Chemistry:Borate sulfate
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Short description: Mixed anion compound containing separate borate and sulfate anions
Borate sulfates are mixed anion compounds containing separate borate and sulfate anions. They are distinct from the borosulfates where the borate is linked to a sulfate via a common oxygen atom.
List
| chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references | |
|---|---|---|---|---|---|---|---|---|---|
| sulfoborite | Mg 3(OH)[B(OH) 4] 2(SO 4)F |
orthorhombic | Pnma | a=10.132, b=12.537, c=7.775 | 987.6 | Biaxial (-) nα=1.527, nβ=1.536, nγ=1.551
2V 79° Max birefringence δ=0.024 |
[1] | ||
| Heidornite | Na 2Ca 3B 5O 8(OH) 2(SO 4) 2Cl |
monoclinic | C2/c | a=10.19, b=7.76, c=18.81
β=93.33° Z=4 |
1,485 | 2.753 | Biaxial (+) nα=1.579, nβ=1.588, nγ=1.604
2V 63° to 77° Max birefringence δ=0.025 |
[2] | |
| Charlesite | Ca 6Al(SO 4) 2B(OH) 4(O,OH) 12 · 26H2O |
trigonal | P31c | a = 11.161, c = 21.212 | 2,288 | 1.77 | Uniaxial (-) nω=1.492(3), nε=1.475(3)
Max birefringence δ=0.017 |
[3] | |
| Vitimite | Ca 6B 14O 19(SO 4)(OH) 14 · 5H2O |
monoclinic | P2/m | a=14.10, b=19.53, c=14.05
β=120.39° Z=4 |
3,337 | Biaxial (-) nα=1.532(3), nβ=1.537(1), nγ=1.540(1)
Max birefringence δ=0.008 |
[4] | ||
| Harkerite | Ca 12Mg 4Al(BO 3) 3(SiO 4) 4(CO 3) 5 · H2O |
trigonal | R3m | a=18.131
α=33.46° |
1,614 | Uniaxial nα=1.651±2, nβ=1.651±2 | [5] | ||
| Tatarinovite | Ca 3Al(SO 4)[B(OH) 4](OH) 6 · 12H2O |
Hexagonal | P63 | a=11.1110, c=10.6294 | 1,136 | 1.79 | colourless
Uniaxial (+) nω=1.475, nε=1.496 Max birefringence δ=0.021 |
[6] | |
| Sturmanite | Ca 6Fe3+ 2(SO 4) 2.5[B(OH) 4](OH) 12 · 25H2O |
trigonal | P31c | a=11.16, c=21.79
Z=2 |
2,350 | yellow
Uniaxial (+/-) nω=1.499-1.500, nε=1.501±4 Max birefringence δ=0.002 |
[7] | ||
| [Ni(atta)(SO 4) 0.5] · [B 5O 6(OH) 4] |
514.13 | monoclinic | P21/c | a=9.0512, b=15.2776, c=15.0142
β=90.325° Z=4 |
2076.14 | 1.645 | [8] | ||
| Buryatite | Ca 3(Si,Fe,Al)(SO 4)[B(OH 4)]O(OH) 5 · 12H2O |
trigonal | P31c | a=11.14, c=20.99
Z=4 |
2,256 | 1.89 | Uniaxial (-) nω=1.523(3), nε=1.532(3)
Max birefringence δ=0.009 |
[9] | |
| Rb 3H(SO 4) 2(B 2O 3) 2 |
hexagonal | P63/m | a=6.502, c=19.02
Z=2 |
2.803 | [10] | ||||
| Fontarnauite | Na 2Sr(SO 4)B 5O 8(OH) · 2H2O |
monoclinic | P21/c | a=6.458, b=22.299, c=8.571
β=103.05° Z=4 |
1,203 | [11] | |||
| Y(SO 4)[B(OH 4)](H 2O) · H2O |
triclinic | P1 | a=5.9679, b=6.8559, c=10.1698
α=79.608°, β=76.673°, γ=89.220° Z=2 |
398.02 | 2.502 | [12] | |||
| Cs 3H(SO 4) 2(B 2O 3) 2 |
hexagonal | P63/m | a = 6.5648, c = 19.5669
Z = 2 |
3.322 | [10] | ||||
| La(SO 4)[B(OH) 4](H 2O) |
331.83 | triclinic | P1 | a=6.2808, b=6.8321, c=8.6830
α=82.475°, β=76.758°, γ=87.300° Z=2 |
359.51 | 3.065 | [12] | ||
| La2B3O4(OH)3(SO4)2 | orthorhombic | Pna21 | a=8.3986 b=6.9230 c=19.4065 | SHG 0.1×KDP | [13] | ||||
| Pr(SO 4)[B(OH) 4](H 2O) 2 |
351.84 | monoclinic | P21/m | a=6.2359, b=9.5542, c=6.8236
β=93.852° Z=2 |
405.64 | 2.881 | [12] | ||
| Nd(SO 4)[B(OH) 4](H 2O) 2 |
355.17 | monoclinic | P21/m | a=6.2119, b=9.5328, c=6.7923
β=93.755° Z=2 |
401.35 | 2.939 | [12] | ||
| Sm(SO 4)[B(OH) 4](H 2O) |
343.27 | triclinic | P1 | a=6.1467, b=6.7280, c=8.6068
α=81.769°, β=76.653°, γ=87.259° Z=2 |
342.71 | 3.326 | [12] | ||
| Sm(SO 4)[B(OH) 4](H 2O) 2 |
361.30 | monoclinic | P21/m | a=6.1601, b=9.5416, c=6.7589
β=93.816° Z=2 |
396.39 | 3.027 | [12] | ||
| Eu(SO 4)[B(OH) 4](H 2O) |
344.88 | triclinic | P1 | a=6.1205, b=6.7090, c=8.5844
α=81.713°, β=76.680°, γ=87.294° Z=2 |
339.40 | 3.375 | [12] | ||
| Eu(SO 4)[B(OH) 4](H 2O) 2 |
362.89 | monoclinic | P21/m | a=6.1322, b=9.5139, c=6.7343
β=93.683° Z=2 |
392.08 | 3.074 | [12] | ||
| Gd(SO 4)[B(OH) 4](H 2O) 2 |
368.19 | monoclinic | P21/m | a=6.1148, b=9.5078, c=6.7164
β=93.611° Z=2 |
389.70 | 3.138 | [12] | ||
| Tb(SO 4)[B(OH) 4](H 2O) · H2O |
369.87 | triclinic | P1 | a=6.0139, b=6.8972, c=10.1753
α=79.616°, β=76.590°, γ=89.106° Z=2 |
403.42 | 3.045 | [12] | ||
| Dy(SO 4)[B(OH) 4](H 2O) · H2O |
373.43 | triclinic | P1 | a=5.9880, b=6.8728, c=10.1638
α=79.652°, β=76.597°, γ=89.153° Z=2 |
400.12 | 3.100 | [12] | ||
| Ho(SO 4)[B(OH) 4](H 2O) · H2O |
375.86 | triclinic | P1 | a=5.9701, b=6.8570, c=10.1580
α=79.588°, β=76.636°, γ=89.193° Z=2 |
397.75 | 3.138 | [12] | ||
| Er(SO 4)[B(OH) 4](H 2O) · H2O |
378.19 | triclinic | P1 | a=5.9529, b=6.8401, c=10.1553
α=79.598°, β=76.642°, γ=89.198° Z=2 |
395.54 | 3.175 | [12] | ||
| Tm(SO 4)[B(OH) 4](H 2O) · H2O |
379.86 | triclinic | P1 | a=5.9289, b=6.8232, c=10.1422
α=79.531°, β=76.663°, γ=89.263° Z=2 |
392.40 | 3.215 | [12] | ||
| Yb(SO 4)[B(OH) 4](H 2O) · H2O |
383.97 | triclinic | P1 | a=5.9150, b=6.8090, c=10.1454
α=79.541°, β=76.669°, γ=89.243° Z=2 |
390.82 | 3.263 | [12] | ||
| Lu(SO 4)[B(OH) 4](H 2O) · H2O |
385.91 | triclinic | P1 | a=5.8992, b=6.7954, c=10.1322
α=79.551°, β=76.691°, γ=89.266° Z=2 |
388.53 | 3.299 | [12] | ||
| Pb 2[(BO 2)(OH)](SO 4) |
570.26 | monoclinic | P21/m | a=6.982, b=5.3917, c=8.167
β=98.643° |
303.9 | 6.231 | decompose 335 °C (635 °F); band gap 4.08 eV | [14] | |
| Pb 4(BO 3) 2(SO 4) |
1042.44 | monoclinic | P21/c | a=6.9363, b=15.8784, c=9.6053
β=110.770° Z=4 |
989.15 | 7.000 | melt 689 °C (1,272 °F); band gap 4.03 eV | [14][15] | |
| Na 2PbB 6O 10SO 4 |
orthorhombic | Pnma | a=12.9566, b=9.9289, c=7.8800
Z=4 |
1013.7 | 3.762 | [16] | |||
| Ca 2.58Pb 0.42B 6O 11SO 4 |
monoclinic | P121/c1 | a=6.4716, b=17.2900, c=9.1455
β=90.411° Z=4 |
1023.30 | 3.423 | [16] |
References
- ↑ "Sulfoborite". https://www.mindat.org/min-3823.html.
- ↑ "Heidornite". https://www.mindat.org/min-1846.html.
- ↑ "Charlesite". https://www.mindat.org/min-971.html.
- ↑ "Vitimite". https://www.mindat.org/min-25601.html.
- ↑ "Harkerite". https://www.mindat.org/min-1819.html.
- ↑ "Tatarinovite". https://www.mindat.org/min-46816.html.
- ↑ "Sturmanite". https://www.mindat.org/min-3817.html.
- ↑ Li, Wei; Deng, Yan-Ling; Pan, Chun-Yang (2022-05-11). "Structural Characterization and ORR Activity of a Copper Complex Borate and an Unexpected [Ni(atta)(SO4)0.5 + Borate-Sulfate"] (in en). Inorganic Chemistry 61 (20): 7787–7793. doi:10.1021/acs.inorgchem.2c00187. ISSN 0020-1669. PMID 35543612. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00187.
- ↑ "Buryatite". https://www.mindat.org/min-11186.html.
- ↑ 10.0 10.1 Daub, Michael; Hillebrecht, Harald (September 2015). "Borosulfates Cs2B2S3O13, Rb4B2S4O17, and A3HB4S2O14 (A = Rb, Cs) - Crystalline Approximants for Vitreous B2O3". European Journal of Inorganic Chemistry 2015 (25): 4176–4181. doi:10.1002/ejic.201500603.
- ↑ Cooper, Mark A.; Hawthorne, Frank C.; García-Veigas, Javier; Alcobé, Xavier; Helvaci, Cahit; Grew, Edward S.; Ball, Neil A. (September 2015). "Fontarnauite, (Na,K)2(Sr,Ca)(SO4)[B5O8(OH)(H 2O)2, A New Sulfate-Borate Mineral From Doğanlar (Emet), Kütahya Province, Western Anatolia, Turkey"] (in en). The Canadian Mineralogist 53 (5): 803–820. doi:10.3749/canmin.1400088. ISSN 0008-4476. Bibcode: 2015CaMin..53..803C. http://www.canmin.org/lookup/doi/10.3749/canmin.1400088.
- ↑ 12.00 12.01 12.02 12.03 12.04 12.05 12.06 12.07 12.08 12.09 12.10 12.11 12.12 12.13 12.14 12.15 Wang, Wen-Wen; Xu, Xiang; Kong, Jin-Tao; Mao, Jiang-Gao (2018-01-02). "RE(SO4)[B(OH)4(H2O), RE(SO4)[B(OH)4](H2O)2, and RE(SO4)[B(OH)4](H2O)·H2O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures"] (in en). Inorganic Chemistry 57 (1): 163–174. doi:10.1021/acs.inorgchem.7b02317. ISSN 0020-1669. PMID 29240405. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02317.
- ↑ Yang, Hui; Wang, Ziyu; Xu, Cuixia; Lin, Yuan; Liu, Guoliang (January 2023). "La2B3O4(OH)3(SO4)2: A new rare-earth borate-sulfate with second-harmonic generation response" (in en). Journal of Solid State Chemistry 317. doi:10.1016/j.jssc.2022.123715. https://linkinghub.elsevier.com/retrieve/pii/S0022459622008404.
- ↑ 14.0 14.1 Ruan, Ting-Ting; Wang, Wen-Wen; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (April 2018). "Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)(SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures"] (in en). Journal of Solid State Chemistry 260: 39–45. doi:10.1016/j.jssc.2018.01.013. Bibcode: 2018JSSCh.260...39R. https://linkinghub.elsevier.com/retrieve/pii/S0022459618300215.
- ↑ Xie, Huiyuan; Wang, Fu; Liao, Biru; Liao, Xiaomin; Chen, Jiayu; Yu, Yang; Hou, Seng; Fan, Xiaoyun (September 2021). "A novel double anion layered photocatalyst Pb4(BO3)2SO4 with enhanced photocatalytic performance for antibiotic degradation". Chemical Engineering Journal 429. doi:10.1016/j.cej.2021.132344. ISSN 1385-8947.
- ↑ 16.0 16.1 Pei, Huan; Li, Zijian; Liu, Shaohuan; Hou, Xueling; Zhang, Fangfang (2025). "Na2PbB6O10SO4 and Ca2.58Pb0.42B6O11SO4: First Borate-Sulfates Featuring 3D Porous Borate Anionic Frameworks" (in en). Inorganic Chemistry Frontiers. doi:10.1039/D5QI00394F. ISSN 2052-1553. http://pubs.rsc.org/en/Content/ArticleLanding/2025/QI/D5QI00394F.
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