Chemistry:Erbium(III) nitrate
From HandWiki
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| Other names
Erbium trinitrate, Erbium nitrate
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3D model (JSmol)
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CompTox Dashboard (EPA)
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| Properties | |
| Er(NO3)3 | |
| Molar mass | 353.274 |
| Appearance | Pink crystals |
| Melting point | 430 °C (806 °F; 703 K) |
| Soluble | |
| Hazards | |
| GHS pictograms |   
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| GHS Signal word | Danger |
| H272, H315, H318, H319, H335 | |
| P210, P220, P221, P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P310, P312, P321, P332+313, P337+313, P362, P370+378, P403+233, P405, P501 | |
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Related compounds
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Terbium(III) nitrate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Erbium(III) nitrate is an inorganic compound, a salt of erbium and nitric acid with the chemical formula Er(NO3)3.[1][2][3] The compound forms pink crystals, readily soluble in water, also forms crystalline hydrates.[4][5]
Synthesis
Dissolving metallic erbium in nitric acid:
- [math]\displaystyle{ \mathsf{Er + 6HNO_3 \ \xrightarrow{}\ Er(NO_3)_3 + 3NO_2 + 3H_2O\uparrow } }[/math]
Dissolving erbium oxide or hydroxide in nitric acid:
- [math]\displaystyle{ \mathsf{Er(OH)_3 + 3HNO_3 \ \xrightarrow{}\ Er(NO_3)_3 + 3H_2O\uparrow } }[/math]
Reaction of nitrogen dioxide with metallic erbium:
- [math]\displaystyle{ \mathsf{Er + 3N_2O_4 \ \xrightarrow{}\ Er(NO_3)_3 + 3NO\uparrow } }[/math]
Physical properties
Erbium(III) nitrate forms pink hygroscopic crystals.
Forms crystalline hydrates of the composition [math]\ce{ Er(NO3)3*5H2O }[/math].
Both erbium(III) nitrate and its crystalline hydrate decompose on heating.
Dissolves in water and EtOH.[6]
Chemical properties
The hydrated erbium nitrate thermally decomposed to form ErONO3 and then to erbium oxide.
Applications
It is used to obtain metallic erbium and is also used as a chemical reagent.
References
- ↑ Steglich, Patrick (21 October 2020) (in en). Electromagnetic Propagation and Waveguides in Photonics and Microwave Engineering. BoD – Books on Demand. p. 42. ISBN 978-1-83968-188-2. https://books.google.com/books?id=LGwtEAAAQBAJ&dq=Erbium(III)+nitrate&pg=PA42. Retrieved 19 August 2021.
- ↑ Милешко, Леонид; Гапоненко, Николай (21 February 2020) (in ru). Основы процессов получения легированных оксидных пленок методами золь-гель технологии и анодного окисления. Litres. p. 42. ISBN 978-5-04-234580-7. https://books.google.com/books?id=x1vSDwAAQBAJ&dq=%D0%BD%D0%B8%D1%82%D1%80%D0%B0%D1%82+%D1%8D%D1%80%D0%B1%D0%B8%D0%B9&pg=PA42.
- ↑ Лидин, Ростислав; Молочко, Вадим; Андреева, Лариса (2 February 2019) (in ru). Константы неорганических веществ. Справочник. Litres. p. 37. ISBN 978-5-04-077039-7. https://books.google.com/books?id=-cQ0DwAAQBAJ&dq=%D0%BD%D0%B8%D1%82%D1%80%D0%B0%D1%82+%D1%8D%D1%80%D0%B1%D0%B8%D0%B9&pg=PA37. Retrieved 19 August 2021.
- ↑ (in en) Registry of Toxic Effects of Chemical Substances. National Institute for Occupational Safety and Health. 1987. p. 2186. https://books.google.com/books?id=gjbHG6ePMywC&dq=Erbium(III)+nitrate&pg=PA2186. Retrieved 19 August 2021.
- ↑ Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3120. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Erbium(III)+nitrate&pg=PA3120. Retrieved 19 August 2021.
- ↑ Sr, Richard J. Lewis (13 June 2008) (in en). Hazardous Chemicals Desk Reference. John Wiley & Sons. p. 591. ISBN 978-0-470-18024-2. https://books.google.com/books?id=WZeBDwAAQBAJ&dq=Erbium(III)+nitrate&pg=PA591. Retrieved 19 August 2021.
Salts and covalent derivatives of the nitrate ion
| HNO3 | He | ||||||||||||||||
| LiNO3 | Be(NO3)2 | B(NO3)−4 | C | NO−3, NH4NO3 |
O | FNO3 | Ne | ||||||||||
| NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | ||||||||||
| KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)3, Fe(NO3)2 |
Co(NO3)2, Co(NO3)3 |
Ni(NO3)2 | Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | Br | Kr |
| RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb | Mo | Tc | Ru | Rh | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In | Sn | Sb(NO3)3 | Te | I | Xe(NO3)2 |
| CsNO3 | Ba(NO3)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg2(NO3)2, Hg(NO3)2 |
Tl(NO3)3, TlNO3 |
Pb(NO3)2 | Bi(NO3)3 BiO(NO3) |
Po | At | Rn | |
| FrNO3 | Ra(NO3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La(NO3)3 | Ce(NO3)3, Ce(NO3)4 |
Pr | Nd(NO3)3 | Pm | Sm | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy | Ho | Er | Tm | Yb | Lu | |||
| Ac(NO3)3 | Th(NO3)4 | Pa | UO2(NO3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||
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