Chemistry:Thulium(III) nitrate
From HandWiki
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| Names | |
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| Other names
Thulium trinitrate, Thulium nitrate
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| Identifiers | |
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3D model (JSmol)
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| ChemSpider | |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| Tm(NO3)3 | |
| Molar mass | 354.949 |
| Appearance | Dark-green crystals |
| Soluble | |
| Hazards | |
| GHS pictograms |  
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| GHS Signal word | Warning |
| H272, H315, H319, H335 | |
| P210, P220, P221, P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P370+378, P403+233, P405, P501 | |
| Related compounds | |
Related compounds
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Terbium(III) nitrate, Lutetium(III) nitrate, Cerium(III) nitrate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Thulium(III) nitrate is an inorganic compound, a salt of thulium and nitric acid with the chemical formula Tm(NO
3)
3.[1][2][3] The compound forms dark-green crystals, readily soluble in water, also forms crystalline hydrates.
Synthesis
Reaction of thulium and nitric acid:[4]
- Tm + 6HNO
3 → Tm(NO
3)
3 + 3NO
2 + 3H
2O
- Tm + 6HNO
Reaction of thulium hydroxide and nitric acid:
- Tm(OH)
3 + 3HNO
3 → Tm(NO
3)
3 + 3H
2O
- Tm(OH)
Physical properties
Thulium(III) nitrate forms dark-green hygroscopic crystals.
Forms crystalline hydrates of the composition Tm(NO
3)
3 · 5H2O.[5][6]
Soluble in water and ethanol.[7]
Chemical properties
Both the compound and its crystalline hydrate decompose on moderate heating.
Hydrated thulium nitrate thermally decomposes to form TmONO
3 and decomposes to thulium oxide upon further heating.
Applications
Thulium(III) nitrate hydrate is used as a reagent. Also used in optical glasses, ceramics, catalysts, electrical components, and photo-optical materials.[8]
References
- ↑ Волков, А.И.; Жарский, И.М. (2005) (in ru). Большой химический справочник. Современная школа. p. 132. ISBN 985-6751-04-7.
- ↑ Skerencak, A.; Panak, Petra J.; Hauser, W.; Neck, Volker; Klenze, R.; Lindqvist-Reis, P.; Fanghänel, Thomas (January 2009). "TRLFS study on the complexation of Cm(III) with nitrate in the temperature range from 5 to 200 °C". Radiochimica Acta 97 (8). doi:10.1524/ract.2009.1631. https://www.degruyter.com/document/doi/10.1524/ract.2009.1631/pdf. Retrieved 19 August 2021.
- ↑ Modolo, Giuseppe; Kluxen, Paul; Geist, Andreas (January 2010). "Demonstration of the LUCA process for the separation of americium(III) from curium(III), californium(III), and lanthanides(III) in acidic solution using a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid and tris(2-ethylhexyl)phosphate". Radiochimica Acta 98 (4). doi:10.1524/ract.2010.1708. http://juser.fz-juelich.de/record/9815/files/%5BRadiochimica%20Acta%5D%20Demonstration%20of%20the%20LUCA%20process%20for%20the%20separation%20of%20americium%28III%29%20from%20curium%28III%29%20californium%28III%29%20and%20lanthanides%28III%29%20in%20acidic%20solution%20using%20a%20synergistic%20mixture%20of%20bis%28chloro.pdf.
- ↑ Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. https://books.google.com/books?id=6IuZAwAAQBAJ&dq=Ytterbium+(III)+nitrate&pg=PA226. Retrieved 19 August 2021.
- ↑ "Thulium(III) nitrate pentahydrate". Sigma Aldrich. https://www.sigmaaldrich.com/RU/ru/product/aldrich/325996.
- ↑ Elements, American. "Thulium(III) Nitrate Pentahydrate" (in en). American Elements. https://www.americanelements.com/thulium-iii-nitrate-pentahydrate-36548-87-5.
- ↑ Haynes, William M. (9 June 2015) (in en). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-95. ISBN 978-1-4822-6097-7. https://books.google.com/books?id=RpLYCQAAQBAJ&dq=Thulium(III)+nitrate&pg=SA4-PA95. Retrieved 19 August 2021.
- ↑ "14579 Thulium(III) nitrate hydrate, REacton®, 99.9% (REO)". Alfa Aesar. https://www.alfa.com/en/catalog/014579/.
Salts and covalent derivatives of the nitrate ion
| HNO3 | He | ||||||||||||||||
| LiNO3 | Be(NO3)2 | B(NO3)−4 | C | NO−3, NH4NO3 |
O | FNO3 | Ne | ||||||||||
| NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | ||||||||||
| KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3, Fe(NO3)2 |
Co(NO3)2, Co(NO3)3 |
Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | Br | Kr |
| RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb | Mo | Tc | Ru | Rh | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In | Sn | Sb(NO3)3 | Te | I | Xe(NO3)2 |
| CsNO3 | Ba(NO3)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2(NO3)2, Hg(NO3)2 |
Tl(NO3)3, TlNO3 |
Pb(NO3)2 | Bi(NO3)3 BiO(NO3) |
Po | At | Rn | |
| FrNO3 | Ra(NO3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La(NO3)3 | Ce(NO3)3, Ce(NO3)4 |
Pr | Nd(NO3)3 | Pm | Sm | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac(NO3)3 | Th(NO3)4 | Pa | UO2(NO3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
 |  |
