Chemistry:Silver hypochlorite
From HandWiki
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| Names | |
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| Other names
Argentous hypochlorite, silver(I) hypochlorite
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| AgClO | |
| Molar mass | 159.32 g·mol−1 |
| very soluble | |
| Related compounds | |
Other anions
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Silver chloride, silver chlorite, silver chlorate, silver perchlorate |
Other cations
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Copper hypochlorite |
Related compounds
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Silver hypobromite, silver hypoiodite |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Silver hypochlorite is an ionic compound of silver and the polyatomic ion hypochlorite.[1] The chemical formula is AgClO.[2] The compound is very unstable and rapidly decomposes.[3]
Synthesis
- Bubbling chlorine through an aqueous suspension of silver oxide.[4]
- [math]\ce{ 12Cl + 3Ag2O + 3H2O -> 6AgCl + 6HClO }[/math]
- [math]\ce{ 6HClO + 3Ag2O -> 3H2O + 6AgClO }[/math]
- Reaction of hypochlorous acid with silver nitrate produces silver hypochlorite and nitric acid.[5]
- [math]\ce{ HClO + AgNO3 -> AgClO + HNO3 }[/math]
Chemical properties
Silver hypochlorite is very unstable, and its solution will soon disproportionate into silver chlorate and silver chloride:
- [math]\ce{ 3AgClO -> AgClO3 + 2AgCl }[/math]
If the AgClO solution is heated to 60 °C, it will rapidly disproportionate. Adding silver oxide stabilizes the solution.[3][dubious ]
References
- ↑ Comey, Arthur Messinger (1896) (in en). A Dictionary of Chemical Solubilities; Inorganic. Macmillan and Company. p. 180. https://books.google.com/books?id=S5QMAQAAIAAJ&dq=Silver+hypochlorite&pg=PA180. Retrieved 10 March 2023.
- ↑ "silver hypochlorite" (in en). chemsrc.com. https://www.chemsrc.com/en/cas/475461-52-0_1274065.html.
- ↑ 3.0 3.1 Massey, A. G.; Thompson, N. R.; Johnson, B. F. G. (6 June 2016) (in en). The Chemistry of Copper, Silver and Gold: Pergamon International Library of Science, Technology, Engineering and Social Studies. Elsevier. p. 108. ISBN 978-1-4831-8169-1. https://books.google.com/books?id=GuxPDAAAQBAJ&dq=Silver+hypochlorite&pg=PA108. Retrieved 10 March 2023.
- ↑ Stas, J. A. (1867). "On the Action of Chlorine on Carbonate of Silver" (in en). The Chemical News and Journal of Physical Science: A Journal of Practical Chemistry in All Its Applications to Pharmacy, Arts, and Manufacturers. American Reprint: 173. https://books.google.com/books?id=ePHNAAAAMAAJ&dq=Silver+hypochlorite&pg=PA173. Retrieved 10 March 2023.
- ↑ "Silver Hypochlorite: Formula, Solubility & Molar Mass". study.com. https://study.com/academy/lesson/silver-hypochlorite-formula-solubility-molar-mass.html.
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