Chemistry:Oxalate sulfate

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Short description: Mixed anion compounds

Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.

Related compounds include the sulfite oxalates[1] and oxalate selenates.[2]

Production

Oxalate sulfates may be deposited from a solution in water of the metal anions and sulfate with oxalic acid when evaporated. Crystals formed this way may be hydrates.[3]

Properties

Many crystal forms are non-centrosymmetric and have non-linear optical properties.[3]

When heated, oxalate sulfates will first dehydrate, and then give off carbon dioxide.[3]

List

name formula system space group unit cell Å volume density comment ref
lithium sulfate monohydrate oxalate ? triclinic P1 a = 3.4014 b = 5.0397 c = 6.120 α = 78.62° β= 84.95°

γ = 81.14°

101.45 band gap 4.57 eV

dielectric constant 29.7 stable below 83°C piezoelectric coefficient 6pC/N

[3]
homopiperazinium dimagnesium dioxalate sulfate dihydrate C5H14N2•Mg2•[C2O4]2•SO4•2H2O monoclinic Ia a=11.5673 b=27.3352 c=16.6097 β=95.255° Z=12 5229.8 1.749 colourless [4]
piperazinium magnesium oxalate sulfate hydrate C4H12N2•Mg•[C2O4]•SO4•H2O monoclinic P21/c a=12.7330 b=8.9240 c=11.8172 β=115.502° Z=4 1211.95 1.724 colourless [4]
potassium sulphato oxalate ? triclinic a = 6.37 b = 7.03 c = 10.61 α = 93.96 ̊ β = 101.37 ̊ γ = 100.1 ̊ colourless > 300nm; SHG 1.6×KDP [5]
bapp = 1,4-bis(3-aminopropyl)piperazine (H4bapp)0.5·VO(SO4)(C2O4) triclinic P1 a=6.2031 b=8.6599 c=12.1853 α=77.130° β=76.207° γ=82.987° [6]
bipy=4,4′-bipyridine; (μ2-Oxalato-O,O',O'',O''')-tetrakis(2,2'-bipyridine)-di-chromium(iii) disulfate 2,2'-bipyridine solvate monohydrate [Cr2(bipy)4(C2O4)](SO4)·(bipy)0.5·H2O triclinic P1 a=11.610 b=12.668 c=17.155 α=77.297° β=83.957° γ=85.458° [7]
depa = 3-(diethylamino)propylamine H2depa⋅Mn2(SO4)(C2O4)2(H2O)⋅H2O orthorhombic Pbca a=14.6293 b=15.6671 c=17.3579 [6]
hpip = homopiperazine H2hpip·Mn2(SO4)(C2O4)2(H2O) orthorhombic P212121 a=9.9066 b=12.4496 c=13.6640 [8]
pip = piperazine; piperazinediium (μ-oxalato)-bis(μ-sulfato)-diaqua-di-manganese(ii) dihydrate H2pip·Mn2(SO4)2(C2O4)(H2O)4 triclinic P1 a 6.6501(4)Å b 7.7034(4)Å c 9.6810(5)Å, α 69.850(4)° β 70.553(5)° γ 83.921(4)° [9]
ipa = 3,3′-iminobis(N,N-dimethylpropylamine) bis(3-dimethylammoniopropyl)ammonium pentakis(μ-oxalato)-bis(μ-sulfato)-tetra-manganese(ii) dihydrate H3ipa⋅Mn2(SO4)(C2O4)2.5·H2O triclinic P1 a 9.9379(6)Å b 11.2423(6)Å c 11.6390(7)Å, α 86.793(5)° β 81.644(5)° γ 74.481(5)° [9]
dpta = dipropylenetriamine; bis(3-ammoniopropyl)ammonium tris(μ-oxalato)-bis(μ-sulfato)-bis(sulfato)-hexa-aqua-tetra-manganese(ii) H3dpta⋅Mn2(SO4)2(C2O4)1.5(H2O)3 triclinic P1 a 8.6819(3)Å b 10.1689(3)Å c 13.7456(5)Å, α 70.197(3)° β 73.406(3)° γ 87.636(3)° [9]
dmen = N,N-dimethylethylenediamine H2dmen·Mn(SO4)(C2O4) monoclinic P21/n a=9.8603 b=12.6525 c=10.0837 β=113.002° [10]
bis(N,N-dimethylpropane-1,3-diaminium) bis(μ-oxalato)-bis(μ-sulfato)-di-manganese triclinic P1 a=8.5307 b=9.0432 c=9.6913 α=69.632° β=64.639° γ=88.148° [11]
butane-1,4-diaminium bis(μ-oxalato)-(μ-sulfato)-aqua-di-manganese triclinic P1 a=8.5468 b=10.0050 c=10.6532 α=75.445° β=79.787° γ=71.848° [11]
Na2Fe(C2O4)SO4⋅H2O orange; most air sensitive [12]
(μ-oxalato)-(μ-sulfato)-iron-di-potassium K2[Fe(C2O4)(SO4)] monoclinic P21/c a=5.8735 b=10.2169 c=13.1491 β=91.226° [13]
tris(μ-oxalato)-bis(μ-sulfato)-tri-iron-tetra-potassium K4[Fe3(C2O4)3(SO4)2] monoclinic P21/c a 13.739 b 5.496 c 12.774 β 97.677° [13]
acid oxalo-bisulfate of roseocobalt ?? Co2(HN3)10(C2O4)(SO4)2 ·H2O·H2C2O4 speculative [14]
[Co(NH3)4(C2O4)]2SO4·2H2O [15]
[Co(NH3)4(C2O4)]2S2O6 [15]
tris(μ-aqua)-tris(μ-oxalato)-tris(μ-sulfato)-tri-cobalt-hexa-sodium Na2[Co(C2O4)(SO4)]·H2O hexagonal P62m a=10.2322 c=6.4774 [13]
tris(μ-oxalato)-bis(μ-sulfato)-bis(2-((2-aminoethyl)amino)ethanaminium)-tetraaqua-tetra-cobalt triclinic P1 a=8.6065 b=9.5595 c=9.5987 α=77.884° β=82.744° γ=87.356° [16]
bis(μ-oxalato)-bis(μ-sulfato)-bis(4-(2-aminoethyl)piperazin-1-ium)-tri-cobalt triclinic P1 a=8.4331 b=9.4691 c=9.5144 α=71.522° β=64.356° γ=89.622° [16]
1,4-dimethylpiperazinedi-ium bis(μ-oxalato)-hepta-aqua-tri-cobalt bis(sulfate) (H2dmp)(SO4)3Co3(C2O4)2(H2O)7 orthorhombic Pnma a=11.1050 b=16.4221 c=13.9815 violet [17]
Bis[tris(oxamide dioxime-2N,N')cobalt(III)] oxalate bis(sulfate) dodecahydrate [Co(C2H6N4O2)3]2(C2O4)(SO4)212H2O triclinic P1 a = 9.430 b = 11.782 c = 12.812 α = 65.494° β = 83.088° γ = 86.735° Z=1 1285.7 1.698 at 193K; red [18]
homopiperazinium dizinc dioxalate sulfate hydrate C5H14N2•Zn2•[C2O4]2•SO4•H2O monoclinic P21 a=15.8356 b=13.5022 c=15.9578 β=109.075° Z=8 3224.7 2.154 colourless [4]
homopiperazinium dizinc dioxalate sulfate dihydrate C5H14N2•Zn2•[C2O4]2•SO4•2H2O monoclinic Ia a=11.5681 b=27.1755 c=16.5979 β=94.946° Z=12 5198.4 2.074 colourless [4]
bis(4-(2-aminoethyl)piperazin-1-ium)-bis(μ-oxalato)-bis(μ-sulfato)-tri-zinc triclinic P1 a=8.407 b=9.523 c=9.543 α=108.39° β=115.52° γ=90.17° [11]
1,4-dimethylpiperazinedi-ium bis(sulfate) bis(μ-oxalato)-hepta-aqua-tri-zinc (H2dmp)(SO4)3Zn3(C2O4)2(H2O)7 orthorhombic Pnma a 11.1058 b 16.3449 c 14.0064 colourless [17]
(Hgly)2·Zn(SO4)(C2O4) monoclinic C2 a 19.1509 b 5.4000 c 12.8206 β 102.878° [19]
RbFe(SO4)(C2O4)0.5·H2O monoclinic P21/c a = 7.9193, b = 9.4907, c = 8.8090, β = 95.180°, Z = 4 [20]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-yttrium diammonium [NH4][Y(H2O)(SO4)(C2O4)] monoclinic P21/n a=6.534 b=8.527 c=13.745 β=92.87° [21]
bis(μ3-Sulfato-O,O,O',O'',O''')-(μ2-oxalato-O,O',O'',O''')-(μ2-piperazine-diium-1,4-diacetato-O,O')-diaqua-di-yttrium(iii) Y2(H2pda)(C2O4)(SO4)2(H2O)2] monoclinic C2/c a 19.392 b 6.2757 c 16.999 β 108.279° [22]
levinsonite-(Y) (Y,Nd,Ce)Al(SO4)2(C2O4) · 12H2O monoclinic P2/n a = 10.289 Å, b = 9.234, c = 11.015

β = 108.50°

992.4 2.181 Biaxial (+) Refractive index:

nα = 1.480 nβ = 1.490 nγ = 1.550

[23][24]
thfa = tetrahydrofurfurylamine; bis(tetrahydrofurfurylammonium) tris(μ-oxalato)-(μ-sulfato)-di-indium(iii) dihydrate (Hthfa)2·In2(SO4)(C2O4)3·2H2O monoclinic P21/c a=10.7581 b=12.9985 c=19.9093 β=92.876° [8]
bapp = N,N′-bis(3-aminopropyl)piperazine H4bapp·[In2(SO4)3(C2O4)2(H2O)2]·H2O monoclinic I2/a a=13.8931 b=14.6792 c=15.2418 β=111.153° [10]
bis(1-ethylpiperazinedi-ium) tris(μ-oxalato)-bis(sulfato)-di-indium H2epip·[In2(SO4)2(C2O4)3] tetragonal I41/a a=26.0767 c=8.9467 colourless [17]
Piperazinediium bis(μ2-oxalato-O,O',O'',O''')-bis(μ2-sulfato-O,O')-diaqua-di-indium dihydrate [C4N2H12]0.5InSO4C2O4·2H2O monoclinic P21/c a=6.478 b=11.067 c=14.317 β=100.302° [25]
Hgly·In(SO4)(C2O4)(gly) monoclinic P21 a 6.5179(2)Å b 10.9928(3)Å c 18.0301(6)Å, α 90° β 93.9700(10)° [19]
CsMn(SO4)(C2O4)0.5·H2O monoclinic P21/c a = 8.065, b = 9.610, c = 9.219, β = 94.564°, Z = 4 [20]
CsFe(SO4)(C2O4)0.5·H2O monoclinic P21/c a = 7.9377, b = 9.5757, c = 9.1474, β = 96.104°, Z = 4 [20]
La2(C2O4)(SO4)2(H2O)3 monoclinic P21/n a=9.838 b=9.817 c=13.111 β=104.258° [26]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-lanthanum diammonium [NH4][La(H2O)(SO4)(C2O4)] monoclinic P21/n a=6.629 b=8.673 c=13.867 β=93.35° [21]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-cerium(iii) dihydrate Ce2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O monoclinic C2/c a 19.353 b 6.836 c 16.400 β 94.312° [22]
coskrenite-(Ce) (Ce,Nd,La)2(C2O4)(SO4)2 · 12H2O triclinic a = 6.007(1) Å, b = 8.368(2) Å, c = 9.189(2) Å

α = 99.90(2)°, β = 105.55(2)°, γ = 107.71(2)°

2.881 Biaxial (-) refractive indices: nα = 1.544 nβ = 1.578 nγ = 1.602; Birefringence: δ = 0.058 [27][28]
zugshunstite-(Ce) (Ce,Nd,La)Al(SO4)2(C2O4) · 12H2O Monoclinic C2/c a = 8.718 b = 18.313 c = 13.128

β = 93.90°

2091 2.121 Large REE; pink in incandescent light; blue in fluorescent light; Biaxial (+) refractive index: nα = 1.455 nβ = 1.485 nγ = 1.528; [29][24]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-praseodymium(iii) dihydrate Pr2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O monoclinic C2/c a 19.295 b 6.8100 c 16.377 β 94.369° [22]
heptakis(μ-oxalato)-bis(μ-sulfato)-tetradecaaqua-hexa-neodymium dihydrate Nd6(SO4)2(C2O4)7(H2O)14·H2O triclinic P1 a=6.0817 b=11.8807 c=16.0749 α=73.230° β=80.873° γ=88.976° [30]
N,N'-dimethylethane-1,2-diaminium tetrakis(μ-sulfato)-tris(μ-oxalato)-octaaqua-tetra-neodymium [C4H14N2]·Nd4(SO4)4(C2O4)3(H2O)8 triclinic P1 a=7.0649 b=11.2771 c=11.8318 α=67.370° β=80.035° γ=82.821° [30]
bis(μ3-Sulfato-O,O,O',O'',O''')-(μ2-oxalato-O,O',O'',O''')-(μ2-piperazine-diium-1,4-diacetato-O,O')-diaqua-di-neodymium(iii) Nd2(H2pda)(C2O4)(SO4)2(H2O)2] monoclinic C2/c a=19.702 b=6.348 c=17.352 β=109.973° [22]
bis(1,4-Diazoniabicyclo[2.2.2]octane) tetrakis(μ2-oxalato-O,O',O'',O''')-tetrakis(μ2-sulfato-O,O',O'')-octa-aqua-tetra-neodymium(iii) dihydrate [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O monoclinic P21/c a=8.523 b=28.628 c=9.306 β=96.497° [31]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-europium(iii) dihydrate Eu2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O monoclinic C2/c a=19.143 b=6.722 c=16.323 β=94.58° [22]
(μ5-Oxalato)-(μ3-sulfato)-(μ2-aqua)-aqua-europium-silver AgEu(μ5-C2O4)(SO4)(H2O)2 monoclinic P21/c a=6.627 b=13.848 c=8.983 β=96.985° [32]
tetrakis(μ2-oxalato)-bis(μ2-sulfato)-dodeca-aqua-tetra-erbium monohydrate Er4(SO4)2(C2O4)4(H2O)12·H2O monoclinic P21/c a=10.5598 b=12.8404 c=12.0835 β=93.327° [30]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-samarium diammonium [NH4][Sm(H2O)(SO4)(C2O4)] monoclinic P21/n a=6.619 b=8.660 c=13.853 β=93.30° [21]
(μ5-Oxalato)-(μ3-sulfato)-(μ2-aqua)-aqua-samarium-silver AgSm(μ5-C2O4)(SO4)(H2O)2 monoclinic P21/c a=6.630 b=13.829 c=9.001 β=97.128° [32]
(NH4)[Gd(C2O4)(SO4)(H2O)] large magnetocaloric effect [33]
K[Gd(C2O4)(SO4)(H2O)] monoclinic P21/c a = 6.5849 b = 8.5660 c = 14.7660(2) Å, β = 112.470° Z=4 769.66 3.439 colourless [34]
potassium aquaterbium(III) oxalate sulfate KTb(C2O4)(SO4)(H2O) monoclinic a = 6.527 b = 8.507 c = 14.591 β = 112.65° Z=4 747.7 at 113K; colourless [35]
(μ6-Oxalato)-(μ4-oxalato)-bis(μ3-sulfato)-diaqua-di-silver-di-terbium AgTb(μ4-C2O4)0.5(μ6-C2O4)0.5(SO4)(H2O) monoclinic C2/m a=13.693 b=6.889 c=9.0885 β=116.73° [32]
(μ6-Oxalato)-(μ4-oxalato)-bis(μ3-sulfato)-diaqua-di-dysprosium-di-silver AgDy(μ4-C2O4)0.5(μ6-C2O4)0.5(SO4)(H2O) monoclinic C2/m a=13.683 b=6.881 c=9.080 β=116.731° [32]
bis(1-ethyl-3-methyl-1H-imidazol-3-ium) (μ-oxalato)-bis(μ-sulfato)-tetraoxo-di-uranium monohydrate monoclinic P21/c a=11.579 b=17.312 c=13.694 β=108.178° yellow [36]
(NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2]⋅6H2O orthorhombic Pbam a = 12.0177 b = 18.6182 c = 6.757 Z=2 [37]
Tetrapotassium bis(μ2-oxalato)-tetraoxo-bis(sulfato)-di-uranium(vi) hexahydrate K2[UO2(C2O4)SO4] · 3H2O triclinic P1 a=5.743 b=9.544 c=11.845 α=89.49° β=84.95° γ=83.01° [38]
K4[(UO2)2C2O4(SO4)2(NCS)2] orthorhombic Pbam a = 11.5548 b = 7.0847 c = 13.5172 β = 93.130° Z=2 1104.90 [39]
Di-rubidium dioxo-(oxalato-O,O')-(μ3-sulfato)-uranium monohydrate Rb2[UO2SO4(C2O4)] · H2O orthorhombic Pna21 a=9.720 b=17.037 c=6.852 [38][40]
Rb4[(UO2)2C2O4(SO4)2(NCS)2] orthorhombic Pbam a = 11.5854 b = 7.3841 c = 13.9072 β = 95.754 V = Z=2 1183.7 [39]
Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] · 4H2O orthorhombic Pbam a = 11.6539 b = 18.379 c = 6.7216 Z=2 [37]
Tetracesium dioxo-bis(oxalato-O,O')-(sulfato-O)-uranium(vi) hydrate Cs4[UO2(C2O4)2SO4] · 2.7H2O orthorhombic Pbca a=9.546 b=21.119 c=21.499 [38]

References

  1. ↑ Tiwari, Ranjay K.; Kumar, Jitendra; Behera, J. N. (2017). "Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures" (in en). Dalton Transactions 46 (45): 15939–15946. doi:10.1039/C7DT03073H. ISSN 1477-9226. PMID 29119180. http://xlink.rsc.org/?DOI=C7DT03073H. 
  2. ↑ Medrish, I. V.; Peresypkina, E. V.; Virovets, A. V.; Serezhkina, L. B. (August 2008). "Synthesis and crystal structure of Rb2[(UO2)2(C2O4)2(SeO4) · 1.33H2O"] (in en). Russian Journal of Coordination Chemistry 34 (8): 629–634. doi:10.1134/S1070328408080125. ISSN 1070-3284. http://link.springer.com/10.1134/S1070328408080125. 
  3. ↑ 3.0 3.1 3.2 3.3 Yadav, Harsh; Sinha, Nidhi; Kumar, Binay (April 2015). "Growth and characterization of new semiorganic nonlinear optical and piezoelectric lithium sulfate monohydrate oxalate single crystals" (in en). Materials Research Bulletin 64: 194–199. doi:10.1016/j.materresbull.2014.12.065. https://linkinghub.elsevier.com/retrieve/pii/S0025540814008228. 
  4. ↑ 4.0 4.1 4.2 4.3 Wen, Xuemei; Long, Ying; Luo, Daibing; Huang, Ling; Zeng, Hongmei; Wang, Xin; Zou, Guohong; Lin, Zhien (2023-04-24). "Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route" (in en). Inorganic Chemistry 62 (16): 6202–6206. doi:10.1021/acs.inorgchem.3c00412. ISSN 0020-1669. PMID 37027523. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c00412. 
  5. ↑ Punniyamoorthy, R.; Manimekalai, R.; Uma, K.; Pasupathi, G. (March 2019). "Synthesis and Investigation on Structural, Thermal, Mechanical, Linear Optical, and Nonlinear Optical Nature of Potassium Sulphato Oxalate Single Crystals" (in en). Crystal Research and Technology 54 (3): 1800203. doi:10.1002/crat.201800203. https://onlinelibrary.wiley.com/doi/10.1002/crat.201800203. 
  6. ↑ 6.0 6.1 Zhang, Ying; Lin, Longzhen; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (August 2019). "Organically templated metal sulfate-oxalates: Solvent-free synthesis, crystal structure, and proton conduction" (in en). Journal of Solid State Chemistry 276: 1–5. doi:10.1016/j.jssc.2019.04.031. Bibcode: 2019JSSCh.276....1Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459619302087. 
  7. ↑ Chen, Xu-Fang; Liu, Li; Ma, Jian-Gong; Yi, Long; Cheng, Peng; Liao, Dai-Zheng; Yan, Shi-Ping; Jiang, Zong-Hui (August 2005). "Synthesis, reaction and structure of a series of chromium(III) complexes containing oxalate ligand" (in en). Journal of Molecular Structure 750 (1–3): 94–100. doi:10.1016/j.molstruc.2005.04.020. Bibcode: 2005JMoSt.750...94C. https://linkinghub.elsevier.com/retrieve/pii/S0022286005003170. 
  8. ↑ 8.0 8.1 Li, Ting; Chen, Cheng; Guo, Furong; Li, Jing; Zeng, Hongmei; Lin, Zhien (July 2018). "Extra-large-pore metal sulfate-oxalates with diamondoid and zeolitic frameworks" (in en). Inorganic Chemistry Communications 93: 33–36. doi:10.1016/j.inoche.2018.05.003. https://linkinghub.elsevier.com/retrieve/pii/S1387700318302673. 
  9. ↑ 9.0 9.1 9.2 Shi, Jingyu; Guo, Furong; Yang, Meng; Zeng, Hongmei; Lin, Zhien (January 2018). "Solvent-free synthesis of three layered manganese sulfate-oxalates with different pore apertures" (in en). Solid State Sciences 75: 77–81. doi:10.1016/j.solidstatesciences.2017.07.011. Bibcode: 2018SSSci..75...77S. https://linkinghub.elsevier.com/retrieve/pii/S1293255816310159. 
  10. ↑ 10.0 10.1 Guo, Caihong; Chen, Cheng; Wang, Kangcai; Zeng, Hongmei; Lin, Zhien (November 2017). "Solvent-free synthesis of open-framework metal sulfate oxalates with dia and ths topologies" (in en). Inorganic Chemistry Communications 85: 96–99. doi:10.1016/j.inoche.2017.07.007. https://linkinghub.elsevier.com/retrieve/pii/S1387700317303970. 
  11. ↑ 11.0 11.1 11.2 Guo, Furong; Xiao, Kang; Yang, Meng; Luan, Lindong; Lin, Zhien (January 2016). "Solvent-free synthesis of new metal sulfate–oxalates containing chain-like building blocks" (in en). Inorganic Chemistry Communications 63: 20–23. doi:10.1016/j.inoche.2015.11.005. https://linkinghub.elsevier.com/retrieve/pii/S1387700315301337. 
  12. ↑ Song, Tianyi; Yao, Wenjiao; Kiadkhunthod, Pinit; Zheng, Yongping; Wu, Nanzhong; Zhou, Xiaolong; Tunmee, Sarayut; Sattayaporn, Suchinda et al. (2020-01-07). "A Low‐Cost and Environmentally Friendly Mixed Polyanionic Cathode for Sodium‐Ion Storage" (in en). Angewandte Chemie International Edition 59 (2): 740–745. doi:10.1002/anie.201912272. ISSN 1433-7851. PMID 31591806. https://onlinelibrary.wiley.com/doi/10.1002/anie.201912272. 
  13. ↑ 13.0 13.1 13.2 Cheng, Fang-Fang; Zhu, Jian-Nan; Zhao, Ming-Yu; Ma, Zhong-Jie; Xiong, Wei-Wei (October 2019). "Preparing transition metal-organic frameworks based on oxalate-sulfate anions in deep eutectic solvents" (in en). Journal of Solid State Chemistry 278: 120904. doi:10.1016/j.jssc.2019.120904. Bibcode: 2019JSSCh.27820904C. https://linkinghub.elsevier.com/retrieve/pii/S0022459619304050. 
  14. ↑ Gibbs, Wolcott (1875). "Researches on the Hexatomic Compounds of Cobalt (Continued)" (in en). Proceedings of the American Academy of Arts and Sciences 11: 1–51. doi:10.2307/20021454. https://www.jstor.org/stable/20021454. 
  15. ↑ 15.0 15.1 Schramm, Walter (1929-04-08). "Die Einwirkung von Oxalsäure und Malonsäure auf die Tetrammin-kobaltikomplexe und ihre Analogen" (in en). Zeitschrift für anorganische und allgemeine Chemie 180 (1): 161–183. doi:10.1002/zaac.19291800119. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19291800119. 
  16. ↑ 16.0 16.1 Wang, Kangcai; Luo, Daibing; Xu, Dingguo; Guo, Furong; Liu, Lin; Lin, Zhien (2014). "New open-framework cobalt sulfate-oxalates based on molecular and chain-like building blocks" (in en). Dalton Trans. 43 (36): 13476–13479. doi:10.1039/C4DT01503G. ISSN 1477-9226. PMID 25110964. http://xlink.rsc.org/?DOI=C4DT01503G. 
  17. ↑ 17.0 17.1 17.2 Guo, Furong; Chen, Cheng; Wang, Kangcai; Zhang, Qinghua; Lin, Zhien (2016-08-15). "Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates" (in en). Inorganic Chemistry 55 (16): 7817–7819. doi:10.1021/acs.inorgchem.6b01341. ISSN 0020-1669. PMID 27454425. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01341. 
  18. ↑ Belombe, Michel M.; Nenwa, Justin; Bebga, Gouet; Fokwa, Boniface P. T.; Dronskowski, Richard (2007-08-15). "Bis[tris(oxamide dioxime-κ 2 N , N ′)cobalt(III) oxalate bis(sulfate) dodecahydrate"]. Acta Crystallographica Section E 63 (8): m2037–m2038. doi:10.1107/S1600536807031169. ISSN 1600-5368. https://scripts.iucr.org/cgi-bin/paper?S1600536807031169. 
  19. ↑ 19.0 19.1 Li, Ying; Luo, Miao; Long, Ying; Huang, Ling; Gao, Daojiang; Zou, Guohong; Lin, Zhien; Zhao, Yan (2023-05-24). "Host–Guest Symmetry and Charge Matching in Glycine-Templated Metal Sulfate–Oxalates Obtained by a Solvent-Free Method" (in en). Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c01469. ISSN 0020-1669. PMID 37222550. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c01469. 
  20. ↑ 20.0 20.1 20.2 Becker, G.; Eschbach, B.; Mundt, O.; Reti, M.; Niecke, E.; Issberner, K.; Nieger, M.; Thelen, V. et al. (1998). "Bis(1,2-dimethoxyethan-O,O′)lithium-phosphanid, -arsanid und -chlorid – drei neue Vertreter des Bis(1,2-dimethoxyethan-O,O′)lithium-bromid-Typs". Zeitschrift für Anorganische und Allgemeine Chemie 624 (3): 469–482. doi:10.1002/(SICI)1521-3749(199803)624:3<469::AID-ZAAC469>3.0.CO;2-F. 
  21. ↑ 21.0 21.1 21.2 Li, Li; Yu, Ranbo; Wang, Dan; Lai, Xiaoyong; Mao, Dan; Yang, Mei (July 2010). "Hydrothermal synthesis and structure of three novel open-framework lanthanide sulfate–oxalates" (in en). Inorganic Chemistry Communications 13 (7): 831–833. doi:10.1016/j.inoche.2010.04.004. https://linkinghub.elsevier.com/retrieve/pii/S1387700310001425. 
  22. ↑ 22.0 22.1 22.2 22.3 22.4 Yang, Juan; Lu, Ning; Zhang, Gong; Cheng, Lin; Gou, Shao-Hua (June 2008). "The first hybrid organic–inorganic frameworks based on lanthanide(III) sulfate chains, in situ generated oxalate and organic pillars of 1,4-piperazinediacetic acid" (in en). Polyhedron 27 (9–10): 2119–2126. doi:10.1016/j.poly.2008.04.003. https://linkinghub.elsevier.com/retrieve/pii/S0277538708001940. 
  23. ↑ "Levinsonite-(Y)". https://www.mindat.org/min-7024.html. 
  24. ↑ 24.0 24.1 Rouse, R.C.; Peacor, D.R.; Essene, E.J.; Coskren, T.D.; Lauf, R.J. (April 2001). "The new minerals levinsonite-(Y) [(Y, Nd,Ce)Al(SO4)2(C2O4) · 12H2O and zugshunstite-(Ce) [(Ce,Nd,La)Al(SO4)2(C2O4) · 12H2O]: Coexisting oxalates with different structures and differentiation of LREE and HREE>"] (in en). Geochimica et Cosmochimica Acta 65 (7): 1101–1115. doi:10.1016/S0016-7037(00)00568-8. Bibcode: 2001GeCoA..65.1101R. https://linkinghub.elsevier.com/retrieve/pii/S0016703700005688. 
  25. ↑ Ramaswamy, Padmini; Hegde, Nayana N.; Prabhu, Ramanath; Vidya, V. M.; Datta, Ayan; Natarajan, Srinivasan (2009-12-21). "Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium" (in en). Inorganic Chemistry 48 (24): 11697–11711. doi:10.1021/ic901744m. ISSN 0020-1669. PMID 19911816. https://pubs.acs.org/doi/10.1021/ic901744m. 
  26. ↑ Yuan, Yan-Ping; Song, Jun-Ling; Mao, Jiang-Gao (January 2004). "Hydrothermal synthesis, crystal structure and characterizations of a lanthanum(III) sulfate oxalate with a 3D network structure" (in en). Inorganic Chemistry Communications 7 (1): 24–26. doi:10.1016/j.inoche.2003.09.018. https://linkinghub.elsevier.com/retrieve/pii/S1387700303003319. 
  27. ↑ "Coskrenite-(Ce)". https://www.mindat.org/min-6890.html. 
  28. ↑ Alpers, Charles N.; Jambor, John L.; Nordstrom, D. (17 December 2018) (in en). Sulfate Minerals: Crystallography, Geochemistry, and Environmental Significance. Walter de Gruyter GmbH & Co KG. pp. 89–90. ISBN 978-1-5015-0866-0. https://books.google.com/books?id=ya96DwAAQBAJ&dq=%22sulfate+oxalate%22+crystal&pg=PA89. 
  29. ↑ "Zugshunstite-(Ce)". https://www.mindat.org/min-7023.html. 
  30. ↑ 30.0 30.1 30.2 Wang, Kangcai; Wang, Yu; Xu, Dingguo; Luo, Daibing; Lin, Zhien (October 2013). "New lanthanide sulfate–oxalate hybrid solids containing different inorganic building blocks" (in en). Inorganic Chemistry Communications 36: 146–149. doi:10.1016/j.inoche.2013.08.040. https://linkinghub.elsevier.com/retrieve/pii/S1387700313003511. 
  31. ↑ Xu, Ning; Xing, Yan; Liu, Xianchun; Song, Danhui; Ma, Ling; Sun, Xiujuan (March 2009). "Synthesis, Structure and Photoluminescent Properties of [C 6 N 2 H 14 [Nd 2 (C 2 O 4 ) 2 (SO 4 ) 2 (H 2 O) 4 ]·H 2 O, a New Organically Templated Neodymium(III) Oxalate-sulfate"] (in en). Zeitschrift für anorganische und allgemeine Chemie 635 (3): 558–562. doi:10.1002/zaac.200801309. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200801309. 
  32. ↑ 32.0 32.1 32.2 32.3 Xiao, Xueying; Wei, Yongqin; Zheng, Wenxu; Wu, Kechen (May 2011). "Organic-inorganic Hybrid Lanthanide-Silver Heterometallic Coordination Frameworks Constructed from Oxalate and Sulfate Anion: Syntheses, Structures, and Photoluminescent Properties" (in en). Zeitschrift für anorganische und allgemeine Chemie 637 (6): 741–747. doi:10.1002/zaac.201000427. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201000427. 
  33. ↑ Li, Jin-Hua; Liu, Ai-Ju; Ma, Yu-Juan; Han, Song-De; Hu, Ji-Xiang; Wang, Guo-Ming (2019). "A large magnetocaloric effect in two hybrid Gd-complexes: the synergy of inorganic and organic ligands towards excellent cryo-magnetic coolants" (in en). Journal of Materials Chemistry C 7 (21): 6352–6358. doi:10.1039/C9TC01475F. ISSN 2050-7526. http://xlink.rsc.org/?DOI=C9TC01475F. 
  34. ↑ Wang, Ning; Yue, Shan-Tang; Liu, Ying-Liang (2009-06-20). "One new lanthanide complex with mixed sulfate and oxalate ligands: hydrothermal synthesis, crystal structure, and magnetic properties" (in en). Journal of Coordination Chemistry 62 (12): 1914–1920. doi:10.1080/00958970902736780. ISSN 0095-8972. https://www.tandfonline.com/doi/full/10.1080/00958970902736780. 
  35. ↑ Sun, Ya-Guang; Guo, Mei-yan; Xiong, Gang; Jiang, Bing; Wang, Lei (2009-07-15). "Potassium aquaterbium(III) oxalate sulfate". Acta Crystallographica Section E 65 (7): i48. doi:10.1107/S1600536809019679. ISSN 1600-5368. PMID 21582643. PMC 2969189. https://scripts.iucr.org/cgi-bin/paper?S1600536809019679. 
  36. ↑ Kohlgruber, Tsuyoshi A.; Felton, Daniel E.; Perry, Samuel N.; Oliver, Allen G.; Burns, Peter C. (2021-02-03). "Effect of Ionothermal Conditions on the Crystallization of Organically Templated Uranyl Sulfate Compounds" (in en). Crystal Growth & Design 21 (2): 861–868. doi:10.1021/acs.cgd.0c01198. ISSN 1528-7483. https://pubs.acs.org/doi/10.1021/acs.cgd.0c01198. 
  37. ↑ 37.0 37.1 Medrish, I. V.; Virovets, A. V.; Peresypkina, E. V.; Serezhkina, L. B. (July 2008). "Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2 · 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2] · 6H2O"] (in en). Russian Journal of Inorganic Chemistry 53 (7): 1034–1039. doi:10.1134/S0036023608070103. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023608070103. 
  38. ↑ 38.0 38.1 38.2 Serezhkin, V. N.; Medrish, I. V.; Serezhkina, L. B. (February 2008). "18-Electron rule and structure of uranyl sulfate complexes" (in en). Russian Journal of Coordination Chemistry 34 (2): 146–155. doi:10.1134/S1070328408020103. ISSN 1070-3284. http://link.springer.com/10.1134/S1070328408020103. 
  39. ↑ 39.0 39.1 Medrish, I. V.; Peresypkina, E. V.; Virovets, A. V.; Serezhkina, L. B. (May 2008). "Crystal structure of M4[(UO2)2C2O4(SO4)2(NCS)2 (M = K+, Rh+) and K4[(UO2)2C2O4(SeO4)2(NCS)2]"] (in en). Crystallography Reports 53 (3): 462–465. doi:10.1134/S1063774508030139. ISSN 1063-7745. Bibcode: 2008CryRp..53..462M. http://link.springer.com/10.1134/S1063774508030139. 
  40. ↑ MISTRYUKOV, V. E; MIKHAILOV, YU N.; KANISHCHEVA, A. S.; SEREZHKINA, L. B.; SEREZHKIN, V. N. (1993). "The crystal structure of Rb2UO2(SO4)C2O4.H2O". The Crystal Structure of Rb2UO2(SO4)C2O4.H2O 38 (9): 1413–1415. ISSN 0036-0236. https://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3802489. 
Compounds containing the sulfate group
H2SO4 He
Li2SO4 BeSO4 B esters
ROSO3−
(RO)2SO2 		(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4 		HOSO4 F Ne
Na2SO4
NaHSO4 		MgSO4 Al2(SO4)3
Al2SO4(OAc)4 		Si P SO42−
HSO3HSO4
(HSO4)2 		Cl Ar
K2SO4
KHSO4 		CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4 		CrSO4
Cr2(SO4)3 		MnSO4 FeSO4
Fe2(SO4)3 		CoSO4 NiSO4 CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4 		ZnSO4 Ga2(SO4)3 Ge As Se Br Kr
RbHSO4
Rb2SO4 		SrSO4 Y2(SO4)3 Zr(SO4)2 Nb Mo Tc Ru Rh2(SO4)3 PdSO4 Ag2SO4 CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2 		Sb2(SO4)3 Te I Xe
Cs2SO4
CsHSO4 		BaSO4   Hf Ta W Re Os Ir Pt AuSO4
Au2(SO4)3 		Hg2SO4
HgSO4 		Tl2SO4
Tl2(SO4)3 		PbSO4 Bi2(SO4)3 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce2(SO4)3
Ce(SO4)2 		Pr2(SO4)3 Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb2(SO4)3 Lu
Ac Th Pa U(SO4)2
UO2SO4 		Np Pu Am Cm Bk Cf Es Fm Md No Lr



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