Chemistry:Selenophosphate

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A selenophosphate is a chemical compound containing phosphate anions substituted with selenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond.[1] Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites.[2]

Different structural anions include hexaselenohypodiphosphate [P2Se6]4− and [P6Se12]4− with decalin structure and [P4Se2]2− with dicyclobutane structure.[1]

Selenophosphates are coloured, often orange. They are semiconductors.

The first selenodiphosphate was discovered in 1973 by H. Hahn.[3]

Selenophosphate compounds may have some or all of the selenium replaced by sulfur.[4]

Formation

Selenophosphates can be produced by melting phosphorus selenide with metal selenides.

Molecular biology

Selenocysteine is produced in many organisms from a selenophosphate. In humans and other eucaryotes, this is facilitated by the enzyme selenophosphate synthetase 1. Selenium is connected to phosphorus using a reaction with selenide and adenosine triphosphate[5]

List

formula name mw crystal system space group unit cell Å volume density comments references
[(py2Li)]4[P2Se6]·2py water stable [6]
(NH4)4(P2Se6)(H2O)2 triclinic P1 a=7.3306 b=7.3761 c=9.5501 α =70.405° β =74.109° γ =60.681° Z=1 420.37 2.544 [7]
[pyH]4[P2Se6]·H2O water stable [6]
(NBu4)2P2Se8 bis(Tetrabutylammonium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide acetonitrile solvate monoclinic P21/c a 9.6284 b 16.9553 c 16.0899 β 96.875° chair config [8]
(NBu4)3P9Se14 orange-red [9]
bis(1-Butyl-3-methylimidazolium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide monoclinic P21/n a =7.6642 b =10.9948 c =17.0380 β =91.211° chair config [8]
bis(tetrakis(Acetonitrile-N)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide orthorhombic Pbam a 20.0535(6)Å b 12.1200(5)Å c 15.0831 cradle config [8]
bis((Tetrapyridine)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide triclinic P1 a 10.1582 b 10.7716 c 12.750 α 95.271° β 94.847° γ 114.219° cradle config [8]
Na2P4Se2 red-brown; P4 bicyclo structure [10]
Na3PSe4 cubic I43m a=7.3094 Z=2 3.53 Na ion conductor 1 mS cm−1 [11]
Na4P2Se6 orthorhombic Cmca a = 11.836 b = 13.311 c = 8.061 Z = 4 1270.0 3.283 [12]
Na4(P2Se6)(H2O)6 monoclinic P21/c a 26.0636 b 7.2350 c 20.7197 β 113.387° Z=8 3586.13 2.726 [7]
Mg2P2Se6 R3 a = 6.404 c = 20.194 Z=3 [13]
KPSe6 orthorhombic Pca21 a = 11.49 b = 6.791 c = 11.29 Z = 4 orange; NLO χ(2)≈142.8 pm V−1; band gap 2.1 eV [14][15][16][17]
K4Sc2(PSe4)2(P2Se6) monoclinic C2/c a=22.668Å b=6.8147Å c=19.828 β=113.91° [18]
K2P2Se6 trigonal P3121 a = 7.2728, c = 18.872 Z = 3 at 298 K; SHG 50× AgGaSe2 [19]
K2P2Se6 trigonal P3121 a = 14.4916 c = 18.7999 Z = 12 at 173 K [19]
K3PSe4·2Se6 cubic Fd3 a = 16.415 at 193 K [20]
K4(P2Se6)(H2O)4 orthorhombic Cmca a =11.921 b =12.46 c =11.752 Z=4 1745.6 2.908 [7]
K6P8Se18 1903.66 monoclinic P21/n a=9.746 b=8.332 c=23.054 β=90.54° Z=2 1872.1 3.377 orange [21]
Ca2P2Se6 monoclinic P21/n a = 9.664 b = 7.519 c = 6.859 β = 92.02° [22]
K4Sc2(PSe4)2(P2Se6) 737.82 monoclinic C2/c a=22.668 b=6.815 c=19.828 β =113.91° Z=8 2800.2 3.500 orange-yellow; turns red in air; band gap 2.25 eV [23]
KTiPSe5 [24]
K4Ti2(P2Se9)2(P2Se7) black [24]
Cr2P2Se6 [25]
MnPSe3 trigonal R3 band gap 2.5 eV [26][27]
K2MnP2Se6 monoclinic P21/n a=6.5349 b=12.696 c=7.589 β=102.67° Z=2 614.3 [28]
FePSe3 [26]
Fe2P2Se6 trigonal R3 band gap 1.3 eV [13][27]
K2FeP2Se6 monoclinic P21/n a=6.421 b=12.720 c=7.535 β=102.58 Z=2 600.7 red [28]
CuP2Se 2D semiconductor; metallises under pressure [29]
m-Cu4P2Se6 monoclinic P21/c a 6.370 b 11.780 c 20.013 β 90.03° [30]
Cu3PSe4 orthorhombic Pmn21 a=7.700 b=6.677 c=6.385 328.3 [31]
t-Cu4P2Se6 triclinic P1 a 7.104 b 11.889 c 12.759 α 74.35° β 79.63° γ 80.85° [30]
Cu4P3Se4 triclinic P1 a 6.440 b 7.085 c 10.616 α 73.11° β 74.86° γ 77.00° [30]
Cu4P4Se3 monoclinic P21/c a 16.446 b 6.515 c 17.339 β 119.08° [30]
CuP2Se orthorhombic Pbca a 5.608 b 6.496 c 16.570 [30]
CuAl[P2Se6] trigonal R3 a = 6.2795 c = 19.9713 Z =3 [32]
K2Cu2P4Se10 1118.78 monoclinic P21/n a=10.627 b=7.767 c=11.966 β=109.125° Z=2 933.2 3.981 red [33]
K3Cu3P3Se9 monoclinic P21/c a = 8.741 b = 10.774, c = 20.033, β = 92.96° [34][35]
[Cu12(P2Se6){Se2P(OEt)2}8] Et=Ethyl; diethyl diselenophosphate hexaselenodiphosphate(IV) [36]
[Cu12(P2Se6){Se2P(OiPr)2}8] iPr=isopropyl [36]
CuCr[P2Se6] monoclinic C2/m a=6.193 b=10.724 c=6.909 β=107.2° Z=2 690.2 4.9 melt 730 °C; dark red [3]
Zn2P2Se6 R3 a = 6.290 c = 19.93 Z=3 [13]
K2ZnP2Se6 monoclinic P21/c a = 12.537 b = 7.274 c = 14.164 β = 109.63° Z = 4 1216 yellow [37][38]
K4GeP4Se12 orthorhombic Pca21 a=13.9465 b=7.2435 c=24.0511 [39]
K4Ge4-xPxSe12 monoclinic P21/c a = 6.7388 b = 13.489 c = 6.3904 β = 91.025° [40]
K7As3(P2Se6)4 monoclinic P21/c a=25.0706 b=9.5948 c=59.6227 β=93.384° melt 388°C [41]
K6As2(P2Se6)3 monoclinic P21/c a 8.0898 b 23.3142 c 12.1919 β 124.809° melt 410°C; orange; band gap 2.2 eV [41]
RbPSe6 orthorhombic Pca21 a = 11.776 b = 6.858 c = 11.460 Z = 4 NLO χ(2)≈150 pm V−1 [15][16]
Rb2P2Se6 trigonal P3121 a = 7.2982 c = 19.002 and Z = 3 100 K [19]
Rb4P2Se9 monoclinic C2/c a = 9.725 b = 10.468 c = 19.155 β = 93.627° Z = 4 1946.1 3.804 [12]
Rb4P6Se12 orthorhombic Pca21 a =16.409 b =10.64 c =15.105 bicyclic with >PP< bridge and -SePSe2PSe2Se- ring [42]
Rb10P4Se25 [43]
Rb4(P2Se6)(H2O)4 orthorhombic Pnnm a 9.834 b 12.456 c 7.585 Z=2 929.1 3.395 [7]
RbTiPSe5 [24]
Rb4Ti2(P2Se9)2(P2Se7) orthorhombic Fdd2 a=35.55 b=37.315 c=6.574 Z=4 8772 3.956 black [24][44]
Rb2MnP2Se6 [28]
Rb2ZnP2Se6 triclinic P1 a = 7.494 b = 7.601 c = 12.729 α = 96.57° β = 105.52° γ = 110.54° Z = 2 636.6 [38]
Rb4GeP4Se12 orthorhombic Pca21 a=14.1881 b=7.3566 c=24.2914 [39]
Rb6Ge2P2Se14 triclinic P1 a = 7.2463 b = 9.707 c = 11.987 α = 79.516° β = 89.524° γ = 68.281° band gap 2.2 eV [40]
Sr2P2Se6 monoclinic P21/n a = 9.844 b = 7.788 c = 6.963 β = 91.50° Z=2 [22]
NaYP2Se6 647.6 triclinic P1 a=6.9456 b=7.4085 c=9.5306 α=88.819° β=87.748° γ=89.580° Z=2 yellow [45][46] follow up refs
KYP2Se6 orthorhombic P212121 a = 6.7366 b = 7.4286 c = 21.603 Z = 4 [45][47]
[(Cp′′2Zr)2(μ,η1:1:1:1-P2Se4)] Cp′′ = C5H3tBu2 1269.41 monoclinic P21/n a=15.2831 b=9.91947 c=18.6250 β=102.835° Z=2 2753 1.531 dark purple [48]
KZrPSe6 orthorhombic Pmc21 a=3.7079 b=15.074 c=18.491 [49]
RbZrPSe6 [49]
KNb2PSe10 monoclinic Pc a=7.2931 b=15.612 c=13.557 β=106.64° resistivity 4.5 Ω·cm [50]
RbNb2PSe10 monoclinic Pc a=7.381 b=7.8359 c=13.564 β=106.75° [50]
K3RuP5Se10 monoclinic P21/m a 11.2099 b 7.2868 c 12.3474 β 93.958° [51]
PdPSe semiconductor [52]
K2PdP2Se6 [24]
Rb2PdP2Se6 [24]
Ag4P2Se6 1013.69 orthorhombic P212121 a=6.5760 b=11.5819 c=14.137 Z=4 1076.8 5.966 melt 642 °C; dark red [53]
AgAl[P2Se6] monoclinic C2/m a=6.348 b=10.989 c=7.028 β=107.2° Z=2 melt 588 °C; yellow [3]
K2Ag2P2Se6 monoclinic P21/c a=8.528 b=11.251 c=20.975 β=93.24° Z=4 2009 orange [28]
AgCr[P2Se6] monoclinic C2/m a=6.305 b=10.917; c=6.991 β=107.7° Z=2 melt 720 °C; dark red [3]
AgGa[P2Se6] orthorhombic Pbca α=12.169 b=22.484 c=7.473 Z=4 2044.7 melt 450 °C; orange [3]
AgGa[P2Se6] trigonal P31/c a=6.375 c=13.320 Z=2 468.81 5.05 dark red [3]
AgScP2Se6 688.54 trigonal P31/c a=6.463 c=13.249 Z=2 482.93 4.735 orange or brown [54]
CdPSe3 [26]
K2CdP2Se6 monoclinic P21/n dark yellow [37]
Rb2CdP2Se6 819.05 monoclinic P21/n a=6.640 b=12.729 c=7.778 β=98.24° Z=2 650.5 4.180 dark yellow; air stable [37]
Rb8Cd4(Se2)(PSe4)4 [24]
InPSe3 [26]
In2(P3Se9) monoclinic P21/n [34]
LiInP2Se6 657.46 trigonal P31/c a=6.397 c=13.350 Z=2 473.15 4.615 band gap 2.06 eV [55]
(Ph4P)[In(P2Se6)] monoclinic C2/c a = 23.127 b = 6.564 c = 19.083 β = 97.42° Z = 4 2873 @23 °C yellow [56]
KInP2Se6 monoclinic P21/n a=7.511 b=6.4861 c=22.789 β=98.91° Z=4 1096.9 [57]
K5In3(μ3-Se)(P2Se6)3 triclinic P1 a 7.6603 b 13.1854 c 18.378 α 87.04° β 88.659° γ 82.025° [58]
K4In4(μ-Se)2(P2Se6)3 monoclinic P21/c a 19.707 b 7.712 c 13.229 α 90° β 106.42° [58]
K4In2(PSe5)2(P2Se6) monoclinic Cc a=11.1564 b=22.8771 c=12.6525 β=109.039° Z=4 brick-red; air stable [59]
K4In4(μ-Se)(P2S2.36Se3.64)3 triclinic P1 a 7.7709 b 13.0007 c 18.9382 α 105.382° β 92.632° γ 91.91° [58]
CuInP2Se6 trigonal P31/c a=6.392 c=13.338 Z=2 472.0 5.0 melt 642 °C; dark red [3]
AgInP2Se6 trigonal P31/c a=6.483 c=13.330 Z=2 485.2 5.2 semiconductor; melt 673 °C; dark red; band gap 1.79 eV [60][3]
SnP2Se6 R3 a = 6.3213 c = 19.962 band gap 1.36–1.41 eV [61]
Sn2P2Se6 [62]
Na11.1Sn2.1P0.9Se12 tetragonal I41/acd a=14.2446 c=28.473 Z=8 5777.4 3.403 Na+ ion conductivity 3.0 mS/cm [63]
Rb3Sn(PSe5)(P2Se6) monoclinic P21/a a=14.013 b=7.3436 c=21.983 β=106.61° Z=4 black [59]
K10Sn3(P2Se6)4 trigonal R3 a = 24.1184 c = 7.6482 @100K; band gap 1.82 eV [64]
Rb4Sn5P4Se20 2638.41 trigonal P3m1 a=7.6163 c=18.6898 Z=1 938.91 4.64 black [65]
Rb4Sn2Ag4(P2Se6)2 monoclinic P21/n a=11.189 b=7.688 c=21.850 β=94.31° Z=2 1874.2 4.639 black [24][66]
Rb5[Sn(PSe5)3] triclinic P1 a 11.745 b 19.23 c 7.278 α 99.97° β 107.03° γ 87.16° [67]
Sb4(P2Se6)3 monoclinic P21/n a = 20.777 b = 7.4935 c = 9.4949 β = 91.25° [68]
KSbP2Se6 696.55 [34]
β-KSbP2Se6 696.55 monoclinic P21 a=6.8925 b=7.8523 c=10.166 β=91.487 Z=2 550.4 4.203 dark red [69]
AgSbP2Se6 hygroscopic [70]
α-CsPSe6 monoclinic P21/n a = 6.877 b = 12.713 c = 11.242 β = 92.735° Z = 4 orange [14][15]
β-CsPSe6 637.64 tetragonal P421c a = 12.526 c = 12.781 Z = 8 2005.3 4.224 red orange; metastable; SHG χ(2) ∼30 pm/V [14]
Cs2P2Se8 orthorhombic Ccce a = 14.982 b = 24.579 c = 13.065 band gap 2.44 ± 0.2 eV; P2Se4 ring; third harmonic generator coefficient 2.4 ± 0.1 × 105 pm2/V2 [71]
Cs3PSe4 orthorhombic Pnma a = 10.0146 b = 11.990 c = 9.9286 Z = 4 1192.2 4.154 [12]
Cs4P2Se9 [24]
Cs4P2Se10 triclinic P1 a=7.359 b=7.455 c=10.142 α=85.938°, β=88.055° γ=85.609° [P2Se10]4− [72]
Cs4[P6Se12] 1664.98 monoclinic P21/n a =10.836 b =10.5437 c =12.273 β =98.661° 1386.3 3.989 orange; melt 697; NLO [73]
Cs5[P5Se12] 1766.92 tetragonal P4 a =13.968 c =7.546 Z=2 1472.2 3.986 orange; NLO; band gap 2.17 eV [73][74]
Cs10P8Se20 orthorhombic Pnnm a = 26.5456 b = 8.0254 c = 11.9031 Z = 2 2535.8 4.133 (PSe2)3Se rings and P2Se6 [75]
Cs4(P2Se6)(H2O)4 orthorhombic Pnnm a=10.0514 b=12.6867 c=7.8403 Z=2 999.8 3.775 [7]
K0.6Cs0.4PSe6 orthorhombic Pca21 a=11.830 b=6.908 c=11.516 Z=4 941.1 4.085 orange; band gap 2.1 eV; SHG χ(2) ∼150 pm/V [14]
KCsP2Se8 orthorhombic Ccce a = 14.782 b = 23.954 c = 13.044 band gap 2.36 ± 0.2 eV [71]
Cs2MnP2Se6 monoclinic P21/n 6.4761 b=13.006 c=7.974 β=93.09° Z=2 670.6 [28]
Cs2FeP2Se6 [28]
Cs2Cu2P2Se6 monoclinic P21/c a=9.958 b=13.067 c=10.720 β=102.46° Z=4 1363 dark green [28]
Cs2ZnP2Se6 triclinic P1 a = 7.6543 b = 7.7006 c = 12.737 α = 97.007° β = 104.335° γ = 109.241° Z = 2 669.5 yellow; band gap 2.67 eV [38][74]
Cs4GeP4Se12 orthorhombic Pca21 a=14.3268 b=7.6202 c=24.6301 [39]
Cs6As2(P2Se6)3 monoclinic P21/c a=19.5759 b=7.9206 c=13.0553 β=101.914° orange band gap 2.1 eV [41]
Cs5As(P2Se6)2 tetragonal P42/m a=13.826 c=7.5173 melt 416°C; red; band gap 2.0 eV [41]
RbCsP2Se8 orthorhombic Ccce band gap 2.41 ± 0.2 eV [71]
CsZrPSe6 band gap 2.0 eV [74][49]
CsNb2PSe10 monoclinic Pc a=14.6257 b=7.8097 c=13.5533 β=98.557° [50]
Cs4Pd(PSe4)2 monoclinic P21/c a = 7.491 b = 13.340 c = 10.030 β = 92.21° Z = 2 red [76]
Cs10Pd(PSe4)4 tetragonal P42c a = 13.949 c = 11.527 Z = 4 red [76]
Cs2PdP2Se6 tetragonal P42/mnm a = 8.5337 c = 10.5595 Z = 4 black [76]
Cs2Ag2P2Se6 monoclinic P21/n a=6.807 b=12.517 c=8.462 β=95.75° Z=2 717.3 yellow [28]
Cs2CdP2Se6 monoclinic P21/n yellow [37]
Cs5In(P2Se6)2 tetragonal P42/m a = 13.886 c = 7.597 Z = 2 1464.9 @23 °C; dark orange [56]
Cs4Sn(P2Se6)2 1721.73 trigonal R3 a=7.808 c=37.905 Z=3 2001.4 4.285 black [77]
α-Cs2SnP2Se6 920.2 monoclinic P21/c a=10.230 b =12.990 c=10.949 β=94.529° 1450.5 4.2126 orange [77]
Cs2SnP2Se6 monoclinic P21/c a = 10.1160 b = 12.7867 c = 11.0828 β = 94.463° @100K [64]
Cs4(Sn3Se8)[Sn(P2Se6)]2 2828.17 tyrigonal P3m1 a=7.695 c=18.797 Z=1 964.0 4.872 black; 2D [77]
Cs6[Sn2Se4(PSe5)2] triclinic P1 a 9.899 b 12.416 c 7.497 α 91.62° β 110.19° γ 79.94° [67]
CuSbP2Se6 C2/m [78]
AgSbP2Se6 C2/m [78]
Cs8Sb4(P2Se6)5 [34]
Ba2P2Se6 monoclinic P21/n a = 10.355 b = 7.862 c = 7.046 β = 90.83° Z=2 [22]
Ba3(PSe4)2 monoclinic P21/a a = 12.282 b = 6.906 c = 18.061 β = 90.23° Z = 4 [79][80]
Ba3PO4PSe4 triclinic P1 a=6.779 b=7.108 c=12.727 α=82.45 β=78.88 γ=81.34 Z=2 orange [79]
KBaPSe4 orthorhombic Pnma a=11.972 b=6.973 c=10.388 Z=4 pale orange [79]
KLaP2Se6 713.71 monoclinic P21/c a=12.425 b=7.8047 c=11.9279 β=109.612° 1089.6 4.351 yellow [34]
K2La(P2Se6)1/2(PSe4) monoclinic P21/n a = 9.4269 b = 7.2054 c = 21.0276 β = 97.484° Z = 4 [81]
K3La(PSe4)2 monoclinic P21/c a = 9.5782 b = 17.6623 c = 9.9869 β = 90.120° Z = 4 [81]
K3LaP2Se8
K4La0.67(PSe4)2 orthorhombic Ibam a = 19.0962 b = 9.1408 c = 10.2588 Z = 4 [81]
K6LaP4Se16
K8.5La1+1/3(PSe4)4 orthorhombic Ccca a = 18.2133 b = 38.0914 c = 10.2665 Z = 8 [81]
Ce4(P2Se6)3 722.06 monoclinic P21/c a = 6.8057 b = 22.969 c = 11.7226 β = 124.096° Z = 6 4.741 orange [82]
NaCeP2Se6 monoclinic P21/c a = 12.1422 b = 7.6982 c = 11.7399 β = 111.545° Z=4 yellow [82]
KCeP2Se6 monoclinic P21/c [45]
Cu0.4Ce1.2P2Se6 monoclinic P21/c a = 12.040 b = 7.6418 c = 11.700 β = 111.269° Z = 4 yellow [82]
Rb2CeP2Se7 monoclinic P21/n red; air sensitive [83]
Rb3CeP2Se8 1090.13 monoclinic P21/c a = 9.6013 b = 18.0604 c = 10.0931 β = 90.619° Z = 4 1750.07 4.137 orange; air sensitive [83]
Rb9Ce(PSe4)4 monoclinic C2/c a=21.446 b=10.575 c=18.784 β =115.94° Z=4 3831 3.980 orange; air and water destroyed; soluble in 18-crown-6 + dmf; band gap 2.26 eV [43]
AgCeP2Se6 monoclinic P21/c a = 9.971 b = 7.482 c = 11.757 β = 145.630° Z=2 orange [82]
CsCe[P2Se6] monoclinic P21/c a = 12.9786 b = 7.7624 c = 11.9843 β = 106.589° Z = 4 [84]
KPrP2Se6 monoclinic P21/c [45]
Cs2PrP2Se7 monoclinic P21/n a=10.2118 b=7.2423 c=20.3741 β =98.624° Z=4 [85]
Eu2P2Se6 monoclinic P21/n a = 9.779 b = 7.793 c = 6.957 β = 91.29° Z=2 [22]
LiEuPSe4 orthorhombic Ama2 a = 10.5592 b = 10.415 c = 6.4924 Z = 4 red; air unstable [86]
Na8Eu2(Si2Se6)2 monoclinic C2/m a=7.090 b=12.228 c=7.950 β=107.427° Z = 1 657.6 [87]
KEuPSe4 monoclinic P21/m a = 6.8469 b = 6.9521 c = 9.0436 β = 107.677° Z = 2 red; air unstable [86]
KEuPSe4 orthorhombic Pnma a = 17.516 b = 7.0126 c = 6.9015 Z = 4 [81]
K4Eu(PSe4)2 orthorhombic Ibam a = 19.020 b = 9.131 c = 10.198 Z = 4 [34][88]
Cs3GdP2Se8 monoclinic P21/c [83]
NaSmP2Se6 709.94 triclinic P1 a 6.8368 b 7.5312 c 9.557 α 90.799° β 91.910° γ 90.351° Z=2 red [45]
Na9Sm(Ge2Se6)2 monoclinic C2/m a = 7.916 b = 12.244 c = 7.105 β = 106.99° Z = 1 658.6 [87]
KSmP2Se6 725.15 monoclinic P21 a=6.7888 b=7.6185 c=10.1962 β=91.508 Z=2 527.17 4.568 red [89]
CsSmP2Se6 orthorhombic P212121 a = 6.8867 b = 7.5448 c = 22.152 Z = 4 [45][84]
NaGdP2Se6 715.94 triclinic P1 a 6.8464 b 7.4916 c 9.5372 α 90.813° β 92.026° γ 90.241° Z=2 yellow [45]
KGdP2Se6 monoclinic P21 a=6.7802 b=7.5809 c=10.1967 β=91.638 Z=2 523.97 4.640 yellow [45][89]
Rb2GdP2Se7 1037.73 monoclinic P21/n a = 10.137 b = 7.212 c = 20.299 β = 98.23° Z = 4 1468.8 4.692 orange; air sensitive [83]
NaTbP2Se6 717.61 triclinic P1 a 6.8854 b 7.4580 c 9.5196 α 89.068° β 87.899° γ 89.974° Z=2 yellow [45]
KTbP2Se6 monoclinic P21 a=6.7609 b=7.5570 c=10.2158 β=91.732 Z=2 521.71 4.671 yellow [45][89]
KTbP2Se6 orthorhombic red over 9.2 GPa [90]
NaDyP2Se6 721.19 triclinic P1 a 6.9114 b 7.4258 c 9.5256 α 88.914° β 87.829° γ 89.695° Z=2 yellow [45]
CsEr[P2Se6] monoclinic P21/c a = 7.5381 b = 12.8192 c = 12.7647 β = 106.898° Z = 4 [84]
AgErP2Se6 810.83 trigonal P31/c a=6.578 c=13.410 Z=2 502.6 5.358 dark brown [54]
AgTmP2Se6 812.50 trigonal P31/c a=6.567 c=13.422 Z=2 501.27 5.383 dark brown [54]
K3AuP2Se8 monoclinic Cc a = 7.122 b = 12.527 c = 18.666 β = 96.06° Z = 4 [91]
Rb3AuP2Se8 monoclinic Cc [91]
Cs3AuP2Se8 monoclinic Cc [91]
K2Au2P2Se6 monoclinic C2/m a = 12.289 b = 7.210 c = 8.107 β = 115.13° Z = 2 black [91]
Rb2Au2P2Se6 monoclinic C2/m [91]
Rb2Au2P2Se6 monoclinic P21/n a=11.961 b=10.069 c=32.137 β=91.37° Z=12 3869 4.653 @-120 °C black [92]
Hg2P2Se6 [34][93]
K2HgP2Se6 monoclinic P21/c a=13.031 b=7.308 c=14.167 β=110.63° Z=4 1262.6 4.285 dark yellow [37]
Rb2HgP2Se6 monoclinic P21/c drak yellow [37]
Rb8Hg4(Se2)(PSe4)4 P42/n a=17.654 c=7.226 [24][94]
Tl4P2Se6 trigonal R3 a=6.3808 c= 20.014 melt 963 K [34][95]
TlInP2Se6 triclinic P1 a=6.4488 b=7.5420 c=12.166 α=100.72° β=93.63° γ=113.32° melt 875K [96][95]
TlSbP2Se6 monoclinic P21 a = 6.843 b = 7.841 c = 9.985 β = 90.77° Z = 2 melt 720K; band gap 1.75 eV [97]
Pb2P2Se6 monoclinic Pn a = 9.742 b = 7.662 c = 6.898 β=91.44° Z=2 514.73 6.13 melt 812 °C;band gap 1.88 eV [34][98][99]
Na1.5Pb0.75PSe4 cubic I43d a=14.3479 Z=16 band gap 2 eV [100]
RbPbPSe4 red water stable [88]
Rb4Pb(PSe4)2 orthorhombic Ibam a = 19.134 b = 9.369 c = 10.488 Z = 4 orange water unstable [88]
CsPbPSe4 orthorhombic Pnma a = 18.607 b = 7.096 c = 6.612 Z = 4 red water stable [88]
Cs4Pb(PSe4)2 orange water unstable [88]
Bi4(P2Se6)3 monoclinic P21/n a = 20.869 b = 7.4745 c = 9.5923 β = 91.73° [68]
β-Bi4(P2Se6)3 triclinic P1 a = 12.2303 b = 6.7640 c = 17.866 α = 90.493° β = 94.133° γ = 91.163° black [101]
KBiP2Se6 783.78 monoclinic P21 a 6.9183 b 7.663 c 10.239 β 91.508° Z=2 542.6 4.797 [34][69]
CuBiP2Se6 R3 a = 6.553 c = 39.76 lamellar; p-type semiconductor; work function 5.26 eV [102][103]
AgBiP2Se6 R3 a = 6.652 c = 39.61 lamellar [102]
Cs5BiP4Se12 orthorhombic Pmc21 a = 7.5357 b = 13.7783 c = 28.0807 Z = 4 band gap 1.85 eV; melt 590 °C [104]
α-TlBiP2Se6 monoclinic P2l/c a =12.539 b =7.499 c =12.248 β =113.731° chains; band gap 1.23,1eV [105]
β-TlBiP2Se6 monoclinic P2l/c a =12.25 b =7.5518 c =22.834 β =97.65° melt 544 °C; layers; band gap 1.27 eV [105]
K2ThP3Se9 triclinic P1 a = 10.4582 b = 16.5384 c = 10.2245 α = 107.637 β = 91.652 γ = 90.343° Z = 2 [106]
β-K2ThP3Se9 monoclinic P21/n a = 10.2697 b = 7.7765 c = 20.472 β = 92.877° Z = 4 yellow [107]
Rb2ThP3Se9 triclinic P1 a = 10.5369 b = 16.6914, c = 10.2864 α = 107.614° β = 92.059° γ = 90.409° Z = 2 [106]
Rb7Th2P6Se21 triclinic P1 a = 11.531 b = 12.359 c = 16.161 α = 87.289° β = 75.903° γ = 88.041° Z = 2 red; band gap 2.0 eV [108]
Cs4Th4P4Se26 orthorhombic Pbca a = 12.0130 b = 14.5747 c = 27.134 Z = 8 orange; (P2Se9)6- anion [109]
Cs4Th2P5Se17 monoclinic P2l/c a = 10.238 b = 32.182 c = 10.749 β = 95.832° Z = 4 [106]
K2UP3Se9 triclinic P1 a = 10.407( b = 16.491 c = 10.143 α= 107.51° β = 91.74° γ = 90.28° Z = 4 black [24][110]
Rb4U2P5Se17 triclinic P1 a =10.0824 b = 10.6905 c = 15.7845 α = 84.678 β = 76.125 γ = 85.874° @100K [111]
Rb4U4P4Se26 3470.84 orthorhombic Pbca a=11.9779 b=14.4874 c=27.1377 Z=4 4709.17 4.895 U5+ [112]
Cs2U2(P2Se9)(Se2)2 orthorhombic Pbca a 11.769 b 14.389 c 26.537 black [113]


References

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  2. ↑ Sanna, Michela; Ng, Siowwoon; Pumera, Martin (August 2021). "Layered transition metal selenophosphites for visible light photoelectrochemical production of hydrogen". Electrochemistry Communications 129: 107077. doi:10.1016/j.elecom.2021.107077. 
  3. ↑ 3.0 3.1 3.2 3.3 3.4 3.5 3.6 3.7 Pfeiff, Regine; Kniep, Rüdiger (July 1992). "Quaternary selenodiphosphates(IV): MIMIII[P2Se6, (MI =Cu, Ag; MIII = Cr, Al, Ga, In)"] (in en). Journal of Alloys and Compounds 186 (1): 111–133. doi:10.1016/0925-8388(92)90626-K. https://linkinghub.elsevier.com/retrieve/pii/092583889290626K. 
  4. ↑ Krauskopf, Thorben; Pompe, Constantin; Kraft, Marvin A.; Zeier, Wolfgang G. (24 October 2017). "Influence of Lattice Dynamics on Na + Transport in the Solid Electrolyte Na 3 PS 4– x Se x". Chemistry of Materials 29 (20): 8859–8869. doi:10.1021/acs.chemmater.7b03474. 
  5. ↑ Tamura, Takashi; Yamamoto, Shinpei; Takahata, Muneaki; Sakaguchi, Hiromich; Tanaka, Hidehiko; Stadtman, Thressa C.; Inagaki, Kenji (16 November 2004). "Selenophosphate synthetase genes from lung adenocarcinoma cells: Sps1 for recycling l -selenocysteine and Sps2 for selenite assimilation". Proceedings of the National Academy of Sciences 101 (46): 16162–16167. doi:10.1073/pnas.0406313101. PMID 15534230. Bibcode: 2004PNAS..10116162T. 
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  7. ↑ 7.0 7.1 7.2 7.3 7.4 Rothenberger, Alexander; Malliakas, Christos D.; Kanatzidis, Mercouri G. (July 2009). "Hydrated Alkali Metal and Ammonium Salts of the [P 2 Se 6 4– Anion"] (in en). Zeitschrift für anorganische und allgemeine Chemie 635 (9–10): 1374–1379. doi:10.1002/zaac.200900184. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200900184. 
  8. ↑ 8.0 8.1 8.2 8.3 Rotter, Christiane; Schuster, Michael; Kidik, Mustafa; Schön, Oliver; Klapötke, Thomas M.; Karaghiosoff, Konstantin (2008-03-01). "Structural and NMR Spectroscopic Investigations of Chair and Twist Conformers of the P 2 Se 8 2− Anion" (in en). Inorganic Chemistry 47 (5): 1663–1673. doi:10.1021/ic7015534. ISSN 0020-1669. PMID 18237117. https://pubs.acs.org/doi/10.1021/ic7015534. 
  9. ↑ Karaghiosoff, Konstantin; Schuster, Michael (2001-01-01). "Monomeric, Dimeric, and Trimeric Triselenometaphosphate" (in en). Phosphorus, Sulfur, and Silicon and the Related Elements 168 (1): 117–122. doi:10.1080/10426500108546540. ISSN 1042-6507. https://www.tandfonline.com/doi/full/10.1080/10426500108546540. 
  10. ↑ Rotter, Christiane; Schuster, Michael; Karaghiosoff, Konstantin (2009-08-17). "An Unusual Binary Phosphorus−Tellurium Anion and Its Seleno- and Thio- Analogues: P 4 Ch 2 2− (Ch = S, Se, Te)" (in en). Inorganic Chemistry 48 (16): 7531–7533. doi:10.1021/ic901149m. ISSN 0020-1669. PMID 19621885. https://pubs.acs.org/doi/10.1021/ic901149m. 
  11. ↑ Zhang, Long; Yang, Kun; Mi, Jianli; Lu, Lei; Zhao, Linran; Wang, Limin; Li, Yueming; Zeng, Hong (December 2015). "Solid Electrolytes: Na 3 PSe 4 : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity (Adv. Energy Mater. 24/2015)" (in en). Advanced Energy Materials 5 (24). doi:10.1002/aenm.201570133. ISSN 1614-6832. https://onlinelibrary.wiley.com/doi/10.1002/aenm.201570133. 
  12. ↑ 12.0 12.1 12.2 Knaust, Jacqueline M.; Dorhout, Peter K. (March 2006). "Synthesis and structures of Na4P2Se6, Cs3PSe4, and Rb4P2Se9" (in en). Journal of Chemical Crystallography 36 (3): 217–223. doi:10.1007/s10870-005-9050-8. ISSN 1074-1542. http://link.springer.com/10.1007/s10870-005-9050-8. 
  13. ↑ 13.0 13.1 13.2 Jörgens, Stefan; Mewis, Albrecht (January 2004). "Die Kristallstrukturen von Hexachalcogeno-Hypodiphosphaten des Magnesiums und Zinks" (in en). Zeitschrift für anorganische und allgemeine Chemie 630 (1): 51–57. doi:10.1002/zaac.200300244. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200300244. 
  14. ↑ 14.0 14.1 14.2 14.3 Haynes, Alyssa S.; Saouma, Felix O.; Otieno, Calford O.; Clark, Daniel J.; Shoemaker, Daniel P.; Jang, Joon I.; Kanatzidis, Mercouri G. (2015-03-10). "Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K (1– x ) Cs x PSe 6 and Metastable β-CsPSe 6" (in en). Chemistry of Materials 27 (5): 1837–1846. doi:10.1021/acs.chemmater.5b00065. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.5b00065. 
  15. ↑ 15.0 15.1 15.2 Chung, In; Do, Junghwan; Canlas, Christian G.; Weliky, David P.; Kanatzidis, Mercouri G. (2004-05-01). "APSe 6 (A = K, Rb, and Cs): Polymeric Selenophosphates with Reversible Phase-Change Properties" (in en). Inorganic Chemistry 43 (9): 2762–2764. doi:10.1021/ic035448q. ISSN 0020-1669. PMID 15106958. https://pubs.acs.org/doi/10.1021/ic035448q. 
  16. ↑ 16.0 16.1 Chung, In; Kim, Myung-Gil; Jang, Joon I.; He, Jiaqing; Ketterson, John B.; Kanatzidis, Mercouri G. (2011-11-11). "Strongly Nonlinear Optical Chalcogenide Thin Films of APSe 6 (A=K, Rb) from Spin-Coating" (in en). Angewandte Chemie International Edition 50 (46): 10867–10870. doi:10.1002/anie.201103691. ISSN 1433-7851. PMID 21936037. https://onlinelibrary.wiley.com/doi/10.1002/anie.201103691. 
  17. ↑ Jang, J. I.; Haynes, A. S.; Saouma, F. O.; Otieno, C. O.; Kanatzidis, M. G. (2013-09-01). "Broadband studies of the strong mid-infrared nonlinear optical responses of KPSe_6" (in en). Optical Materials Express 3 (9): 1302. doi:10.1364/OME.3.001302. ISSN 2159-3930. Bibcode: 2013OMExp...3.1302J. https://opg.optica.org/ome/abstract.cfm?uri=ome-3-9-1302. 
  18. ↑ Syrigos, Jonathan C.; Kanatzidis, Mercouri G. (2016-05-02). "Scandium Selenophosphates: Structure and Properties of K 4 Sc 2 (PSe 4 ) 2 (P 2 Se 6 )" (in en). Inorganic Chemistry 55 (9): 4664–4668. doi:10.1021/acs.inorgchem.6b00535. ISSN 0020-1669. PMID 27078201. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b00535. 
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  21. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-05-01). "[P 8 Se 18 6 - : A New Oligomeric Selenophosphate Anion with P 4+ and P 3+ Centers and Pyramidal [PSe 3 ] Fragments"] (in en). Inorganic Chemistry 37 (10): 2582–2584. doi:10.1021/ic980024v. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/ic980024v. 
  22. ↑ 22.0 22.1 22.2 22.3 Jörgens, Stefan; Mewis, Albrecht; Hoffmann, Rolf-Dieter; Pöttgen, Rainer; Mosel, Bernd D. (March 2003). "Neue Hexachalcogeno-Hypodiphosphate der Erdalkalimetalle und des Europiums" (in en). Zeitschrift für anorganische und allgemeine Chemie 629 (3): 429–433. doi:10.1002/zaac.200390071. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200390071. 
  23. ↑ Syrigos, Jonathan C.; Kanatzidis, Mercouri G. (2016-05-02). "Scandium Selenophosphates: Structure and Properties of K 4 Sc 2 (PSe 4 ) 2 (P 2 Se 6 )" (in en). Inorganic Chemistry 55 (9): 4664–4668. doi:10.1021/acs.inorgchem.6b00535. ISSN 0020-1669. PMID 27078201. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b00535. 
  24. ↑ 24.00 24.01 24.02 24.03 24.04 24.05 24.06 24.07 24.08 24.09 24.10 Konstantinos, Chondroudis (1997). "Molten salt synthesis of multinary selenophosphates" (in en). https://www.proquest.com/openview/6b04fd46d6bd3b91ce7d70978798767b/1. 
  25. ↑ Qian, Eric K.; Iyer, Abishek K.; Cheng, Matthew; Ryan, Kevin M.; Jirousek, Lillian; Chica, Daniel G.; Krantz, Patrick; Lee, Yea-Shine et al. (2023-05-09). "Synthesizing Mono- and Bimetallic 2D Selenophosphates Using a P 2 Se 5 Reactive Flux" (in en). Chemistry of Materials 35 (9): 3671–3685. doi:10.1021/acs.chemmater.3c00342. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.3c00342. 
  26. ↑ 26.0 26.1 26.2 26.3 Chen, Xu; Wang, Junjie; Ying, Tianping; Huang, Dajian; Gou, Huiyang; Zhang, Qinghua; Li, Yanchun; Hosono, Hideo et al. (2022-11-02). "Insulator-metal-superconductor transition in the medium-entropy van der Waals compound M P Se 3 ( M = Fe , Mn , Cd , and In ) under high pressure" (in en). Physical Review B 106 (18): 184502. doi:10.1103/PhysRevB.106.184502. ISSN 2469-9950. https://link.aps.org/doi/10.1103/PhysRevB.106.184502. 
  27. ↑ 27.0 27.1 Du, Ke-zhao; Wang, Xing-zhi; Liu, Yang; Hu, Peng; Utama, M. Iqbal Bakti; Gan, Chee Kwan; Xiong, Qihua; Kloc, Christian (2016-02-23). "Weak Van der Waals Stacking, Wide-Range Band Gap, and Raman Study on Ultrathin Layers of Metal Phosphorus Trichalcogenides" (in en). ACS Nano 10 (2): 1738–1743. doi:10.1021/acsnano.5b05927. ISSN 1936-0851. PMID 26607168. https://pubs.acs.org/doi/10.1021/acsnano.5b05927. 
  28. ↑ 28.0 28.1 28.2 28.3 28.4 28.5 28.6 28.7 McCarthy, Timothy J.; Kanatzidis, Mercouri G. (March 1995). "Synthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)" (in en). Inorganic Chemistry 34 (5): 1257–1267. doi:10.1021/ic00109a037. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00109a037. 
  29. ↑ Li, Weiwei; Feng, Jiajia; Zhang, Xiaoliang; Li, Cong; Dong, Hongliang; Deng, Wen; Liu, Junxiu; Tian, Hua et al. (2021-12-08). "Metallization and Superconductivity in the van der Waals Compound CuP 2 Se through Pressure-Tuning of the Interlayer Coupling" (in en). Journal of the American Chemical Society 143 (48): 20343–20355. doi:10.1021/jacs.1c09735. ISSN 0002-7863. PMID 34813695. https://pubs.acs.org/doi/10.1021/jacs.1c09735. 
  30. ↑ 30.0 30.1 30.2 30.3 30.4 Kuhn, Alexander; Schoop, Leslie M.; Eger, Roland; Moudrakovski, Igor; Schwarzmüller, Stefan; Duppel, Viola; Kremer, Reinhard K.; Oeckler, Oliver et al. (2016-08-15). "Copper Selenidophosphates Cu 4 P 2 Se 6 , Cu 4 P 3 Se 4 , Cu 4 P 4 Se 3 , and CuP 2 Se, Featuring Zero-, One-, and Two-Dimensional Anions" (in en). Inorganic Chemistry 55 (16): 8031–8040. doi:10.1021/acs.inorgchem.6b01161. ISSN 0020-1669. PMID 27447868. https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01161. 
  31. ↑ Neisius, Nathan A.; MacHale, Luke T.; Snyder, Erin R.; Finke, Richard G.; Prieto, Amy L. (2023-12-27). "Copper Selenophosphate, Cu 3 PSe 4 , Nanoparticle Synthesis: Octadecane Is the Key to a Simplified, Atom-Economical Reaction" (in en). Nano Letters 23 (24): 11430–11437. doi:10.1021/acs.nanolett.3c02620. ISSN 1530-6984. PMID 38085913. Bibcode: 2023NanoL..2311430N. https://pubs.acs.org/doi/10.1021/acs.nanolett.3c02620. 
  32. ↑ Pfeiff, Regine; Kniep, Rüdiger (1993-09-01). "Darstellung von quaternären Selenodiphosphaten(IV) aus Halogenidschmelzen: Die Kristallstruktur des CuAl[P 2 Se 6 ] / Preparation of Quaternary Selenodiphosphates(IV) from Halide Melts: The Crystal Structure of CuAl[P 2 Se 6 ]" (in en). Zeitschrift für Naturforschung B 48 (9): 1270–1274. doi:10.1515/znb-1993-0916. ISSN 1865-7117. 
  33. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-05-01). "Flux Synthesis of K 2 Cu 2 P 4 Se 10 : A Layered Selenophosphate with a New Cyclohexane-like [P 4 Se 10 4 - Group"] (in en). Inorganic Chemistry 37 (9): 2098–2099. doi:10.1021/ic971539+. ISSN 0020-1669. PMID 11670358. https://pubs.acs.org/doi/10.1021/ic971539%2B. 
  34. ↑ 34.0 34.1 34.2 34.3 34.4 34.5 34.6 34.7 34.8 34.9 Chen, John H.; Dorhout, Peter K. (November 1995). "Synthesis and Structural Characterization of a New Rare-Earth Selenodiphosphate: KLaP2Se6" (in en). Inorganic Chemistry 34 (23): 5705–5706. doi:10.1021/ic00127a003. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00127a003. 
  35. ↑ Dorhout, Peter K.; Malo, Todd M. (March 1996). "A three-dimensional network structure built from selenodiphosphate(IV) and copper selenide tetrahedral building blocks: K 3 Cu 3 P 3 Se 9" (in en). Zeitschrift für anorganische und allgemeine Chemie 622 (3): 385–391. doi:10.1002/zaac.19966220302. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19966220302. 
  36. ↑ 36.0 36.1 Liu, C. W.; Chen, Hsiu-Chih; Wang, Ju-Chung; Keng, Tai-Chiun (2001-06-18). "[Cu12(P2Se6){Se2P(OR)2}8: Discrete Copper Clusters Containing an Ethane-Like Hexaselenodiphosphate(IV)"] (in de). Angewandte Chemie 113 (12): 2404–2406. doi:10.1002/1521-3757(20010618)113:12<2404::AID-ANGE2404>3.0.CO;2-7. ISSN 0044-8249. https://onlinelibrary.wiley.com/doi/10.1002/1521-3757(20010618)113:123.0.CO;2-7. 
  37. ↑ 37.0 37.1 37.2 37.3 37.4 37.5 Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (July 1998). "Group 10 and Group 12 One-Dimensional Selenodiphosphates:A2MP2Se6(A=K, Rb, Cs;M=Pd, Zn, Cd, Hg)" (in en). Journal of Solid State Chemistry 138 (2): 321–328. doi:10.1006/jssc.1998.7791. https://linkinghub.elsevier.com/retrieve/pii/S002245969897791X. 
  38. ↑ 38.0 38.1 38.2 Haynes, Alyssa S.; Lee, Katherine; Kanatzidis, Mercouri G. (September 2016). "One-Dimensional Zinc Selenophosphates: A 2 ZnP 2 Se 6 ( A = K, Rb, Cs)" (in en). Zeitschrift für anorganische und allgemeine Chemie 642 (19): 1120–1125. doi:10.1002/zaac.201600231. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201600231. 
  39. ↑ 39.0 39.1 39.2 Morris, Collin D.; Chung, In; Park, Sungoh; Harrison, Connor M.; Clark, Daniel J.; Jang, Joon I.; Kanatzidis, Mercouri G. (2012-12-26). "Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation" (in en). Journal of the American Chemical Society 134 (51): 20733–20744. doi:10.1021/ja309386e. ISSN 0002-7863. PMID 23157167. https://pubs.acs.org/doi/10.1021/ja309386e. 
  40. ↑ 40.0 40.1 Morris, Collin D.; Malliakas, Christos D.; Kanatzidis, Mercouri G. (2011-10-17). "Germanium Selenophosphates: The Incommensurately Modulated 1 / ∞ [Ge 4-x P x Se 12 4– and the Molecular [Ge 2 P 2 Se 14 ] 6–"] (in en). Inorganic Chemistry 50 (20): 10241–10248. doi:10.1021/ic201249w. ISSN 0020-1669. PMID 21928764. https://pubs.acs.org/doi/10.1021/ic201249w. 
  41. ↑ 41.0 41.1 41.2 41.3 Morris, Collin D.; Kanatzidis, Mercouri G. (2010-10-04). "Arsenic-Containing Chalcophosphate Molecular Anions" (in en). Inorganic Chemistry 49 (19): 9049–9054. doi:10.1021/ic101461w. ISSN 0020-1669. PMID 20825231. https://pubs.acs.org/doi/10.1021/ic101461w. 
  42. ↑ Chung, In; Karst, Angela L.; Weliky, David P.; Kanatzidis, Mercouri G. (2006-04-01). "[P 6 Se 12 4 - : A Phosphorus-Rich Selenophosphate with Low-Valent P Centers"] (in en). Inorganic Chemistry 45 (7): 2785–2787. doi:10.1021/ic0601135. ISSN 0020-1669. PMID 16562935. https://pubs.acs.org/doi/10.1021/ic0601135. 
  43. ↑ 43.0 43.1 Chondroudis, Konstantinos; Kanatzidis, Mercouri G (February 1998). "[Ce(PSe4)49−: a highly anionic Ce3+ selenophosphate coordination complex"] (in en). Inorganic Chemistry Communications 1 (2): 55–57. doi:10.1016/S1387-7003(98)00011-2. https://linkinghub.elsevier.com/retrieve/pii/S1387700398000112. 
  44. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (October 1995). "Complex Multinary Compounds from Molten Alkali Metal Polyselenophosphate Fluxes. Layers and Chains in A4Ti2(P2Se9)2(P2Se7) and ATiPSe5 (A = K, Rb). Isolation of [P2Se94-, a Flux Constituent Anion"] (in en). Inorganic Chemistry 34 (22): 5401–5402. doi:10.1021/ic00126a004. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00126a004. 
  45. ↑ 45.00 45.01 45.02 45.03 45.04 45.05 45.06 45.07 45.08 45.09 45.10 Zhao, Chen-Yi; Chen, Zi-Xia; Yao, Wen-Dong; Zhou, Wenfeng; Liu, Wenlong; Guo, Sheng-Ping (11 December 2023). "NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties". Inorganic Chemistry 62 (49): 19843–19847. doi:10.1021/acs.inorgchem.3c03695. PMID 38032849. 
  46. ↑ Zhao, Chen-Yi; Chen, Zi-Xia; Yao, Wen-Dong; Zhou, Wenfeng; Liu, Wenlong; Guo, Sheng-Ping (2023-12-11). "NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties"] (in en). Inorganic Chemistry 62 (49): 19843–19847. doi:10.1021/acs.inorgchem.3c03695. ISSN 0020-1669. PMID 38032849. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c03695. 
  47. ↑ Chen, John H.; Dorhout, Peter K.; Ostenson, J. E. (1996-01-01). "A Comparative Study of Two New Structure Types. Synthesis and Structural and Electronic Characterization of K(RE)P 2 Se 6 (RE = Y, La, Ce, Pr, Gd)" (in en). Inorganic Chemistry 35 (19): 5627–5633. doi:10.1021/ic9516121. ISSN 0020-1669. PMID 11666755. https://pubs.acs.org/doi/10.1021/ic9516121. 
  48. ↑ Seitz, A. E.; Heinl, V.; Timoshkin, A. Y.; Scheer, M. (2017). "Transformation of nortricyclane type cage compounds P 4 S 3 , P 4 Se 3 and As 4 S 3 by [Cp′′ 2 Zr(CO) 2 "] (in en). Chemical Communications 53 (6): 1172–1175. doi:10.1039/C6CC09427A. ISSN 1359-7345. PMID 28054088. http://xlink.rsc.org/?DOI=C6CC09427A. 
  49. ↑ 49.0 49.1 49.2 Banerjee, Santanu; Malliakas, Christos D.; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G. (2008-09-17). "1 / ∞ [ZrPSe 6 − : A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts"] (in en). Journal of the American Chemical Society 130 (37): 12270–12272. doi:10.1021/ja804166m. ISSN 0002-7863. PMID 18715000. https://pubs.acs.org/doi/10.1021/ja804166m. 
  50. ↑ 50.0 50.1 50.2 Syrigos, Jonathan C.; Clark, Daniel J.; Saouma, Felix O.; Clarke, Samantha M.; Fang, Lei; Jang, Joon I.; Kanatzidis, Mercouri G. (2015-01-13). "Semiconducting Properties and Phase-Matching Nonlinear Optical Response of the One-Dimensional Selenophosphates ANb 2 PSe 10 (A = K, Rb, and Cs)" (in en). Chemistry of Materials 27 (1): 255–265. doi:10.1021/cm5038217. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm5038217. 
  51. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997-07-04). "[P 3 Se: A Novel Polyanion in K 3 RuP 5 Se 10 ; Formation of RuP Bonds in a Molten Polyselenophosphate Flux"] (in en). Angewandte Chemie International Edition in English 36 (12): 1324–1326. doi:10.1002/anie.199713241. ISSN 0570-0833. https://onlinelibrary.wiley.com/doi/10.1002/anie.199713241. 
  52. ↑ Duan, Ruihuan; Zhu, Chao; Zeng, Qingsheng; Wang, Xiaowei; Gao, Yang; Deng, Ya; He, Yanchao; Yang, Jiefu et al. (August 2021). "PdPSe: Component-Fusion-Based Topology Designer of Two-Dimensional Semiconductor" (in en). Advanced Functional Materials 31 (35). doi:10.1002/adfm.202102943. ISSN 1616-301X. https://onlinelibrary.wiley.com/doi/10.1002/adfm.202102943. 
  53. ↑ Xia, Houping; Ma, Qian (April 2019). "Experimental study on nonlinear−optical property of Ag4P2Se6" (in en). Journal of Alloys and Compounds 780: 727–733. doi:10.1016/j.jallcom.2018.11.403. https://linkinghub.elsevier.com/retrieve/pii/S0925838818345353. 
  54. ↑ 54.0 54.1 54.2 Pfitzner, Arno; Seidlmayer, Stefan (April 2009). "Synthesis and Structure Determination of AgScP 2 Se 6 , AgErP 2 Se 6 and AgTmP 2 Se 6" (in en). Zeitschrift für anorganische und allgemeine Chemie 635 (4–5): 704–707. doi:10.1002/zaac.200900004. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200900004. 
  55. ↑ Chica, Daniel G.; He, Yihui; McCall, Kyle M.; Chung, Duck Young; Pak, Rahmi O.; Trimarchi, Giancarlo; Liu, Zhifu; De Lurgio, Patrick M. et al. (2020-01-16). "Direct thermal neutron detection by the 2D semiconductor 6LiInP2Se6" (in en). Nature 577 (7790): 346–349. doi:10.1038/s41586-019-1886-8. ISSN 0028-0836. PMID 31942050. https://www.nature.com/articles/s41586-019-1886-8. 
  56. ↑ 56.0 56.1 Chondroudis, Konstantinos; Chakrabarty, Debojit; Axtell, Enos A.; Kanatzidis, Mercouri G. (June 1998). "Synthesis of the One-dimensional Compound (Ph4P)[In(P2Se6) in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5- - a Discrete Molecular Fragment of the [In(P2Se6)]nn- Chain"] (in de). Zeitschrift für anorganische und allgemeine Chemie 624 (6): 975–979. doi:10.1002/(SICI)1521-3749(199806)624:6<975::AID-ZAAC975>3.0.CO;2-1. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/(SICI)1521-3749(199806)624:63.0.CO;2-1. 
  57. ↑ Coste, Servane; Kopnin, Evgeni; Evain, Michel; Jobic, Stéphane; Brec, Raymond; Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (April 2002). "Polychalcogenophosphate flux synthesis of 1D-KInP2Se6 and 1D and 3D-NaCrP2S6" (in en). Solid State Sciences 4 (5): 709–716. doi:10.1016/S1293-2558(02)01317-1. https://linkinghub.elsevier.com/retrieve/pii/S1293255802013171. 
  58. ↑ 58.0 58.1 58.2 Rothenberger, Alexander; Wang, Hsien-Hau; Chung, DuckYoung; Kanatzidis, Mercouri G. (2010-02-01). "Structural Diversity by Mixing Chalcogen Atoms in the Chalcophosphate System K/In/P/Q (Q = S, Se)" (in en). Inorganic Chemistry 49 (3): 1144–1151. doi:10.1021/ic902105j. ISSN 0020-1669. PMID 20030374. https://pubs.acs.org/doi/10.1021/ic902105j. 
  59. ↑ 59.0 59.1 Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (February 1998). "K4In2(PSe5)2(P2Se6) and Rb3Sn(PSe5)(P2Se6): One-Dimensional Compounds with Mixed Selenophosphate Anions" (in en). Journal of Solid State Chemistry 136 (1): 79–86. doi:10.1006/jssc.1997.7659. https://linkinghub.elsevier.com/retrieve/pii/S0022459697976593. 
  60. ↑ Zhang, Cheng-gong; Ji, Wei-xiao; Li, Ping; Zhang, Chang-wen; Wang, Pei-Ji (October 2021). "Tuning the electronic and optical properties of two-dimensional AgBiP2Se6 and AgInP2Se6 Janus monolayers" (in en). Chemical Physics Letters 780: 138933. doi:10.1016/j.cplett.2021.138933. https://linkinghub.elsevier.com/retrieve/pii/S0009261421006163. 
  61. ↑ Chica, Daniel; Sangwan, Vinod; Chu, Ting-Ching; Cheng, Matthew; Quintero, Michael; Hao, Shiqiang; Choi, Hyeonseon; Liu, Yukun et al. (2022-10-17). SnP2Se6: A Chiral 2D Semiconductor for High-Performance Electronics and Optoelectronics (Report). In Review. doi:10.21203/rs.3.rs-2143024/v1. https://www.researchsquare.com/article/rs-2143024/v1. 
  62. ↑ Eijt, S; Maior, M.M (May 1999). "Raman and infrared hard mode spectroscopy of the internal vibrations in Sn2P2Se6" (in en). Journal of Physics and Chemistry of Solids 60 (5): 631–643. doi:10.1016/S0022-3697(98)00319-9. Bibcode: 1999JPCS...60..631E. https://linkinghub.elsevier.com/retrieve/pii/S0022369798003199. 
  63. ↑ Duchardt, Marc; Neuberger, Sven; Ruschewitz, Uwe; Krauskopf, Thorben; Zeier, Wolfgang G.; Schmedt auf der Günne, Jörn; Adams, Stefan; Roling, Bernhard et al. (2018-06-26). "Superion Conductor Na 11.1 Sn 2.1 P 0.9 Se 12 : Lowering the Activation Barrier of Na + Conduction in Quaternary 1–4–5–6 Electrolytes" (in en). Chemistry of Materials 30 (12): 4134–4139. doi:10.1021/acs.chemmater.8b01656. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.8b01656. 
  64. ↑ 64.0 64.1 Chung, In; Kanatzidis, Mercouri G. (2011-01-17). "Stabilization of Sn 2+ in K 10 Sn 3 (P 2 Se 6 ) 4 and Cs 2 SnP 2 Se 6 Derived from a Basic Flux" (in en). Inorganic Chemistry 50 (2): 412–414. doi:10.1021/ic101140r. ISSN 0020-1669. PMID 21142146. https://pubs.acs.org/doi/10.1021/ic101140r. 
  65. ↑ Chung, In; Biswas, Kanishka; Song, Jung-Hwan; Androulakis, John; Chondroudis, Konstantinos; Paraskevopoulos, Konstantinos M.; Freeman, Arthur J.; Kanatzidis, Mercouri G. (2011-09-12). "Rb 4 Sn 5 P 4 Se 20 : A Semimetallic Selenophosphate" (in en). Angewandte Chemie International Edition 50 (38): 8834–8838. doi:10.1002/anie.201104050. ISSN 1433-7851. PMID 21812086. https://onlinelibrary.wiley.com/doi/10.1002/anie.201104050. 
  66. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-06-01). "Rb 4 Sn 2 Ag 4 (P 2 Se 6 ) 3 : First Example of a Quinary Selenophosphate and an Unusual Sn−Ag s 2 −d 10 Interaction" (in en). Inorganic Chemistry 37 (12): 2848–2849. doi:10.1021/ic971468e. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/ic971468e. 
  67. ↑ 67.0 67.1 Chondroudis, Konstantinos; Kanatizidis, Mercouri G. (1996). "Isolation of [Sn(PSe 5 ) 3 5– and [Sn 2 Se 4 (PSe 5 ) 2 ] 6– ; the first discrete complexes from molten alkali-metal polyselenophosphate fluxes"] (in en). Chem. Commun. (11): 1371–1372. doi:10.1039/CC9960001371. ISSN 1359-7345. http://xlink.rsc.org/?DOI=CC9960001371. 
  68. ↑ 68.0 68.1 Ruck, Michael (August 1995). "Darstellung und Kristallstruktur der Hexaselenodiphosphate(IV) von Antimon und Bismut" (in en). Zeitschrift für anorganische und allgemeine Chemie 621 (8): 1344–1350. doi:10.1002/zaac.19956210812. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19956210812. 
  69. ↑ 69.0 69.1 Breshears, Jean D.; Kanatzidis, Mercouri G. (2000-08-01). "β-KMP 2 Se 6 (M = Sb, Bi): Kinetically Accessible Phases Obtained from Rapid Crystallization of Amorphous Precursors" (in en). Journal of the American Chemical Society 122 (32): 7839–7840. doi:10.1021/ja001270k. ISSN 0002-7863. https://pubs.acs.org/doi/10.1021/ja001270k. 
  70. ↑ Vu, Tuan V.; Lavrentyev, A.A.; Gabrelian, B.V.; Vo, Dat D.; Sabov, V.I.; Sabov, M.Yu.; Barchiy, I.E.; Piasecki, M. et al. (August 2020). "Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations" (in en). Chemical Physics 536: 110813. doi:10.1016/j.chemphys.2020.110813. https://linkinghub.elsevier.com/retrieve/pii/S0301010420304584. 
  71. ↑ 71.0 71.1 71.2 Haynes, Alyssa S.; Banerjee, Abhishek; Saouma, Felix O.; Otieno, Calford O.; Jang, Joon I.; Kanatzidis, Mercouri G. (2016-04-12). "Phase Transition, Conformational Exchange, and Nonlinear Optical Third Harmonic Generation of A CsP 2 Se 8 ( A = K, Rb, Cs)" (in en). Chemistry of Materials 28 (7): 2374–2383. doi:10.1021/acs.chemmater.6b00551. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.6b00551. 
  72. ↑ Gave, Matthew A.; Canlas, Christian G.; Chung, In; Iyer, Ratnasabapathy G.; Kanatzidis, Mercouri G.; Weliky, David P. (October 2007). "Cs4P2Se10: A new compound discovered with the application of solid-state and high temperature NMR" (in en). Journal of Solid State Chemistry 180 (10): 2877–2884. doi:10.1016/j.jssc.2007.08.002. https://linkinghub.elsevier.com/retrieve/pii/S0022459607003143. 
  73. ↑ 73.0 73.1 Chung, In; Jang, Joon I.; Gave, Matthew A.; Weliky, David P.; Kanatzidis, Mercouri G. (2007). "Low valent phosphorus in the molecular anions [P5Se125– and β-[P6Se12]4–: phase change behavior and near infrared second harmonic generation"] (in en). Chemical Communications (47): 4998–5000. doi:10.1039/b714301j. ISSN 1359-7345. PMID 18049732. http://xlink.rsc.org/?DOI=b714301j. 
  74. ↑ 74.0 74.1 74.2 李, 梦月; 谢, 秀媛; 吴, 新涛; 李, 晓芳; 林, 华 (2021). "Quaternary Selenophosphate Cs_2ZnP_2Se_6 Featuring Unique One-dimensional Chains and Exhibiting Remarkable Photo-electrochemical Response". Chinese Journal of Structural Chemistry 40 (2): 246–255. doi:10.14102/j.cnki.0254-5861.2011-2822. ISSN 0254-5861. http://kns.cnki.net/kcms/detail/detail.aspx?doi=10.14102/j.cnki.0254-5861.2011-2822. 
  75. ↑ Chung, In; Holmes, Daniel; Weliky, David P.; Kanatzidis, Mercouri G. (2010-04-05). "[P 3 Se 7 3− : A Phosphorus-Rich Square-Ring Selenophosphate"] (in en). Inorganic Chemistry 49 (7): 3092–3094. doi:10.1021/ic902561h. ISSN 0020-1669. PMID 20180545. https://pubs.acs.org/doi/10.1021/ic902561h. 
  76. ↑ 76.0 76.1 76.2 Chondroudis, Konstantinos; Kanatzidis, Mercouri G.; Sayettat, Julien; Jobic, Stéphane; Brec, Raymond (1997-12-01). "Palladium Chemistry in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of K 4 Pd(PS 4 ) 2 , Cs 4 Pd(PSe 4 ) 2 , Cs 10 Pd(PSe 4 ) 4 , KPdPS 4 , K 2 PdP 2 S 6 , and Cs 2 PdP 2 Se 6" (in en). Inorganic Chemistry 36 (25): 5859–5868. doi:10.1021/ic970593n. ISSN 0020-1669. PMID 11670209. https://pubs.acs.org/doi/10.1021/ic970593n. 
  77. ↑ 77.0 77.1 77.2 Haynes, Alyssa S.; Stoumpos, Constantinos C.; Chen, Haijie; Chica, Daniel; Kanatzidis, Mercouri G. (2017-08-09). "Panoramic Synthesis as an Effective Materials Discovery Tool: The System Cs/Sn/P/Se as a Test Case" (in en). Journal of the American Chemical Society 139 (31): 10814–10821. doi:10.1021/jacs.7b05423. ISSN 0002-7863. PMID 28665593. https://pubs.acs.org/doi/10.1021/jacs.7b05423. 
  78. ↑ 78.0 78.1 Galdámez, A; Manrı́quez, V; Kasaneva, J; Avila, R.E (May 2003). "Synthesis, characterization and electrical properties of quaternary selenodiphosphates: AMP2SE6 with A = Cu, Ag and M = Bi, Sb" (in en). Materials Research Bulletin 38 (6): 1063–1072. doi:10.1016/S0025-5408(03)00068-0. https://linkinghub.elsevier.com/retrieve/pii/S0025540803000680. 
  79. ↑ 79.0 79.1 79.2 Jörgens, Stefan; Mewis, Albrecht (2005-04-01). "Neue Chalcogenophosphate: KBaPS 4 , KBaPSe 4 und Ba 3 PO 4 PSe 4 / New Chalcogenophosphates: KBaPS 4 , KBaPSe 4 , and Ba 3 PO 4 PSe 4" (in en). Zeitschrift für Naturforschung B 60 (4): 431–436. doi:10.1515/znb-2005-0414. ISSN 1865-7117. 
  80. ↑ Jörgens, Stefan; Mewis, Albrecht (April 2007). "Synthese und Kristallstrukturen von α- und β -Ba 3 (PS 4 ) 2 sowie von Ba 3 (PSe 4 ) 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 633 (4): 570–574. doi:10.1002/zaac.200600360. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.200600360. 
  81. ↑ 81.0 81.1 81.2 81.3 81.4 Evenson; Dorhout, Peter K. (2001-06-01). "Selenophosphate Phase Diagrams Developed in Conjunction with the Synthesis of the New Compounds K 2 La(P 2 Se 6 ) 1/2 (PSe 4 ), K 3 La(PSe 4 ) 2 , K 4 La 0.67 (PSe 4 ) 2 , K 9- x La 1+ x /3 (PSe 4 ) 4 ( x = 0.5), and KEuPSe 4" (in en). Inorganic Chemistry 40 (12): 2875–2883. doi:10.1021/ic000595z. ISSN 0020-1669. PMID 11375707. https://pubs.acs.org/doi/10.1021/ic000595z. 
  82. ↑ 82.0 82.1 82.2 82.3 Aitken, Jennifer A.; Evain, Michel; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (2002-01-01). "NaCeP 2 Se 6 , Cu 0.4 Ce 1.2 P 2 Se 6 , Ce 4 (P 2 Se 6 ) 3 , and the Incommensurately Modulated AgCeP 2 Se 6 : New Selenophosphates Featuring the Ethane-Like [P 2 Se 6 4 - Anion"] (in en). Inorganic Chemistry 41 (2): 180–191. doi:10.1021/ic010618p. ISSN 0020-1669. PMID 11800606. https://pubs.acs.org/doi/10.1021/ic010618p. 
  83. ↑ 83.0 83.1 83.2 83.3 Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-07-01). "New Lanthanide Selenophosphates. Influence of Flux Composition on the Distribution of [PSe 4 3 - /[P 2 Se 6 ] 4 - Units and the Stabilization of the Low-Dimensional Compounds A 3 REP 2 Se 8 , and A 2 (RE)P 2 Se 7 (A = Rb, Cs; RE = Ce, Gd)"] (in en). Inorganic Chemistry 37 (15): 3792–3797. doi:10.1021/ic980025n. ISSN 0020-1669. PMID 11670481. https://pubs.acs.org/doi/10.1021/ic980025n. 
  84. ↑ 84.0 84.1 84.2 Schulz, Beate M.; Lange, Pia L.; Schleid, Thomas (2020-11-26). "Three of a kind? The non-isotypic triple CsCe[P 2 Se 6 , CsSm[P 2 Se 6 ] and CsEr[P 2 Se 6 ]"] (in en). Zeitschrift für Naturforschung B 75 (11): 959–967. doi:10.1515/znb-2020-0148. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2020-0148/html. 
  85. ↑ (in en) 26th Annual Conference of the German Crystallographic Society, March 5–8, 2018, Essen, Germany. Walter de Gruyter GmbH & Co KG. 2018-03-05. pp. 97. ISBN 978-3-11-059599-4. https://books.google.com/books?id=VQNPDwAAQBAJ&dq=Cs2PrP2Se7&pg=PA97. 
  86. ↑ 86.0 86.1 Aitken, Jennifer A.; Chondroudis, Konstantinos; Young, Victor G.; Kanatzidis, Mercouri G. (2000-04-01). "LiEuPSe 4 and KEuPSe 4 : Novel Selenophosphates with the Tetrahedral [PSe 4 3 - Building Block"] (in en). Inorganic Chemistry 39 (7): 1525–1533. doi:10.1021/ic991090f. ISSN 0020-1669. PMID 12526459. https://pubs.acs.org/doi/10.1021/ic991090f. 
  87. ↑ 87.0 87.1 Martin, Benjamin R.; Polyakova, Larisa A.; Dorhout, Peter K. (February 2006). "Synthesis and characterization of a family of two related quaternary selenides: Na8Eu2(Si2Se6)2 and Na9Sm(Ge2Se6)2" (in en). Journal of Alloys and Compounds 408-412: 490–495. doi:10.1016/j.jallcom.2004.12.091. https://linkinghub.elsevier.com/retrieve/pii/S0925838805006341. 
  88. ↑ 88.0 88.1 88.2 88.3 88.4 Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G. (1996-01-01). "Chemistry in Molten Alkali Metal Polyselenophosphate Fluxes. Influence of Flux Composition on Dimensionality. Layers and Chains in APbPSe 4 , A 4 Pb(PSe 4 ) 2 (A = Rb, Cs), and K 4 Eu(PSe 4 ) 2" (in en). Inorganic Chemistry 35 (4): 840–844. doi:10.1021/ic950479+. ISSN 0020-1669. PMID 11666254. https://pubs.acs.org/doi/10.1021/ic950479%2B. 
  89. ↑ 89.0 89.1 89.2 Chen, Zi-Xia; Zhao, Chen-Yi; Li, Xiao-Hui; Yao, Wen-Dong; Liu, Wenlong; Guo, Sheng-Ping (February 2023). "KREP 2 Se 6 (RE = Sm, Gd, Tb): The First Rare-Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE- and P-Based Motifs" (in en). Small 19 (8): e2206910. doi:10.1002/smll.202206910. ISSN 1613-6810. PMID 36504482. https://onlinelibrary.wiley.com/doi/10.1002/smll.202206910. 
  90. ↑ Orgzall, I.; Lorenz, B.; Dorhout, P.K.; Van Calcar, P.M.; Brister, K.; Sander, T.; Hochheimer, H.D. (January 2000). "High pressure optical and X-ray diffraction studies of two polymorphs of K(RE)P2Se6 (RE=Pr and Tb)" (in en). Journal of Physics and Chemistry of Solids 61 (1): 123–134. doi:10.1016/S0022-3697(99)00012-8. Bibcode: 2000JPCS...61..123O. https://linkinghub.elsevier.com/retrieve/pii/S0022369799000128. 
  91. ↑ 91.0 91.1 91.2 91.3 91.4 Chondroudis, Konstantinos; Hanko, Jason A.; Kanatzidis, Mercouri G. (1997-06-01). "Chemistry of Gold in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of the Low-Dimensional Compounds A 3 AuP 2 Se 8 (A = K, Rb, Cs), A 2 Au 2 P 2 Se 6 (A = K, Rb), A 2 AuPS 4 (A = K, Rb, Cs), and AAuP 2 S 7 (A = K, Rb)" (in en). Inorganic Chemistry 36 (12): 2623–2632. doi:10.1021/ic961376+. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/ic961376%2B. 
  92. ↑ Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G. (1996-01-01). "A 2 AuP 2 Se 6 (A = K, Rb): Mixed-Valent Compounds with All Possible Coordination Geometries for Gold" (in en). Inorganic Chemistry 35 (12): 3451–3452. doi:10.1021/ic9516020. ISSN 0020-1669. https://pubs.acs.org/doi/10.1021/ic9516020. 
  93. ↑ Brockner, Wolfgang; Pätzmann, Ulrich (1987-05-01). "Schwingungsspektrum des Quecksilber-Hexaselenidohypodiphosphates Hg 2 P 2 Se 6" (in en). Zeitschrift für Naturforschung A 42 (5): 517–518. doi:10.1515/zna-1987-0518. ISSN 1865-7109. https://www.degruyter.com/document/doi/10.1515/zna-1987-0518/html. 
  94. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997). "[M4(Se2)2(PSe4)4 8−: a novel, tetranuclear, cluster anion with a stellane-like core"]. Chemical Communications (4): 401–402. doi:10.1039/a607549e. http://xlink.rsc.org/?DOI=a607549e. 
  95. ↑ 95.0 95.1 Nawaz, Zeeshan (2017-12-01). "Methyl-Tert-Butyl-Ether Synthesis Reactor Modelling and Optimization Using an Aspen Custom Modeler". Hungarian Journal of Industry and Chemistry 45 (2): 1–7. doi:10.1515/hjic-2017-0012. ISSN 2450-5102. http://archive.sciendo.com/HJIC/hjic.2017.45.issue-2/hjic-2017-0012/hjic-2017-0012.pdf. 
  96. ↑ Barchii, I. E.; Tovt, V. A.; Piasecki, M.; Fedorchuk, A. A.; Solomon, A. M.; Pogodin, A. I. (April 2018). "Physicochemical Interaction in the TlInSe2–TlInP2Se6 System" (in en). Russian Journal of Inorganic Chemistry 63 (4): 537–542. doi:10.1134/S0036023618040034. ISSN 0036-0236. http://link.springer.com/10.1134/S0036023618040034. 
  97. ↑ Vu, Tuan V.; Lavrentyev, A.A.; Gabrelian, B.V.; Sabov, V.I.; Sabov, M.Y.; Pogodin, A.I.; Barchiy, I.E.; Fedorchuk, A.O. et al. (December 2020). "TlSbP2Se6 - a new layered single crystal: growth, structure and electronic properties" (in en). Journal of Alloys and Compounds 848: 156485. doi:10.1016/j.jallcom.2020.156485. https://linkinghub.elsevier.com/retrieve/pii/S0925838820328498. 
  98. ↑ Wang, Peng L.; Liu, Zhifu; Chen, Pice; Peters, John A.; Tan, Gangjian; Im, Jino; Lin, Wenwen; Freeman, Arthur J. et al. (August 2015). "Hard Radiation Detection from the Selenophosphate Pb 2 P 2 Se 6" (in en). Advanced Functional Materials 25 (30): 4874–4881. doi:10.1002/adfm.201501826. ISSN 1616-301X. https://onlinelibrary.wiley.com/doi/10.1002/adfm.201501826. 
  99. ↑ Becker, Robert; Brockner, Wolfgang; Schäfer, Herbert (1984-04-01). "Kristallstruktur und Schwingungsspektren des Di-Blei-Hexaselenohypodiphosphates Pb 2 P 2 Se 6 / Crystal Structure and Vibrational Spectra of Pb 2 P 2 Se 6" (in en). Zeitschrift für Naturforschung A 39 (4): 357–361. doi:10.1515/zna-1984-0407. ISSN 1865-7109. https://www.degruyter.com/document/doi/10.1515/zna-1984-0407/html. 
  100. ↑ Aitken, Jennifer A.; Marking, Gregory A.; Evain, Michel; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (August 2000). "Flux Synthesis and Isostructural Relationship of Cubic Na1.5Pb0.75PSe4, Na0.5Pb1.75GeS4, and Li0.5Pb1.75GeS4" (in en). Journal of Solid State Chemistry 153 (1): 158–169. doi:10.1006/jssc.2000.8767. https://linkinghub.elsevier.com/retrieve/pii/S002245960098767X. 
  101. ↑ Qian, Eric K.; Iyer, Abishek K.; Cheng, Matthew; Ryan, Kevin M.; Jirousek, Lillian; Chica, Daniel G.; Krantz, Patrick; Lee, Yea-Shine et al. (2023-05-09). "Synthesizing Mono- and Bimetallic 2D Selenophosphates Using a P 2 Se 5 Reactive Flux" (in en). Chemistry of Materials 35 (9): 3671–3685. doi:10.1021/acs.chemmater.3c00342. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/acs.chemmater.3c00342. 
  102. ↑ 102.0 102.1 Gave, Matthew A.; Bilc, Daniel; Mahanti, S. D.; Breshears, Jean D.; Kanatzidis, Mercouri G. (2005-07-01). "On the Lamellar Compounds CuBiP 2 Se 6 , AgBiP 2 Se 6 and AgBiP 2 S 6 . Antiferroelectric Phase Transitions Due to Cooperative Cu + and Bi 3+ Ion Motion" (in en). Inorganic Chemistry 44 (15): 5293–5303. doi:10.1021/ic050357+. ISSN 0020-1669. PMID 16022528. https://pubs.acs.org/doi/10.1021/ic050357%2B. 
  103. ↑ He, Wei; Kong, Lingling; Yu, Peng; Yang, Guowei (April 2023). "Record-High Work-Function p-Type CuBiP 2 Se 6 Atomic Layers for High-Photoresponse van der Waals Vertical Heterostructure Phototransistor" (in en). Advanced Materials 35 (14): e2209995. doi:10.1002/adma.202209995. ISSN 0935-9648. PMID 36640444. Bibcode: 2023AdM....3509995H. https://onlinelibrary.wiley.com/doi/10.1002/adma.202209995. 
  104. ↑ Chung, In; Song, Jung-Hwan; Jang, Joon I.; Freeman, Arthur J.; Ketterson, John B.; Kanatzidis, Mercouri G. (2009-02-25). "Flexible Polar Nanowires of Cs 5 BiP 4 Se 12 from Weak Interactions between Coordination Complexes: Strong Nonlinear Optical Second Harmonic Generation" (in en). Journal of the American Chemical Society 131 (7): 2647–2656. doi:10.1021/ja808242g. ISSN 0002-7863. PMID 19183006. https://pubs.acs.org/doi/10.1021/ja808242g. 
  105. ↑ 105.0 105.1 Gave, Matthew A.; Malliakas, Christos D.; Weliky, David P.; Kanatzidis, Mercouri G. (2007-04-30). "Wide Compositional and Structural Diversity in the System Tl/Bi/P/Q (Q = S, Se) and Observation of Vicinal P−Tl J Coupling in the Solid State" (in en). Inorganic Chemistry 46 (9): 3632–3644. doi:10.1021/ic062465h. ISSN 0020-1669. PMID 17397145. https://pubs.acs.org/doi/10.1021/ic062465h. 
  106. ↑ 106.0 106.1 106.2 Briggs Piccoli, Paula M.; Abney, Kent D.; Schoonover, Jon R.; Dorhout, Peter K. (2000-07-01). "Synthesis and Structural Characterization of Quaternary Thorium Selenophosphates: A 2 ThP 3 Se 9 (A = K, Rb) and Cs 4 Th 2 P 5 Se 17" (in en). Inorganic Chemistry 39 (14): 2970–2976. doi:10.1021/ic990767w. ISSN 0020-1669. PMID 11196891. https://pubs.acs.org/doi/10.1021/ic990767w. 
  107. ↑ Briggs-Piccoli, Paula M.; Abney, Kent D.; Dorhout, Peter K. (November 2002). "The Synthesis and Structural Characterization of a New Beta Phase of K 2 ThP 3 Se 9" (in en). Journal of Nuclear Science and Technology 39 (sup3): 611–615. doi:10.1080/00223131.2002.10875542. ISSN 0022-3131. Bibcode: 2002JNST...39S.611B. https://www.tandfonline.com/doi/full/10.1080/00223131.2002.10875542. 
  108. ↑ Chan, Benny C.; Hess, Ryan F.; Feng, Patrick L.; Abney, Kent D.; Dorhout, Peter K. (2005-03-21). "Synthesis and Characterization of Two Quaternary Thorium Chalcophosphates: Cs 4 Th 2 P 6 S 18 and Rb 7 Th 2 P 6 Se 21" (in en). Inorganic Chemistry 44 (6): 2106–2113. doi:10.1021/ic049101e. ISSN 0020-1669. PMID 15762739. https://pubs.acs.org/doi/10.1021/ic049101e. 
  109. ↑ Briggs Piccoli, Paula M.; Abney, Kent D.; Schoonover, Jon D.; Dorhout, Peter K. (2001-09-01). "Synthesis, Structure, and Properties of Cs 4 Th 4 P 4 Se 26 : A Quaternary Thorium Selenophosphate Containing the (P 2 Se 9 ) 6 - Anion" (in en). Inorganic Chemistry 40 (19): 4871–4875. doi:10.1021/ic001103l. ISSN 0020-1669. PMID 11531433. https://pubs.acs.org/doi/10.1021/ic001103l. 
  110. ↑ K., Chondroudis; M.G., Kanatzidis (1996). "Synthesis and characterization of K2UP3Se9. The first actinide seleno-phosphate" (in English). Comptes Rendus de l'Academie des Sciences. Serie 2, Mecanique, Physique, Chimie, Astronomie 322 (12). ISSN 1251-8069. https://inis.iaea.org/search/search.aspx?orig_q=RN:28011434. 
  111. ↑ Bellott, Brian J.; Ibers, James A. (December 2012). "Synthesis and Structure of the Rubidium Uranium Selenophosphate Rb 4 U 2 P 5 Se 17" (in en). Zeitschrift für anorganische und allgemeine Chemie 638 (15): 2473–2476. doi:10.1002/zaac.201200316. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201200316. 
  112. ↑ Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997-03-01). "Stabilization of U 5+ in Rb 4 U 4 P 4 Se 26 . An Actinide Compound with a Mixed Selenophosphate/Polyselenide Framework and Ion-Exchange Properties" (in en). Journal of the American Chemical Society 119 (10): 2574–2575. doi:10.1021/ja963673j. ISSN 0002-7863. https://pubs.acs.org/doi/10.1021/ja963673j. 
  113. ↑ Mesbah, Adel; Prakash, Jai; Beard, Jessica C.; Lebègue, Sébastien; Ibers, James A. (2018-11-30). "Synthesis and Crystal Structure of Cs 2 U 2 (P 2 Se 9 )(Se 2 ) 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 644 (22): 1480–1484. doi:10.1002/zaac.201800263. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201800263. 

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