Chemistry:Alkoxy group

From HandWiki
Short description: Chemical group (R–O)
Alkoxy groups
Aryloxy groups

In chemistry, the alkoxy group is an alkyl group which is singularly bonded to oxygen; thus R–O. Denoted usually with apostrophe('). The range of alkoxy groups is vast, the simplest being methoxy (CH
3
O–
).[1] An ethoxy group (CH
3
CH
2
O–
) is found in the organic compound ethyl phenyl ether (C
6
H
5
OCH
2
CH
3
, also known as ethoxybenzene).

Related to alkoxy groups are aryloxy groups, which have an aryl group singularly bonded to oxygen such as the phenoxy group (C
6
H
5
O–
).

An alkoxy or aryloxy group bonded to an alkyl or aryl (R–O–R') is an ether. If bonded to H it is an alcohol.

The term alkoxide refers to the anionic conjugate bases of alcohols (RO
) or to ionic compounds containing such an anion. Alkoxide compounds are derivatives of alcohols where the hydrogen of the –OH group is replaced by a metal;[2] for example, the sodium salt of ethanol (CH
3
CH
2
OH
) is sodium ethoxide, containing ethoxide anions CH
3
CH
2
O
and sodium cations Na+
.

References