Chemistry:Silver decamolybdate
From HandWiki
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Other names
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3D model (JSmol)
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| Properties | |
| Ag6Mo10O33 | |
| Molar mass | 2134.68 g·mol−1 |
| Appearance | Yellow solid[1] |
| Structure[2] | |
| triclinic | |
| P1 (No. 1) | |
a = 7.59 Å, b = 8.31 Å, c = 11.42 Å α = 82.6°, β = 102.9°, γ = 106.4°
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Formula units (Z)
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1 formula per cell |
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Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Silver decamolybdate is an inorganic compound with the chemical formula Ag
6Mo
10O
33. It can be prepared by hydrothermal synthesis[3] and grown into nanorods by melt-quenching.[4] It is used as an alternative to platinum electrocatalysts for oxygen reduction reactions.[5] Silver decamolybdate films can detect ammonia in air at concentrations greater than 2 ppm.[6]
References
- ↑ Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2017-07-24) (in en). Handbook of Inorganic Substances 2017. Walter de Gruyter GmbH & Co KG. p. 195. ISBN 978-3-11-044540-4. https://books.google.com/books?id=ROEsDwAAQBAJ.
- ↑ Gatehouse, B. M.; Leverett, P. (1970-04-01). "The crystal structure of silver decamolybdate, Ag6Mo10O33". Journal of Solid State Chemistry 1 (3): 484–496. doi:10.1016/0022-4596(70)90131-3. ISSN 0022-4596. https://dx.doi.org/10.1016/0022-4596%2870%2990131-3.
- ↑ Adachi, Motonari; Lockwood, David J. (2006-10-31) (in en). Self-Organized Nanoscale Materials. Springer Science & Business Media. ISBN 978-0-387-27976-3. https://books.google.com/books?id=nQ1O2jnX4noC.
- ↑ Bhattacharya, S.; Ghosh, A. (2007-03-30). "Silver molybdate nanoparticles, nanowires, and nanorods embedded in glass nanocomposites" (in en). Physical Review B 75 (9). doi:10.1103/PhysRevB.75.092103. ISSN 1098-0121. Bibcode: 2007PhRvB..75i2103B. https://link.aps.org/doi/10.1103/PhysRevB.75.092103.
- ↑ Kumar, Vipin; Matz, Sebastian; Hoogestraat, Dirk; Bhavanasi, Venkateswarlu; Parida, Kaushik; Al-Shamery, Katharina; Lee, Pooi See (2016). "Design of Mixed-Metal Silver Decamolybdate Nanostructures for High Specific Energies at High Power Density". Advanced Materials 28 (32): 6966–6975. doi:10.1002/adma.201601158. ISSN 1521-4095. PMID 27185225. Bibcode: 2016AdM....28.6966K. https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.201601158.
- ↑ Prabhu, E.; Muthuraja, S.; Gnanasekar, K. I.; Jayaraman, V.; Sivabalan, S.; Gnanasekaran, T. (May 2008). "Ammonia sensing properties of thick and thin films of Ag 6 Mo 10 O 33 and Cr 1·8 Ti 0·2 O 3+ δ" (in en). Surface Engineering 24 (3): 170–175. doi:10.1179/174329408X298229. ISSN 0267-0844. https://journals.sagepub.com/doi/10.1179/174329408X298229.
General references
- Kumar, Vipin; Matz, Sebastian; Hoogestraat, Dirk; Bhavanasi, Venkateswarlu; Parida, Kaushik; Al-Shamery, Katharina; Lee, Pooi See (2016). "Design of Mixed-Metal Silver Decamolybdate Nanostructures for High Specific Energies at High Power Density". Advanced Materials 28 (32): 6966–6975. doi:10.1002/adma.201601158. ISSN 1521-4095. PMID 27185225. Bibcode: 2016AdM....28.6966K. https://onlinelibrary.wiley.com/doi/abs/10.1002/adma.201601158.
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