Chemistry:Praseodymium monoselenide

From HandWiki
Praseodymium monoselenide
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 234-872-0
Properties
PrSe
Molar mass 219.87
Density 6.9 g/cm3
Melting point 2,100 °C (3,810 °F; 2,370 K)
Related compounds
Other anions
PrS
PrTe
Other cations
CeSe
NdSe
Related compounds
Pr2Se3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Praseodymium monoselenide is a compound with the chemical formula PrSe. It forms crystals.

Preparation

Praseodymium monoselenide can be prepared by directly reacting praseodymium and selenium at 2100 °C:[1]

Pr + Se → PrSe

The temperature at which selenium and praseodymium start to react when they come into contact is 620 K.[2]

Properties

Praseodymium monoselenide forms cubic crystals, space group Fm3m, unit cell parameters a = 0.5741 nm, Z = 4, and a structure similar to that of sodium chloride.[3][4]

The compound melts congruently[clarification needed] at 2100 °C.[4]

References

  1. Sergeeva, K. P. (2015-07-28). "The territorial structures in the settlement pattern and urbanization". Izvestiya Rossiiskoi Akademii Nauk. Seriya Geograficheskaya. (2): 122. doi:10.15356/0373-2444-2015-2-122. ISSN 0373-2444. http://dx.doi.org/10.15356/0373-2444-2015-2-122. 
  2. Andreev, O. V.; Kharitontsev, V. B.; Elyshev, A. V. (2013-08-01). "Compositions of phases in the interaction of rare-earth metals with selenium" (in en). Russian Journal of Inorganic Chemistry 58 (8): 910–914. doi:10.1134/S0036023613080020. ISSN 1531-8613. https://doi.org/10.1134/S0036023613080020. 
  3. Predel, B., "Se-Tm (Selenium-Thulium)" (in en), Pu-Re – Zn-Zr (Berlin/Heidelberg: Springer-Verlag): pp. 1–2, doi:10.1007/10551312_2721, ISBN 3-540-61742-6, https://dx.doi.org/10.1007/10551312_2721, retrieved 2024-01-22 
  4. 4.0 4.1 Diagrammy sostojanija dvojnych metalličeskich sistem: spravočnik v trech tomach. 3,2. Moskva: Mašinostroenie. 2001. ISBN 978-5-217-02932-7.