Chemistry:Iodate nitrate
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Iodate nitrates are mixed anion compounds that contain both iodate and nitrate anions.
Giant birefringence
Iodate nitrates can have high birefringence. The scandium salt has a giant birefringence of 0.348 at 546 nm. When discovered in 2021 it was a record high birefringence for oxyanion compounds, but it was exceeded by CeF2(SO4) just a month later with a value of 0.361[1] and sodium hydrogen squarate hydrate, NaHC4O4·H2O with a value of 0.52 at 1064 nm.[2] All of these are beaten by hexagonal boron nitride (h-BN) with birefringence of 0.7 in visible light.[3]
List
formula | name | formula
weight |
system | space group | cell Å | volume | density | comments | ref |
---|---|---|---|---|---|---|---|---|---|
Al(IO3)2NO3•6H2O | aluminium diiodate nitrate hexahydrate | hexagonal | P321 | a=6.764 c=8.09 Z=1 | [4] | ||||
KIO3•KNO3•2HIO3 | dipotassium dihydrogen triiodate nitrate | orthorhombic | P212121 | a=7.109 b=10.638 c=15.5 | [5] | ||||
Sc(IO3)2(NO3) | scandium diiodate nitrate | 1370.31 | trigonal | R32 | a=5.3536 c=23.567 Z=1 | 584.96 | 3.890 | colourless; giant birefringence 0.348 at 546 nm; SHG 4.0×KDP; UV edge 298 nm; stable to 360°C | [6] |
In(IO3)2(NO3) | indium diiodate nitrate | 526.63 | trigonal | R32 | a=5.2165 c=24.195, γ=120° Z=3 | 570.2 | 4.601 | colourless | [7] |
[In(IO3)(OH)(H2O)](NO3) | 386.75 | monoclinic | P21/n | a=5.5756 b=16.410 c=7.734, β=109.95 Z=4 | 665.2 | 3.862 | colourless | [7] | |
La(IO3)2(NO3) | lanthanum diiodate nitrate | trigonal | P3121 | a=7.1002 c=38.177 Z=9 | SHG 0.6 × KDP; band gap 4.23 eV | [8] | |||
Ce(IO3)2(NO3) | cerium diiodate nitrate | 551.93 | trigonal | P3121 | a=7.0537 c=37.972 Z=9 | 1639.8 | 5.030 | SHG 1 × KDP | [9] |
α-Th(IO3)2(NO3)(OH) | triclinic | P1 | a=6.9581 b=7.2294 c=9.8989 α=68.896° β=88.759° γ=66.620° | [10] | |||||
β-Th(IO3)2(NO3)(OH) | orthorhombic | Pbca | a=7.1459 b=14.140 c=16.612 | [10] |
References
- ↑ Wu, Chao; Wu, Tianhui; Jiang, Xingxing; Wang, Zujian; Sha, Hongyuan; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng et al. (2021-03-24). "Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4 ) Induced by Highly Polarizable Polyhedra" (in en). Journal of the American Chemical Society 143 (11): 4138–4142. doi:10.1021/jacs.1c00416. ISSN 0002-7863. PMID 33625206. https://pubs.acs.org/doi/10.1021/jacs.1c00416.
- ↑ Zhang, Xiaodong; Cao, Dongxu; Yang, Daqing; Wang, Ying; Wu, Kui; Lee, Ming-Hsien; Zhang, Bingbing (2022-04-04). "Finding the First Squarates Nonlinear Optical Crystal NaHC 4 O 4 ·H 2 O with Strong Second Harmonic Generation and Giant Birefringence" (in en). ACS Materials Letters 4 (4): 572–576. doi:10.1021/acsmaterialslett.2c00114. ISSN 2639-4979. https://pubs.acs.org/doi/10.1021/acsmaterialslett.2c00114.
- ↑ Segura, A.; Artús, L.; Cuscó, R.; Taniguchi, T.; Cassabois, G.; Gil, B. (6 February 2018). "Natural optical anisotropy of h-BN: Highest giant birefringence in a bulk crystal through the mid-infrared to ultraviolet range". Physical Review Materials 2 (2): 024001. doi:10.1103/PhysRevMaterials.2.024001.
- ↑ Cradwick, Peter D.; de Endredy, Andrew S. (1975). "Crystal structure of aluminium iodate nitrate hexahydrate" (in en). Journal of the Chemical Society, Dalton Transactions (19): 1926–1929. doi:10.1039/dt9750001926. ISSN 0300-9246. http://xlink.rsc.org/?DOI=dt9750001926.
- ↑ Kalinin, V.R.; Ilyukhin, V.V.; Belov, N.V. (1978). "Crystal structure of acid mixed potassium iodate-nitrate KIO3xKNO3x2HIO3" (in Russian). Doklady Akademii Nauk SSSR 239 (6). https://inis.iaea.org/search/search.aspx?orig_q=RN:10454338.
- ↑ Wu, Chao; Jiang, Xingxing; Wang, Zujian; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G. et al. (2021-02-15). "Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )" (in en). Angewandte Chemie International Edition 60 (7): 3464–3468. doi:10.1002/anie.202012456. ISSN 1433-7851. PMID 33146456. https://onlinelibrary.wiley.com/doi/10.1002/anie.202012456.
- ↑ 7.0 7.1 Huang, Yu; Jiang, Ting-kun; Yang, Bing-Ping; Hu, Chun-Li; Fang, Zhi; Mao, Jiang-Gao (2022-02-14). "Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements" (in en). Inorganic Chemistry 61 (8): 3374–3378. doi:10.1021/acs.inorgchem.2c00079. ISSN 0020-1669. PMID 35156368. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00079.
- ↑ Mao, Fei-Fei; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2017-11-20). "Acentric La 3 (IO 3 ) 8 (OH) and La(IO 3 ) 2 (NO 3 ): Partial Substitution of Iodate Anions in La(IO 3 ) 3 by Hydroxide or Nitrate Anion" (in en). Inorganic Chemistry 56 (22): 14357–14365. doi:10.1021/acs.inorgchem.7b02508. ISSN 0020-1669. PMID 29120615. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02508.
- ↑ Ma, Nan; Huang, Yu; Hu, Chun-Li; Zhang, Ming-Zhi; Li, Bing-Xuan; Mao, Jiang-Gao (2023-09-07). "Ce(IO 3 ) 3 F and Ce(IO 3 ) 2 (NO 3 ): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties" (in en). Inorganic Chemistry 62 (37): 15329–15333. doi:10.1021/acs.inorgchem.3c02651. ISSN 0020-1669. PMID 37677152. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c02651.
- ↑ 10.0 10.1 Wang, Yaxing; Duan, Tao; Weng, Zhehui; Ling, Jie; Yin, Xuemiao; Chen, Lanhua; Sheng, Daopeng; Diwu, Juan et al. (2017-11-06). "Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds" (in en). Inorganic Chemistry 56 (21): 13041–13050. doi:10.1021/acs.inorgchem.7b01855. ISSN 0020-1669. PMID 28991439. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01855.
Salts and covalent derivatives of the nitrate ion
HNO3 | He | ||||||||||||||||
LiNO3 | Be(NO3)2 | B(NO3)−4 | C | NO−3, NH4NO3 |
O | FNO3 | Ne | ||||||||||
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | ||||||||||
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3, Fe(NO3)2 |
Co(NO3)2, Co(NO3)3 |
Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | Br | Kr |
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb | Mo | Tc | Ru | Rh | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In | Sn | Sb(NO3)3 | Te | I | Xe(NO3)2 |
CsNO3 | Ba(NO3)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2(NO3)2, Hg(NO3)2 |
Tl(NO3)3, TlNO3 |
Pb(NO3)2 | Bi(NO3)3 BiO(NO3) |
Po | At | Rn | |
FrNO3 | Ra(NO3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
↓ | |||||||||||||||||
La(NO3)3 | Ce(NO3)3, Ce(NO3)4 |
Pr | Nd(NO3)3 | Pm | Sm | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy | Ho | Er | Tm | Yb | Lu | |||
Ac(NO3)3 | Th(NO3)4 | Pa | UO2(NO3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |
Original source: https://en.wikipedia.org/wiki/Iodate nitrate.
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