)-selenido-pentadeca-tin] (Bmmim)6[Mn(dien)2]2Sn15Se35 monoclinic P21/n a=13.4256 b=29.904 c=19.5845 β=106.643° red [49]
catena-[hemikis(tris(ethane-1,2-diamine)-manganese) hemikis((N-methylethane-1,2-diamine)-bis(ethane-1,2-diamine)-mangnaese) heptakis(μ-selenido)-tri-tin] [Mn(en)2.5(en-Me)0.5][Sn3Se7] monoclinic P21/c a=12.1058 b=13.2204 c=18.2504 β=120.839° Z=4 2507.9 3.049 orange [56]
catena-(bis(4-Aminobutan-1-aminium) tetrakis(μ2-selenido)-manganese-tin) (1,4-dabH)2MnSnSe4 orthorhombic Fdd2 a =23.287 b=25.410 c=6.6053 [57]
tetrakis(2,2'-bipyridine)-hexakis(μ-selenido)-di-tin-di-manganese {Mn(2,2′-bipy)2}2(μ2-Sn2Se6) monoclinic P 21/n a=8.756 b=20.960 c=12.484 β=95.66° [58]
hexakis(μ2-Selenido)-bis(1,4,8,11-tetraazacyclotetradecane)-di-manganese(ii)-di-tin {Mn(cyclam)}2(μ-Sn2Se6.15) monoclinic P21/n a=9.949 b=16.783 c=11.649 β=105.208° [59]
hexakis(μ2-Selenido)-bis(2,2';6',2''-terpyridine)-di-manganese(ii)-di-tin {Mn(terpy)}2(μ-Sn2Se6) triclinic P1 a=9.430 b=10.872 c=11.090 α=117.86° β=102.83° γ=103.22° [59]
tris(μ2-Selenido)-(2,2';6',2''-terpyridine)-manganese(ii)-tin {Mn(terpy)}2(μ-Sn2Se6) triclinic P1 a=9.923 b=10.027 c=10.959 α=107.29° β=97.57° γ=115.10° [59]
(NMe4)2[MnSn4Se10] tetragonal I4 a=9.865 c =15.317 red [60]
Li4MnSn2Se7 monoclinic Cc a=18.126 b=7.221 c=10.470 β=93.43° Z=4 1403.2 4.132 orange [61]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene [DBNH]2[MnSnSe4] tetragonal P42/ncm a=13.0305 c =6.6220 [62]
[Fe(tatda)]Sn3Se7 monoclinic P21/n 1.93 eV [4]
catena-((bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-iron) [Fe(dien)2]FeSnSe4 orthorhombic C2221 a =8.974 b =17.755 c =12.967 band gap 2.21 eV [51]
bis(bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-tetraselenido-di-tin [Fe(dien)2]2Sn2Se6 monoclinic P21/n a=12.563 b=9.655 c=15.566 β=102.76° band gap 2.60 eV [51]
bis(bis(diethylenetriamine)-iron(ii)) ethane-1,2-diammonium bis(2-ammonioethyl)amine bis(bis(μ-selenido)-tetraselenido-di-tin) [H2en][H2dien][Fe(dien)2]2(Sn2Se6)2 triclinic P1 a=8.727 b=12.794 c=14.918, α=66.09° β=84.06° γ=75.33° band gap 2.58 eV [51]
catena-[tris(ethane-1,2-diamine)-iron(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] [Fe(en)3]Sn3Se6(Se2) monoclinic P21/c a =11.950 b =14.083 c =17.995 β =120.25° [52]
tris(ethane-1,2-diamine)-iron(ii) tris[tetraselanato]-tin [Fe(en)3][Sn(Se4)3] triclinic P1 a 10.223 b 12.106 c 12.263, α 89.40° β 89.40° γ 75.45° [52]
tatda = 3,6,9,12-tetraazatetradecane-1,14-diamine

catena-[(3,6,9,12-tetraazatetradecane-1,14-diamine)-iron heptakis(μ-selenido)-tri-tin]

[Fe(tatda)]Sn3Se7 monoclinic P21/n a 12.1067 b 13.3225 c 17.0827 β 96.978° [50]
hexakis(μ2-selenido)-tetrakis(1,10-phenanthroline)-di-iron-di-tin [Fe(phen)2]2(μ2-Sn2Se6) monoclinic C2/c a 26.192 b 11.248 c 17.843 β 98.816° [17]
catena-(bis(tris(1,10-phenanthroline)-iron) bis(μ3-selenido)-dodecakis(μ2-selenido)-hexa-tin hydrate) [Fe(phen)3](Sn3Se7)·1.25H2O trigonal R3c a=13.9483 c 75.476 band gap 1.97 eV [17]
bipy = bipyridine

catena-[nonakis(μ-selenido)-tetra-tin tris(2,2'-bipyridine)-iron dihydrate]

[Fe(bipy)3]Sn4Se9·2H2O trigonal R3c a=26.902 c 30.673 [63]
[Fe(bipy)3]2[Sn3Se7]2·bipy·2H2O monoclinic P21/c a 27.055 b 13.391 c 24.756, β 103.88° [63]
heptakis(μ-selenido)-(tetra-ethylenepentamine)-iron-tri-tin Sn3Se7Fe(tepa) orthorhombic P212121 a 12.4958 b 13.7745 c 14.0233 3.112 black [22]
bis[tris(ethane-1,2-diamine)-iron] 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [Fe(en)3]2Sn2Se6 orthorhombic Pbca a =15.5062(9)Å b=11.8662 c=19.0966 2.146 red [22]
{CpFe(CO)2}3{CpFe(CO)}Sn3Se4 triclinic P1 a 12.2066 b 12.584 c 13.0007, α 90.632° β 90.068° γ 120.836° [64]
(NMe4)2[FeSn4Se10] tetragonal I4 a=9.878 c=15.345 [60]
[Co(en)3]2Sn2Se6 orthorhombic Pbca a=15.640 b=11.564 c=18.742 [46]
[Co(dien)2]2Sn2Se6 monoclinic P21/n a=10.2224 b=14.5788 c=12.3921 β=91.237° 1846.4 yellow; black with water, ultrasound turns yellow [65][46][66]
[Co(en)(trien)]2Sn2Se6 monoclinic P21/n a 7.929 b 15.855 c 14.262 β 93.436° [67]
bis(tris(2,2'-bipyridine)-cobalt(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate [Co(2,2′-bipy)3]2[Sn3Se7]2·(2,2′-bipy)·H2O monoclinic P21/c a=27.032 b=13.392 c=24.763 β=103.85° [58]
catena-[tris(ethylenediamine)-nickel hemikis(heptakis(μ-selenato)-selenato-tri-tin) hemikis(hexakis(μ-selenato)-selenato-tri-tin)] [Ni(en)3][Sn3Se6.5(Se2)0.5] orthorhombic Pca21 a =14.88 b =1.8872Å c =13.859 1.95 eV;chains of [Sn3Se7]n2n– and [Sn3Se6(Se)2]n2n– [2]
tris(ethylenediamine)-nickel(ii) tetrakis(μ-selanyl)-selanyl-di-tin [Ni(en)3][Sn2Se5] monoclinic P21/n a=8.7998 b=10.0736 c=22.655 β=90.763° [68]
[Ni(en)3]2[Sn2Se6] orthorhombic a=15.288 b=11.937 c=19.239 3511.0 [46]
catena-[tris(ethylenediamine)-nickel heptakis(μ-selenato)-tri-tin] [Ni(en)3][Sn3Se7] monoclinic P21/n a=12.32 b=13.19 c=15.73 β=101.07° band gap 2.01 eV [2]
catena-[tris(1,2-diaminoethane)-nickel(ii) pentakis(μ-selenido)-bis(selenido)-tri-tin(iv)] [Ni(en)3]Sn3Se7.5 orthorhombic Pca21 a 14.869 b 11.888 c 13.860 [52]
tris(ethane-1,2-diamine)-nickel tris[tetraselanato]-tin [Ni(en)3][Sn(Se4)3] triclinic P1 a 10.104 b 12.048 c 12.107, α 89.52° β 75.44° γ 75.78° [52]
phen = 1,10-phenanthroline

tris(1,10-phenanthroline)-nickel(ii) heptakis(μ-selenato)-tri-tin(iv) sesquihydrate

[Ni(phen)3]Sn3Se7·1.5H2O trigonal R3 a=13.971 c=38.281 [69]
[(Ni0.4Zn0.6)(en)6]Sn2Se6 [65]
catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) hemikis((μ2-triethylenetetramine)-bis(triethylenetetramine)-di-nickel) tris(μ3-selenido)-heptadecakis(μ2-selenido)-selenido-nona-tin) 2D-(Bmmim)8[Ni2(teta)2(μ-teta)]Sn18Se42 monoclinic P21/n a =18.9764 b= 25.1081 c =20.5731 β =100.870° [70]
teta = triethylenetetramine

(ethylenediamine)-(triethylenetetramine)-nickel(ii) (triethylenetetramine)-(N-(2-hydroxyethyl)ethylenediamine)-nickel(ii) hexakis(μ-selenido)-tetrakis(selenido)-tetra-tin

[Ni(teta)(en)][Ni(teta)(hda)][Sn4Se10] monoclinic P21/n a 12.3191 b 17.7104 c 22.643 β 95.278° [70]
tepa=tetraethylenepentamine

catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) bis(chloro-(tetraethylenepentamine)-nickel) pentakis(μ3-selenido)-tricosakis(μ2-selenido)-(tetraethylenepentamine)-nickel-dodeca-tin)

2D-(Bmmim)4[Ni(tepa)Cl]2[Ni(tepa)Sn12Se28] monoclinic Pn a=21.2230 b=13.4993 c=23.8715 β =112.461° [70]
Bmmim=1-butyl-2,3-dimethylimidazolium 2D-(Bmmim)3[Ni(en)3]2[Sn9Se21]Cl monoclinic P21/c a 19.488 b 19.626 c 26.793 β 109.930° [53]
catena-(bis(1-n-Butyl-2,3-dimethylimidazolium) bis(tris(propane-1,2-diamine)-nickel) bis(bis(μ3-selenido)-heptakis(μ2-selenido)-tetra-tin)) 3D-(Bmmim)2[Ni(1,2-pda)3]Sn8Se18 trigonal R3c a=27.7913 c 47.4281 [70]
catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-nickel sesquikis(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) hemikis(2-amino-N-(2-aminoethyl)ethylammonium) octadecakis(μ-selenido)-octa-tin] 2D-(Bmmim)2[Ni(teta)(en)][Sn3Se7]2 monoclinic P21/c a=31.088 b=10.5393 c=19.9712 β=99.966° [71]
catena-[(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-(ethane-1,2-diamine)-nickel bis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) tridecakis(μ-selenido)-selenido-hexa-tin] 3D-(Bmmim)1.5(dienH)0.5Ni(dien)2[Sn4Se9]2 monoclinic P21/c a=24.3753 b=13.3778 c=17.7885 β=93.949° [71]
[Ni(tren)(en)]SnSe3∙H2O 638.64 monoclinic P21/n a=12.8150 b=10.0094

c=15.6626 β=???? Z=4

1885.8 band gap [72]
bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin dihydrate [Ni(tren)(en)]2[Sn2S6]·2H2O monoclinic P21/n a 12.7041 b 9.8000 c 15.3989 β 108.843° 3.23 eV [73]
bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin hexahydrate [Ni(tren)(en)]2[Sn2S6]·6H2O monoclinic P21/c a 12.5580 b 9.7089 c 16.0359 β 91.827° 3.16 eV [73]
bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin trihydrate [Ni(tren)(1,2-dach)]2[Sn2S6]·3H2O triclinic P1 a 9.8121 b 10.0080 c 12.422, α 86.38° β 79.65° γ 65.71° 3.43 eV [73]
bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate [Ni(tren)(1,2-dach)]2[Sn2S6]·4H2O monoclinic P21/c a 10.7119 b 19.0797 c 11.1005 β 104.803° 3.29 eV [73]
bis((tris(2-aminoethyl)amine)-(propane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate [Ni(tren)(1,2-dap)]2[Sn2S6]·4H2O monoclinic C2/c a 14.3925 b 15.1550 c 18.9307 β 99.108° 3.32 eV [73]
bis((tris(2-aminoethyl)amine)-(2-(aminomethyl)pyridine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin decahydrate [Ni(tren)(2amp)]2[Sn2S6]·10H2O monoclinic P21/n a 12.1933 b 13.4025 c 14.8920 β 103.090° 3.28 eV [73]
L1 = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane [Ni(L1)][Ni(L1)Sn2S6]n·2H2O monoclinic P21/c a 11.6481 b 14.4268 c 10.8450 β 95.449° brown [74]
L2 = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane [Ni(L2)]2[Sn2S6]·4H2O triclinic P1 a 9.1562 b 10.3705 c 12.2897 α 66.761° β 85.350° γ 81.308° [74]
(μ2-triethylenetetramine)-bis(triethylenetetramine)-di-nickel(ii) tetrachloride dihydrate [Ni2(trien)2(μ-trien)]Cl4·2H2O orthorhombic Pbca a 13.737 b 13.089 c 18.193 [67]
bis(tris(2,2'-bipyridine)-nickel(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate [Ni(2,2′-bipy)3]2[Sn3Se7]2·(2,2′-bipy)·H2O monoclinic P 21/c a=26.999 b=13.383 c=24.714 β=103.89° [58]
Cu2SnSe4 F3m thermoelectric [75]
(1,4-dabH2)Cu2SnSe4 orthorhombic P42/n a=14.956 b=14.956 c=12.017 [57]
Na6Cu8Sn3Se13 cubic Fm3c a =18.4754 [76]
[Cu2SnSe5][Mn(Hen)2(en)] monoclinic P21/c a 9.640 b 21.04 c 10.611 β 100.72° 1.49 eV [77]
[(Mn1.67Zn0.33)(en)6]Sn2Se6 [65]
K2Cu2Sn2Se6 monoclinic C2/c Z=8 black; band gap 1.04 eV [78]
Copper zinc tin selenide Cu2ZnSnSe4 black; photovoltaic 11.6% efficient [29]
catena-[tris(ethane-1,2-diamine)-zinc(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] [Zn(en)3]Sn3Se6(Se2) monoclinic P21/n a 11.949 b 14.060 c 15.794 β 100.39° [52]
tris(ethane-1,2-diamine)-zinc(ii) tris[tetraselanato]-tin [Zn(en)3][Sn(Se4)3] triclinic P1 a 10.156 b 12.096 c 12.109, α 89.64° β 75.49° γ 75.87° [52]
Zn2(en)2(μ4-SnSe4) tetragonal I41/a a =7.8032 c =31.528 [53]
tetrakis(μ-selenido)-bis(selenido)-bis(N,N-bis(2-aminoethyl)ethane-1,2-diamine)-di-tin(iv)-di-zinc(ii) {Zn(tren)}2(μ-Sn2Se6) monoclinic C2/c a 12.414 b 9.846 c 23.970° β 102.395° 2861.5 band gap 2.38 eV [79]
tetrakis(μ-selenido)-bis(selenido)-bis(bis(2-(2-aminoethyl)aminoethyl)amine)-di-tin(iv)-di-zinc(ii) {Zn(tepa)}2(μ-Sn2Se6) tetragonal I41/a a=26.6205 c =10.0533 7124.3 band gap 2.31 eV [79]
catena-[bis(dimethylammonium) octakis(μ-selenido)-tri-tin(iv)-zinc(ii)] [(Me)2NH2]2ZnSn3Se8 monoclinic C2 a=10.961 b=11.056 c=9.683 β=105.17° [80]
(Me4N)2Zn[Sn4Se10] [81]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene [DBNH]2[ZnSnSe4] tetragonal P42/ncm a=13.033 c 6.548 band gap 2.42 eV [62]
K2ZnSn3Se8 monoclinic P21 a 7.639 b 12.400 c 18.384 β 98.13° band gap 2.10 eV [82]
Cu2ZnSnSe4 [75]
[NH4]2Ga4Se8Sn4 monoclinic P21/c a 7.582 b 12.501 c 18.377 β 96.43° [83]
catena-(1-ethylpyridinium hexakis(μ-selenido)-gallium-di-tin hydrate) H3CCH2NC5H5GaSn2Se6 ∙ 0.25H2O tetragonal I41/a a=26.401 c =10.464 orange [84]
x~0.25 Na2−xGa2−xSn1+xSe6 monoclinic C2 a=13.308 b=7.594 c=13.842 β=118.730° 1226.7 [85]
K3Ga6Sn6Se12 cubic Pa3 a=13.5555 Z=12 2490.8 4.347 colourless [86]
KGaSnSe4 cubic Pa3 a=13.5555 Z=12 2490.8 4.347 orange [86]
[(TEPA)Mn]2+4[Sn4Ga4Zn2Se20]8− tetragonal P4b2 a=17.4951 c 13.5849 [87]
(Et4N)2[Sn6Se10Br6] monoclinic P21/n a = 14.0826 b = 14.1904 c = 24.277 β = 92.809° Z = 4 4845.6 [88]
Rb2Sn2Se5 monoclinic C2/c a=11.555 b=8.478 c=12.030 β=108.60 Z=4 1117 4.78 black; oxygen sensitive [89]
Rb4Sn4Se10·1.5H2O R3 a 15.539 c 21.373 [39]
Rb2Cu2Sn2Se6 monoclinic C2/c Z=8 black; band gap 1.04 eV [78]
RbGaSnSe4 cubic Pa3 a=13.7200 2582.63 4.550 orange [86]
Rb2Sn4Se9-H2O orthorhombic Pnma a=13.298 b=12.418 c=12.563 [90]
Rb2MnSn3Se8 monoclinic P21 a 7.7864 b 12.6343 c 18.4878 β 95.810° [91]
Rb2MnSnSe4 monoclinic P21/n a=8.6015 b=10.956 c=10.675 β=90° [92]
Rb4Cu8Sn3S12 cubic Fm3c a=18.0851 [93]
(H3O)RbCu6Sn2S8 tetragonal I4/m a=14.8834 c=7.6466 [93]
SrZnSnSe4 orthorhombic Fdd2 a 21.6984 b 21.873 c 13.1140 [94]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-yttrium] [Y2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.4190 b=13.6062 c=20.6569 Z=8 2.467 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-yttrium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Y2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.24 c=10.940 2.025 yellow [95]
Ru(bpy)3[Sn4Se9] 1755.02 trigonal R3c a=27.240 c=31.01 Z=18 19927 2.632 dark red [96]
β-Ag8SnSe6 Pmn21 [4]
[NH4]3AgSn3Se8 tetragonal P4/nbm a=8.2155 c=13.413 thermochromic: gold-darkred-gold [4][80]
[NH4]4Ag12Sn7Se22 monoclinic C2/c a=52.634 b=6.8175 c=13.5176 β=99.955 Z=4 4959.1 5.270 black; band gap 1.21 eV [4][97]
[(Me)2NH2]0.75[Ag1.25SnSe3] tetragonal P421m a=13.998 c=8.685 Z=8 1701.9 4.403 dark red; band gap 1.85 eV [4][98]
[CH3NH3]2[H3O]Ag5Sn4Se12·C2H5OH tetragonal P421m a=13.6350 c 9.1491 Z=8 band gap 1.80 eV [4][80]
catena-[bis(methylammonium) dimethylammonium dodecakis(μ-selenido)-penta-silver-tetra-tin] [NH3CH3]0.5[NH2(CH3)2]0.25Ag1.25SnSe3 tetragonal P421m b =13.7193 c 9.0964 4.019 [99]
[bmmim]7[AgSn12Se28] triclinic P1 band gap 2.2 eV [4]
heptakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ3-selenido)-hexacosakis(μ2-selenido)-dodeca-tin-silver [Mmpmim]7Ag5Sn4Se12∙3H2O triclinic P1 a 10.8983 b 13.5554 c 23.091 α 88.904° β 86.700° γ 68.230° [11]
catena-[N1-(2-azaniumylethyl)ethane-1,2-bis(aminium) dodeca-selenium-tetra-tin-penta-silver trihydrate] [H3dien][Ag5Sn4Se12]∙3H2O P421 a =14.2623 b =14.2623 c =9.3022 [100]
K2Ag2SnSe4 P2/c band gap 1.8 eV [4]
K2Ag2Sn2Se6 P4/mmc [4]
K3AgSn3Se8 P4/nbm band gap 1.8 eV [4]
[Mn(NH3)6][Ag4Mn4Sn3Se13] orthorhombic F43c a 19.1263Å b 19.1263Å c 19.1263 [101]
catena-(2-aminoethylammonium bis(μ4-sulfido)-bis(μ3-sulfido)-tin-di-copper-silver) [enH][Cu2AgSnS4] orthorhombic Pnma a=19.726 b=7.8544 c=6.5083 Z=4 1008.35 3.577 red [102]
[Zn(NH3)6][Ag4Zn4Sn3Se13] orthorhombic F43c a=18.9679 b=18.9679 c=18.9679 [101]
(1,4-dabH2)Cu1.72Ag0.28SnSe4 tetragonal P42/n a=14.990 c=12.059 band gap 2.43 eV [103]
Rb3AgSn3Se8 P4/nbm band gap 1.8 eV [4]
Li6.4Cd4.8Sn4Se16 orthorhombic Pna21 a=14.400 b=8.399 c=6.787 band gap 1.95 eV [104]
tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ3-diselenido)-undecakis(μ2-selenido)-tri-cadmium-tetra-tin [DBNH]4[Cd3Sn4Se11(Se2)2] monoclinic C2/c a=22.236 b=12.623 c=21.756 β=109.91° [105]
Cd(tren)SnSe3 triclinic P1 a=7.752 b=8.128 c=12.467, α=97.299° β=103.639° γ=107.325° Z=2 712.1 2.865 [106]
K2CdSnSe4 625.16 tetragonal I42m a=8.084 c=6.920 452.24 photocatalyst [107]
Cu2CdSnSe4 [75]
catena-(1-ethylpyridinium hexakis(μ-selenido)-indium-di-tin hydrate) CH3CH2NC5H5InSn2Se6 ∙ 0.25H2O tetragonal I41/a a=26.946 c =10.283 orange [84]
[NH4]2[In2Sn2Se8] tetragonal I4/mcm a=b 8.3731 c 6.719
catena-[tris(1,10-phenanthroline)-cobalt octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate] Co(phen)3In2Sn2Se8 ∙ C6H11NH2 ∙ 4H2O monoclinic P21/n a=15.610 b=24.238 c=15.828 β=107.04° Z=4 5726 2.169 orange [108]
tris(1,10-phenanthroline)-nickel octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate Ni(phen)3In2Sn2Se8 ∙ C6H11NH2 monoclinic P21/n a=15.574 b=24.083 c=15.804 β=107.11° Z=4 5665 2.192 orange [108]
RbInSnSe4 cubic Pa3 a=13.9728 Z=12 2728.04 4.637 red; air sensitive [109]
RbInSnSe4 monoclinic P21/c a= 7.8104 b= 12.6533 c= 18.7062

β= 96.297

1837.52 4.589 orange [109]
Cs2Sn2Se5 . H2O orthorhombic Ama2 a =12.05 b =12.405 c =9.426 [7]
Cs2Sn2Se5 
Cs2Sn2Se6 triclinic P1 a =7.129 b =7.285 c =7.965, α =95.8° β =115.38° γ =108.46° [90]
Cs2Sn3Se7 monoclinic C2/c a = 23.214, b = 13.679, c =14,657, β= 111.92°, Z = 8, 4317 red; SnSe5 trigonal bipyramids connected in sheets [4][27]
Cs4Sn2Se6 yellow; tetrahedral edge-shared pairs [27]
Cs4Sn4Se10·3.2H2O triclinic P1 a=7.235 b=9.468 c=11.235 α=68.77° β=83.25° γ=84.53° [39]
Cs2Sn4Se9-H2O orthorhombic Pnma a =13.514 b =12.54 c =12.679 [90]
(4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium tris(μ3-selenido)-tris(μ2-selenido)-bis(1,2-ethylenediamine-N)-(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-di-cesium-potassium-di-tin(iv) [K-(2,2,2-crypt)]2Cs2Sn2Se6·2en triclinic P1 a=10.0019 b=13.8929 c=24.478 α=100.204° β=95.701° γ=90.147° [43]
Cs[Cr(en)2SnSe4] 739.67 monoclinic P21/n a=7.6800 b=13.1483 c=15.7069 β=91.176° Z=4 1585.7 3.098 black [110]
Cs2MnSnSe4 orthorhombic Fddd a=6.4075 b=14.416 c=24.820 [92]
Cs2MgSn3Se8 orthorhombic P212121 a 7.9055 b 12.7661 c 18.474 [111]
Cs2MnSn3Se8 orthorhombic P212121 a 7.8798 b 12.7040 c 18.4556 [91]
Mn4Cs10Se17Sn4 ∙ 15.5H2O triclinic P1 a 13.717 b 15.502 c 18.481 α 77.02° β 74.35° γ 69.71° Z=2 3512 3.418 red [56]
Zn4Cs10Se17Sn4 ∙ 17H2O triclinic P1 a 13.537 b 15.256 c 18.41, α 76.98° β 73.78° γ 69.57° Z=2 3386 3.577 yellow [56]
Cs2ZnSn3Se8 orthorhombic P212121 a 7.8146 b 12.6534 c 18.3747 [111]
CsGaSnSe4 orthorhombic Pmcn a 7.6785Å b 12.655Å c 18.278 [85]
Cd4Cs10Se17Sn4 ∙ 17H2O triclinic P1 a 17.8678 b 17.7949 c 23.5518 α 98.682° β 105.75° γ 90.307° Z=4 7116 3.617 yellow [56]
Cs2CdSn3Se8 orthorhombic P212121 a 7.9335 b 12.7336 c 18.5387 [111]
CsInSnSe4 cubic Pa3 a=14.1932 Z=12 2959.2 4.755 red; air sensitive [109]
Ba2SnSe4 709.21 monoclinic P21/c a 8.582 b 9.255 c 12.460 β 114.28° Z=4 902.2 5.221 orange [112]
α-Ba2SnSe5 orthorhombic P212121 dark brown [113]
β-Ba2SnSe5 monoclinic P21/c a = 9.3949 b = 8.8656 c = 12.5745 β = 113.299° Z = 4 961.9 high temperature; red [113]
m-Ba2SnSe5 monoclinic P121/c1 a = 21.17189 b = 9.0915 c = 24.7141 β = 125.621° [114]
Ba6Sn6Se13 orthorhombic P212121 a 9.2998 b 12.384 c 26.896 Z=4 3097.8 5.495 black; 1.52 eV [115]
Li2Ba7Sn4Se16 cubic I43d a=15.1628 Z=4 3486.1 5.170 ? red [116]
Na2Ba7Sn4Se16 cubic I43d a=14.807 Z=4 3246 4.082 red [116]
BaZnSnSe4 orthorhombic Fdd2 a 22.2402 b 22.7047 c 13.1972 6664.0 5.081 red; band gap 1.95 eV [117]
BaGa2SnSe6 trigonal R3 a = 10.145 c = 9.249 Z = 3 824.4 5.253 red

NLO 5.2 × AgGaS2 at 2.09 μm birefringence 0.1649 at 1.064 μm

[118]
Ba4Ga4SnSe12 band gap 2.14 [119]
BaAg2SnSe4 orthorhombic I222 a=7.10 b=7.47 c=8.30 band gap 0.2 eV [4][120]
BaCdSnSe4 684.27 orthorhombic Fdd2 a 22.38 b 22.71 c 13.588 Z=32 6907 5.265 orange [112]
catena-(hexakis(μ2-selenido)-(N-(2-(amino)ethyl)-N'-(2-((2-(amino)ethyl)amino)ethyl)ethane-1,2-diaminato)-di-tin-lanthanum hemihydrate) (H3O)[La(tepa)(μ-1κ2:2κ2-Sn2Se6)] monoclinic C2/c a=13.845 b=9.805 c=22.010 β=105.949° [121]
tetrakis(μ-selenido)-bis(3,6,9,12-tetraazatetradecane-1,14-diamine)-nitrato-chloro-di-lanthanum(iii)-tin {La(peha)(Cl)}{La(peha)(NO3)}(μ-1κ2:2κ2-SnSe4)] triclinic P1 a 8.411 b 14.760 c 16.244 α 92.57° β 91.95° γ 102.18° Z=2 1967.3 2.15 light yellow [122]
2,2'-(ethane-1,2-diyldiimino)diethanaminium tetrakis(μ-selenido)-tetrakis(triethylenetetramine )-diselenido-di-tin-di-lanthanum(iii) bis(μ-selenido)-tetraselenido-di-tin monohydrate [H2trien][{La(trien)2}2(μ-1κ:2κ-Sn2Se6)][Sn2Se6]·H2O monoclinic P21/c a=14.903 b=16.763 c=16.552 β=101.231° Z=2 4056 2.01 orange [122]
[{La(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ triclinic P1 a 10.253 b 13.061 c 15.847 α 80.62° β 73.59° γ 88.60° Z=1 2007.9 2.514 red [123]
[La2(en)8(μ-Se2)]Sn2Se monoclinic P21/n a 10.079 b 14.843 c 14.918 β 90.599° Z=2 2231.7 2.422 yellow [123]
La3AgSnSe7 P63 [4]
catena-(hexakis(μ2-Selenido)-(tetraethylenepentamine)-cerium-di-tin monohydrate) (H3O)[Ce(tepa)(μ-1κ2:2κ2-Sn2Se6)] monoclinic C2/c a=13.852 b=9.802 c=22.035 β=105.98° [124]
tetrakis(μ2-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-cerium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ2-selenido)-tetraselenido-di-tin [Htrien]2[{Ce(trien)(tren)}2(μ-1κ:2κ-Sn2Se6)] triclinic P1 a 9.832 b 10.584 c 18.091, α 90.097° β 92.448° γ 94.500° [124]
[{Ce(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ triclinic P1 a 10.2333 b 13.0790 c 15.7663, α 80.422° β 73.738° γ 88.376° Z=1 1997.1 2.532 orange [125]
[{Ce(en)4}2(μ-Se2)]Sn2Se6 monoclinic P21/n a 10.094 b 16.616 c 13.397 β 101.878° Z=2 2198.9 2.462 light yellow [125]
BaCeSn2Se6 orthorhombic Pmc21 a=4.1908 b=20.749 c=12.406 [126]
tetrakis(μ2-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-neodymium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ2-selenido)-tetraselenido-di-tin [Htrien]2[{Pr(trien)(tren)}2(μ-1κ:2κ-Sn2Se6)] triclinic P1 a 9.842 b 10.578 c 18.080, α 90.065° β 92.532° γ 94.511° [124]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-praseodymium] [Pr2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.450 b=13.617 c=21.005 Z=8 2.622 orange [95]
[{Pr(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a 10.197 b 11.7622 c 15.497 β 98.967° Z=2 1835.9 2.510 yellow [125]
catena-(bis(μ2-hydroxo)-tetrakis(μ2-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-neodymium-di-tin) [{Nd(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)] orthorhombic Pbca a=12.485 b=13.601 c=20.917 [121]
[{Nd(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a 10.176 b 11.772 c 15.470 β 99.128° Z=2 1829.8 2.531 yellow [125]
[{Nd(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ triclinic P1 a 10.184 b 12.979 c 15.751, α 80.448° β 73.991° γ 88.552° Z=1 1973.1 2.576 red [125]
ethane-1,2-diaminium tris(N-(2-(amino)ethyl)ethane-1,2-diamine)-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [Hen][Sm(dien)3]Sn2Se6 triclinic P1 a=10.044 b=12.803 c=15.811 α=66.32° β=72.86° γ=68.35° [127]
bis(bis(N,N-bis(2-(amino)ethyl)ethane-1,2-diamine)-chloro-samarium) hemikis(N,N-bis(2-aminoethyl)ethane-1,2-diamine) bis(μ-selenido)-tetrakis(selenido)-di-tin [Sm(trien)(tren)(Cl)]2Sn2Se6·0.5en triclinic P1 a=10.348 b=10.575 c=14.043 α=77.26° β=87.78° γ=61.410° [127]
bis(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-bis(ethane-1,2-diamine)-bis(μ-hydroxy)di-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [{Sm(en)(trien)}2(μ-OH)2]Sn2Se6 triclinic P1 a=10.044 b=12.803 c=15.811, α=66.32° β=72.86° γ=68.35° [127]
catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-samarium-tin hemihydrate] [{Sm(tepa)(μ-OH)}2 (μ-1κ:2κ-Sn2Se6)]n·nH2O monoclinic C2/c a=22.944 b=11.946 c=18.907 β=125.53° Z=4 4217 2.27 yellow [122]
[Hdien][Sm(dien)2(μ-SnSe4)] monoclinic P2/c a 10.185 b 9.471 c 13.808 β 102.256° [128]
Eu8(Sn4Se14)(Se3)2 orthorhombic P21212 a = 11.990 b = 16.425 c = 8.543 [129]
catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-europium-tin hemihydrate] [{Eu(tepa)(μ-OH)}2 (μ-1κ:2κ-Sn2Se6)]n·nH2O monoclinic C2/c a=22.904 b=11.981 c=18.894 β=125.52° Z=4 4220 2.28 yellow [122]
[Hdien][Eu(dien)2(μ-SnSe4)] monoclinic P2/c a 10.185 b 9.453 c 13.791 β 102.165° [128]
[Eu2(dien)4(μ-OH)2]Sn2Se6 monoclinic P21/n a 12.027 b 11.802 c 13.827 β 99.179° [128]
[{Eu(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a = 10.136 b = 11.771 c = 15.423 β = 99.322° Z = 2 1815.8 [130]
catena-(bis(μ2-hydroxo)-tetrakis(μ2-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-gadolinium-di-tin monohydrate) [{Gd(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]·H2O monoclinic C2/c a=22.82 b=11.975 c=18.918 β=125.975° [121]
[{Gd(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a 9.993 b 11.842 c 15.313° β 99.979° Z=2 1784.6 2.643 yellow [125]
[Hdien][Gd(dien)2(μ-SnSe4)] monoclinic P21/c a 10.300 b 9.426 c 13.875 β 101.678° Z=2 1319.3 2.271 red [125]
[Gd(dap)4]2[Sn2Se6]Cl2 monoclinic P21/c a=10.2385 b=14.1276 c=18.068 β =102.745° [131]
[{Tb(en)3}2(μ-OH)2]Sn2Se6 1423.62 monoclinic P21/n a=10.120 b=11.781 c=15.403 β=99.534° Z=2 1811.1 2.611 [132]
bis(tetrakis(propane-1,2-diamine)-terbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate [Tb(dap)4]2[Sn2Se6]Cl2·H2O monoclinic P21/c a=10.240 b=14.116 c=18.030 β=102.808° [131]
catena-[bis(μ2-selenido)-(μ2-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-dysprosium-tin] [Dy2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.4132 b=13.5901 c=20.6722 Z=8 2.759 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-dysprosium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Dy2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.2390 c=11.0380 2.229 yellow [95]
[Dy2(en)6(μ2-OH)2][Sn2Se6] [133]
bis(tetrakis(propane-1,2-diamine)-dysprosium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate [Dy(dap)4]2[Sn2Se6]Cl2·H2O monoclinic P21/c a=10.214 b=14.118 c=18.000 β=102.798° [131]
bis(tetrakis(Propane-1,2-diamine)-holmium chloride) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [Ho(dap)4]2[Sn2Se6]Cl2 monoclinic P21/c a=10.1839 b=14.1303 c=18.0100 β=102.571° Z=4 2529.5 yellow [134]
bis(μ2-Hydroxo)-tetrakis(diethylenetriamine)-di-holmium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) {[Ho(dien)2]2(μ2-OH)2}[Sn2Se6] monoclinic P21/n a=12.0096 b=11.7181 c=13.7717 β=99.138° Z=2 1913.5 2.586 yellow [134]
bis(bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-bis(μ-hydroxo)-di-holmium) tricyclo[3.3.1.13,7]tetrastannaselenane-1,3,5,7-tetrakis(selenolate) tetrahydrate [Ho2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.076 c 10.948 8629.6 2.281 yellow; supertetrahedron [134]
catena-[bis(μ2-selenido)-(μ2-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-erbium-tin] [Er2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.418 b=13.605 c=20.636 Z=8 2.778 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-erbium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Er2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.1622 c=11.0089 2.261 yellow [95]
[Er2(en)6(μ2-OH)2][Sn2S6] monoclinic P21/n a 9.951 b 11.860 c 15.278 β 100.239° [133]
bis(tetrakis(propane-1,2-diamine)-erbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate [Er(dap)4]2[Sn2Se6]Cl2·H2O monoclinic P21/c a=10.204 b=14.176 c=18.041 β=102.530° [131]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-thulium [Tm2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.399 b=13.518 c=20.504 Z=8 2.820 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-thulium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Tm2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.2080 c=11.0142 2.258 yellow [95]
[Hen]4[Tm(en)4]2[Ag6Sn6S20]·3en monoclinic C2/m a 14.517 b 24.380 c 13.422 β 94.46° [135]
catena-((μ2-Hydroxo)-bis(μ2-selenido)-selenide-(tetraethylenepentamine)-tin-ytterbium hemihydrate) [{Yb(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]·H2O monoclinic C2/c a=21.255 b=12.835 c=17.633 β=125.41° [124]
bis(μ2-Hydroxo)-tetrakis(diethylenetriamine)-di-ytterbium bis(μ2-selenido)-tetraselenido-di-tin [{Yb(dien)2}2(μ-OH)2]Sn2Se6 monoclinic P21/n a=12.026 b=11.666 c=13.819 β=98.971° Z=4 [124]
DBU=1,8-diazabicyclo[5.4.0]undec-7-ene

catena-(bis(2,3,4,6,7,8,9,10-Octahydropyrimido(1,2-a)azepin-1-ium) bis(μ3-selenido)-pentakis(μ2-selenido)-di-mercury)

[DBUH]2[Hg2Sn2Se6(Se2)] triclinic P1 a 10.390 b 12.244 c 13.977 α 86.58° β 79.51° γ 70.14° Z=2 1644.3 3.025 yellow [136]
catena-(bis(2,3,4,6,7,8,9,10-Octahydro-1H-pyrimido(1,2-a)azepin-5-ium) (μ3-diselenido)-(μ3-selenido)-pentakis(μ2-selenido)-di-mercury-di-tin) [DBUH]2[Hg2Sn2Se5(Se2)] monoclinic P21/c a=14.7289 b=18.6045 c=13.5200 β=111.571 3445.33 3.040 red [136]
(tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ3-diselenido)-undecakis(μ2-selenido)-tri-mercury-tetra-tin [DBNH]4[Hg3Sn4Se11(Se2)2] monoclinic C2/c a 22.137 b 12.663 c 21.780° β 109.48° [105]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene [DBNH]2[HgSnSe4] tetragonal P42/ncm a=12.8605 c 6.85560 band gap 2.46 eV [62]
Li4HgSn2Se7 monoclinic Cc a 18.286b 7.197 c 10.809 β 93.44° red [137]
Li2HgSnSe4 orthorhombic Pna21 a=14.458 b=8.378 c=6.8215 Z=4 826.3 5.217 red; SHG 6.0 × AgGaS2 [138]
Na2HgSn2Se6 tetragonal I4/mcm a=7.8571 c=20.214 [139]
Na2Hg3Sn2Se8 1516.81 tetragonal P4c2 a=9.3749 c=9.790 Z=2 860.5 5.854 red [138]
K2HgSnSe4 tetragonal I4/mcm a=8.0531Å c=6.9501 [76]
phen = 1,10-phenanthroline; eta = ethanolamine [Fe(phen)3]Hg2Sn2Se7·1.5eta·0.25H2O triclinic P1 a 13.0238 b 13.6275 c 14.4626 α 81.104° β 88.117° γ 82.840° [140]
teta = triethylenetetramine [Ni2(teta)2(μ-teta)]HgSn3Se9 orthorhombic Pmc21 a 22.731 b 13.2151 c 14.6495 [140]
SrHgSnSe4 orthorhombic Fdd2 a 21.9027 b 21.9059 c 13.5010 SHG 5 × AgGaS2 [141]
Cs2HgSn3Se8 orthorhombic P212121 a 7.9196 b 12.6657 c 18.5375 [111]
BaHgSnSe4 orthorhombic Fdd2 a 22.441 b 22.760 c 13.579 SHG 5 × AgGaS2 [141]
Tl4Sn2Se6 tetrahedral edge-shared pairs [27]
TlGaSnSe4 monoclinic P21/c a=7.501 b= 12.175 c= 18.203

β= 97.164 Z=8

1649.4 5.646 red [86]
TlGaSnSe4 cubic Pa3 a=13.4755 Z=12 2447.0 5.770 red [86]

References

  1. ↑ 1.0 1.1 Krebs, Bernt; Hürter, Hans-Ulrich (March 1980). "Selenostannate aus wäßriger Lösung: Darstellung und Struktur von Na4SnSe4 · 16 H2O" (in de). Zeitschrift für anorganische und allgemeine Chemie 462 (1): 143–151. doi:10.1002/zaac.19804620115. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19804620115. 
  2. ↑ 2.0 2.1 2.2 2.3 Cai, Ting; Zhu, Jian-Nan; Cheng, Fang-Fang; Li, Peng; Li, Wei; Zhao, Ming-Yu; Xiong, Wei-Wei (January 2019). "Growing crystalline selenidostannates in deep eutectic solvent" (in en). Inorganica Chimica Acta 484: 214–218. doi:10.1016/j.ica.2018.09.046. https://linkinghub.elsevier.com/retrieve/pii/S0020169318313318. 
  3. ↑ Dehnen, Stefanie; Zimmermann, Christian; Anson, Christopher E. (January 2002). "Syntheses, Crystal Structures, and Energetics of a Complete Series of Lithium Salts of Binary or Ternary Hexachalcogenodistannates(IV), Li4Sn2E6 · 8en (E = S, Se, Te), Li4Sn2S1.36Se4.64 · 8en, Li4Sn2Se2Te4 · 8en, Li4Sn2Se2Te4 · 9en, and Li4Sn2S2Te4 · 10en" (in de). Zeitschrift für anorganische und allgemeine Chemie 628 (1): 279–288. doi:10.1002/1521-3749(200201)628:1<279::AID-ZAAC279>3.0.CO;2-L. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/1521-3749(200201)628:13.0.CO;2-L. 
  4. ↑ 4.00 4.01 4.02 4.03 4.04 4.05 4.06 4.07 4.08 4.09 4.10 4.11 4.12 4.13 4.14 4.15 4.16 4.17 4.18 4.19 4.20 4.21 4.22 4.23 4.24 4.25 4.26 4.27 4.28 4.29 4.30 4.31 4.32 4.33 4.34 4.35 Wang, Kai-Yao; Liu, Hua-Wei; Zhang, Shu; Ding, Dong; Cheng, Lin; Wang, Cheng (2019-03-04). "Selenidostannates and a Silver Selenidostannate Synthesized in Deep Eutectic Solvents: Crystal Structures and Thermochromic Study" (in en). Inorganic Chemistry 58 (5): 2942–2953. doi:10.1021/acs.inorgchem.8b02610. ISSN 0020-1669. PMID 30789725. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b02610. 
  5. ↑ 5.0 5.1 5.2 Sheldrick, W. S.; Braunbeck, H. G. (July 1993). "Darstellung und Kristallstruktur von Ethylendiammonium-Selenostannaten(IV) sowie von [2 SnSe2 · en?"] (in de). Zeitschrift für anorganische und allgemeine Chemie 619 (7): 1300–1306. doi:10.1002/zaac.19936190725. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19936190725. 
  6. ↑ 6.0 6.1 Dehnen, Stefanie; Zimmermann, Christian (2002). "Syntheses, Crystal Structures, and Reactivity of [enH]4[Sn2Se6]·en, [enH]4[Sn2Te6]·en and [enH]4[Sn2S6]: Known Anions within Novel Coordination Spheres obtained by Novel Synthesis Routes". Zeitschrift für Anorganische und Allgemeine Chemie 628 (11): 2463–2469. doi:10.1002/1521-3749(200211)628:11<2463::AID-ZAAC2463>3.0.CO;2-Y. 
  7. ↑ 7.0 7.1 7.2 Loose, Anja; Sheldrick, William S. (1999). "Synthesis and Structure of [Sn4Se11]6-,1∞ [Sn2Se52-], and1∞ [Sn3Se72-] - Model Anions for the Solventothermal Reaction Pathway to Lamellar Selenidostannates(IV)". Zeitschrift für Anorganische und Allgemeine Chemie 625 (2): 233–240. doi:10.1002/(SICI)1521-3749(199902)625:2<233::AID-ZAAC233>3.0.CO;2-M. 
  8. ↑ Park, Chang-Woo; Pell, Michael A.; Ibers, James A. (1996-01-01). "Electrochemical Synthesis of [NEt42[enH]2[Ge2Se6 ] and [NEt4]4[Sn4Se10]"] (in en). Inorganic Chemistry 35 (16): 4555–4558. doi:10.1021/ic9514859. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/ic9514859. 
  9. ↑ Kim, Kang–Woo (2022-06-27). "Crystal structure of bis(tetrapropylammonium) nonaselenidotetrastannate(IV), (Pr4N)2[Sn4Se9]" (in en). Zeitschrift für Kristallographie - New Crystal Structures 237 (3): 409–411. doi:10.1515/ncrs-2022-0091. ISSN 1433-7266. 
  10. ↑ 10.0 10.1 Lu, Sheming; Ke, Yanxiong; Li, Jianmin; Zhou, Shuxi; Wu, Xintao; Du, Wenxin (December 2003). "Solvothermal Synthesis and Structure of Two 2D Tin–Selenides with Long Alkyldiamine NH2(CH2)nNH2 (n = 8, 10)" (in en). Structural Chemistry 14 (6): 637–642. doi:10.1023/B:STUC.0000007574.13596.f6. ISSN 1040-0400. http://link.springer.com/10.1023/B:STUC.0000007574.13596.f6. 
  11. ↑ 11.0 11.1 11.2 11.3 11.4 11.5 Li, Jian-Rong; Xiong, Wei-Wei; Xie, Zai-Lai; Du, Cheng-Feng; Zou, Guo-Dong; Huang, Xiao-Ying (2013). "From selenidostannates to silver-selenidostannate: structural variation of chalcogenidometallates synthesized in ionic liquids" (in en). Chem. Commun. 49 (2): 181–183. doi:10.1039/C2CC37051D. ISSN 1359-7345. PMID 23169004. http://xlink.rsc.org/?DOI=C2CC37051D. 
  12. ↑ 12.0 12.1 Wang, Zi; Du, Cheng-Feng; Cheng, Chu-Chu; Shen, Nan-Nan; Li, Jian-Rong; Huang, Xiao-Ying (December 2016). "Two new selenidostannates with a [Sn3Se7n2n− layer from the imidazolium-based ionic liquids: The role of (Bzmim)+ and aggregated cation of [(Emim)3Cl]2+"] (in en). Inorganic Chemistry Communications 74: 58–61. doi:10.1016/j.inoche.2016.10.040. https://linkinghub.elsevier.com/retrieve/pii/S1387700316302970. 
  13. ↑ Wang, Kai-Yao; Ding, Dong; Zhang, Shu; Wang, Yanlong; Liu, Wei; Wang, Shuao; Wang, Shuai-Hua; Liu, Dan et al. (2018) (in en), CCDC 1821847: Experimental Crystal Structure Determination, Cambridge Crystallographic Data Centre, doi:10.5517/ccdc.csd.cc1z4s85, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1z4s85&sid=DataCite, retrieved 2022-07-05 
  14. ↑ Wang, Kai-Yao; Ding, Dong; Zhang, Shu; Wang, Yanlong; Liu, Wei; Wang, Shuao; Wang, Shuai-Hua; Liu, Dan et al. (2018) (in en), CCDC 1821848: Experimental Crystal Structure Determination, Cambridge Crystallographic Data Centre, doi:10.5517/ccdc.csd.cc1z4s96, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1z4s96&sid=DataCite, retrieved 2022-07-05 
  15. ↑ Kim, Kang-Woo; Heo, Man-Young (2018-03-28). "Crystal structure of bis( N,N,N -trimethylbutanaminium) poly[heptaselenidotristannate(IV)], C14H36N2Se7Sn3" (in en). Zeitschrift für Kristallographie - New Crystal Structures 233 (2): 255–257. doi:10.1515/ncrs-2017-0255. ISSN 2197-4578. 
  16. ↑ Han, Xiaohui; Meng, Junling; Xu, Jin; Liu, Xiaojuan; Liu, Dan; Wang, Cheng (January 2016). "Synthesis, crystal structure, and optical property of a one-dimensional selenidostannate: [AEPPH22[Sn5Se12] (AEPP = N -aminoethylpiperazine)"] (in en). Inorganic Chemistry Communications 63: 42–47. doi:10.1016/j.inoche.2015.11.009. https://linkinghub.elsevier.com/retrieve/pii/S1387700315301374. 
  17. ↑ 17.0 17.1 17.2 17.3 17.4 17.5 Liu, Guang-Ning; Guo, Guo-Cong; Zhang, Ming-Jian; Guo, Jin-Shuang; Zeng, Hui-Yi; Huang, Jin-Shun (2011-10-03). "Different Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline) m 2+ ( m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components"] (in en). Inorganic Chemistry 50 (19): 9660–9669. doi:10.1021/ic201413h. ISSN 0020-1669. PMID 21902192. https://pubs.acs.org/doi/10.1021/ic201413h. 
  18. ↑ 18.0 18.1 18.2 18.3 Santner, Silke; Sprenger, Jan A. P.; Finze, Maik; Dehnen, Stefanie (2018-03-07). "The Role of [BF 4 − and [B(CN) 4 ] − Anions in the Ionothermal Synthesis of Chalcogenidometalates"] (in en). Chemistry: A European Journal 24 (14): 3474–3480. doi:10.1002/chem.201705297. PMID 29266707. https://onlinelibrary.wiley.com/doi/10.1002/chem.201705297. 
  19. ↑ 19.0 19.1 19.2 Lin, Yumei; Xie, Dewang; Massa, Werner; Mayrhofer, Leonhard; Lippert, Sina; Ewers, Benjamin; Chernikov, Alexey; Koch, Martin et al. (2013-07-01). "Changes in the Structural Dimensionality of Selenidostannates in Ionic Liquids: Formation, Structures, Stability, and Photoconductivity" (in en). Chemistry: A European Journal 19 (27): 8806–8813. doi:10.1002/chem.201300807. PMID 23677670. https://onlinelibrary.wiley.com/doi/10.1002/chem.201300807. 
  20. ↑ Lin, Yumei; Dehnen, Stefanie (2011-09-05). "[BMIm4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure"] (in en). Inorganic Chemistry 50 (17): 7913–7915. doi:10.1021/ic200697k. ISSN 0020-1669. PMID 21809815. https://pubs.acs.org/doi/10.1021/ic200697k. 
  21. ↑ 21.0 21.1 Wang, Kai-Yao; Ding, Dong; Zhang, Shu; Wang, Yanlong; Liu, Wei; Wang, Shuao; Wang, Shuai-Hua; Liu, Dan et al. (2018). "Preparation of thermochromic selenidostannates in deep eutectic solvents" (in en). Chemical Communications 54 (38): 4806–4809. doi:10.1039/C8CC01614C. ISSN 1359-7345. PMID 29687106. http://xlink.rsc.org/?DOI=C8CC01614C. 
  22. ↑ 22.0 22.1 22.2 22.3 Hu, Dandan; Zhang, Yingying; Yang, Huajun; Lin, Jian; Wu, Tao (2017). "Structural transformation of selenidostannates from 1D to 0D and 2D via a stepwise amine-templated assembly strategy" (in en). Dalton Transactions 46 (23): 7534–7539. doi:10.1039/C7DT01546A. ISSN 1477-9226. PMID 28573282. http://xlink.rsc.org/?DOI=C7DT01546A. 
  23. ↑ Kim, Kang-Woo (2005-12-20). "DMF Solvothermal Synthesis and Structural Characterization of [dabcoH]2[(CH3)2NH2]2[Sn2Se6]". Journal of the Korean Chemical Society 49 (6): 603–608. doi:10.5012/JKCS.2005.49.6.603. 
  24. ↑ Mitzi, David B. (2005-05-01). "Synthesis, Structure, and Thermal Properties of Soluble Hydrazinium Germanium(IV) and Tin(IV) Selenide Salts" (in en). Inorganic Chemistry 44 (10): 3755–3761. doi:10.1021/ic048276l. ISSN 0020-1669. PMID 15877460. https://pubs.acs.org/doi/10.1021/ic048276l. 
  25. ↑ Blecher, Axel; Dräger, Martin; Mathiasch, Bernd (1981-11-01). "(MeSn)4Se6, Geometrie und Schwingungsformen eines Adamantan-Gerüstes aus Zinn-Selen-Bindungen / (MeSn)4Se6 , Geometry and Vibrational Modes of an Adamantane Framework Formed by Tin-Selenium Bonds" (in en). Zeitschrift für Naturforschung B 36 (11): 1361–1367. doi:10.1515/znb-1981-1103. ISSN 1865-7117. 
  26. ↑ 26.0 26.1 26.2 Hartmann, Felix; Benkada, Assma; Indris, Sylvio; Poschmann, Michael; Lühmann, Henning; Duchstein, Patrick; Zahn, Dirk; Bensch, Wolfgang (2022-07-04). "Directed Dehydration as Synthetic Tool for Generation of a New Na 4 SnS 4 Polymorph: Crystal Structure, Na + Conductivity, and Influence of Sb-Substitution" (in en). Angewandte Chemie International Edition 61 (36). doi:10.1002/anie.202202182. ISSN 1433-7851. PMID 35648135. 
  27. ↑ 27.0 27.1 27.2 27.3 27.4 27.5 27.6 Sheldrick, W. S.; Braunbeck, H.-G. (1990-12-01). "Darstellung und Kristallstruktur von Cs2Sn3Se7, ein Cäsium-selenostannat(IV) mit fünffach koordiniertem Zinn / Preparation and Crystal Structure of Cs2Sn3Se7, a Cesium Selenostannate(IV) with Pentacoordinated Tin" (in en). Zeitschrift für Naturforschung B 45 (12): 1643–1646. doi:10.1515/znb-1990-1208. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-1990-1208/html. 
  28. ↑ Lühmann, Henning; Jeß, Inke; Näther, Christian; Bensch, Wolfgang (2020-02-28). "Crystal Structures and Selected Properties of Co II Containing Thiostannates prepared by a New Room Temperature Route" (in en). Zeitschrift für anorganische und allgemeine Chemie 646 (4): 234–240. doi:10.1002/zaac.201900227. ISSN 0044-2313. 
  29. ↑ 29.0 29.1 29.2 Ritchie, Cameron; Chesman, Anthony Sidney Richard; Jasieniak, Jacek; Mulvaney, Paul (2019-03-26). "Aqueous Synthesis of Cu2ZnSnSe4 Nanocrystals" (in en). Chemistry of Materials 31 (6): 2138–2150. doi:10.1021/acs.chemmater.9b00100. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.9b00100. 
  30. ↑ Krebs, Bernt; Müller, Herbert (January 1983). "Selenogermanate aus wäßriger Lösung: Darstellung und Struktur von Na4Ge2Se6 . 16 H2O" (in de). Zeitschrift für anorganische und allgemeine Chemie 496 (1): 47–57. doi:10.1002/zaac.19834960106. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19834960106. 
  31. ↑ Loose, A.; Sheldrick, W. S. (2001). "Synthesis and Structure of the Bicyclic [Sn4Se11]6– Anion in Na6Sn4Se11 · 22 H2O". Zeitschrift für Anorganische und Allgemeine Chemie 627 (9): 2051. doi:10.1002/1521-3749(200109)627:9<2051::AID-ZAAC2051>3.0.CO;2-6. 
  32. ↑ Du, Cheng-Feng; Li, Jian-Rong; Shen, Nan-Nan; Huang, Xiao-Ying (June 2016). "Ionothermal synthesis and electrochemical properties of a selenidostannate containing the mixed cations of Na+ and enH+" (in en). Journal of Solid State Chemistry 238: 203–209. doi:10.1016/j.jssc.2016.03.036. Bibcode: 2016JSSCh.238..203D. https://linkinghub.elsevier.com/retrieve/pii/S0022459616301086. 
  33. ↑ Ruzin, Eugen; Zimmermann, Christian; Hillebrecht, Pierre; Dehnen, Stefanie (May 2007). "Syntheses and Structures of Solvated Tetrasodiumtetrachalcogenostannates [Na 4 ( en ) 4 [SnE 4 ] ( en = 1,2-diaminoethane; E = Te, Se), and their Reactions Toward Further Ternary or Quaternary Chalcogenometallates [Mn(en)3]2[Sn2Te6]·4H2O or [Na10(H2O)34][Mn4(μ4-Se)(SnSe4)4]"] (in en). Zeitschrift für anorganische und allgemeine Chemie 633 (5–6): 820–829. doi:10.1002/zaac.200700071. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200700071. 
  34. ↑ Gao, Hongbo; Zhang, Kewang; Abudurusuli, Ailijiang; Bai, Chen; Yang, Zhihua; Lai, Kangrong; Li, Junjie; Pan, Shilie (2021-10-18). "Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)" (in en). Materials 14 (20): 6166. doi:10.3390/ma14206166. ISSN 1996-1944. PMID 34683761. Bibcode: 2021Mate...14.6166G. 
  35. ↑ Shi, Zhi-Hui; Yang, Mei; Yao, Wen-Dong; Liu, Wenlong; Guo, Sheng-Ping (2021-09-20). "SnPQ 3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ 8 Units" (in en). Inorganic Chemistry 60 (18): 14390–14398. doi:10.1021/acs.inorgchem.1c02178. ISSN 0020-1669. PMID 34464110. https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c02178. 
  36. ↑ Klepp, Kurt O. (1992-03-01). "Na4SnSe4 und K4SnSe4 , zwei neue Selenostannate mit isolierten Anionen / Na4SnSe4 and K4SnSe4, Two New Selenostannates with Discrete Anions" (in en). Zeitschrift für Naturforschung B 47 (3): 411–417. doi:10.1515/znb-1992-0319. ISSN 1865-7117. 
  37. ↑ Peters, Bertram; Santner, Silke; Dehnen, Stefanie (2020-09-30). "Dimensional Reduction of a Selenido Stannate Salt in Ionic Liquids to form 2D-K2Sn2Se5, a Direct Heavy Analogue of an Oxo Silicate" (in en). Zeitschrift für anorganische und allgemeine Chemie 646 (18): 1466–1469. doi:10.1002/zaac.202000162. ISSN 0044-2313. 
  38. ↑ Yao, Hua–Gang; Zhang, Ren–Chun; Ji, Shou–Hua; Ji, Min; An, Yong–Lin; Ning, Gui–Ling (November 2010). "Mineralizer effect on the synthesis of two types of one-dimensional chains silver-selenogermanate and selenostannate" (in en). Inorganic Chemistry Communications 13 (11): 1296–1298. doi:10.1016/j.inoche.2010.07.020. https://linkinghub.elsevier.com/retrieve/pii/S1387700310003175. 
  39. ↑ 39.0 39.1 39.2 Loose, Anja; Sheldrick, William S (October 1999). "Solventothermal Synthesis and Structure of Lamellar Alkali Metal Selenidostannates(IV) A4Sn4Se10·xH2O with 20- (A=Cs; x=3.2) and 36-Membered Pores (A=K, Rb; x=4.5, 1.5)" (in en). Journal of Solid State Chemistry 147 (1): 146–153. doi:10.1006/jssc.1999.8205. https://linkinghub.elsevier.com/retrieve/pii/S0022459699982051. 
  40. ↑ Campbell, Janette; Devereux, Lesley A.; Gerken, Michael; Mercier, Hélène P. A.; Pirani, Ayaaz M.; Schrobilgen, Gary J. (1996-01-01). "Ditin(IV) Chalcogenide Anions: 77 Se, 119 Sn, and 125 Te Solution NMR Study of the Sn 2 Ch 6 4- and Sn 2 Ch 7 4- (Ch = Se, Te) Anions, X-ray Crystal Structures and Raman Spectra of K + (N(CH 3 ) 4 + ) 3 Sn2Se64- , (enH+)2(2,2,2-crypt-K+)2Sn2Se64-, and (K+)2(2,2,2-crypt-K+)2Sn2Te64-, and X-ray Crystal Structures of K+(2,2,2-crypt-K+)2HOSnTe33- and K+(2,2,2-crypt-K+)2HOSnTe33-·en" (in en). Inorganic Chemistry 35 (10): 2945–2962. doi:10.1021/ic950917c. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/ic950917c. 
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  44. ↑ Menezes, Prashanth W.; Fässler, Thomas F. (June 2012). "Synthesis and Crystal Structure of Ca(en)4Ca(en)3[Sn2Se6 and Ca(en)4Se4 in Superheated and Supercritical Ethylenediamine"] (in de). Zeitschrift für anorganische und allgemeine Chemie 638 (7–8): 1109–1113. doi:10.1002/zaac.201200120. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201200120. 
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  53. ↑ 53.0 53.1 53.2 53.3 53.4 Luo, Hai-Ying; Zhou, Jian (2018). "A series of new hybrid selenidostannates with metal complexes prepared in alkylol amines" (in en). Dalton Transactions 47 (41): 14751–14759. doi:10.1039/C8DT03322F. ISSN 1477-9226. PMID 30289148. http://xlink.rsc.org/?DOI=C8DT03322F. 
  54. ↑ 54.0 54.1 Zhou, Jian; Bian, Guo-Qing; Dai, Jie; Zhang, Yong; Tang, Ai-bin; Zhu, Qin-Yu (2007-03-01). "Synthesis of a Selenidostannate(IV), [Mn(tepa)·Sn3Se7n , Demonstrating the Transformation from Achiral to Chiral and Dimeric to Polymeric Structure"] (in en). Inorganic Chemistry 46 (5): 1541–1543. doi:10.1021/ic062403r. ISSN 0020-1669. PMID 17269765. https://pubs.acs.org/doi/10.1021/ic062403r. 
  55. ↑ Zhou, Jian; Xiao, Hong; Zou, Hua-Hong; Liu, Xing (2017). "A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior" (in en). Dalton Transactions 46 (46): 16009–16013. doi:10.1039/C7DT03331A. ISSN 1477-9226. PMID 29120468. http://xlink.rsc.org/?DOI=C7DT03331A. 
  56. ↑ 56.0 56.1 56.2 56.3 Santner, Silke; Dehnen, Stefanie (2015-02-16). "[M4Sn4Se1710– Cluster Anions (M = Mn, Zn, Cd) in a Cs+ Environment and as Ternary Precursors for Ionothermal Treatment"] (in en). Inorganic Chemistry 54 (4): 1188–1190. doi:10.1021/ic5026087. ISSN 0020-1669. PMID 25622069. https://pubs.acs.org/doi/10.1021/ic5026087. 
  57. ↑ 57.0 57.1 Baiyin, Menghe; Naren, Jiruga; Gang, Gang; Wang, Xiaojing; Xu, Xiaoqing (September 2013). "Two new quaternary selenostannates synthesized under solvothermal conditions: Crystal structure and reflectance spectra of (1,4-dabH)2MnSnSe4 and (1,4-dabH2) Cu2SnSe4" (in en). Inorganic Chemistry Communications 35: 135–139. doi:10.1016/j.inoche.2013.06.001. https://linkinghub.elsevier.com/retrieve/pii/S1387700313002359. 
  58. ↑ 58.0 58.1 58.2 Li, Shufen; Wei, Zheng; Chen, Niannian; Gao, Yan; Jia, Dingxian (2019-12-17). "Hydrothermal syntheses, crystal structures, and optical properties of transition metal selenidostannates" (in en). Journal of Coordination Chemistry 72 (22–24): 3562–3574. doi:10.1080/00958972.2019.1705286. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958972.2019.1705286. 
  59. ↑ 59.0 59.1 59.2 Kromm, Anna; Sheldrick, William S. (June 2008). "Synthesis and Structures of Dimanganese(II) Complexes with Spirotricyclic [Mn(μ-Ge2Se7)Mn and [Mn(μ-Sn2Se6)Mn] Cores"] (in en). Zeitschrift für anorganische und allgemeine Chemie 634 (6–7): 1005–1010. doi:10.1002/zaac.200700551. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200700551. 
  60. ↑ 60.0 60.1 Haddadpour, Sima; Melullis, Maike; Staesche, Halgard; Mariappan, C. R.; Roling, Bernhard; Clérac, Rodolphe; Dehnen, Stefanie (2009-02-16). "Inorganic Frameworks from Selenidotetrelate Anions [T2Se64− (T = Ge, Sn): Synthesis, Structures, and Ionic Conductivity of [K2(H2O)3][MnGe4Se10] and (NMe4)2[MSn4Se10] (M = Mn, Fe)"] (in en). Inorganic Chemistry 48 (4): 1689–1698. doi:10.1021/ic802170f. ISSN 0020-1669. PMID 19159241. https://pubs.acs.org/doi/10.1021/ic802170f. 
  61. ↑ Kaib, Thomas; Haddadpour, Sima; Andersen, Hanne Flåten; Mayrhofer, Leonhard; Järvi, Tommi T.; Moseler, Michael; Möller, Kai-Christian; Dehnen, Stefanie (2013-12-10). "Quaternary Diamond-Like Chalcogenidometalate Networks as Efficient Anode Material in Lithium-Ion Batteries" (in en). Advanced Functional Materials 23 (46): 5693–5699. doi:10.1002/adfm.201301025. https://onlinelibrary.wiley.com/doi/10.1002/adfm.201301025. 
  62. ↑ 62.0 62.1 62.2 Xiong, Wei-Wei; Li, Pei-Zhou; Zhou, Tian-Hua; Zhao, Yanli; Xu, Rong; Zhang, Qichun (August 2013). "Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH[M1/2Sn1/2Se2] (M=Mn, Zn, Hg)"] (in en). Journal of Solid State Chemistry 204: 86–90. doi:10.1016/j.jssc.2013.05.023. https://linkinghub.elsevier.com/retrieve/pii/S0022459613002673. 
  63. ↑ 63.0 63.1 Tang, Chunying; Wang, Fang; Lu, Jialin; Jia, Dingxian; Jiang, Wenqing; Zhang, Yong (2014-09-02). "Novel One-, Two-, and Three-Dimensional Selenidostannates Templated by Iron(II) Complex Cation" (in en). Inorganic Chemistry 53 (17): 9267–9273. doi:10.1021/ic501381v. ISSN 0020-1669. PMID 25119287. https://pubs.acs.org/doi/10.1021/ic501381v. 
  64. ↑ Zimmermann, Christian; Anson, Christopher E.; Dehnen, Stefanie (2007-09-04). "Chalcogenido-Bridged Clusters by Reactions of Chalcogenostannate Salts" (in en). Journal of Cluster Science 18 (3): 618–629. doi:10.1007/s10876-007-0130-0. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-007-0130-0. 
  65. ↑ 65.0 65.1 65.2 Tian, Xinyu; Teri, Gele; Shele, Muge; E, Namila; Qi, Liming; Liu, Min; Baiyin, Menghe (May 2022). "Five new TM-Sn-Q (TM = transition metals;Q = S,Se) photoelectrocatalytic materials" (in en). Polyhedron 217. doi:10.1016/j.poly.2022.115729. https://linkinghub.elsevier.com/retrieve/pii/S027753872200081X. 
  66. ↑ Ren, Hai-Yun; Ning, Zhi-Xue; Hou, Juan-Juan (2014-03-19). "Ultrasound and solvent-induced reversible chromism in a luminescent chalcogenidostannate" (in en). Journal of Coordination Chemistry 67 (6): 1079–1087. doi:10.1080/00958972.2014.901505. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958972.2014.901505. 
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  68. ↑ Tan, Hong-Hui; Liu, Xing; Huang, Chun-Mei; Zhou, Jian (2023-07-17). "One-Dimensional Selenidostannates Based on an Infrequent Tetrameric Cluster [Sn4Se12 Exhibiting Electro-Catalytic Properties"] (in en). Inorganic Chemistry 62 (28): 11240–11247. doi:10.1021/acs.inorgchem.3c01538. ISSN 0020-1669. PMID 37390501. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01538. 
  69. ↑ Zhang, Bo; Li, Lian-Zhi; Li, Jun; Zhang, Yue-Chan; Liu, Shu-Hua; Deng, Yan-Li; Huang, Xiao-Ying (August 2019). "[Ni(phen)3Sn3Se7·1.5H2O: A new two-dimensional layered selenidostannate templated by [Ni(phen)3]2+ complexes"] (in en). Inorganic Chemistry Communications 106: 76–80. doi:10.1016/j.inoche.2019.05.035. https://linkinghub.elsevier.com/retrieve/pii/S1387700319304599. 
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  71. ↑ 71.0 71.1 Du, Cheng-Feng; Shen, Nan-Nan; Li, Jian-Rong; Hao, Min-Ting; Wang, Zi; Cheng, Chu-Chu; Huang, Xiao-Ying (2016). "Two novel selenidostannates from mixed structure-directing systems: the large ten-membered ring of [Sn3Se4 semicubes and the 3D [Sn4Se9]n2n− with multi-channels"] (in en). Dalton Transactions 45 (23): 9523–9528. doi:10.1039/C6DT01482H. ISSN 1477-9226. PMID 27193871. http://xlink.rsc.org/?DOI=C6DT01482H. 
  72. ↑ Jia, Guo-Xin; Jiang, Qi-Qi; Baiyin, Menghe; Teri, Gele (2022-09-28). Solvothermal synthesis, crystal structure and properties of selenidostannate containing zero-dimensional cluster structure (Report). In Review. doi:10.21203/rs.3.rs-2091815/v1. https://www.researchsquare.com/article/rs-2091815/v1. 
  73. ↑ 73.0 73.1 73.2 73.3 73.4 73.5 Hilbert, Jessica; Näther, Christian; Bensch, Wolfgang (2017-09-06). "Applying Ni(II) Amine Complexes and Sodium Thiostannate as Educts for the Generation of Thiostannates at Room Temperature" (in en). Crystal Growth & Design 17 (9): 4766–4775. doi:10.1021/acs.cgd.7b00728. ISSN 1528-7483. Bibcode: 2017CrGrD..17.4766H. https://pubs.acs.org/doi/10.1021/acs.cgd.7b00728. 
  74. ↑ 74.0 74.1 Benkada, Assma; Näther, Christian; Bensch, Wolfgang (2020-08-31). "Room Temperature Synthesis of New Thiostannates by Slow Interdiffusion of Different Solvents" (in en). Zeitschrift für anorganische und allgemeine Chemie 646 (16): 1352–1358. doi:10.1002/zaac.202000199. ISSN 0044-2313. 
  75. ↑ 75.0 75.1 75.2 Zheng, Li-Xian; Hu, Jian-Feng; Luo, Jun (2020). "Thermoelectric properties of Cu-doped Cu<sub>2</sub>SnSe<sub>4</sub> compounds". Acta Physica Sinica 69 (24): 247102. doi:10.7498/aps.69.20200861. ISSN 1000-3290. 
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  77. ↑ Zhang, Yingying; Hu, Dandan; Yang, Huajun; Lin, Jian; Wu, Tao (July 2017). "Synthesis, crystal structure, near-IR photoelectric response of two 1-D selenides: [Cu2MSe5·[Mn(H+-en)2(en)] (M=Ge, Sn)"] (in en). Journal of Solid State Chemistry 251: 61–64. doi:10.1016/j.jssc.2017.04.006. https://linkinghub.elsevier.com/retrieve/pii/S0022459617301135. 
  78. ↑ 78.0 78.1 Liao, Ju Hsiou; Kanatzidis, Mercouri G. (1993-10-01). "Quaternary rubidium copper tin sulfides (Rb2Cu2SnS4, A2Cu2Sn2S6 (A = Na, K, Rb, Cs), A2Cu2Sn2Se6 (A = K, Rb), potassium gold tin sulfides, K2Au2SnS4, and K2Au2Sn2S6. Syntheses, structures, and properties of new solid-state chalcogenides based on tetrahedral [SnS44- units"] (in en). Chemistry of Materials 5 (10): 1561–1569. doi:10.1021/cm00034a029. ISSN 0897-4756. https://pubs.acs.org/doi/abs/10.1021/cm00034a029. 
  79. ↑ 79.0 79.1 Sun, Pei-pei; Liu, Shu-zhen; Shen, Ya-li; Tang, Chun-ying; Han, Jing-yu; Liu, Yun; Jiang, Wen-qing; Jia, Ding-xian (October 2017). "Solvothermal Syntheses, Crystal Structures and Optical Properties of New Members of Transition Metal Complexes Based on Hexaselenidobistannate Ligand" (in en). Journal of Chemical Crystallography 47 (5): 133–139. doi:10.1007/s10870-017-0689-8. ISSN 1074-1542. Bibcode: 2017JCCry..47..133S. http://link.springer.com/10.1007/s10870-017-0689-8. 
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  81. ↑ Tsamourtzi, Konstantina; Song, Jung-Hwan; Bakas, Thomas; Freeman, Arthur J.; Trikalitis, Pantelis N.; Kanatzidis, Mercouri G. (2008-12-15). "Straightforward Route to the Adamantane Clusters [Sn4Q104− (Q = S, Se, Te) and Use in the Assembly of Open-Framework Chalcogenides (Me4N)2M[Sn4Se10] (M = Mn II , Fe II , Co II , Zn II ) Including the First Telluride Member (Me4N)2Mn[Ge4Te10]"] (in en). Inorganic Chemistry 47 (24): 11920–11929. doi:10.1021/ic801762h. ISSN 0020-1669. PMID 18998670. https://pubs.acs.org/doi/10.1021/ic801762h. 
  82. ↑ Zhou, Molin; Jiang, Xingxing; Yang, Yi; Guo, Yangwu; Lin, Zheshuai; Yao, JJiyong; Wu, Yicheng (2017-06-19). "K2ZnSn3Se8: A Non-Centrosymmetric Zinc Selenidostannate(IV) Featuring Interesting Covalently Bonded [ZnSn3Se82− Layer and Exhibiting Intriguing Second Harmonic Generation Activity"] (in en). Chemistry: An Asian Journal 12 (12): 1282–1285. doi:10.1002/asia.201700426. PMID 28436178. https://onlinelibrary.wiley.com/doi/10.1002/asia.201700426. 
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  103. ↑ Teri, Gele; Tong, Qian; Jia, Qiang-Qiang (November 2023). "Solvothermal syntheses and characterization of one-dimensional (1,4-dabH2)Cu1.72Ag0.28SnSe4 (1) and (1,4-dabH2)Cu2SnSe4 (2)" (in en). Inorganic Chemistry Communications 157. doi:10.1016/j.inoche.2023.111413. https://linkinghub.elsevier.com/retrieve/pii/S1387700323010250. 
  104. ↑ Guo, Yangwu; Li, Xiaoshuang; Feng, Kai; Li, Chao; Zhou, Molin; Wu, Yicheng; Yao, Jiyong (2018-04-04). "Li7Cd4.5Ge4Se16 and Li6.4Cd4.8Sn4Se16: Strong Nonlinear Optical Response in Quaternary Diamond-Like Selenide Networks" (in en). Chemistry: An Asian Journal 13 (7): 871–876. doi:10.1002/asia.201800090. PMID 29392886. https://onlinelibrary.wiley.com/doi/10.1002/asia.201800090. 
  105. ↑ 105.0 105.1 Xiong, Wei-Wei; Ye, Kaiqi; Ye, Ling; Zhang, Qichun (September 2013). "Syntheses, crystal structures, and properties of two new one-dimensional heterometallic selenides: [DBNH4[M3Sn4Se11(Se2)2] (M=Cd, Hg)"] (in en). Inorganic Chemistry Communications 35: 337–341. doi:10.1016/j.inoche.2013.07.015. https://linkinghub.elsevier.com/retrieve/pii/S1387700313003067. 
  106. ↑ Qi, F.-Y.; Baiyin, M.-H. "硒代锡酸盐Cd(tren)SnSe3的溶剂热合成与晶体结构". Rengong Jingti Xuebao/Journal of Synthetic Crystals 46 (12): 2422–2426. 
  107. ↑ Sun, Baohua; He, Jianqiao; Song, Changsheng; Wang, Dong; Bu, Kejun; Yin, Guoheng; Zhang, Xian; Huang, Fuqiang (2017-07-11). "An Intermediate Band Material K2CdSnSe4 and Its Visible-Light Photocatalytic Activity" (in en). ChemistrySelect 2 (20): 5655–5659. doi:10.1002/slct.201700731. https://onlinelibrary.wiley.com/doi/10.1002/slct.201700731. 
  108. ↑ 108.0 108.1 Wu, Jing; Pu, Ya-Yang; Zhao, Xiao-Wei; Qian, Li-Wen; Bian, Guo-Qing; Zhu, Qin-Yu; Dai, Jie (2015). "Photo-electroactive ternary chalcogenido-indate-stannates with a unique 2-D porous structure" (in en). Dalton Transactions 44 (10): 4520–4525. doi:10.1039/C4DT03333G. ISSN 1477-9226. PMID 25653182. http://xlink.rsc.org/?DOI=C4DT03333G. 
  109. ↑ 109.0 109.1 109.2 Friedrich, Daniel; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Kanatzidis, Mercouri G. (2021-08-24). "Vast Structural and Polymorphic Varieties of Semiconductors AMM′Q 4 (A = K, Rb, Cs, Tl; M = Ga, In; M′ = Ge, Sn; Q = S, Se)" (in en). Chemistry of Materials 33 (16): 6572–6583. doi:10.1021/acs.chemmater.1c02211. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.1c02211. 
  110. ↑ Wang, Yingqi; Wang, Ruiqi; Liu, Qinglong; Lai, Xiaofang; Zhang, Xian; Chen, Haijie; Zheng, Chong; Lin, Jianhua et al. (2016). "Solvothermal synthesis, structure and physical properties of Cs[Cr(en)2MSe4 (M = Ge, Sn) with [MSe4]4− tetrahedra as chelating ligand"] (in en). Dalton Transactions 45 (22): 9097–9102. doi:10.1039/C6DT00233A. ISSN 1477-9226. PMID 27164409. http://xlink.rsc.org/?DOI=C6DT00233A. 
  111. ↑ 111.0 111.1 111.2 111.3 Morris, Collin D.; Li, Hao; Jin, Hosub; Malliakas, Christos D.; Peters, John A.; Trikalitis, Pantelis N.; Freeman, Arthur J.; Wessels, Bruce W. et al. (2013-08-27). "Cs 2 M II M IV 3 Q 8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps" (in en). Chemistry of Materials 25 (16): 3344–3356. doi:10.1021/cm401817r. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm401817r. 
  112. ↑ 112.0 112.1 Wu, Kui; Su, Xin; Yang, Zhihua; Pan, Shilie (2015). "An investigation of new infrared nonlinear optical material: BaCdSnSe4 , and three new related centrosymmetric compounds: Ba2SnSe4, Mg2GeSe4, and Ba2Ge2S6" (in en). Dalton Transactions 44 (46): 19856–19864. doi:10.1039/C5DT03215F. ISSN 1477-9226. PMID 26509847. http://xlink.rsc.org/?DOI=C5DT03215F. 
  113. ↑ 113.0 113.1 Zelinska, Mariya; Assoud, Abdeljalil; Graf, Christian; Kleinke, Holger (2010-02-01). "Reversible Reconstructive Phase Transition of Ba2SnSe5: A New High Temperature Modification with Completely Different Structural Motifs" (in en). Inorganic Chemistry 49 (3): 1090–1093. doi:10.1021/ic901989j. ISSN 0020-1669. PMID 20038157. https://pubs.acs.org/doi/10.1021/ic901989j. 
  114. ↑ Graf, Christian; Assoud, Abdeljalil; Zelinska, Mariya; Kleinke, Holger (September 2010). "The metastable m -Ba2SnSe5– Synthesis, Phase Transition, Crystal Structure, Structural Relations and Electronic Structure" (in en). Zeitschrift für anorganische und allgemeine Chemie 636 (9–10): 1821–1826. doi:10.1002/zaac.201000058. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201000058. 
  115. ↑ Feng, Kai; Jiang, Xingxing; Kang, Lei; Yin, Wenlong; Hao, Wenyu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng et al. (2013). "Ba6Sn6Se13: a new mixed valence selenostannate with NLO property" (in en). Dalton Transactions 42 (37): 13635–13641. doi:10.1039/c3dt51317c. ISSN 1477-9226. PMID 23900234. http://xlink.rsc.org/?DOI=c3dt51317c. 
  116. ↑ 116.0 116.1 Abudurusuli, Ailijiang; Wu, Kui; Pan, Shilie (2018). "Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation" (in en). New Journal of Chemistry 42 (5): 3350–3355. doi:10.1039/C7NJ04288D. ISSN 1144-0546. http://xlink.rsc.org/?DOI=C7NJ04288D. 
  117. ↑ Li, Ya-Nan; Chen, Zi-Xia; Yao, Wen-Dong; Tang, Ru-Ling; Guo, Sheng-Ping (2021). "Heterovalent cations substitution to design asymmetric chalcogenides with promising nonlinear optical performances" (in en). Journal of Materials Chemistry C 9 (27): 8659–8665. doi:10.1039/D1TC01806J. ISSN 2050-7526. http://xlink.rsc.org/?DOI=D1TC01806J. 
  118. ↑ Li, Xiaoshuang; Li, Chao; Gong, Pifu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2015). "BaGa2SnSe6: a new phase-matchable IR nonlinear optical material with strong second harmonic generation response" (in en). Journal of Materials Chemistry C 3 (42): 10998–11004. doi:10.1039/C5TC02337H. ISSN 2050-7526. http://xlink.rsc.org/?DOI=C5TC02337H. 
  119. ↑ Azam, Sikander; Khan, Saleem Ayaz; Goumri-Said, Souraya (September 2015). "Exploring the electronic structure and optical properties of the quaternary selenide compound, Ba4Ga4SnSe12: For photovoltaic applications" (in en). Journal of Solid State Chemistry 229: 260–265. doi:10.1016/j.jssc.2015.06.015. Bibcode: 2015JSSCh.229..260A. https://linkinghub.elsevier.com/retrieve/pii/S0022459615300244. 
  120. ↑ Nian, Leyan; Wu, Kui; He, Guijie; Yang, Zhihua; Pan, Shilie (2018-03-19). "Effect of Element Substitution on Structural Transformation and Optical Performances in I 2 BaM IV Q 4 ( I = Li, Na, Cu, and Ag; M IV = Si, Ge, and Sn; Q = S and Se)" (in en). Inorganic Chemistry 57 (6): 3434–3442. doi:10.1021/acs.inorgchem.8b00220. ISSN 0020-1669. PMID 29509412. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b00220. 
  121. ↑ 121.0 121.1 121.2 Tang, Weiwei; Chen, Ruihong; Jiang, Wenqing; Zhang, Yong; Jia, Dingxian (October 2012). "The First Tetradentate μ-1κ 2 :2κ 2 -Sn2Se6 Ligand to a Lanthanide(III) Center: Solvothermal Syntheses and Characterizations of Lanthanide Selenidostannate Polymers with Tetraethylenepentamine as a Second Ligand" (in en). European Journal of Inorganic Chemistry 2012 (30): 4907–4913. doi:10.1002/ejic.201200649. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.201200649. 
  122. ↑ 122.0 122.1 122.2 122.3 Liu, Shuzhen; Sun, Peipei; Shen, Yali; Han, Jingyu; Sun, Hui; Jia, Dingxian (2017-04-01). "Lanthanide(III) complexes with μ-SnSe4 and μ-Sn2Se6 linkers: solvothermal syntheses and properties of new Ln(III) selenidostannates decorated with linear polyamine" (in en). Zeitschrift für Naturforschung B 72 (4): 231–240. doi:10.1515/znb-2016-0236. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2016-0236/html. 
  123. ↑ 123.0 123.1 Chen, Jiang-Fang; Jin, Qin-Yan; Pan, Ying-Li; Zhang, Yong; Jia, Ding-Xian (2009). "An unprecedented μ4-Sn2Se9 ligand: solvothermal syntheses and characterizations of novel lanthanum selenidostannates [{La(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)∞ and [La2(en)8(μ-Se2)]Sn2Se6"] (in en). Chemical Communications (46): 7212–7214. doi:10.1039/b914603b. ISSN 1359-7345. http://xlink.rsc.org/?DOI=b914603b. 
  124. ↑ 124.0 124.1 124.2 124.3 124.4 Tang, Chunying; Wang, Fang; Chen, Ruihong; Jiang, Wenqing; Zhang, Yong; Jia, Dingxian (August 2013). "Complexation of Sn2Se6 with lanthanide(III) centers influenced by ethylene polyamines: Solvothermal syntheses, crystal structures, and optical properties of lanthanide selenidostannates" (in en). Journal of Solid State Chemistry 204: 70–77. doi:10.1016/j.jssc.2013.05.008. Bibcode: 2013JSSCh.204...70T. https://linkinghub.elsevier.com/retrieve/pii/S0022459613002521. 
  125. ↑ 125.0 125.1 125.2 125.3 125.4 125.5 125.6 Liang, Jingjing; Chen, Jiangfang; Zhao, Jing; Pan, Yingli; Zhang, Yong; Jia, Dingxian (2011). "Effects of lanthanide metal size and amino ligand denticity on the solvothermal systems Ln/Sn/Se/en and Ln/Sn/Se/dien (Ln = lanthanide)" (in en). Dalton Transactions 40 (11): 2631–2637. doi:10.1039/c0dt01424a. ISSN 1477-9226. PMID 21293819. http://xlink.rsc.org/?DOI=c0dt01424a. 
  126. ↑ Feng, Kai; Zhang, Xu; Yin, Wenlong; Shi, Youguo; Yao, Jiyong; Wu, Yicheng (2014-02-17). "New Quaternary Rare-Earth Chalcogenides Ba Ln Sn 2 Q 6 ( Ln = Ce, Pr, Nd, Q = S; Ln = Ce, Q = Se): Synthesis, Structure, and Magnetic Properties" (in en). Inorganic Chemistry 53 (4): 2248–2253. doi:10.1021/ic402934m. ISSN 0020-1669. PMID 24498849. https://pubs.acs.org/doi/10.1021/ic402934m. 
  127. ↑ 127.0 127.1 127.2 Tang, Chunying; Liu, Yun; Wang, Fang; Lu, Jialin; Shen, Yali; Zhang, Yong; Jia, Dingxian (April 2015). "Solvothermal syntheses and characterizations of the first example of lanthanide selenidostannates prepared in mixed ethylene polyamines" (in en). Inorganica Chimica Acta 429: 67–72. doi:10.1016/j.ica.2014.12.038. https://linkinghub.elsevier.com/retrieve/pii/S0020169315000717. 
  128. ↑ 128.0 128.1 128.2 Zhu, Ai-Mei; Jin, Qin-Yan; Jia, Ding-Xian; Gu, Jian-Sheng; Zhang, Yong (October 2008). "The First Example of the Tetraselenidostannate Anion [SnSe44– as a Chelating Ligand to a Lanthanide Complex Ion: Solvothermal Synthesis and Characterization of Lanthanoid Selenidostannates [Hdien][Ln(dien)2(μ-SnSe4)] (Ln = Sm, Eu) and [Eu2(dien)4 (μ-OH)2]Sn2Se6"] (in en). European Journal of Inorganic Chemistry 2008 (30): 4756–4761. doi:10.1002/ejic.200800577. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200800577. 
  129. ↑ Evenson IV, Carl R.; Dorhout, Peter K. (September 2001). "Synthesis, Structural, and Optical Characterization of a New Europium(II) Tin Selenide, Eu8(Sn4Se14)(Se3)2 with a (Sn4Se14)12– Building Block". Zeitschrift für anorganische und allgemeine Chemie 627 (9): 2178. doi:10.1002/1521-3749(200109)627:9<2178::AID-ZAAC2178>3.0.CO;2-S. https://onlinelibrary.wiley.com/doi/10.1002/1521-3749(200109)627:93.0.CO;2-S. 
  130. ↑ Chen, Rui-hong; Wang, Fang; Tang, Chun-ying; Zhang, Yong; Jia, Ding-xian (June 2013). "Solvothermal Syntheses and Crystal Structures of Hexachalcogenidodistannates with Europium Complexes of Different Ethylene Polyamine Ligands" (in en). Journal of Chemical Crystallography 43 (6): 319–324. doi:10.1007/s10870-013-0423-0. ISSN 1074-1542. Bibcode: 2013JCCry..43..319C. http://link.springer.com/10.1007/s10870-013-0423-0. 
  131. ↑ 131.0 131.1 131.2 131.3 Xiao, Hong; Liu, Xing; Zhou, Jian; Wang, Miaohui; Wang, Peng; Zhang, Xiaoyan (July 2016). "Solvothermal Syntheses and Characterization of a Series of New Selenidostannates with Lanthanide Complexes as Counterions" (in en). Journal of Cluster Science 27 (4): 1475–1484. doi:10.1007/s10876-016-1013-z. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-016-1013-z. 
  132. ↑ "Solvothermal Synthesis,Crystal Structure and Optical Property of Lanthanide Selenidostannate [{Tb(en)_3}_2(μ-OH)_2Sn_2Se_6 with a 3-D H-bonded Network"]. Chinese Journal of Structural Chemistry (12): 1869–1873. December 2010. http://www.cqvip.com/qk/95925x/201012/36294902.html. 
  133. ↑ 133.0 133.1 Jia, Ding-Xian; Zhu, Ai-Mei; Deng, Jie; Suzhou, Yong Zhang (July 2007). "Solvothermal Synthesis and Characterization of Lanthanide Chalcogenidostannates [Ln2(en)6(μ2-OH)2[Sn2S6] (Ln = Dy, Er) and [Dy2(en)6(μ2-OH)2][Sn2Se6]"] (in de). Zeitschrift für anorganische und allgemeine Chemie 633 (8): 1246–1250. doi:10.1002/zaac.200700035. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200700035. 
  134. ↑ 134.0 134.1 134.2 Xiao, Hong-Ping; Zhou, Jian; Wang, Xiao-Li; Zou, Hua-Hong; Zhao, Rong-Qing; Xiao, Hong (2014-07-02). "Solvothermal syntheses and characterizations of three new holmium selenidostannates( iv ): a rare example of adamantane-like [Sn4Se104− selenidostannate( iv ) with lanthanide complexes"] (in en). Dalton Transactions 43 (32): 12306–12312. doi:10.1039/C4DT00972J. ISSN 1477-9226. PMID 24986054. http://xlink.rsc.org/?DOI=C4DT00972J. 
  135. ↑ Han, Jingyu; Liu, Yun; Lu, Jialin; Tang, Chunying; Wang, Fang; Shen, Yali; Zhang, Yong; Jia, Dingxian (August 2015). "Heterometallic sulfide cluster [Ag6Sn6S2010−: Solvothermal syntheses and characterizations of silver thiostannates with lanthanide complex counter cations"] (in en). Inorganic Chemistry Communications 57: 18–21. doi:10.1016/j.inoche.2015.04.018. https://linkinghub.elsevier.com/retrieve/pii/S1387700315001707. 
  136. ↑ 136.0 136.1 Xiong, Wei-Wei; Li, Pei-Zhou; Zhou, Tian-Hua; Tok, Alfred Iing Yoong; Xu, Rong; Zhao, Yanli; Zhang, Qichun (2013-04-15). "Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media" (in en). Inorganic Chemistry 52 (8): 4148–4150. doi:10.1021/ic4002169. ISSN 0020-1669. PMID 23556509. https://pubs.acs.org/doi/10.1021/ic4002169. 
  137. ↑ Guo, Yangwu; Liang, Fei; Li, Zhuang; Xing, Wenhao; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2019-10-02). "Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I 4 –II–IV 2 –VI 7 Diamond-like Family" (in en). Crystal Growth & Design 19 (10): 5494–5497. doi:10.1021/acs.cgd.9b01074. ISSN 1528-7483. Bibcode: 2019CrGrD..19.5494G. https://pubs.acs.org/doi/10.1021/acs.cgd.9b01074. 
  138. ↑ 138.0 138.1 Gao, Lihua; Xu, Jingjing; Tian, Xinyu; Zhang, Bingbing; Wu, Xiaowen; Wu, Kui (2022-06-26). "AgGaSe2 -Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury" (in en). Chemistry of Materials 34 (13): 5991–5998. doi:10.1021/acs.chemmater.2c01011. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.2c01011. 
  139. ↑ Li, Zhuang; Liu, Youquan; Zhang, Shengzi; Xing, Wenhao; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2020-06-01). "Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability" (in en). Inorganic Chemistry 59 (11): 7614–7621. doi:10.1021/acs.inorgchem.0c00490. ISSN 0020-1669. PMID 32412240. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c00490. 
  140. ↑ 140.0 140.1 Wang, Yu-Long; Feng, Mei-Ling; Wang, Kai-Yao; Li, Jian-Rong; Wang, Ze-Ping; Zou, Guo-Dong; Huang, Xiao-Ying (July 2013). "Two novel one-dimensional mercury selenidostannates with transition metal complexes: [Fe(phen)3Hg2Sn2Se7·1.5eta·0.25H2O and [Ni2(teta)2(μ-teta)]HgSn3Se9"] (in en). Inorganic Chemistry Communications 33: 10–14. doi:10.1016/j.inoche.2013.03.033. https://linkinghub.elsevier.com/retrieve/pii/S1387700313001342. 
  141. ↑ 141.0 141.1 Guo, Yangwu; Liang, Fei; Li, Zhuang; Xing, Wenhao; Lin, Zhe-shuai; Yao, Jiyong; Mar, Arthur; Wu, Yicheng (2019-08-05). "AHgSnQ 4 (A = Sr, Ba; Q = S, Se): A Series of Hg-Based Infrared Nonlinear-Optical Materials with Strong Second-Harmonic-Generation Response and Good Phase Matchability" (in en). Inorganic Chemistry 58 (15): 10390–10398. doi:10.1021/acs.inorgchem.9b01572. ISSN 0020-1669. PMID 31342744. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01572. 



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