Chemistry:Samarium pentaphosphide
From HandWiki
| Identifiers | |
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3D model (JSmol)
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| Properties | |
| P5Sm | |
| Molar mass | 305.23 g·mol−1 |
| Appearance | crystals |
| Density | 3.99 g/cm3[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Samarium pentaphosphide is a binary inorganic compound of samarium metal and phosphorus with the chemical formula SmP
5.[2][3]
Preparation
Samarium pentaphosphide can be prepared by heating stoichiometric amounts of samarium and phosphorus at 700 °C:
- 4 Sm + 5 P
4 → 4 SmP
5
Properties
Samarium pentaphosphide forms crystals of monoclinic crystal system, spatial group P121/m1 or P21.[4][5] It decomposes at 700 °C.
References
- ↑ "mp-9849: SmP5 (monoclinic, P2_1/m, 11)". Materials Project. https://legacy.materialsproject.org/materials/mp-9849/.
- ↑ (in en) Zeitschrift Für Kristallographie. Akademische Verlagsgesellschaft. 1998. p. 461. https://books.google.com/books?id=FiRIAQAAIAAJ&q=Samarium+pentaphosphide. Retrieved 16 March 2024.
- ↑ (in en) Max-Planck-Gesellschaft Jahrbuch. 1999. p. 249. ISBN 978-3-525-86129-5. https://books.google.com/books?id=VLFMAQAAIAAJ&q=%22Samarium+pentaphosphide+SmP5%22. Retrieved 16 March 2024.
- ↑ Schnering, H. G. von; Wittmann, M.; Peters, K. (1 April 1998). "Crystal structure of praseodymium pentaphosphide, PrP5 and of samarium pentaphosphide, SmP5" (in de). Zeitschrift für Kristallographie - New Crystal Structures 213 (1–4): 489–490. doi:10.1524/ncrs.1998.213.14.489. ISSN 2197-4578. Bibcode: 1998ZK....213..489S.
- ↑ Predel., B. (1998) (in en). Landolt-Börnstein - Group IV Physical Chemistry. p. 1. https://materials.springer.com/lb/docs/sm_lbs_978-3-540-70692-2_2381. Retrieved 16 March 2024.
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