Chemistry:Barium acetylacetonate

From HandWiki
Barium acetylacetonate
Names
IUPAC name
Barium(2+); (Z)-4-oxopent-2-en-2-olate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 235-151-3
Properties
C10H14BaO4
Molar mass 335.545 g·mol−1
Appearance White solid
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H302, H332
P261, P264, P270, P271, P301+312, P304+312, P304+340, P312, P330, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Barium acetylacetonate is a compound with formula Ba(C5H7O2)2. It is the Ba2+ complex of the anion acetylacetonate. The compound is typically encountered as an ill-defined hydrate, which would accord with the high coordination number characteristic of barium.[1][2]

Uses

thumb|left|Structure of gaseous barium acetylacetonate.

Barium acetylacetonate has been examined in metal organic chemical vapour deposition of BaTiO3 thin films.[3] The related complex with hexafluoroacetylacetonate Ba(hfa)2(tetraglyme) has also been investigated. Its formation of a sublimable adduct containing a polyether illustrates the high coordination numbers typical of barium.[4]

References

  1. Paw, Witold; Baum, Thomas H.; Lam, Kin-Chung; Rheingold, Arnold L. (2000). "Low-Melting, Mononuclear Tetrahydrofuran Complexes of M(2,2,6,6-tetramethylheptane-3,5-dionate)2 (M = Ba, Sr) and Related Analogues". Inorganic Chemistry 39 (9): 2011–2014. doi:10.1021/ic990641z. PMID 11428125. 
  2. Rossetto, G.; Polo, A.; Benetollo, F.; Porchia, M.; Zanella, P. (1992). "Studies on molecular barium precursors for MOCVD: Synthesis and characterization of barium 2,2,6,6-tetramethyl-3,5-heptanedionate. X-ray crystal structure of [Ba(THD)2·Et2O]2". Polyhedron 11 (8): 979–985. doi:10.1016/S0277-5387(00)83351-3. 
  3. Lee, C. H.; Park, S. J. (1990-12-01). "Preparation of ferroelectric BaTiO3 thin films by metal organic chemical vapour deposition". Journal of Materials Science: Materials in Electronics 1 (4): 219–224. doi:10.1007/BF00696081. 
  4. Schulz, Douglas L.; Neumayer, Deborah A.; Marks, Tobin J. (1997). "Volatile β-Diketonate Complexes of Calcium(II), Strontium(II), and Barium(II)". Inorganic Syntheses 31: 1–7. doi:10.1002/9780470132623.ch1. ISBN 9780470132623.