Template:Infobox samarium

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Samarium, 62Sm
Samarium-2.jpg
Samarium
Pronunciation/səˈmɛəriəm/ (sə-MAIR-ee-əm)
Appearancesilvery white
Standard atomic weight Ar, std(Sm)150.36(2)[1]
Samarium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson


Sm

Pu
promethiumsamariumeuropium
Atomic number (Z)62
Groupgroup n/a
Periodperiod 6
Block  f-block
Element category  f-block
Electron configuration[Xe] 4f6 6s2
Electrons per shell2, 8, 18, 24, 8, 2
Physical properties
Phase at STPsolid
Melting point1345 K ​(1072 °C, ​1962 °F)
Boiling point2173 K ​(1900 °C, ​3452 °F)
Density (near r.t.)7.52 g/cm3
when liquid (at m.p.)7.16 g/cm3
Heat of fusion8.62 kJ/mol
Heat of vaporization192 kJ/mol
Molar heat capacity29.54 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1001 1106 1240 (1421) (1675) (2061)
Atomic properties
Oxidation states0,[2] +2, +3 (a mildly basic oxide)
ElectronegativityPauling scale: 1.17
Ionization energies
  • 1st: 544.5 kJ/mol
  • 2nd: 1070 kJ/mol
  • 3rd: 2260 kJ/mol
Atomic radiusempirical: 180 pm
Covalent radius198±8 pm
Color lines in a spectral range
Spectral lines of samarium
Other properties
Natural occurrenceprimordial
Crystal structurerhombohedral
Rhombohedral crystal structure for samarium
Speed of sound thin rod2130 m/s (at 20 °C)
Thermal expansion(r.t.) (α, poly) 12.7 µm/(m·K)
Thermal conductivity13.3 W/(m·K)
Electrical resistivity(r.t.) (α, poly) 0.940 µΩ·m
Magnetic orderingparamagnetic[3]
Magnetic susceptibility+1860.0·10−6 cm3/mol (291 K)[4]
Young's modulusα form: 49.7 GPa
Shear modulusα form: 19.5 GPa
Bulk modulusα form: 37.8 GPa
Poisson ratioα form: 0.274
Vickers hardness410–440 MPa
Brinell hardness440–600 MPa
CAS Number7440-19-9
History
Namingafter the mineral samarskite (itself named after Vassili Samarsky-Bykhovets)
Discovery and first isolationLecoq de Boisbaudran (1879)
Main isotopes of samarium
Iso­tope Abun­dance Physics:Half-life (t1/2) Decay mode Pro­duct
144Sm 3.08% stable
145Sm syn 340 d ε 145Pm
146Sm syn 6.8×107 y α 142Nd
147Sm 15.00% 1.06×1011 y α 143Nd
148Sm 11.25% 7×1015 y α 144Nd
149Sm 13.82% stable
150Sm 7.37% stable
151Sm syn 90 y β 151Eu
152Sm 26.74% stable
153Sm syn 46.284 h β 153Eu
154Sm 22.74% stable
Category Category: Samarium
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Sm
data m.p. cat
in calc from C diff report ref
C 1072
K 1345 1345 0
F 1962 1962 0
max precision 0
WD


input C: 1072, K: 1345, F: 1962
comment
Sm
data b.p. cat
in calc from C diff report ref
C 1900
K 2173 2170 3 delta
F 3452 3450 2 delta
max precision 0
WD


input C: 1900, K: 2173, F: 3452
comment
[]  Data sets read by {{Infobox element}}
Name and identifiers
Top image (caption, alt)
Pronunciation
Category (enwiki)
Standard atomic weight
  most stable isotope
Natural occurrence
Phase at STP
Chemistry:Oxidation states
Spectral lines image
Physics:Electron configuration (cmt, ref)
Term symbol * (cmt, ref)
Wikidata *
* Not used in {{Infobox element}} (2019-02-03)
See also {{Infobox element/symbol-to--navbox}}

References

  1. Meija, Juris; Coplen, Tyler B.; Berglund, Michael; Brand, Willi A.; De Bièvre, Paul; Gröning, Manfred; Holden, Norman E.; Irrgeher, Johanna et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry 88 (3): 265–91. doi:10.1515/pac-2015-0305. 
  2. Yttrium and all lanthanides except Ce and Pm have been observed in the oxidation state 0 in bis(1,3,5-tri-t-butylbenzene) complexes, see Cloke, F. Geoffrey N. (1993). "Zero Oxidation State Compounds of Scandium, Yttrium, and the Lanthanides". Chem. Soc. Rev. 22: 17–24. doi:10.1039/CS9932200017.  and Arnold, Polly L.; Petrukhina, Marina A.; Bochenkov, Vladimir E.; Shabatina, Tatyana I.; Zagorskii, Vyacheslav V.; Cloke (2003-12-15). "Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation". Journal of Organometallic Chemistry 688 (1–2): 49–55. doi:10.1016/j.jorganchem.2003.08.028. 
  3. Lide, D. R., ed (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5. https://web.archive.org/web/20110303222309/http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf. 
  4. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4. 

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