Chemistry:Silver perrhenate
From HandWiki
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| IUPAC name
Silver(1+) perrhenate
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| AgReO4 | |
| Molar mass | 358.073 g/mol |
| Density | 7.05 g/cm3 |
| Melting point | 430 °C (806 °F; 703 K) |
| 0.01 g/mL (20 °C)[1] | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Silver perrhenate is a chemical compound with the formula AgReO4. It is isostructural with the mineral scheelite (CaWO4).[2]
Properties
Silver perrhenate is soluble in O-donor and N-donor solvents as well as aromatic hydrocarbons.[1] It forms solvates with acetonitrile and pyridine, adducts with triphenylphosphine, and 2,2′-Bipyridine.[1]
Preparation
Silver perrhenate can be precipitated by combining rhenium heptoxide and silver nitrate solutions.[1]
Reactions
Silver perrhenate reacts with trimethylsilyl chloride to give the silyl "ester" (CH3)3SiOReO3.[3]
It reacts with boron trichloride to form rhenium oxytetrachloride.[1]
References
- ↑ 1.0 1.1 1.2 1.3 1.4 Woolf, Alfred A. (1978-09-01). "A comparison of silver perrhenate with silver perchlorate". Journal of the Less Common Metals 61 (1): 151–160. doi:10.1016/0022-5088(78)90154-6. ISSN 0022-5088.
- ↑ Naumov, D. Yu.; Virovets, A. V.; Korenev, S. V.; Gubanov, A. I. (1999). "Silver perrhenate, AgReO4". Acta Crystallographica Section C 55 (8): IUC9900097. doi:10.1107/S0108270199099138. Bibcode: 1999AcCrC..55C0097N.
- ↑ US patent 2008262256, Wolfgang A. Herrmann, Fritz E. Kuhn, Richard Fischer, "Method for efficiently producing methyltrioxorhenium(vii) (mto) and organorhenium(vii) oxides", issued 2005-08-30
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