Chemistry:Iodate sulfate
From HandWiki
Iodate sulfates are mixed anion compounds that contain both iodate and sulfate anions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements.[1] Related compounds include the iodate selenates[2] and chromate iodates.[3]
Iodate sulfates can be produced from water solutions of iodic acid and sulfate salts.[4]
List
formula | name | formula
weight |
system | space group | cell Å | volume | density | comments | ref |
---|---|---|---|---|---|---|---|---|---|
Na7(IO3)(SO4)3 | 624.01 | orthorhombic | P212121 | a=6.839 b=10.851 c=18.519 Z=4 | 1374.2 | 3.016 | at 100K; band gap 4.83; SHQ 0.5×KDP; birefringence 0.075 at 1064 nm | [5] | |
Na9(IO3)(SO4)4 | Hectorfloresite | monoclinic | P21/a | a = 18.775 b = 6.9356 c = 14.239 β = 108.91° Z = 4 | [5][6] | ||||
K2SO4·HIO3 | 350.17 | monoclinic | P21/n | a=7.4215 b=7.1578 c=13.802 β=93.330° Z=4 | 731.9 | 3.178 | colourless; birefingence 0.14 at 589.3 nm; UV edge 275 nm | [7] | |
K3Na5Mg5(IO3)6(SO4)6(H2O)5 | trigonal | P3c1 | |||||||
K7.2Na8.8Mg10(IO3)12(SO4)12(H2O)12 | Fuenzalidaite | trigonal | P3c1 | a = 9.4643 c = 27.336 | 2,120.52 | colourless; Uniaxial (-) nω = 1.622 nε = 1.615; Birefringence = 0.007 | [5][8][9] | ||
Nb2O3(IO3)2(SO4) | 679.68 | monoclinic | P21 | a=5.299 b=20.479 c=5.452 β=119.095° Z=2 | 517.0 | 4.366 | band gap 3.25; SHG 6 × KDP; birefringence 0.22 at 1064 nm; stable below 580 °C | [5][10] | |
Ce(IO3)2(SO4) | CISO | 585.98 | orthorhombic | P212121 | a=7.5366 b=8.9787 c=11.6121 Z=4 | 785.78 | 4.953 | yellow; SHG 3.5 × KDP; birefringence 0.259 at 546 nm | [11] |
Sm(IO3)(SO4) | monoclinic | P21/c | a=9.3148 b=6.8678 c=8.2852 β=104.701° | [12] | |||||
Sm2(IO3)3(SO4)OH·3H2O | triclinic | P1 | a 7.3858 b 9.6166 c 11.8629 α=66.482° β=76.884° γ=69.101° | [12] | |||||
Eu(IO3)(SO4) | monoclinic | P21/c | a=9.3083 b=6.8460 c=8.2575 β=104.696° | [5][1] | |||||
Eu2(IO3)3(SO4)OH·3H2O | triclinic | P1 | a=7.3666 b=9.5817 c=11.8263 α=66.5365° β=76.8591° γ=69.1131° | [12] | |||||
Dy(IO3)(SO4)(H2O) | orthorhombic | P212121 | a=7.3088 b=9.4824 c=11.7302 α=66.6573° β=76.8745° γ=69.2970° | [5] | |||||
Dy(IO3)(SO4)(H2O)3 | orthorhombic | P212121 | a=6.682 b=8.791 c=13.632 | [1] | |||||
Dy2(IO3)3(SO4)OH·3H2O | triclinic | P1 | [12] | ||||||
Hg2(IO3)2(SO4) | monoclinic | C2/c | a=12.040 b=4.7133 c=15.533 β=102.43° | [13] | |||||
Hg2(IO3)2(SO4)(H2O) | monoclinic | C2 | a=11.767 b=4.9190 c=7.8076 β=97.10° | band gap 3.98 eV; SHG 6 × KDP; dehydrate 250 °C | [13] | ||||
Bi(IO3)(SO4) | 479.94 | monoclinic | P21/c | a=9.4355 b=6.9168 c=8.3374 β=105.168° Z=4 | 525.17 | 6.070 | band gap 3.91 eV; birefringence 0.087 at 1064 nm; colourless | [14] | |
Bi2O(SO4)(IO3)2 | monoclinic | P21/n | a=7.2391 b=17.907 c=7.7964 β = 109.652° Z =4 | [4] | |||||
AgBi(SO4)(IO3)2 | 1525.42 | triclinic | P1 | a=5.5189 b=6.9129 c=11.8527 α=90.598° β=92.151° γ=109.895° Z=1 | 424.78 | 5.963 | colourless; SHG 3.0 × KDP | [15] | |
CdBi(IO3)(SO4)2 | 688.40 | monoclinic | P21/c | a=12.777 b=6.8491 c=9.984 β=103.23° Z=4 | 850.5 | 5.376 | band gap 4.03 eV; birefringence 0.100 at 1064 nm | [14] |
References
- ↑ Jump up to: 1.0 1.1 1.2 Lu, Huangjie; Guo, Xiaojing; Wang, Yaxing; Diefenbach, Kariem; Chen, Lanhua; Wang, Jian-Qiang; Lin, Jian; Wang, Shuao (2019). "Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation" (in en). Dalton Transactions 48 (34): 12808–12811. doi:10.1039/C9DT02387A. ISSN 1477-9226. PMID 31348473. http://xlink.rsc.org/?DOI=C9DT02387A.
- ↑ Chen, Qian-Qian; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2023). "[M(OH) 2 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology"] (in en). Inorganic Chemistry Frontiers 10 (10): 3121–3130. doi:10.1039/D3QI00415E. ISSN 2052-1553. http://xlink.rsc.org/?DOI=D3QI00415E.
- ↑ Sullens, Tyler A.; Almond, Philip M.; Byrd, Jessica A.; Beitz, James V.; Bray, Travis H.; Albrecht-Schmitt, Thomas E. (April 2006). "Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2" (in en). Journal of Solid State Chemistry 179 (4): 1192–1201. doi:10.1016/j.jssc.2006.01.017. Bibcode: 2006JSSCh.179.1192S. https://linkinghub.elsevier.com/retrieve/pii/S0022459606000211.
- ↑ Jump up to: 4.0 4.1 Shi, Long; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (January 2017). "Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 8+ clusters"] (in en). Solid State Sciences 63: 54–61. doi:10.1016/j.solidstatesciences.2016.11.010. Bibcode: 2017SSSci..63...54S. https://linkinghub.elsevier.com/retrieve/pii/S1293255816304745.
- ↑ Jump up to: 5.0 5.1 5.2 5.3 5.4 5.5 Ding, Mengmeng; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021). "Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 and [SO 4 ] units"] (in en). Chemical Communications 57 (75): 9598–9601. doi:10.1039/D1CC03483A. ISSN 1359-7345. PMID 34546233. http://xlink.rsc.org/?DOI=D1CC03483A.
- ↑ George E. Ericksen; Howard T. Evans; Mary E. Mrose; James J. Mcgee; John W. Marinenko; Judith A. Konnert (1 October 1989). "Mineralogical studies of the nitrate deposits of Chile; VI, Hectorfloresite, Na9(IO3(SO4)4, a new saline mineral". https://pubs.geoscienceworld.org/msa/ammin/article-abstract/74/9-10/1207/42337/Mineralogical-studies-of-the-nitrate-deposits-of.
- ↑ Bai, Zhiyong; Ok, Kang Min (2023). "Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3" (in en). Inorganic Chemistry Frontiers 10 (6): 1919–1925. doi:10.1039/D3QI00192J. ISSN 2052-1553. http://xlink.rsc.org/?DOI=D3QI00192J.
- ↑ "Fuenzalidaite". https://www.mindat.org/min-1618.html.
- ↑ "Mineralogical studies of the nitrate deposits of Chile: VII. Two new saline minerals with the composition K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O: Fuenzalidaite (X = S) and carlosruizite (X = Se)". https://pubs.geoscienceworld.org/msa/ammin/article-abstract/79/9-10/1003/42908/Mineralogical-studies-of-the-nitrate-deposits-of.
- ↑ Tang, Hong‐Xin; Zhang, Yu‐Xiao; Zhuo, Chao; Fu, Rui‐Biao; Lin, Hua; Ma, Zu‐Ju; Wu, Xin‐Tao (2019-03-18). "A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design" (in en). Angewandte Chemie 131 (12): 3864–3868. doi:10.1002/ange.201813122. ISSN 0044-8249. https://onlinelibrary.wiley.com/doi/10.1002/ange.201813122.
- ↑ Wu, Tianhui; Jiang, Xingxing; Zhang, Yiran; Wang, Zujian; Sha, Hongyuan; Wu, Chao; Lin, Zheshuai; Huang, Zhipeng et al. (2021-12-14). "From CeF 2 (SO 4 )·H 2 O to Ce(IO 3 ) 2 (SO 4 ): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence" (in en). Chemistry of Materials 33 (23): 9317–9325. doi:10.1021/acs.chemmater.1c03053. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.1c03053.
- ↑ Jump up to: 12.0 12.1 12.2 12.3 Aslani, Ceren Kutahyali; Klepov, Vladislav V.; zur Loye, Hans-Conrad (July 2022). "Hydrothermal synthesis of new mixed-oxoanion materials: Rare earth iodate sulfates Sm(IO3)(SO4) and Ln2(IO3)3(SO4)OH·3H2O (Ln = Sm, Eu, Dy)" (in en). Solid State Sciences 129: 106918. doi:10.1016/j.solidstatesciences.2022.106918. Bibcode: 2022SSSci.12906918A. https://linkinghub.elsevier.com/retrieve/pii/S1293255822001133.
- ↑ Jump up to: 13.0 13.1 Li, Yi‐Lin; Ji, Meng‐Ya; Hu, Chun‐Li; Chen, Jin; Li, Bing‐Xuan; Lin, Yuan; Mao, Jiang‐Gao (April 2022). "Explorations of New SHG Materials in Mercury Iodate Sulfate System**" (in en). Chemistry – A European Journal 28 (19): e202200001. doi:10.1002/chem.202200001. ISSN 0947-6539. PMID 35156759. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202200001.
- ↑ Jump up to: 14.0 14.1 Li, Yilin; Hu, Chunli; Chen, Jin; Mao, Jianggao (2021). "Two bismuth iodate sulfates with enhanced optical anisotropy" (in en). Dalton Transactions 50 (44): 16139–16146. doi:10.1039/D1DT02514G. ISSN 1477-9226. PMID 34677566. http://xlink.rsc.org/?DOI=D1DT02514G.
- ↑ Liu, Hongming; Wu, Qingchen; Liu, Lili; Lin, Zheshuai; Halasyamani, P. Shiv; Chen, Xingguo; Qin, Jingui (2021). "AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement" (in en). Chemical Communications 57 (30): 3712–3715. doi:10.1039/D0CC07862J. ISSN 1359-7345. PMID 33729224. http://xlink.rsc.org/?DOI=D0CC07862J.
![]() | Original source: https://en.wikipedia.org/wiki/Iodate sulfate.
Read more |