Chemistry:Borate sulfate
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Short description: Mixed anion compound containing separate borate and sulfate anions
Borate sulfates are mixed anion compounds containing separate borate and sulfate anions. They are distinct from the borosulfates where the borate is linked to a sulfate via a common oxygen atom.
List
| chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references | |
|---|---|---|---|---|---|---|---|---|---|
| sulfoborite | Mg3(OH)[B(OH)4]2(SO4)F | orthorhombic | Pnma | a=10.132 b=12.537 c=7.775 | 987.6 | Biaxial (-) nα = 1.527 nβ = 1.536 nγ = 1.551
2V 79° Max birefringence δ = 0.024 |
[1] | ||
| Heidornite | Na2Ca3B5O8(OH)2(SO4)2Cl | monoclinic | C2/c | a = 10.19, b = 7.76, c = 18.81
β = 93.33° Z=4 |
1,485 | 2.753 | Biaxial (+) nα = 1.579 nβ = 1.588 nγ = 1.604
2V 63° to 77° Max birefringence δ = 0.025 |
[2] | |
| Charlesite | Ca6Al(SO4)2B(OH)4(O,OH)12•26H2O | trigonal | P31c | a = 11.161, c = 21.212 | 2,288 | 1.77 | Uniaxial (-) nω = 1.492(3) nε = 1.475(3)
Max birefringence δ = 0.017 |
[3] | |
| Vitimite | Ca6B14O19(SO4)(OH)14•5H2O | monoclinic | P2/m | a = 14.10, b = 19.53, c = 14.05 β = 120.39°=4 | 3,337 | Biaxial (-) nα = 1.532(3) nβ = 1.537(1) nγ = 1.540(1)
Max birefringence δ = 0.008 |
[4] | ||
| Harkerite | Ca12Mg4Al(BO3)3(SiO4)4(CO3)5 · H2O | trigonal | R3m | a = 18.131 Å α = 33.46° | 1,614 | Uniaxial nα = 1.649 - 1.653 nβ = 1.649 - 1.653 | [5] | ||
| Tatarinovite | Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O | Hexagonal | P63 | a = 11.1110, c = 10.6294 | 1,136 | 1.79 | colourless
Uniaxial (+) nω = 1.475 nε = 1.496 Max birefringence δ = 0.021 |
[6] | |
| Sturmanite | Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12•25H2O | trigonal | P31c | a = 11.16, c = 21.79 Z=2 | 2,350 | yellow
Uniaxial (+/-) nω = 1.499 - 1.500 nε = 1.497 - 1.505 Max birefringence δ = 0.002 |
[7] | ||
| [Ni(atta)(SO4)0.5]·[B5O6(OH)4] | 514.13 | monoclinic | P21/c | a=9.0512 b=15.2776 c =15.0142, β=90.325° Z=4 | 2076.14 | 1.645 | [8] | ||
| Buryatite | Ca3(Si,Fe,Al)(SO4)[B(OH)4]O(OH)5 · 12H2O | trigonal | P31c | a = 11.14, c = 20.99 Z=4 | 2,256 | 1.89 | Uniaxial (-) nω = 1.523(3) nε = 1.532(3)
Max birefringence δ = 0.009 |
[9] | |
| Rb3H(SO4)2(B2O3)2 | hexagonal | P63/m | a = 6.502, c = 19.02 Z=2 | 2.803 | [10] | ||||
| Fontarnauite | Na2Sr(SO4)B5O8(OH)•2H2O | monoclinic | P21/c | a=6.458 b=22.299 c=8.571 β=103.05 Z=4 | 1,203 | [11] | |||
| Y(SO4)[B(OH)4](H2O)·H2O | triclinic | P1 | a=5.9679 b=6.8559 c=10.1698 α=79.608 β=76.673 γ=89.220 Z=2 | 398.02 | 2.502 | [12] | |||
| Cs3H(SO4)2(B2O3)2 | hexagonal | P63/m | a = 6.5648, c = 19.5669 Z = 2 | 3.322 | [10] | ||||
| La(SO4)[B(OH)4](H2O) | 331.83 | triclinic | P1 | a=6.2808 b=6.8321 c=8.6830 α=82.475 β=76.758 γ=87.300 Z=2 | 359.51 | 3.065 | [12] | ||
| Pr(SO4)[B(OH)4](H2O)2 | 351.84 | monoclinic | P21/m | a=6.2359 b=9.5542 c=6.8236 β=93.852 Z=2 | 405.64 | 2.881 | [12] | ||
| Nd(SO4)[B(OH)4](H2O)2 | 355.17 | monoclinic | P21/m | a=6.2119 b=9.5328 c=6.7923 β=93.755 Z=2 | 401.35 | 2.939 | [12] | ||
| Sm(SO4)[B(OH)4](H2O) | 343.27 | triclinic | P1 | a=6.1467 b=6.7280 c=8.6068 α=81.769 β=76.653 γ=87.259 Z=2 | 342.71 | 3.326 | [12] | ||
| Sm(SO4)[B(OH)4](H2O)2 | 361.30 | monoclinic | P21/m | a=6.1601 b=9.5416 c=6.7589 β=93.816 Z=2 | 396.39 | 3.027 | [12] | ||
| Eu(SO4)[B(OH)4](H2O) | 344.88 | triclinic | P1 | a=6.1205 b=6.7090 c=8.5844 α=81.713 β=76.680 γ=87.294 Z=2 | 339.40 | 3.375 | [12] | ||
| Eu(SO4)[B(OH)4](H2O)2 | 362.89 | monoclinic | P21/m | a=6.1322 b=9.5139 c=6.7343 β=93.683 Z=2 | 392.08 | 3.074 | [12] | ||
| Gd(SO4)[B(OH)4](H2O)2 | 368.19 | monoclinic | P21/m | a=6.1148 b=9.5078 c=6.7164 β=93.611 Z=2 | 389.70 | 3.138 | [12] | ||
| Tb(SO4)[B(OH)4](H2O)·H2O | 369.87 | triclinic | P1 | a=6.0139 b=6.8972 c=10.1753 α=79.616 β=76.590 γ=89.106 Z=2 | 403.42 | 3.045 | [12] | ||
| Dy(SO4)[B(OH)4](H2O)·H2O | 373.43 | triclinic | P1 | a=5.9880 b=6.8728 c=10.1638 α=79.652 β=76.597 γ=89.153 Z=2 | 400.12 | 3.100 | [12] | ||
| Ho(SO4)[B(OH)4](H2O)·H2O | 375.86 | triclinic | P1 | a=5.9701 b=6.8570 c=10.1580 α=79.588 β=76.636 γ=89.193 Z=2 | 397.75 | 3.138 | [12] | ||
| Er(SO4)[B(OH)4](H2O)·H2O | 378.19 | triclinic | P1 | a=5.9529 b=6.8401 c=10.1553 α=79.598 β=76.642 γ=89.198 Z=2 | 395.54 | 3.175 | [12] | ||
| Tm(SO4)[B(OH)4](H2O)·H2O | 379.86 | triclinic | P1 | a=5.9289 b=6.8232 c=10.1422 α=79.531 β=76.663 γ=89.263 Z=2 | 392.40 | 3.215 | [12] | ||
| Yb(SO4)[B(OH)4](H2O)·H2O | 383.97 | triclinic | P1 | a=5.9150 b=6.8090 c=10.1454 α=79.541 β=76.669 γ=89.243 Z=2 | 390.82 | 3.263 | [12] | ||
| Lu(SO4)[B(OH)4](H2O)·H2O | 385.91 | triclinic | P1 | a=5.8992 b=6.7954 c=10.1322 α=79.551 β=76.691 γ=89.266 Z=2 | 388.53 | 3.299 | [12] | ||
| Pb2[(BO2)(OH)](SO4) | 570.26 | monoclinic | P21/m | a=6.982 b=5.3917 c=8.167 β=98.643° | 303.9 | 6.231 | decompose 335 °C; band gap 4.08 | [13] | |
| Pb4(BO3)2(SO4) | 1042.44 | monoclinic | P21/c | a=6.9363 b=15.8784 c=9.6053 β=110.770° Z=4 | 989.15 | 7.000 | melt 689 °C; band gap 4.03 eV | [13][14] |
References
- ↑ "Sulfoborite". https://www.mindat.org/min-3823.html.
- ↑ "Heidornite". https://www.mindat.org/min-1846.html.
- ↑ "Charlesite". https://www.mindat.org/min-971.html.
- ↑ "Vitimite". https://www.mindat.org/min-25601.html.
- ↑ "Harkerite". https://www.mindat.org/min-1819.html.
- ↑ "Tatarinovite". https://www.mindat.org/min-46816.html.
- ↑ "Sturmanite". https://www.mindat.org/min-3817.html.
- ↑ Li, Wei; Deng, Yan-Ling; Pan, Chun-Yang (2022-05-11). "Structural Characterization and ORR Activity of a Copper Complex Borate and an Unexpected [Ni(atta)(SO 4 ) 0.5 + Borate-Sulfate"] (in en). Inorganic Chemistry 61 (20): 7787–7793. doi:10.1021/acs.inorgchem.2c00187. ISSN 0020-1669. PMID 35543612. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00187.
- ↑ "Buryatite". https://www.mindat.org/min-11186.html.
- ↑ 10.0 10.1 Daub, Michael; Hillebrecht, Harald (September 2015). "Borosulfates Cs 2 B 2 S 3 O 13 , Rb 4 B 2 S 4 O 17 , and A 3 HB 4 S 2 O 14 ( A = Rb, Cs) - Crystalline Approximants for Vitreous B 2 O 3 ?: Borosulfates Cs 2 B 2 S 3 O 13 , Rb 4 B 2 S 4 O 17 , and A 3 HB 4 S 2 O 14 ( A = Rb, Cs)". European Journal of Inorganic Chemistry 2015 (25): 4176–4181. doi:10.1002/ejic.201500603.
- ↑ Cooper, Mark A.; Hawthorne, Frank C.; García-Veigas, Javier; Alcobé, Xavier; Helvaci, Cahit; Grew, Edward S.; Ball, Neil A. (September 2015). "Fontarnauite, (Na,K) 2 (Sr,Ca)(SO 4 )[B 5 O 8 (OH)(H 2 O) 2 , A New Sulfate-Borate Mineral From Doğanlar (Emet), Kütahya Province, Western Anatolia, Turkey"] (in en). The Canadian Mineralogist 53 (5): 803–820. doi:10.3749/canmin.1400088. ISSN 0008-4476. Bibcode: 2015CaMin..53..803C. http://www.canmin.org/lookup/doi/10.3749/canmin.1400088.
- ↑ 12.00 12.01 12.02 12.03 12.04 12.05 12.06 12.07 12.08 12.09 12.10 12.11 12.12 12.13 12.14 12.15 Wang, Wen-Wen; Xu, Xiang; Kong, Jin-Tao; Mao, Jiang-Gao (2018-01-02). "RE (SO 4 )[B(OH) 4 (H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures"] (in en). Inorganic Chemistry 57 (1): 163–174. doi:10.1021/acs.inorgchem.7b02317. ISSN 0020-1669. PMID 29240405. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02317.
- ↑ 13.0 13.1 Ruan, Ting-Ting; Wang, Wen-Wen; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (April 2018). "Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)(SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures"] (in en). Journal of Solid State Chemistry 260: 39–45. doi:10.1016/j.jssc.2018.01.013. Bibcode: 2018JSSCh.260...39R. https://linkinghub.elsevier.com/retrieve/pii/S0022459618300215.
- ↑ Xie, Huiyuan; Wang, Fu; Liao, Biru; Liao, Xiaomin; Chen, Jiayu; Yu, Yang; Hou, Seng; Fan, Xiaoyun (September 2021). "A novel double anion layered photocatalyst Pb4(BO3)2SO4 with enhanced photocatalytic performance for antibiotic degradation". Chemical Engineering Journal 429: 132344. doi:10.1016/j.cej.2021.132344. ISSN 1385-8947.
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