Hafnium, 72 Hf Hafnium Pronunciation (HAF -nee-əm ) Appearance steel gray Standard atomic weight A r, std (Hf) 178.486(6)[1] Hafnium in the periodic table
Atomic number (Z ) 72 Group group 4 Period period 6 Block d-block Element category d-block Electron configuration [Xe ] 4f14 5d2 6s2 Electrons per shell 2, 8, 18, 32, 10, 2 Physical properties Phase at STP solid Melting point 2506 K (2233 °C, 4051 °F) Boiling point 4876 K (4603 °C, 8317 °F) Density (near r.t. ) 13.31 g/cm3 when liquid (at m.p. ) 12 g/cm3 Heat of fusion 27.2 kJ/mol Heat of vaporization 648 kJ/mol Molar heat capacity 25.73 J/(mol·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
2689
2954
3277
3679
4194
4876
Atomic properties Oxidation states −2, 0, +1, +2, +3, +4 (an amphoteric oxide) Electronegativity Pauling scale: 1.3 Ionization energies 1st: 658.5 kJ/mol 2nd: 1440 kJ/mol 3rd: 2250 kJ/mol Atomic radius empirical: 159 pm Covalent radius 175±10 pm Spectral lines of hafniumOther properties Natural occurrence primordial Crystal structure hexagonal close-packed (hcp) Speed of sound thin rod 3010 m/s (at 20 °C) Thermal expansion 5.9 µm/(m·K) (at 25 °C) Thermal conductivity 23.0 W/(m·K) Electrical resistivity 331 nΩ·m (at 20 °C) Magnetic ordering paramagnetic [2] Magnetic susceptibility +75.0·10−6 cm3 /mol (at 298 K)[3] Young's modulus 78 GPa Shear modulus 30 GPa Bulk modulus 110 GPa Poisson ratio 0.37 Mohs hardness 5.5 Vickers hardness 1520–2060 MPa Brinell hardness 1450–2100 MPa CAS Number 7440-58-6 History Naming after Hafnia . Latin for: Copenhagen , where it was discovered Prediction Dmitri Mendeleev (1869) Discovery and first isolationDirk Coster and George de Hevesy (1922)Main isotopes of hafnium
Category: Hafnium view · talk · edit
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Hf
data m.p. cat
C
2233
—
—
K
2506
2506
0
F
4051
4051
0
max precision
0
WD
input
C: 2233, K: 2506, F: 4051
comment
Hf
data b.p. cat
C
4603
—
—
K
4876
4876
0
F
8317
8317
0
max precision
0
WD
input
C: 4603, K: 4876, F: 8317
comment
References
These references will appear in the article, but this list appears only on this page.
↑ Meija, Juris; Coplen, Tyler B.; Berglund, Michael; Brand, Willi A.; De Bièvre, Paul; Gröning, Manfred; Holden, Norman E.; Irrgeher, Johanna et al . (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry 88 (3): 265–91. doi :10.1515/pac-2015-0305 .
↑ Lide, D. R., ed (2005). "Magnetic susceptibility of the elements and inorganic compounds" . CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5 . https://web.archive.org/web/20110303222309/http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf .
↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics . Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4 .
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