Engineering:Steel and tin cans

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Short description: Sealed container for storage of foods


An empty tin can

A steel can, tin can, tin (especially in British English, Australian English, Canadian English and South African English), steel packaging, or can is a container for the distribution or storage of goods, made of thin metal. Many cans require opening by cutting the "end" open; others have removable covers. They can store a broad variety of contents: food, beverages, oil, chemicals, etc. Steel cans are made of tinplate (tin-coated steel) or of tin-free steel. In some dialects, even aluminium cans are called "tin cans".[1]

Steel cans are highly recyclable, with around 65% of steel cans being recycled.[2]

History

The tin canning process was conceived by the Frenchman Philippe de Girard, who had British merchant Peter Durand patent the idea in 1810.[3][4] The canning concept was based on experimental food preservation work in glass containers the year before by the French inventor Nicholas Appert. Durand did not pursue food canning, but, in 1812, sold his patent to two Englishmen, Bryan Donkin and John Hall, who refined the process and product, and set up the world's first commercial canning factory on Southwark Park Road, London. By 1813 they were producing their first tin canned goods for the Royal Navy. By 1820, tin canisters or cans were being used for gunpowder, seeds, and turpentine.

Early tin cans were sealed by soldering with a tin–lead alloy, which could lead to lead poisoning.

In 1901 in the United States, the American Can Company was founded, at the time producing 90% of the tin cans in the United States.[5]

Canned food in tin cans was already quite popular in various countries when technological advancements in the 1920s lowered the cost of the cans even further.[6]:155–170; 265–280 In 1935, the first beer in metal cans was sold; it was an instant sales success.[6]:155–170; 265–280


Description

Most cans are right circular cylinders with identical and parallel round tops and bottoms with vertical sides. However, in cans for small volumes or particularly-shaped contents, the top and bottom may be rounded-corner rectangles or ovals. Other contents may suit a can that is somewhat conical in shape.

Fabrication of most cans results in at least one rim—a narrow ring slightly larger than the outside diameter of the rest of the can. The flat surfaces of rimmed cans are recessed from the edge of any rim (toward the middle of the can) by about the width of the rim; the inside diameter of a rim, adjacent to this recessed surface, is slightly smaller than the inside diameter of the rest of the can.

Three-piece can construction results in top and bottom rims. In two-piece construction, one piece is a flat top and the other a deep-drawn cup-shaped piece that combines the (at least roughly) cylindrical wall and the round base. Transition between wall and base is usually gradual. Such cans have a single rim at the top. Some cans have a separate cover that slides onto the top or is hinged.

Two piece steel cans can be made by "drawing" to form the bottom and sides and adding an "end" at the top: these do not have side seams. Cans can be fabricated with separate slip-on, or friction fit covers and with covers attached by hinges. Various easy opening methods are available.[7]

In the mid-20th century, a few milk products were packaged in nearly rimless cans, reflecting different construction; in this case, one flat surface had a hole (for filling the nearly complete can) that was sealed after filling with a quickly solidifying drop of molten solder. Concern arose that the milk contained unsafe levels of lead leached from this solder plug.

Advantages of steel cans

A number of factors make steel cans ideal containers for beverages. Steel cans are stronger than cartons or plastic, and less fragile than glass, protecting the product in transit and preventing leakage or spillage, while also reducing the need for secondary packaging.[8][9]

Steel and aluminium packaging offer complete protection against light, water and air, and metal cans without resealable closures are among the most tamper-evident of all packaging materials.[10] Food and drink packed in steel cans has equivalent vitamin content to freshly prepared, without needing preserving agents.[10] Steel cans also extend the product's shelf-life, allowing longer sell-by and use-by dates and reducing waste.[8]

As an ambient packaging medium, steel cans do not require cooling in the supply chain, simplifying logistics and storage, and saving energy and cost.[8] At the same time, steel's relatively high thermal conductivity means canned drinks chill much more rapidly and easily than those in glass or plastic bottles.[11]

A World Steel Association initiative, Choose Steel, is encouraging the use of steel for beverage cans.[12]

  • A can of French linseed oil

  • Compressed gas with dispensing valve

  • Flip-top can[13] with hinged cover

  • Can of lighter fluid

  • Special can for dispensing oil

  • Camp stove fuel in "F-Style" can[13]

  • Paint can with double friction cover (plug)

  • Can with slip-on cover

  • Can of shoe polish

  • Tea tin

Materials

No cans currently in wide use are composed primarily or wholly of tin;[14] that term rather reflects the nearly exclusive use in cans[clarification needed], until the second half of the 20th century, of tinplate steel, which combined the physical strength and relatively low price of steel with the corrosion resistance of tin. Depending on contents and available coatings, some canneries still use tin-free steel.

In some local dialects, any metal can, even aluminium, might be called a "tin can". Use of aluminium in cans began in 1957.[15] Aluminium is less costly than tin-plated steel but offers the same resistance to corrosion in addition to greater malleability, resulting in ease of manufacture; this gave rise to the two-piece can, where all but the top of the can is simply stamped out of a single piece of aluminium.

A can traditionally has a printed paper or plastic label glued to the outside of the curved surface, indicating its contents. Some labels contain additional information, such as recipes, on the reverse side. More recently labels are sometimes printed directly onto the metal before or after the metal sheet is formed into the individual cans.

In November 1991, US can manufacturers voluntarily eliminated lead seams in food cans. However, imported food cans continued to include lead soldered seams.[16] In 1995, the US FDA issued a rule prohibiting lead soldered food cans, including both domestic and imported food cans.[17]

In modern times, the majority of food cans in the UK[18] have been lined with a plastic coating containing bisphenol A (BPA). The coating prevents acids and other substances from corroding the tin or aluminium of the can, but leaching of BPA into the can's contents was investigated as a potential health hazard.[19]

Standard sizes

Cans come in a variety of shapes and sizes. Walls are often stiffened with rib bulges, especially on larger cans, to help the can resist dents that can cause seams to split.

Can sizes in the United States have an assortment of designations and sizes. For example, size 7/8 contains one serving of half a cup with an estimated weight of 4 ounces; size 1 "picnic" has two or three servings totalling one and a quarter cups with an estimated weight of 10​1⁄2 ounces; size 303 has four servings totalling 2 cups weighing 15​1⁄2 ounces; and size 10 cans, most widely used by food services selling to cafeterias and restaurants, have twenty-five servings totalling 13 cups with an estimated weight of 103​1⁄2 ounces (size of a roughly 3 pound coffee can). These are U.S. customary cups, not British Imperial standard.

In the United States, cook books sometimes reference cans by size. The Can Manufacturers Institute defines these sizes, expressing them in three-digit numbers, as measured in whole and sixteenths of an inch for the container's nominal outside dimensions: a 307 × 512 would thus measure 3 and 7/16" in diameter by 5 and 3/4" (12/16") in height. Older can numbers are often expressed as single digits, their contents being calculated for room-temperature water as approximately eleven ounces (#1 "picnic" can), twenty ounces (#2), thirty-two ounces (#3), fifty-eight ounces (#5), and one-hundred-ten ounces (#10 "coffee" can).[20]

Can Name Dimensions (inches) Capacity (U.S. fluid ounces) No. 2 can equivalent Typical products
6Z 2​2⁄16 × 3​1⁄2 6.08 0.295
8Z Short 2​11⁄16 × 3 7.93 0.386
8Z Tall 2​11⁄16 × 3​2⁄8 8.68 0.422
No. I (Picnic) 2​11⁄16 × 4 10.94 0.532
No. 211 Cylinder 2​11⁄16 × 4​14⁄16 13.56 0.660
No. 300 3 × 4​7⁄16 15.22 0.741 Cranberry Sauce, Pork & Beans
No. 300 Cylinder 3 × 5​9⁄16 19.40 0.945
No. I Tall 3​1⁄16 × 4​11⁄16 16.70 0.813
No. 303 3​3⁄16 × 4​3⁄8 16.88 0.821 Fruits, Vegetables, Soups
No. 303 Cylinder 3​3⁄16 × 5​9⁄16 21.86 1.060
No. 2 Vacuum 3​7⁄16 × 3​3⁄8 14.71 0.716
No. 2 3​7⁄16 × 4​9⁄16 20.55 1.000 Juices, Soups, Vegetables
Jumbo 3​7⁄16 × 5​5⁄8 25.80 1.2537
No. 2 Cylinder 3​7⁄16 × 5​6⁄8 26.40 1.284
No. 1.25 4​1⁄16 × 2​3⁄8 13.81 0.672
No. 2.5 4​1⁄16 × 4​11⁄16 29.79 1.450 Fruits, Vegetables
No. 3 Vacuum 4​1⁄4 × 3​7⁄16 23.90 1.162
No. 3 Cylinder 4​1⁄4 × 7 51.70 2.515
No. 5 5​1⁄8 × 5​5⁄8 59.10 2.8744 Fruit Juice, Soups
No. 10 6​3⁄16 × 7 109.43 5.325 Fruits, Vegetables

In parts of the world using the metric system, tins are made in 250, 500, 750 ml (millilitre) and 1 L (litre) sizes (250 ml is approximately 1 cup or 8 ounces). Cans imported from the US often have odd sizes such as 3.8 L (1 US gallon), 1.9 L (1/2 US gallon), and 946 ml (2 US pints / 1 quart).

In the UK and Australia, cans are usually measured by net weight. A standard size tin can holds roughly 400 g; though the weight can vary between 385 g and 425 g depending on the density of the contents. The smaller half sized can holds roughly 200 g, typically varying between 170 g and 225 g.

Fabrication of cans

Rimmed three-piece can construction involves several stages;

  • Forming a tube and welding or soldering the seam of the sides
  • Joining the bottom end to the tube
  • Printing or attaching labels to the can
  • Filling the can with content; sterilization or retorting is required for many food products
  • Joining the wall and top "end".

Double seam rims are crucial to the joining of the wall to a top or bottom surface. An extremely tight fit between the pieces must be accomplished to prevent leakage; the process of accomplishing this radically deforms the rims of the parts. Part of the tube that forms the wall is bent, almost at its end, turning outward through 90 degrees, and then bent further, toward the middle of the tube, until it is parallel to the rest of the tube, a total bend of 180 degrees.

The outer edge of the flat piece is bent against this toward the middle of the tubular wall, until parallel with the wall, turning inward through 90 degrees. The edge of bent portion is bent further through another 90 degrees, inward now toward the axis of the tube and parallel to the main portion of the flat piece, making a total bend of 180 degrees. It is bent far enough inward that its circular edge is now slightly smaller in diameter than the edge of the tube. Bending it yet further, until it is parallel with the tube's axis, gives it a total bend of 270 degrees. It now envelops the outward rim of the tube.

Looking outward from the axis of the tube, the first surface is the unbent portion of the tube. Slightly further out is a narrow portion of the top, including its edge. The outward-bent portion of the tube, including its edge, is still slightly further out. Furthest out is the 90-degree-bent portion of the flat surface.

The combined interacting forces, as the portion of the flat surface adjacent to the interior of the tube is indented toward the middle of the tube and then outward forward the axis of the tube, and the other bent portions of the flat piece and the tube are all forced toward the axis of the tube, drives these five thicknesses of metal against each other from inside and out, forming a "dry" joint so tight that welding or solder is not needed to strengthen or seal it. Illustrations of this process can be found on pages 20–22 of the FAO Fisheries Technical Paper 285 "Manual on fish canning" located here.

  • Inside of a tin can.

Design and manufacture

Steel for can making

The majority of steel used in packaging is tinplate, which is steel that has been coated with a thin layer of tin, whose functionality is required for the production process.[21] The tin layer is usually applied by electroplating.[22]

Two-piece steel can design

Most steel beverage cans are two-piece designs, made from 1) a disc re-formed into a cylinder with an integral end, double-seamed after filling and 2) a loose end to close it.[9] Steel cans are made in many different diameters and volumes, with opening mechanisms that vary from ring pulls and tab openers, to wide open mouths.[23] Modern can making lines may produce up to 1000 cans per minute.[21]

Drawn-and-ironed (DWI) steel cans

The process of re-forming sheet metal without changing its thickness is known as 'drawing'. Thinning the walls of a two-piece can by passing it through circular dies is called 'ironing'. Steel beverage cans are therefore generally referred to as drawn-and-ironed, or DWI, cans (sometimes D&I). The DWI process is used for making cans where the height is greater than the diameter, and is particularly suited to making large volumes of cans of the same basic specification.[9]

Steel can wall thicknesses are now[when?] 30% thinner and weigh 40% less than 30 years ago, reducing the amounts of raw materials and energy required to make them. They are also up to 40% thinner than aluminium.[24]

Magnetic properties

Steel is a ferrous metal and is therefore magnetic. For beverage packaging this is unique. This allows the use of magnetic conveyor systems[25] to transfer empty cans through the filling and packing processes, increasing accuracy and reducing potential spillage and waste.[26] In recycling facilities, steel cans may be readily separated from other waste using magnetic equipment including cross-belt separators, also known as overband magnets, and drum magnets.[27]

Opening cans

The first cans were heavy-weight containers that required ingenuity to open, with implements such as knives. Not until several years later, after can manufacturers started using thinner metal sheets, were any dedicated can openers developed.

While beverage cans or cans of fluid such as broth can merely be punctured to remove the product, solid or semisolid contents require removing one end of the can. This can be accomplished with a heavy knife or other sharp tool—but can openers are much more convenient.

Some cans, such as those used for sardines, have a specially scored lid so that the user can break out the metal by the leverage of winding it around a slotted twist-key or church key. Until the mid-20th century, some sardine tins had solder-attached lids, and the twist-key or church key worked by forcing the solder joint apart.

The advent of pull tabs in beverage cans spread to the canning of various food products, such as pet food or nuts (and non-food products such as motor oil and tennis balls). The ends are known as easy open lids because they open without any tools or implements.[28] An additional innovation developed for specifically for food cans uses a tab that is bent slightly upwards, creating a larger surface area for easier finger access.[29]

Cans can be made with easy open features. Some cans have screw caps for pouring liquids and resealing. Some have hinged covers or slip-on covers for easy access. Paint cans often have a removable plug on the top for access and for reclosing.

  • Mechanism of a can opener

  • Can that requires a can opener

  • Soup can with a ring-pull tab

  • Opened can with a ring-pull tab

  • Keyed side opening

  • Easy open sardine can

  • Stay-on tab

Recycling and re-use

Steel from cans and other sources is the most recycled packaging material.[8] Around 65% of steel cans are recycled.[2] In the United States, 63% of steel cans are recycled, compared to 52% of aluminium cans.[30] In Europe, the recycling rate in 2016 is 79.5%.[8] Most can recycling occurs at the smelters, but individual consumers also directly reuse cans in various ways. For instance some people use two tin cans to form a camp or survival stove to cook small meals.[citation needed]

Food tin cans reused for art and storage

Sustainability and recycling of steel beverage cans

Steel recycling

Spike Jones with tin cans in the background .

From an ecological perspective, steel may be regarded as a closed-loop material: post-consumer waste can be collected, recycled and used to make new cans or other products.[31] Each tonne of scrap steel recycled saves 1.5 tonnes of CO2, 1.4 tonnes of iron ore and 740 kg of coal. Steel is the world's most recycled material, with more than 85% of all the world's steel products being recycled at the end of their life: an estimated 630 million tonnes of steel scrap were recycled in 2017, saving 945 million tonnes of CO2.[32]

Steel can recycling

A steel can can be recycled again and again without loss of quality;[33] however, for the food grade steel it's required to remove tin from the scrap metal, which is done by way of electrochemistry: the tin is leached from a high pH solution at low negative voltage.[34]

Recycling a single can saves the equivalent power for one laundry load, 1 hour of TV or 24 hours of lighting (10W LED bulb).[35]

Steel beverage cans are recycled by being melted down in an electric arc furnace or basic oxygen furnace.[citation needed]

Most steel cans also carry some form of recycling identification such as the Metal Recycles Forever Mark [36] Recyclable Steel [37] and the Choose Steel campaign logo.[12] There is also a campaign in Europe called Every Can Counts, encouraging can recycling in the workplace [38]

Smaller carbon footprint

All beverage packaging creates CO2 emissions at every stage in the production process, from raw material extraction, processing and manufacture through to recycling. However, steel cans are an ecological top performer, as cans can always be recycled. The steel industry needs the used cans and will use them in the production of new steel product. By recycling the cans and closing the loop, CO2 emissions are dramatically reduced. There is also the potential for higher global steel recycling rates as consumers become more aware of the benefits.[citation needed]

Health issues

Dissolution of tin into the food

Tin is corrosion resistant, but acidic food like fruits and vegetables can corrode the tin layer. Nausea, vomiting, and diarrhea have been reported after ingesting canned food containing 200 mg/kg of tin.[39] A 2002 study showed that 99.5% of 1200 tested cans contained below the UK regulatory limit of 200 mg/kg of tin, an improvement over most previous studies largely attributed to the increased use of fully lacquered cans for acidic foods, and concluded that the results do not raise any long term food safety concerns for consumers. The two non-compliant products were voluntarily recalled.[40]

Evidence of tin impurities can be indicated by color, as in the case of pears, but lack of color change does not guarantee that a food is not tainted with tin.[41]

Bisphenol-A

The chemical compound Bisphenol A found in can linings "...is associated with organizational changes in the prostate, breast, testis, mammary glands, body size, brain structure and chemistry, and behavior of laboratory animals",[42] unborn children and adults.

Bisphenol-A (BPA) is a controversial chemical compound present in commercially available tin can plastic linings[43] and transferred to canned food. The inside of the can is coated with an epoxy coating, in an attempt to prevent food or beverage from coming into contact with the metal. The longer food is in a can, and the warmer and more acidic it is, the more BPA leaches into it. In September 2010, Canada became the first country to declare BPA a toxic substance.[44][45] In the European Union and Canada, BPA use is banned in baby bottles. The FDA does not regulate BPA (see BPA controversy). Several companies, like Campbell's Soup, announced plans to eliminate BPA from the linings of their cans,[43] but have not said which chemical they plan to replace it with. (See BPA controversy.)[citation needed]

See also

References

  1. ↑ Kraus, F J (2009). "Steel Cans". in Yam, K L. Encyclopedia of Packaging Technology. Wiley. pp. 205–216. ISBN 978-0-470-08704-6. https://archive.org/details/wileyencyclopedi00yamk. 
  2. ↑ 2.0 2.1 "64.9% of steel cans are recycled". worldsteel.org. 10 January 2007. http://www.worldsteel.org/?action=newsdetail&latest=1&id=181. 
  3. ↑ Robertson, Gordon L (2016). Food packaging (3rd ed.). CRC Press. p. 123. 
  4. ↑ Geoghegan, Tom (2013-04-21). "BBC News – The story of how the tin can nearly wasn't". Bbc.co.uk. https://www.bbc.co.uk/news/magazine-21689069. 
  5. ↑ American Can Company: Revolution in Containers , Excerpts of William C. Stolk; Address of The Newcomen Society of North America, April 21, 1960 – Printed July 1960, from oilcans.net, retrieved 16 July 2010
  6. ↑ 6.0 6.1 Reutter, Mark (1988). Sparrows Point: Making Steel—the Rise and Ruin of American Industrial Might. University of Illinois Press. ISBN 9780671553357. https://books.google.com/books?id=bdkUfDoY24QC. 
  7. ↑ Soroka (2002) Fundamentals of Packaging Technology, Institute of Packaging Professionals ISBN:1-930268-25-4
  8. ↑ 8.0 8.1 8.2 8.3 8.4 "APEAL – Steel for packaging: cans, Home, Food, Beverage, Aerosol, Paint, and Specialty cans". apeal.org. http://www.apeal.org/index.php. 
  9. ↑ 9.0 9.1 9.2 "Beverage | Tata Steel in Europe". https://www.tatasteeleurope.com/en/markets/packaging/beverage. 
  10. ↑ 10.0 10.1 "Steel For Packaging – Home" (in en). http://www.steelforpackaging.org/. 
  11. ↑ "Does a Drink Stay Colder in a Metal Can or a Plastic Bottle?" (in en). https://sciencing.com/drink-metal-can-plastic-bottle-5518851.html. 
  12. ↑ 12.0 12.1 "Home" (in en). http://www.votesteel.com. 
  13. ↑ 13.0 13.1 Soroka, W. Illustrated Glossary of Packaging Terminology (Second ed.). Institute of Packaging Professionals. http://www.iopp.org/i4a/pages/Index.cfm?pageID=1. 
  14. ↑ Hertzberg, Ruth; Greene, Janet; Vaughan, Beatrice (2010-05-25) (in en-US). Putting Food By: Fifth Edition. Penguin. ISBN 9781101539903. https://books.google.com/books?id=4Ikg0vIlGHMC&q=No+cans+currently+in+wide+use+are+made+of+tin&pg=PT61. 
  15. ↑ Petroleum week , Volume 9, 1959, p. 82 (Google Books)
  16. ↑ PUZO, DANIEL P. (29 April 1993). "Lead in Cans: Still a Problem, Still Preventable". Los Angeles Times. http://articles.latimes.com/1993-04-29/food/fo-28432_1_blood-lead-levels. 
  17. ↑ Code of Federal Regulations. United States of America. April 1, 2017. pp. 21CFR189.240. https://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr=189.240. Retrieved 29 August 2018. 
  18. ↑ Hickman, Martin (2010-04-01). "Revealed: the nasty secret in your kitchen cupboard". The Independent (London). https://www.independent.co.uk/life-style/food-and-drink/news/revealed-the-nasty-secret-in-your-kitchen-cupboard-1932742.html. 
  19. ↑ "Are Cans BPA-Free in the UK?". Food Standards Agency. 2018-10-26. https://www.food.gov.uk/safety-hygiene/bpa-in-plastic. 
  20. ↑ "Can standards". cancentral.com. http://www.cancentral.com/standard.cfm. 
  21. ↑ 21.0 21.1 "Steel packaging" (in en). https://www.worldsteel.org/steel-by-topic/steel-markets/food-and-water/steel-packaging.html. [yes|permanent dead link|dead link}}]
  22. ↑ "Tinning" (in en), Wikipedia, 2018-03-03, https://en.wikipedia.org/w/index.php?title=Tinning&oldid=828613739, retrieved 2018-07-09 
  23. ↑ "Beverage can" (in en), Wikipedia, 2018-07-01, https://en.wikipedia.org/w/index.php?title=Beverage_can&oldid=848402943, retrieved 2018-07-09 
  24. ↑ "Steel Cans – Developments in Design and Materials" (in en). 2002-10-11. https://www.azom.com/article.aspx?ArticleID=1693. 
  25. ↑ "Magnets for transport of aerosol cans and tins". Goudsmit Magnetics. https://www.goudsmitmagnets.com/industrial-magnetic-systems/magnetic-handling/magnets-for-transport-of-cans. 
  26. ↑ "How cans are filled" (in en-US). The Can Makers. http://www.canmakers.co.uk/education/how-cans-are-filled. 
  27. ↑ "Recycling" (in en). 15 March 2018. http://www.buntingeurope.com/magnetic_separation_and_metal_detection/industrial_applications/recycling.aspx. 
  28. ↑ "The Canmaker". canmaker.com. http://www.canmaker.com/news/index.php/home/faqs. 
  29. ↑ Jing Han (1 August 2005). "Ergonomics designs of aluminum beverage cans & bottles". ResearchGate. https://www.researchgate.net/publication/36427590. 
  30. ↑ "Recyclings FAQ". cancentral.com. http://www.cancentral.com/recFAQ.cfm. 
  31. ↑ "The sustainable material | Tata Steel in Europe". https://www.tatasteeleurope.com/en/sustainability/steel%E2%80%93for%E2%80%93a%E2%80%93sustainable%E2%80%93future/sustainable-material. 
  32. ↑ "Blog: steel – the surprising recycling champion" (in en). https://www.worldsteel.org/media-centre/blog/2018/blog-steel-surprising-recycling-champion.html. 
  33. ↑ "Steel – the Permanent Material in the Circular Economy" (in en). https://www.worldsteel.org/media-centre/press-releases/2016/steel-permanent-material-circular-economy.html. 
  34. ↑ "Tin can processing: Leaching and electrolysis of tin from steel cans". United Kingdom: Cambridge University. 2008. https://www.doitpoms.ac.uk/tlplib/recycling-metals/tin_cans.php. 
  35. ↑ "Circular Economy" (in en). http://circulareconomy-worldsteel.org/. 
  36. ↑ "Recycles Mark | Metal Packaging Europe" (in en). http://www.metalpackagingeurope.org/recyclesmark. 
  37. ↑ "Archived copy". http://www.canzbac.co.nz/images/RecyclingGuideforSteelFillers2006.pdf. 
  38. ↑ "Every Can Counts – Who we are" (in en-GB). Every Can Counts. https://www.everycancounts.co.uk/who-we-are/. 
  39. ↑ Blunden, Steve; Wallace, Tony (2003). "Tin in canned food: a review and understanding of occurrence and effect". Food and Chemical Toxicology 41 (12): 1651–1662. doi:10.1016/S0278-6915(03)00217-5. PMID 14563390. 
  40. ↑ "Tin in canned fruit and vegetables (Number 29/02)". Food Standards Agency. 2002-08-22. http://www.food.gov.uk/multimedia/pdfs/fsis2902tin.pdf. 
  41. ↑ Chandler, BV; Clegg, K Marry (1970). "Pink discoloration in canned pears I.—Role of tin in pigment formation". Journal of the Science of Food and Agriculture 21 (6): 315. doi:10.1002/jsfa.2740210612. Bibcode: 1970JSFA...21..315C. 
  42. ↑ Vogel, S. (2009). "The Politics of Plastics: The Making and Unmaking of Bisphenol A 'Safety'" . American Journal of Public Health 99 (S3): 559–566.
  43. ↑ 43.0 43.1 "Campbells Eliminating BPA in Soup Cans". www.torontosun.com. http://www.torontosun.com/2012/03/08/campbells-eliminating-bpa-in-soup-cans. 
  44. ↑ "Regulatory Impact Analysis Statement" (in en). Canada Gazette Part II 144 (21): 1806–18. 13 October 2010. Archived from the original on 18 March 2012. https://web.archive.org/web/20120318200617/http://www.gazette.gc.ca/rp-pr/p2/2010/2010-10-13/pdf/g2-14421.pdf. Retrieved 14 July 2023. 
  45. ↑ Martin Mittelstaedt (13 October 2010). "Canada first to declare bisphenol A toxic". Globe and Mail (Canada). Archived from the original on 2 January 2012. https://web.archive.org/web/20120102154838/http://www.theglobeandmail.com/news/national/canada-first-to-declare-bisphenol-a-toxic/article1755272/. 

General references, further reading

External links



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