Physics:Hydrogen storage

From HandWiki
Short description: Methods of storing hydrogen for later use
Liquid hydrogen Tank at NASA Kennedy Space Center

Several methods exist for storing hydrogen. These include mechanical approaches such as using high pressures and low temperatures, or employing chemical compounds that release H2 upon demand. While large amounts of hydrogen are produced by various industries, it is mostly consumed at the site of production, notably for the synthesis of ammonia. For many years hydrogen has been stored as compressed gas or cryogenic liquid, and transported as such in cylinders, tubes, and cryogenic tanks for use in industry or as propellant in space programs. Interest in using hydrogen for on-board storage of energy in zero-emissions vehicles is motivating the development of new methods of storage, more adapted to this new application. The overarching challenge is the very low boiling point of H2: it boils around 20.268 K (−252.882 °C or −423.188 °F). Achieving such low temperatures requires expending significant energy.

Established technologies

Net storage density of hydrogen

Compressed hydrogen

Compressed hydrogen is a storage form whereby hydrogen gas is kept under pressures to increase the storage density. Compressed hydrogen in hydrogen tanks at 350 bar (5,000 psi) and 700 bar (10,000 psi) are used for hydrogen tank systems in vehicles, based on type IV carbon-composite technology.[1] Car manufacturers have been developing this solution, such as Honda[2] or Nissan.[3]

Liquefied hydrogen

Liquid hydrogen tanks for cars, producing for example the BMW Hydrogen 7. Japan has a liquid hydrogen (LH2) storage site in Kobe port.[4] Hydrogen is liquefied by reducing its temperature to −253 °C, similar to liquefied natural gas (LNG) which is stored at −162 °C. A potential efficiency loss of only 12.79% can be achieved, or 4.26 kW⋅h/kg out of 33.3 kW⋅h/kg.[5]

Chemical storage

Hydrogen gravimetric capacity of proposed storage materials for hydrogen fuel as a function of hydrogen release temperature. The targets have since been lowered.[6]

Chemical storage could offer high storage performance due to the high storage densities. For example, supercritical hydrogen at 30 °C and 500 bar only has a density of 15.0 mol/L while methanol has a hydrogen density of 49.5 mol H2/L methanol and saturated dimethyl ether at 30 °C and 7 bar has a density of 42.1 mol H2/L dimethyl ether.

Regeneration of storage material is problematic. A large number of chemical storage systems have been investigated. H2 release can be induced by hydrolysis reactions or catalyzed dehydrogenation reactions. Illustrative storage compounds are hydrocarbons, boron hydrides, ammonia, and alane etc.[7] A most promising chemical approach is electrochemical hydrogen storage, as the release of hydrogen can be controlled by the applied electricity.[8] Most of the materials listed below can be directly used for electrochemical hydrogen storage.

As shown before, nanomaterials offer advantage for hydrogen storage systems. Nanomaterials offer an alternative that overcomes the two major barriers of bulk materials, rate of sorption and release temperature.

Enhancement of sorption kinetics and storage capacity can be improved through nanomaterial-based catalyst doping, as shown in the work of the Clean Energy Research Center in the University of South Florida.[9] This research group studied LiBH4 doped with nickel nanoparticles and analyzed the weight loss and release temperature of the different species. They observed that an increasing amount of nanocatalyst lowers the release temperature by approximately 20 °C and increases the weight loss of the material by 2-3%. The optimum amount of Ni particles was found to be 3 mol%, for which the temperature was within the limits established (around 100 °C) and the weight loss was notably greater than the undoped species.

The rate of hydrogen sorption improves at the nanoscale due to the short diffusion distance in comparison to bulk materials. They also have favorable surface-area-to-volume ratio.

The release temperature of a material is defined as the temperature at which the desorption process begins. The energy or temperature to induce release affects the cost of any chemical storage strategy. If the hydrogen is bound too weakly, the pressure needed for regeneration is high, thereby cancelling any energy savings. The target for onboard hydrogen fuel systems is roughly <100 °C for release and <700 bar for recharge (20–60 kJ/mol H2).[10] A modified van ’t Hoff equation, relates temperature and partial pressure of hydrogen during the desorption process. The modifications to the standard equation are related to size effects at the nanoscale.

[math]\displaystyle{ \ln(p_\mathrm{H_\mathrm{2}}) = \frac{\Delta H(r)}{RT}+\frac{3 V_\mathrm{m} \gamma}{rRT}+\frac{\Delta S(r)}{R} }[/math]

Where pH2 is the partial pressure of hydrogen, ΔH is the enthalpy of the sorption process (exothermic), ΔS is the change in entropy, R is the ideal gas constant, T is the temperature in Kelvin, Vm is the molar volume of the metal, r is the radius of the nanoparticle and γ is the surface free energy of the particle.

From the above relation we see that the enthalpy and entropy change of desorption processes depend on the radius of the nanoparticle. Moreover, a new term is included that takes into account the specific surface area of the particle and it can be mathematically proven that a decrease in particle radius leads to a decrease in the release temperature for a given partial pressure.[11]

Hydrogenation of CO2

Current approach to reduce CO2 includes capturing and storing from facilities across the world. However, storage poses technical and economic barriers preventing global scale application. To utilize CO2 at the point source, CO2 hydrogenation is a realistic and practical approach. Conventional hydrogenation reduces unsaturated organic compounds by addition of H2. One method of CO2 hydrogenation is via the methanol pathway. Methanol can be used to produce long chain hydrocarbons. Some barriers of CO2 hydrogenation includes purification of captured CO2, H2 source from splitting water and energy inputs for hydrogenation. To overcome these barriers, we can further develop green H2 technology and encourage catalyst research at industrial and academic level. For industrial applications, CO2 is often converted to methanol. Until now, much progress has been made for CO2 to C1 molecules. However, CO2 to high value molecules still face many roadblocks and the future of CO2 hydrogenation depends on the advancement of catalytic technologies.[12]

Metal hydrides

Metal hydride hydrogen storage

Metal hydrides, such as MgH2, NaAlH4, LiAlH4, LiH, LaNi5H6, TiFeH2, ammonia borane, and palladium hydride represent sources of stored hydrogen. Again the persistent problems are the % weight of H2 that they carry and the reversibility of the storage process.[13] Some are easy-to-fuel liquids at ambient temperature and pressure, whereas others are solids which could be turned into pellets. These materials have good energy density, although their specific energy is often worse than the leading hydrocarbon fuels.

LiNH2, LiBH4, and NaBH4.[14]

An alternative method for lowering dissociation temperatures is doping with activators. This strategy has been used for aluminium hydride, but the complex synthesis makes the approach unattractive.[15]

Proposed hydrides for use in a hydrogen economy include simple hydrides of magnesium[16] or transition metals and complex metal hydrides, typically containing sodium, lithium, or calcium and aluminium or boron. Hydrides chosen for storage applications provide low reactivity (high safety) and high hydrogen storage densities. Leading candidates are lithium hydride, sodium borohydride, lithium aluminium hydride and ammonia borane. A French company McPhy Energy is developing the first industrial product, based on magnesium hydride, already sold to some major clients such as Iwatani and ENEL.

Reversible hydrogen storage is exhibited by frustrated Lewis pair, which produces a borohydride.[17][18][19]

Phosphino borane hydrogenstorage

The phosphino-borane on the left accepts one equivalent of hydrogen at one atmosphere and 25 °C and expels it again by heating to 100 °C. The storage capacity is 0.25 wt%.

Aluminium

Main page: Chemistry:Aluminium

Hydrogen can be produced using aluminium by reacting it with water.[20] It was previously believed that, to react with water, aluminium must be stripped of its natural oxide layer using caustic substances, alloys,[21] or mixing with gallium (which produces aluminium nanoparticles that allow 90% of the aluminium to react).[22] It has since been demonstrated that efficient reaction is possible by increasing the temperature and pressure of the reaction.[23] The byproduct of the reaction to create hydrogen is aluminium oxide, which can be recycled back into aluminium with the Hall–Héroult process, making the reaction theoretically renewable. Although this requires electrolysis, which consumes a large amount of energy, the energy is then stored in the aluminium (and released when the aluminium is reacted with water).

Magnesium

Mg-based hydrogen storage materials can be generally fell into three categories, i.e., pure Mg, Mg-based alloys, and Mg-based composites. Particularly, more than 300 sorts of Mg-based hydrogen storage alloys have been receiving extensive attention [24] because of the relatively better overall performance. Nonetheless, the inferior hydrogen absorption/desorption kinetics rooting in the overly undue thermodynamic stability of metal hydride make the Mg-based hydrogen storage alloys currently not appropriate for the real applications, and therefore, massive attempts have been dedicated to overcoming these shortages. Some sample preparation methods, such as smelting, powder sintering, diffusion, mechanical alloying, hydriding combustion synthesis method, surface treatment, and heat treatment, etc., have been broadly employed for altering the dynamic performance and cycle life of Mg-based hydrogen storage alloys. Besides, some intrinsic modification strategies, including alloying,[25][26][27][28] nanostructuring,[29][30][31] doping by catalytic additives,[32][33] and acquiring nanocomposites with other hydrides,[34][35] etc., have been mainly explored for intrinsically boosting the performance of Mg-based hydrogen storage alloys.[36] Like aluminium, magnesium also reacts with water to produce hydrogen.[37]

Of the primary hydrogen storage alloys progressed formerly, Mg and Mg-based hydrogen storage materials are believed to provide the remarkable possibility of the practical application, on account of the advantages as following: 1) the resource of Mg is plentiful and economical. Mg element exists abundantly and accounts for ~2.35% of the earth's crust with the rank of the eighth; 2) low density of merely 1.74 g cm-3; 3) superior hydrogen storage capacity. The theoretical hydrogen storage amounts of the pure Mg is 7.6 wt % (weight percent),[38][39][40] and the Mg2Ni is 3.6 wt%, respectively.[36]

Alanates-based systems

Sodium Alanate(NaAlH4) is a complex hydride for H2 storage. The crystal structure was first determined through a single crystal X-ray diffraction study in 1979. The atomic structure consisted of isolated [AlH4]− tetrahedra in which the Na atoms are surrounded by eight [AlH4]− tetrahedra in a distorted square. Hydrogen release from NaAlH4 is known since the 1950s. In 1997, Bogdanovic discovered that TiO2 doping of materials makes the process reversible at modest temperature and pressure. TiO2-doped materials are reversible in hydrogen storage, NaAlH4 is currently the state of the art reversible solid state hydrogen storage material which can be used in low temperature and has 5.6 wt.% hydrogen contained. The chemical reaction is, 3NaAlH4 ← catalyst → Na3AlH6 + 2Al + 3H2 ← catalyst → 3NaH + Al + 3/2H2. The heat required to change from NaAlH4 to Na3AlH6 is 37 kJ/mol. The heat required to change from Na3AlH6 to NaH is 47 kJ/mol. In principle, the first step of NaAlH4 releases 3.7 wt.% hydrogen at about 190 °C and the second step releases 1.8 wt.% hydrogen at about 225 °C upon heating. Further dehydrogenation of NaH occurs only at temperature higher than 400 °C. This temperature is too high for technical applications, therefore, can not be used in a fuel cell vehicle.

Lithium alanate (LiAlH4) was synthesized for the first time in 1947 by dissolution of lithium hydride in an ether solution of aluminium chloride.[41] LiAlH4 has a theoretical gravimetric capacity of 10.5 wt %H2 and dehydrogenates in the following three steps:[42][43][44] 3LiAlH4 ↔ Li3AlH6 + 3H2 + 2Al (423–448 K; 5.3 wt %H2; ∆H = −10 kJ·mol−1 H2); Li3AlH6 ↔ 3LiH + Al + 1.5H2 (453–493 K; 2.6 wt %H2; ∆H = 25 kJ·mol−1 H2); 3LiH + 3Al ↔ 3LiAl + 3/2H2 (>673 K; 2.6 wt %H2; ∆H = 140 kJ·mol−1 H2).[45] The first two steps lead to a total amount of hydrogen released equal to 7.9 wt %, which could be attractive for practical applications, but the working temperatures and the desorption kinetics are still far from the practical targets. Several strategies have been applied in the last few years to overcome these limits, such as ball-milling and catalysts additions.[46][47][48][49][50][45]

Potassium Alanate (KAlH4) was first prepared by Ashby et al.[51] by one-step synthesis in toluene, tetrahydrofuran, and diglyme. Concerning the hydrogen absorption and desorption properties, this alanate was only scarcely studied. Morioka et al.,[52] by temperature programmed desorption (TPD) analyses, proposed the following dehydrogenation mechanism: 3KAlH4 →K3AlH6 + 2Al + 3H2 (573 K, ∆H = 55 kJ·mol−1 H2; 2.9 wt %H2), K3AlH6 → 3KH + Al + 3/2H2 (613 K, ∆H = 70 kJ·mol−1 H2; 1.4 wt %H2), 3KH → 3K + 3/2H2 (703 K, 1.4 wt %H2). These reactions were demonstrated reversible without catalysts addition at relatively low hydrogen pressure and temperatures. The addition of TiCl3 was found to decrease the working temperature of the first dehydrogenation step of 50 K,[53] but no variations were recorded for the last two reaction steps.[45]

Organic hydrogen carriers

Main page: Physics:Liquid organic hydrogen carriers
Reversible hydrogenation of N-ethylcarbazole.

Unsaturated organic compounds can store huge amounts of hydrogen. These Liquid Organic Hydrogen Carriers (LOHC) are hydrogenated for storage and dehydrogenated again when the energy/hydrogen is needed. Using LOHCs, relatively high gravimetric storage densities can be reached (about 6 wt-%) and the overall energy efficiency is higher than for other chemical storage options such as producing methane from the hydrogen.[54] Both hydrogenation and dehydrogenation of LOHCs requires catalysts.[55] It was demonstrated that replacing hydrocarbons by hetero-atoms, like N, O etc. improves reversible de/hydrogenation properties.

Cycloalkanes

Research on LOHC was concentrated on cycloalkanes at an early stage, with its relatively high hydrogen capacity (6-8 wt %) and production of COx-free hydrogen.[55] Heterocyclic aromatic compounds (or N-Heterocycles) are also appropriate for this task. A compound featuring in LOHC research is N-Ethylcarbazole (de) (NEC)[56] but many others do exist.[57] Dibenzyltoluene, which is already used as a heat transfer fluid in industry, was identified as potential LOHC. With a wide liquid range between -39 °C (melting point) and 390 °C (boiling point) and a hydrogen storage density of 6.2 wt% dibenzyltoluene is ideally suited as LOHC material.[58] Formic acid has been suggested as a promising hydrogen storage material with a 4.4wt% hydrogen capacity.[59]

Cycloalkanes reported as LOHC include cyclohexane, methyl-cyclohexane and decalin. The dehydrogenation of cycloalkanes is highly endothermic (63-69 kJ/mol H2), which means this process requires high temperature.[55] Dehydrogenation of decalin is the most thermodynamically favored among the three cycloalkanes, and methyl-cyclohexane is second because of the presence of the methyl group.[60] Research on catalyst development for dehydrogenation of cycloalkanes has been carried out for decades. Nickel (Ni), Molybdenum (Mo) and Platinum (Pt) based catalysts are highly investigated for dehydrogenation. However, coking is still a big challenge for catalyst's long-term stability.[61][62]

The addition of second metal such as W, Ir, Re, Rh and Pd etc. and/or promoter (such as Ca) and selection of suitable support (such as CNF and Al2O3) are effective against coking. For cyclohexane, there are two dehydrogenation mechanisms, the sextet mechanism and the doublet mechanism. The difference between the two mechanisms lies in whether they are intermediate products during dehydrogenation. In the sextet mechanism, cyclohexane overlies on the catalyst surface and undergoes dehydrogenation directly to benzene. In contrast, in the double mechanism, hydrogen will be released step by step because of the C=C double bound.

N-Heterocycles

The temperature required for hydrogenation and dehydrogenation drops significantly for heterocycles vs simple carbocycles.[63] Among all the N-heterocycles, the saturated-unsaturated pair of dodecahydro-N-ethylcarbazole (12H-NEC) and NEC has been considered as a promising candidate for hydrogen storage with a fairly large hydrogen content (5.8wt%).[64] The figure on the top right shows dehydrogenation and hydrogenation of the 12H-NEC and NEC pair. The standard catalyst for NEC to 12H-NEC is Ru and Rh based. The selectivity of hydrogenation can reach 97% at 7 MPa and 130 °C-150 °C.[55] Although N-Heterocyles can optimize the unfavorable thermodynamic properties of cycloalkanes, a lot of issues remain unsolved, such as high cost, high toxicity and kinetic barriers etc.[55]

The imidazolium ionic liquids such alkyl(aryl)-3-methylimidazolium N-bis(trifluoromethanesulfonyl)imidate salts can reversibly add 6–12 hydrogen atoms in the presence of classical Pd/C or Ir0 nanoparticle catalysts and can be used as alternative materials for on-board hydrogen-storage devices. These salts can hold up to 30 g L−1 of hydrogen at atmospheric pressure.[65]

Formic acid

Formic acid is a highly effective hydrogen storage material, although its H2density is low. Carbon monoxide free hydrogen has been generated in a very wide pressure range (1–600 bar). A homogeneous catalytic system based on water-soluble ruthenium catalysts selectively decompose HCOOH into H2 and CO2 in aqueous solution.[66] This catalytic system overcomes the limitations of other catalysts (e.g. poor stability, limited catalytic lifetimes, formation of CO) for the decomposition of formic acid making it a viable hydrogen storage material.[67] And the co-product of this decomposition, carbon dioxide, can be used as hydrogen vector by hydrogenating it back to formic acid in a second step. The catalytic hydrogenation of CO2 has long been studied and efficient procedures have been developed.[68][69] Formic acid contains 53 g L−1 hydrogen at room temperature and atmospheric pressure. By weight, pure formic acid stores 4.3 wt% hydrogen. Pure formic acid is a liquid with a flash point 69 °C (cf. gasoline −40 °C, ethanol 13 °C). 85% formic acid is not flammable.

Carbohydrates

Carbohydrates (polymeric C6H10O5) release H2 in a bioreformer mediated by the enzyme cocktail—cell-free synthetic pathway biotransformation. Carbohydrates provide high hydrogen storage densities as a liquid with mild pressurization and cryogenic constraints: It can also be stored as a solid powder. Carbohydrates are the most abundant renewable bioresource in the world.

Polysaccharides (C6H10O5)n undergo a hydrolysis reaction of C6H10O5 + 7H2O → 12H2 +6CO2. As a result, hydrogen storage density in polysaccharides is 14.8 mass%. Carbohydrates are much less costly than other carriers. Hydrogen generation from carbohydrates can be implemented at mild conditions of 30~80 °C and about 1 atm, the process does not need any costly high pressure reactor, and high purity hydrogen mixed with CO
2 is generated, making extra product purification unnecessary. Under the mild reaction conditions, separation of gaseous products and aqueous reaction is easy and nearly no cost. Moreover, renewable carbohydrates are non-flammable and not toxic at all.

Compared to other hydrogen carriers, carbohydrates are very appealing due to their low cost, renewable source, high purity hydrogen generated, and so on.

Ammonia and related compounds

Further information: Chemistry:Ammonia production

Ammonia

Ammonia (NH3) releases H2 in an appropriate catalytic reformer. Ammonia provides high hydrogen storage densities as a liquid with mild pressurization and cryogenic constraints: It can also be stored as a liquid at room temperature and pressure when mixed with water. Ammonia is the second most commonly produced chemical in the world and a large infrastructure for making, transporting, and distributing ammonia exists. Ammonia can be reformed to produce hydrogen with no harmful waste, or can mix with existing fuels and under the right conditions burn efficiently. Since there is no carbon in ammonia, no carbon by-products are produced; thereby making this possibility a "carbon neutral" option for the future. Pure ammonia burns poorly at the atmospheric pressures found in natural gas fired water heaters and stoves. Under compression in an automobile engine it is a suitable fuel for slightly modified gasoline engines. Ammonia is a suitable alternative fuel because it has 18.6 MJ/kg energy density at NTP and carbon-free combustion byproducts.[70]

Ammonia has several challenges to widespread adaption as a hydrogen storage material. Ammonia is a toxic gas with a potent odor at standard temperature and pressure.[71] Additionally, advances in the efficiency and scalability of ammonia decomposition are needed for commercial viability, as fuel cell membranes are highly sensitive to residual ammonia and current decomposition techniques have low yield rates.[72] A variety of transition metals can be used to catalyze the ammonia decomposition reaction, the most effective being ruthenium. This catalysis works through chemisorption, where the adsorption energy of N2 is less than the reaction energy of dissociation.[73] Hydrogen purification can be achieved in several ways. Hydrogen can be separated from unreacted ammonia using a permeable, hydrogen-selective membrane.[74] It can also be purified through the adsorption of ammonia, which can be selectively trapped due to its polarity.[75]

In September 2005 chemists from the Technical University of Denmark announced a method of storing hydrogen in the form of ammonia saturated into a salt tablet. They claim it will be an inexpensive and safe storage method.[76][needs update]

Positive attributes of Ammonia
  • High theoretical energy density
  • Wide spread availability
  • Large scale commercial production
  • Benign decomposition pathway to H2 and N2
Negative attributes of Ammonia
  • Toxicity
  • Corrosive
  • High decomposition temperature leading to efficiency loss

Hydrazine

Hydrazine breaks down in the cell to form nitrogen and hydrogen/[77] Silicon hydrides and germanium hydrides are also candidates of hydrogen storage materials, as they can subject to energetically favored reaction to form covalently bonded dimers with loss of a hydrogen molecule.[78][79]

Chemical hydrides

Chemical hydride is an irreversible hydrogen storage material. The reaction of hydrogen releasing from chemical hydrides are usually exothermic, which makes regeneration of the fuel energy-intensive. NaBH4 + 2H2O → NaBO2 + 4H2 + 300 kJ. The chemical reaction gives potential for high density storage, but current systems produce much lower effective density. The NaBH4 has a theoretical effective density of 10.8 wt.%, however there is only 1.1 wt.% of effective density in reality. Examples of chemical hydride reactions: NaBH4 (20~35% solution, stabilized with 1~3% NaOH) + 2H2O (from fuel cell exhaust) → NaBO2 (Borax in NaOH) + 4H2. 2LiH + 2H2O → 2LiOH + 2H2.[citation needed]

A leading chemical hydride is NH3BH3, which is a waxy solid at room temperature with a melting point of 90 °C. Hydrogen will be released from NH3BH3 around 90 °C because of thermal decomposition. NH3BH3 is a promising material for hydrogen storing because it has one of the highest theoretical hydrogen weight percentages at 19.6% and also the highest hydrogen volume density at 151 kg H2 per volume[clarification needed]. Hydrogen release from NH3BH3 occurs stepwise, where the onset temperature for the first equivalent is 90 °C, the temperature for second equivalent is 150 °C. The remaining hydrogen will be released at the temperature higher than 150 °C.[citation needed]

Amine boranes

Prior to 1980, several compounds were investigated for hydrogen storage including complex borohydrides, or aluminohydrides, and ammonium salts. These hydrides have an upper theoretical hydrogen yield limited to about 8.5% by weight. Amongst the compounds that contain only B, N, and H (both positive and negative ions), representative examples include: amine boranes, boron hydride ammoniates, hydrazine-borane complexes, and ammonium octahydrotriborates or tetrahydroborates. Of these, amine boranes (and especially ammonia borane) have been extensively investigated as hydrogen carriers. During the 1970s and 1980s, the U.S. Army and Navy funded efforts aimed at developing hydrogen/deuterium gas-generating compounds for use in the HF/DF and HCl chemical lasers, and gas dynamic lasers. Earlier hydrogen gas-generating formulations used amine boranes and their derivatives. Ignition of the amine borane(s) forms boron nitride (BN) and hydrogen gas. In addition to ammonia borane (H3BNH3), other gas-generators include diborane diammoniate, H2B(NH3)2BH4.

Physical storage

In this case hydrogen remains in physical forms, i.e., as gas, supercritical fluid, adsorbate, or molecular inclusions. Theoretical limitations and experimental results are considered [80] concerning the volumetric and gravimetric capacity of glass microvessels, microporous, and nanoporous media, as well as safety and refilling-time demands. Because hydrogen is the smallest molecule, it easily escapes from containers and during transfer from container to container, and leaked hydrogen has a global warming effect 11.6 times stronger than CO₂.[81]

Zeolites

Zeolites are microporous and highly crystalline aluminosilicate materials. As they exhibit cage and tunnel structures, they offer the potential for the encapsulation of non-polar gases such as H2. In this system, hydrogen is physisorbed on the surface of the zeolite pores through a mechanism of adsorption that involves hydrogen being forced into the pores under pressure and low temperature.[82] Therefore, similar to other porous materials, its hydrogen storage capacity depends on the BET surface area, pore volume, the interaction of molecular hydrogen with the internal surfaces of the micropores, and working conditions such as pressure and temperature.[83]

Research shows that the channel diameter is also one of the parameters determining this capacity, especially at high pressure. In this case, an effective material should exhibit a large pore volume and a channel diameter close to the kinetic diameter of the hydrogen molecule (dH=2.89 Å).[82]

Table below shows the hydrogen uptake of several zeolites at liquid nitrogen temperature (77K):

H2 uptake of several high surface area zeolites[84]
Zeolite Framework Type (IZA Code) Pressure (bar) H2 Uptake (wt%) BET Surface Area (m2/g)
NaY (Si/Al = 2.4) FAU 0.57 0.37
HY (Si/Al = 2.7) FAU 0.95 0.56
MCM-41 1 0.58 1017
H-ZSM-5 (Si/Al = 40) MFI 0.92 0.71 418
H-SAPO-34 CHA 0.92 1.09 547
H-CHA (Si/Al = 2.1) CHA 0.92 1.10 490
H-SSZ-13 (Si/Al = 11.6) CHA 0.92 1.28 638
NaA LTA 0.93 1.21
LiX (Si/Al = 1.4) FAU 0.60 0.88
NaX (Si/Al = 1.05) FAU 0.61 1.22
CaX (Si/Al = 1.4) FAU 1.01 1.25 669
Li-LSX (Si/Al = 1.0) FAU 1.01 1.50 717
Na-LSX (Si/Al = 1.0) FAU 1.01 1.46 642
K-LSX (Si/Al = 1.0) FAU 1.01 1.33 570

Porous or layered carbon

Activated carbons are highly porous amorphous carbon materials with high apparent surface area. Hydrogen physisorption can be increased in these materials by increasing the apparent surface area and optimizing pore diameter to around 7 Å.[85] These materials are of particular interest due to the fact that they can be made from waste materials, such as cigarette butts which have shown great potential as precursor materials for high-capacity hydrogen storage materials.[86][87]

Graphene can store hydrogen efficiently. The H2 adds to the double bonds giving graphane. The hydrogen is released upon heating to 450 °C.[88][89]

Carbon nanotubes

Hydrogen carriers based on nanostructured carbon (such as carbon buckyballs and nanotubes) have been proposed. However, hydrogen content amounts up to ≈3.0-7.0 wt% at 77K which is far from the value set by US Department of Energy (6 wt% at nearly ambient conditions).

To realize carbon materials as effective hydrogen storage technologies, carbon nanotubes (CNTs) have been doped with MgH2.[9] The metal hydride has proven to have a theoretical storage capacity (7.6 wt%) that fulfills the United States Department of Energy requirement of 6 wt%, but has limited practical applications due to its high release temperature. The proposed mechanism involves the creation of fast diffusion channels by CNTs within the MgH2 lattice. Fullerene substances are other carbonaceous nanomaterials that have been tested for hydrogen storage in this center. Fullerene molecules are composed of a C60 close-caged structure, that allows for hydrogenation of the double bonded carbons leading to a theoretical C60H60 isomer with a hydrogen content of 7.7 wt%. However, the release temperature in these systems is high (600 °C).

Metal-organic frameworks

Metal-organic frameworks represent another class of synthetic porous materials that store hydrogen and energy at the molecular level. MOFs are highly crystalline inorganic-organic hybrid structures that contain metal clusters or ions (secondary building units) as nodes and organic ligands as linkers. When guest molecules (solvent) occupying the pores are removed during solvent exchange and heating under vacuum, porous structure of MOFs can be achieved without destabilizing the frame and hydrogen molecules will be adsorbed onto the surface of the pores by physisorption. Compared to traditional zeolites and porous carbon materials, MOFs have very high number of pores and surface area which allow higher hydrogen uptake in a given volume. Thus, research interests on hydrogen storage in MOFs have been growing since 2003 when the first MOF-based hydrogen storage was introduced. Since there are infinite geometric and chemical variations of MOFs based on different combinations of SBUs and linkers, many researches explore what combination will provide the maximum hydrogen uptake by varying materials of metal ions and linkers.

Factors influencing hydrogen storage ability

Temperature, pressure and composition of MOFs can influence their hydrogen storage ability. The adsorption capacity of MOFs is lower at higher temperature and higher at lower temperatures. With the rising of temperature, physisorption decreases and chemisorption increases.[90] For MOF-519 and MOF-520, the isosteric heat of adsorption decreased with pressure increase.[91] For MOF-5, both gravimetric and volumetric hydrogen uptake increased with increase in pressure.[90] The total capacity may not be consistent with the usable capacity under pressure swing conditions. For instance, MOF-5 and IRMOF-20, which have the highest total volumetric capacity, show the least usable volumetric capacity.[92] Absorption capacity can be increased by modification of structure. For example, the hydrogen uptake of PCN-68 is higher than PCN-61.[93] Porous aromatic frameworks (PAF-1), which is known as a high surface area material, can achieve a higher surface area by doping.[94]

Modification of MOFs

There are many different ways to modify MOFs, such as MOF catalysts, MOF hybrids, MOF with metal centers and doping. MOF catalysts have high surface area, porosity and hydrogen storage capacity. However, the active metal centers are low. MOF hybrids have enhanced surface area, porosity, loading capacity and hydrogen storage capacity. Nevertheless, they are not stable and lack active centers. Doping in MOFs can increase hydrogen storage capacity, but there might be steric effect and inert metals have inadequate stability. There might be formation of interconnected pores and low corrosion resistance in MOFs with metal centers, while they might have good binding energy and enhanced stability. These advantages and disadvantages for different kinds of modified MOFs show that MOF hybrids are more promising because of the good controllability in selection of materials for high surface area, porosity and stability.[90]

In 2006, chemists achieved hydrogen storage concentrations of up to 7.5 wt% in MOF-74 at a low temperature of 77 K.[95][96] In 2009, researchers reached 10 wt% at 77 bar (1,117 psi) and 77 K with MOF NOTT-112.[97] Most articles about hydrogen storage in MOFs report hydrogen uptake capacity at a temperature of 77K and a pressure of 1 bar because these conditions are commonly available and the binding energy between hydrogen and the MOF at this temperature is large compared to the thermal vibration energy. Varying several factors such as surface area, pore size, catenation, ligand structure, and sample purity can result in different amounts of hydrogen uptake in MOFs.

In 2020, researchers reported that NU-1501-Al, an ultraporous metal–organic framework (MOF) based on metal trinuclear clusters, yielded "impressive gravimetric and volumetric storage performances for hydrogen and methane", with a hydrogen delivery capacity of 14.0% w/w, 46.2 g/litre. [98] [99]

Cryo-compressed

Cryo-compressed storage of hydrogen is the only technology that meets 2015 DOE targets for volumetric and gravimetric efficiency (see "CcH2" on slide 6 in [100]).

Furthermore, another study has shown that cryo-compression exhibits interesting cost advantages: ownership cost (price per mile) and storage system cost (price per vehicle) are actually the lowest when compared to any other technology (see third row in slide 13 of [101]). For example, a cryo-compressed hydrogen system would cost $0.12 per mile (including cost of fuel and all other associated costs), while conventional gasoline vehicles cost between $0.05 and $0.07 per mile.[citation needed]

Like liquid storage, cryo-compressed uses cold hydrogen (20.3 K and slightly above) in order to reach a high energy density. However, the main difference is that, when the hydrogen would warm-up due to heat transfer with the environment ("boil off"), the tank is allowed to go to pressures much higher (up to 350 bars versus a couple of bars for liquid storage). As a consequence, it takes more time before the hydrogen has to vent, and in most driving situations, enough hydrogen is used by the car to keep the pressure well below the venting limit.

Consequently, it has been demonstrated that a high driving range could be achieved with a cryo-compressed tank : more than 650 miles (1,050 km) were driven with a full tank mounted on a hydrogen-fueled engine of Toyota Prius.[102] Research is still underway to study and demonstrate the full potential of the technology.[103]

As of 2010, the BMW Group has started a thorough component and system level validation of cryo-compressed vehicle storage on its way to a commercial product.[104]

Cryo-supercritical

Clathrate hydrates

H2 caged in a clathrate hydrate was first reported in 2002, but requires very high pressures to be stable. In 2004, researchers showed solid H2-containing hydrates could be formed at ambient temperature and tens of bars by adding small amounts of promoting substances such as THF.[105][106] These clathrates have a theoretical maximum hydrogen densities of around 5 wt% and 40 kg/m3.

Glass capillary arrays

A team of Russian, Israeli and German scientists have collaboratively developed an innovative technology based on glass capillary arrays for the safe infusion, storage and controlled release of hydrogen in mobile applications.[107][108] The C.En technology has achieved the United States Department of Energy (DOE) 2010 targets for on-board hydrogen storage systems.[109] DOE 2015 targets can be achieved using flexible glass capillaries and cryo-compressed method of hydrogen storage.[110]

Glass microspheres

Hollow glass microspheres (HGM) can be utilized for controlled storage and release of hydrogen. HGMs with a diameter of 1 to 100 μm, a density of 1.0 to 2.0 gm/cc and a porous wall with openings of 10 to 1000 angstroms are considered for hydrogen storage. The advantages of HGMs for hydrogen storage are that they are nontoxic, light, cheap, recyclable, reversible, easily handled at atmospheric conditions, capable of being stored in a tank, and the hydrogen within is non-explosive.[111] Each of these HGMs is capable of containing hydrogen up to 150 MPa without the heaviness and bulk of a large pressurized tank. All of these qualities are favorable in vehicular applications. Beyond these advantages, HGMs are seen as a possible hydrogen solution due to hydrogen diffusivity having a large temperature dependence. At room temperature, the diffusivity is very low, and the hydrogen is trapped in the HGM. The disadvantage of HGMs is that to fill and outgas hydrogen effectively the temperature must be at least 300 °C which significantly increases the operational cost of HGM in hydrogen storage.[112] The high temperature can be partly attributed to glass being an insulator and having a low thermal conductivity; this hinders hydrogen diffusivity, and subsequently a higher temperature is required to achieve the desired storage capacity.

To make this technology more economically viable for commercial use, research is being done to increase the efficiency of hydrogen diffusion through the HGMs. One study done by Dalai et al. sought to increase the thermal conductivity of the HGM through doping the glass with cobalt. In doing so they increased the thermal conductivity from 0.0072 to 0.198 W/m-K at 10 wt% Co. Increases in hydrogen adsorption though were only seen up to 2 wt% Co (0.103 W/m-K) as the metal oxide began to cover pores in the glass shell. This study concluded with a hydrogen storage capacity of 3.31 wt% with 2 wt% Co at 200 °C and 10 bar.[111]

A study done by Rapp and Shelby sought to increase the hydrogen release rate through photo-induced outgassing in doped HGMs in comparison to conventional heating methods. The glass was doped with optically active metals to interact with the high-intensity infrared light. The study found that 0.5 wt% Fe3O4 doped 7070 borosilicate glass had hydrogen release increase proportionally to the infrared lamp intensity. In addition to the improvements to diffusivity by infrared alone, reactions between the hydrogen and iron-doped glass increased the Fe2+/Fe3+ ratio which increased infrared absorption therefore further increasing the hydrogen yield.[113]

As of 2020, the progress made in studying HGMs has increased its efficiency but it still falls short of Department of Energy targets for this technology. The operation temperatures for both hydrogen adsorption and release are the largest barrier to commercialization.[114]

Stationary hydrogen storage

Unlike mobile applications, hydrogen density is not a huge problem for stationary applications. As for mobile applications, stationary applications can use established technology:

Underground hydrogen storage

'Available storage technologies, their capacity and discharge time.'[116]:12

Underground hydrogen storage[117] is the practice of hydrogen storage in caverns, salt domes and depleted oil and gas fields. Large quantities of gaseous hydrogen have been stored in caverns by ICI for many years without any difficulties.[118] The storage of large quantities of liquid hydrogen underground can function as grid energy storage. The round-trip efficiency is approximately 40% (vs. 75-80% for pumped-hydro (PHES)), and the cost is slightly higher than pumped hydro, if only a limited number of hours of storage is required.[119] Another study referenced by a European staff working paper found that for large scale storage, the cheapest option is hydrogen at €140/MWh for 2,000 hours of storage using an electrolyser, salt cavern storage and combined-cycle power plant.[116]:15 The European project Hyunder[120] indicated in 2013 that for the storage of wind and solar energy an additional 85 caverns are required as it cannot be covered by PHES and CAES systems.[121] A German case study on storage of hydrogen in salt caverns found that if the German power surplus (7% of total variable renewable generation by 2025 and 20% by 2050) would be converted to hydrogen and stored underground, these quantities would require some 15 caverns of 500,000 cubic metres each by 2025 and some 60 caverns by 2050 – corresponding to approximately one third of the number of gas caverns currently operated in Germany.[122] In the US, Sandia Labs are conducting research into the storage of hydrogen in depleted oil and gas fields, which could easily absorb large amounts of renewably produced hydrogen as there are some 2.7 million depleted wells in existence.[123]

Power to gas

Power to gas is a technology which converts electrical power to a gas fuel. There are two methods: the first is to use the electricity for water splitting and inject the resulting hydrogen into the natural gas grid; the second, less efficient method is used to convert carbon dioxide and hydrogen to methane, (see natural gas) using electrolysis and the Sabatier reaction. A third option is to combine the hydrogen via electrolysis with a source of carbon (either carbon dioxide or carbon monoxide from biogas, from industrial processes or via direct air-captured carbon dioxide) via biomethanation,[124][125] where biomethanogens (archaea) consume carbon dioxide and hydrogen and produce methane within an anaerobic environment. This process is highly efficient, as the archaea are self-replicating and only require low-grade (60 °C) heat to perform the reaction.

Another process has also been achieved by SoCalGas to convert the carbon dioxide in raw biogas to methane in a single electrochemical step, representing a simpler method of converting excess renewable electricity into storable natural gas.[126]

The UK has completed surveys and is preparing to start injecting hydrogen into the gas grid as the grid previously carried 'town gas' which is a 50% hydrogen-methane gas formed from coal. Auditors KPMG found that converting the UK to hydrogen gas could be £150bn to £200bn cheaper than rewiring British homes to use electric heating powered by lower-carbon sources.[127]

Excess power or off peak power generated by wind generators or solar arrays can then be used for load balancing in the energy grid. Using the existing natural gas system for hydrogen, Fuel cell maker Hydrogenics and natural gas distributor Enbridge have teamed up to develop such a power to gas system in Canada.[128]

Pipeline storage of hydrogen where a natural gas network is used for the storage of hydrogen. Before switching to natural gas, the German gas networks were operated using towngas, which for the most part (60-65%) consisted of hydrogen. The storage capacity of the German natural gas network is more than 200,000 GW·h which is enough for several months of energy requirement. By comparison, the capacity of all German pumped storage power plants amounts to only about 40 GW·h. The transport of energy through a gas network is done with much less loss (<0.1%) than in a power network (8%). The use of the existing natural gas pipelines for hydrogen was studied by NaturalHy[129]

Automotive onboard hydrogen storage

Portability is one of the biggest challenges in the Automotive industry , where high density storage systems are problematic due to safety concerns. High-pressure tanks weigh much more than the hydrogen they can hold. For example, in the 2014 Toyota Mirai, a full tank contains only 5.7% hydrogen, the rest of the weight being the tank.[130]

The US Department of Energy has set targets for onboard hydrogen storage for light vehicles. The list of requirements include parameters related to gravimetric and volumetric capacity, operability, durability and cost. These targets have been set as the goal for a multiyear research plan expected to offer an alternative to fossil fuels.[131] The FreedomCAR Partnership, which was established under U.S. President George W. Bush, set targets for hydrogen vehicle fuel systems. The 2005 targets were not reached.[132] The targets were revised in 2009 to reflect new data on system efficiencies obtained from fleets of test cars.[133] In 2017 the 2020 and ultimate targets were lowered, with the ultimate targets set to 65 g H2 per kg total system weight, and 50 g H2 per litre of system.[6][134]

FreedomCAR targets for on-board hydrogen storage assuming storage of 5 kg of hydrogen. (Now out of date.)[135]

It is important to note that these targets are for the hydrogen storage system, not the hydrogen storage material such as a hydride. System densities are often around half those of the working material, thus while a material may store 6 wt% H2, a working system using that material may only achieve 3 wt% when the weight of tanks, temperature and pressure control equipment, etc., is considered.

In 2010, only two storage technologies were identified as having the potential to meet DOE targets: MOF-177 exceeds 2010 target for volumetric capacity, while cryo-compressed H2 exceeds more restrictive 2015 targets for both gravimetric and volumetric capacity (see slide 6 in [100]).

The target for fuel cell powered vehicles is to provide a driving range of over 300 miles. A long-term goal set by the US Fuel Cell Technology Office involves the use of nanomaterials to improve maximum range.[136]

Fuel cells and storage

Due to its clean-burning characteristics, hydrogen is a clean fuel alternative for the automotive industry. Hydrogen-based fuel could significantly reduce the emissions of greenhouse gases such as CO2, SO2 and NOx. Three problems for the use of hydrogen fuel cells (HFC) are efficiency, size, and safe onboard storage of the gas. Other major disadvantages of this emerging technology involve cost, operability and durability issues, which still need to be improved from the existing systems. To address these challenges, the use of nanomaterials has been proposed as an alternative option to the traditional hydrogen storage systems. The use of nanomaterials could provide a higher density system and increase the driving range towards the target set by the DOE at 300 miles. Carbonaceous materials such as carbon nanotube and metal hydrides are the main focus of research. They are currently being considered for onboard storage systems due to their versatility, multi-functionality, mechanical properties and low cost with respect to other alternatives.[137]

Other advantages of nanomaterials in fuel cells

The introduction of nanomaterials in onboard hydrogen storage systems may be a major turning point in the automotive industry. However, storage is not the only aspect of the fuel cell to which nanomaterials may contribute. Different studies have shown that the transport and catalytic properties of Nafion membranes used in HFCs can be enhanced with TiO2/SnO2 nanoparticles.[137] The increased performance is caused by an improvement in hydrogen splitting kinetics due to catalytic activity of the nanoparticles. Furthermore, this system exhibits faster transport of protons across the cell which makes HFCs with nanoparticle composite membranes a promising alternative.

Another application of nanomaterials in water splitting has been introduced by a research group at Manchester Metropolitan University in the UK using screen-printed electrodes consisting of a graphene-like material.[138] Similar systems have been developed using photoelectrochemical techniques.

Economy

The Hydrogen Storage Materials research field is vast, having tens of thousands of published papers.[139] According to Papers in the 2000 to 2015 period collected from Web of Science and processed in VantagePoint® bibliometric software, a scientometric review of research in hydrogen storage materials was constituted. According to the literature, hydrogen energy went through a hype-cycle type of development in the 2000s. Research in Hydrogen Storage Materials grew at increasing rates from 2000 to 2010. Afterwards, growth continued but at decreasing rates, and a plateau was reached in 2015. Looking at individual country output, there is a division between countries that after 2010 inflected to a constant or slightly declining production, such as the European Union countries, the US and Japan, and those whose production continued growing until 2015, such as China and South Korea. The countries with most publications were China, the EU and the United States, followed by Japan. China kept the leading position throughout the entire period, and had a higher share of hydrogen storage materials publications in its total research output.[140]

Among materials classes, Metal-Organic Frameworks were the most researched materials, followed by Simple Hydrides. Three typical behaviors were identified:

  1. New materials, researched mainly after 2004, such as MOFs and Borohydrides;
  2. Classic materials, present through the entire period with growing number of papers, such as Simple Hydrides, and
  3. Materials with stagnant or declining research through the end of the period, such as AB5 alloys and Carbon Nanotubes.[140]

However, current physisorption technologies are still far from being commercialized. The experimental studies are executed for small samples less than 100 g.[141] The described technologies require high pressure and/or low temperatures as a rule. Therefore, at their current state of the art these techniques are not considered as a separate novel technology but as a type of valuable add-on to current compression and liquefaction methods.

Physisorption processes are reversible since no activation energy is involved and the interaction energy is very low. In materials such as metal–organic frameworks, porous carbons, zeolites, clathrates, and organic polymers, hydrogen is physisorbed on the surface of the pores. In these classes of materials, the hydrogen storage capacity mainly depends on the surface area and pore volume. The main limitation of use of these sorbents as H2storage materials is weak van der Waals interaction energy between hydrogen and the surface of the sorbents. Therefore, many of the physisorption based materials have high storage capacities at liquid nitrogen temperature and high pressures, but their capacities become very low at ambient temperature and pressure.

LOHC, liquid organic hydrogen storage systems is a promising technique for future hydrogen storage. LOHC are organic compounds that can absorb and release hydrogen through chemical reactions. These compounds are characterized by the fact that they can be loaded and un-loaded with considerable amounts of hydrogen in a cyclic process. In principle, every unsaturated compound (organic molecules with C-C double or triple bonds) can take up hydrogen during hydrogenation. This technique ensures that the release of compounds into the atmosphere are entirely avoided in hydrogen storage. Therefore, LOHCs is an attractive way to provide wind and solar energy for mobility applications in the form of liquid energy carrying molecules of similar energy storage densities and manageability as today's fossil fuels.[142]

See also

References

  1. ↑ Eberle, Ulrich; Mueller, Bernd; von Helmolt, Rittmar (2012). "Fuel cell electric vehicles and hydrogen infrastructure: status 2012". Energy & Environmental Science 5 (10): 8780. doi:10.1039/C2EE22596D. https://www.researchgate.net/publication/233987484. Retrieved 2014-12-19. 
  2. ↑ "FCX Clarity". http://world.honda.com/FCXClarity/package/index.html. 
  3. ↑ "X-TRAIL FCV '03 model". http://www.nissan-global.com/EN/TECHNOLOGY/INTRODUCTION/DETAILS/XTRAIL-FCV/index.html. 
  4. ↑ Savvides, Nick (2017-01-11). "Japan plans to use imported liquefied hydrogen to fuel Tokyo 2020 Olympics". IHS Markit Maritime Portal. https://fairplay.ihs.com/ship-construction/article/4280251/japan-plans-to-use-imported-liquefied-hydrogen-to-fuel-tokyo-2020-olympics. 
  5. ↑ Sadaghiani, Mirhadi S. (2 March 2017). "Introducing and energy analysis of a novel cryogenic hydrogen liquefaction process configuration". International Journal of Hydrogen Energy 42 (9): 6033–6050. doi:10.1016/j.ijhydene.2017.01.136. 
  6. ↑ 6.0 6.1 "Target Explanation Document: Onboard Hydrogen Storage forLight-Duty Fuel Cell Vehicles". US Department of Energy. https://www.energy.gov/sites/default/files/2017/05/f34/fcto_targets_onboard_hydro_storage_explanation.pdf. 
  7. ↑ Sunita, Satyapal (2007). "The U.S. Department of Energy's National Hydrogen Storage Project: Progress towards meeting hydrogen-powered vehicle requirements". Catalysis Today 120 (3–4): 246–256. doi:10.1016/j.cattod.2006.09.022. https://zenodo.org/record/1258818. Retrieved 2019-06-27. 
  8. ↑ Eftekhari, Ali; Baizeng, Fang (2017). "Electrochemical hydrogen storage: Opportunities for fuel storage, batteries, fuel cells, and supercapacitors". International Journal of Hydrogen Energy 42 (40): 25143–25165. doi:10.1016/j.ijhydene.2017.08.103. 
  9. ↑ 9.0 9.1 Niemann, Michael U.; Srinivasan, Sesha S.; Phani, Ayala R.; Kumar, Ashok; Goswami, D. Yogi; Stefanakos, Elias K. (2008). "Nanomaterials for hydrogen storage applications: a review". Journal of Nanomaterials 2008: 1–9. doi:10.1155/2008/950967. 
  10. ↑ EU Hydrogen Storage . (PDF) . Retrieved on 2012-01-08.
  11. ↑ Sunandana, C.S. (2007). "Nanomaterials for hydrogen storage". Resonance 12 (5): 31–36. doi:10.1007/s12045-007-0047-9. 
  12. ↑ WEATHERBEE, G (October 1982). "Hydrogenation of CO2 on group VIII metals II. Kinetics and mechanism of CO2 hydrogenation on nickel". Journal of Catalysis 77 (2): 460–472. doi:10.1016/0021-9517(82)90186-5. ISSN 0021-9517. http://dx.doi.org/10.1016/0021-9517(82)90186-5. Retrieved 2021-11-19. 
  13. ↑ DOE Metal hydrides . eere.energy.gov (2008-12-19). Retrieved on 2012-01-08.
  14. ↑ Christian, Meganne; Aguey-Zinsou, Kondo François (2012). "Core–Shell Strategy Leading to High Reversible Hydrogen Storage Capacity for NaBH4". ACS Nano 6 (9): 7739–7751. doi:10.1021/nn3030018. PMID 22873406. 
  15. ↑ Graetz, J.; Reilly, J.; Sandrock, G.; Johnson, J.; Zhou, W. M.; Wegrzyn, J. (2006). Aluminum Hydride, A1H3, As a Hydrogen Storage Compound. doi:10.2172/899889. https://digital.library.unt.edu/ark:/67531/metadc887034/. Retrieved 2019-06-27. 
  16. ↑ CNRS Institut Neel H2 Storage . Neel.cnrs.fr. Retrieved on 2012-01-08.
  17. ↑ Welch, G. C.; Juan, R. R. S.; Masuda, J. D.; Stephan, D. W. (2006). "Reversible, Metal-Free Hydrogen Activation". Science 314 (5802): 1124–6. doi:10.1126/science.1134230. PMID 17110572. Bibcode: 2006Sci...314.1124W. 
  18. ↑ Elizabeth Wilson H2 Activation, Reversibly Metal-free compound readily breaks and makes hydrogen , Chemical & Engineering News November 20, 2006
  19. ↑ Mes stands for a mesityl substituent and C6F5 for a pentafluorophenyl group, see also tris(pentafluorophenyl)boron
  20. ↑ White Paper: A Novel Method For Grid Energy Storage Using Aluminium Fuel , Alchemy Research, April 2012.
  21. ↑ "New process generates hydrogen from aluminium alloy to run engines, fuel cells". https://phys.org/news/2007-05-hydrogen-aluminium-alloy-fuel-cells.html. 
  22. ↑ Blain, Loz (2022-09-02). "Aluminum-gallium powder bubbles hydrogen out of dirty water" (in en-US). https://newatlas.com/energy/aluminum-gallium-hydrogen-powder/. 
  23. ↑ Trowell, Keena A.; Goroshin, Sam; Frost, David L.; Bergthorson, Jeffrey M. (2020). "The use of supercritical water for the catalyst-free oxidation of coarse aluminum for hydrogen production" (in en). Sustainable Energy & Fuels 4 (11): 5628–5635. doi:10.1039/D0SE00996B. ISSN 2398-4902. http://xlink.rsc.org/?DOI=D0SE00996B. Retrieved 2022-09-06. 
  24. ↑ Zhao, Dong-Liang; Zhang, Yang-Huan (2014-10-01). "Research progress in Mg-based hydrogen storage alloys" (in en). Rare Metals 33 (5): 499–510. doi:10.1007/s12598-014-0398-9. ISSN 1867-7185. https://doi.org/10.1007/s12598-014-0398-9. Retrieved 2021-11-20. 
  25. ↑ Cui, N.; He, P.; Luo, J. L. (1999-10-19). "Magnesium-based hydrogen storage materials modified by mechanical alloying" (in en). Acta Materialia 47 (14): 3737–3743. doi:10.1016/S1359-6454(99)00249-9. ISSN 1359-6454. Bibcode: 1999AcMat..47.3737C. https://www.sciencedirect.com/science/article/pii/S1359645499002499. 
  26. ↑ Bobet, J-L; Akiba, E; Nakamura, Y; Darriet, B (2000-10-01). "Study of Mg-M (M=Co, Ni and Fe) mixture elaborated by reactive mechanical alloying — hydrogen sorption properties" (in en). International Journal of Hydrogen Energy 25 (10): 987–996. doi:10.1016/S0360-3199(00)00002-1. ISSN 0360-3199. https://www.sciencedirect.com/science/article/pii/S0360319900000021. 
  27. ↑ Yamaura, Shin-ichi; Kim, Hyang-Yeon; Kimura, Hisamichi; Inoue, Akihisa; Arata, Yoshiaki (2002-12-16). "Electrode properties of rapidly solidified Mg67Ni23Pd10 amorphous alloy" (in en). Journal of Alloys and Compounds 347 (1): 239–243. doi:10.1016/S0925-8388(02)00759-4. ISSN 0925-8388. https://www.sciencedirect.com/science/article/pii/S0925838802007594. 
  28. ↑ Dehouche, Z; Djaozandry, R; Goyette, J; Bose, T. K (1999-06-29). "Evaluation techniques of cycling effect on thermodynamic and crystal structure properties of Mg2Ni alloy" (in en). Journal of Alloys and Compounds 288 (1): 269–276. doi:10.1016/S0925-8388(99)00085-7. ISSN 0925-8388. https://www.sciencedirect.com/science/article/pii/S0925838899000857. Retrieved 2021-11-20. 
  29. ↑ Li, Weiyang; Li, Chunsheng; Ma, Hua; Chen, Jun (2007-05-01). "Magnesium Nanowires: Enhanced Kinetics for Hydrogen Absorption and Desorption". Journal of the American Chemical Society 129 (21): 6710–6711. doi:10.1021/ja071323z. ISSN 0002-7863. PMID 17488082. https://doi.org/10.1021/ja071323z. 
  30. ↑ Nielsen, Thomas K.; Manickam, Kandavel; Hirscher, Michael; Besenbacher, Flemming; Jensen, Torben R. (2009-11-24). "Confinement of MgH2 Nanoclusters within Nanoporous Aerogel Scaffold Materials". ACS Nano 3 (11): 3521–3528. doi:10.1021/nn901072w. ISSN 1936-0851. PMID 19883120. https://doi.org/10.1021/nn901072w. 
  31. ↑ Zhao-Karger, Zhirong; Hu, Jianjiang; Roth, Arne; Wang, Di; Kübel, Christian; Lohstroh, Wiebke; Fichtner, Maximilian (2010-11-01). "Altered thermodynamic and kinetic properties of MgH2 infiltrated in microporous scaffold" (in en). Chemical Communications 46 (44): 8353–8355. doi:10.1039/C0CC03072D. ISSN 1364-548X. PMID 20890496. https://pubs.rsc.org/en/content/articlelanding/2010/cc/c0cc03072d. Retrieved 2021-11-20. 
  32. ↑ Du, Jiaqi; Lan, Zhiqiang; Zhang, Hao; Lü, Shaoxia; Liu, Haizhen; Guo, Jin (2019-09-25). "Catalytic enhanced hydrogen storage properties of Mg-based alloy by the addition of reduced graphene oxide supported V2O3 nanocomposite" (in en). Journal of Alloys and Compounds 802: 660–667. doi:10.1016/j.jallcom.2019.06.221. ISSN 0925-8388. https://www.sciencedirect.com/science/article/pii/S0925838819323059. 
  33. ↑ Xu, Cheng; Lin, Huai-Jun; Wang, Yunlei; Zhang, Peng; Meng, Yuying; Zhang, Yao; Liu, Yana; Zhang, Jiguang et al. (2019-04-25). "Catalytic effect of in situ formed nano-Mg2Ni and Mg2Cu on the hydrogen storage properties of Mg-Y hydride composites" (in en). Journal of Alloys and Compounds 782: 242–250. doi:10.1016/j.jallcom.2018.12.223. ISSN 0925-8388. https://www.sciencedirect.com/science/article/pii/S0925838818347790. 
  34. ↑ Zhu, M.; Wang, H.; Ouyang, L. Z.; Zeng, M. Q. (2006-02-01). "Composite structure and hydrogen storage properties in Mg-base alloys" (in en). International Journal of Hydrogen Energy. HTM 2004 31 (2): 251–257. doi:10.1016/j.ijhydene.2005.04.030. ISSN 0360-3199. https://www.sciencedirect.com/science/article/pii/S0360319905001357. 
  35. ↑ Lu, Chong; Zou, Jianxin; Zeng, Xiaoqin; Ding, Wenjiang; Shao, Huaiyu (2019-11-25). "Enhanced hydrogen sorption properties of core-shell like structured Mg@NaBH4/MgB2 composite" (in en). Journal of Alloys and Compounds 810: 151763. doi:10.1016/j.jallcom.2019.151763. ISSN 0925-8388. https://www.sciencedirect.com/science/article/pii/S0925838819329962. 
  36. ↑ 36.0 36.1 Ouyang, Liuzhang; Liu, Fen; Wang, Hui; Liu, Jiangwen; Yang, Xu-Sheng; Sun, Lixian; Zhu, Min (August 2020). "Magnesium-based hydrogen storage compounds: A review" (in en). Journal of Alloys and Compounds 832: 154865. doi:10.1016/j.jallcom.2020.154865. https://linkinghub.elsevier.com/retrieve/pii/S0925838820312287. Retrieved 2021-11-20. 
  37. ↑ Yabe, T.; Bagheri, B.; Ohkubo, T.; Uchida, S.; Yoshida, K.; Funatsu, T.; Oishi, T.; Daito, K. et al. (2008-10-15). "100 W-class solar pumped laser for sustainable magnesium-hydrogen energy cycle" (in en). Journal of Applied Physics 104 (8): 083104–083104–8. doi:10.1063/1.2998981. ISSN 0021-8979. Bibcode: 2008JAP...104h3104Y. http://aip.scitation.org/doi/10.1063/1.2998981. Retrieved 2022-09-06. 
  38. ↑ Li, Jun-Jiao; Wang, Chong-Chen; Guo, Jie; Cui, Jing-Rui; Wang, Peng; Zhao, Chen (2018-01-08). "Three coordination compounds based on tris(1-imidazolyl)benzene: Hydrothermal synthesis, crystal structure and adsorption performances toward organic dyes" (in en). Polyhedron 139: 89–97. doi:10.1016/j.poly.2017.10.011. ISSN 0277-5387. https://www.sciencedirect.com/science/article/pii/S0277538717306526. 
  39. ↑ "Scopus preview - Scopus - Welcome to Scopus". https://www.scopus.com/home.uri. 
  40. ↑ Shao, Huaiyu; Xin, Gongbiao; Zheng, Jie; Li, Xingguo; Akiba, Etsuo (2012-07-01). "Nanotechnology in Mg-based materials for hydrogen storage" (in en). Nano Energy 1 (4): 590–601. doi:10.1016/j.nanoen.2012.05.005. ISSN 2211-2855. https://www.sciencedirect.com/science/article/pii/S2211285512001127. Retrieved 2021-11-20. 
  41. ↑ Fichtner, Maximilian; Engel, Jens; Fuhr, Olaf; Glöss, Andreas; Rubner, Oliver; Ahlrichs, Reinhart (2003-10-01). "The Structure of Magnesium Alanate". Inorganic Chemistry 42 (22): 7060–7066. doi:10.1021/ic034160y. ISSN 0020-1669. PMID 14577773. http://dx.doi.org/10.1021/ic034160y. 
  42. ↑ Dilts, J. A.; Ashby, E. C. (June 1972). "Thermal decomposition of complex metal hydrides". Inorganic Chemistry 11 (6): 1230–1236. doi:10.1021/ic50112a015. ISSN 0020-1669. http://dx.doi.org/10.1021/ic50112a015. 
  43. ↑ RESAN, M; HAMPTON, M; LOMNESS, J; SLATTERY, D (October 2005). "Effects of various catalysts on hydrogen release and uptake characteristics of LiAlH". International Journal of Hydrogen Energy 30 (13–14): 1413–1416. doi:10.1016/j.ijhydene.2004.12.009. ISSN 0360-3199. http://dx.doi.org/10.1016/j.ijhydene.2004.12.009. Retrieved 2021-11-20. 
  44. ↑ Ares, J.R.; Aguey-Zinsou, K.-F.; Porcu, M.; Sykes, J.M.; Dornheim, M.; Klassen, T.; Bormann, R. (May 2008). "Thermal and mechanically activated decomposition of LiAlH4". Materials Research Bulletin 43 (5): 1263–1275. doi:10.1016/j.materresbull.2007.05.018. ISSN 0025-5408. http://dx.doi.org/10.1016/j.materresbull.2007.05.018. 
  45. ↑ 45.0 45.1 45.2 Milanese, Chiara; Garroni, Sebastiano; Gennari, Fabiana; Marini, Amedeo; Klassen, Thomas; Dornheim, Martin; Pistidda, Claudio (2018-07-24). "Solid State Hydrogen Storage in Alanates and Alanate-Based Compounds: A Review". Metals 8 (8): 567. doi:10.3390/met8080567. ISSN 2075-4701.  CC-BY icon.svg Text was copied from this source, which is available under a Creative Commons Attribution 4.0 International License .
  46. ↑ Balema, V.P.; Wiench, J.W.; Dennis, K.W.; Pruski, M.; Pecharsky, V.K. (November 2001). "Titanium catalyzed solid-state transformations in LiAlH4 during high-energy ball-milling". Journal of Alloys and Compounds 329 (1–2): 108–114. doi:10.1016/s0925-8388(01)01570-5. ISSN 0925-8388. http://dx.doi.org/10.1016/s0925-8388(01)01570-5. Retrieved 2021-11-20. 
  47. ↑ Ismail, M.; Zhao, Y.; Yu, X.B.; Ranjbar, A.; Dou, S.X. (March 2011). "Improved hydrogen desorption in lithium alanate by addition of SWCNT–metallic catalyst composite". International Journal of Hydrogen Energy 36 (5): 3593–3599. doi:10.1016/j.ijhydene.2010.12.050. ISSN 0360-3199. http://dx.doi.org/10.1016/j.ijhydene.2010.12.050. Retrieved 2021-11-20. 
  48. ↑ Li, Li; Qiu, Fangyuan; Wang, Yijing; Xu, Yanan; An, Cuihua; Liu, Guang; Jiao, Lifang; Yuan, Huatang (March 2013). "Enhanced hydrogen storage properties of TiN–LiAlH4 composite". International Journal of Hydrogen Energy 38 (9): 3695–3701. doi:10.1016/j.ijhydene.2013.01.088. ISSN 0360-3199. http://dx.doi.org/10.1016/j.ijhydene.2013.01.088. Retrieved 2021-11-20. 
  49. ↑ Li, Zhibao; Liu, Shusheng; Si, Xiaoliang; Zhang, Jian; Jiao, Chengli; Wang, Shuang; Liu, Shuang; Zou, Yong-Jin et al. (February 2012). "Significantly improved dehydrogenation of LiAlH4 destabilized by K2TiF6". International Journal of Hydrogen Energy 37 (4): 3261–3267. doi:10.1016/j.ijhydene.2011.10.038. ISSN 0360-3199. http://dx.doi.org/10.1016/j.ijhydene.2011.10.038. Retrieved 2021-11-20. 
  50. ↑ Tan, Chia-Yen; Tsai, Wen-Ta (August 2015). "Catalytic and inhibitive effects of Pd and Pt decorated MWCNTs on the dehydrogenation behavior of LiAlH4". International Journal of Hydrogen Energy 40 (32): 10185–10193. doi:10.1016/j.ijhydene.2015.06.106. ISSN 0360-3199. http://dx.doi.org/10.1016/j.ijhydene.2015.06.106. Retrieved 2021-11-20. 
  51. ↑ Ashby, E. C.; Kobetz, P. (September 1966). "The Direct Synthesis of Na3AlH6". Inorganic Chemistry 5 (9): 1615–1617. doi:10.1021/ic50043a034. ISSN 0020-1669. http://dx.doi.org/10.1021/ic50043a034. 
  52. ↑ Morioka, Hiroyuki; Kakizaki, Kenichi; Chung, Sai-Cheong; Yamada, Atsuo (April 2003). "Reversible hydrogen decomposition of KAlH4". Journal of Alloys and Compounds 353 (1–2): 310–314. doi:10.1016/s0925-8388(02)01307-5. ISSN 0925-8388. http://dx.doi.org/10.1016/s0925-8388(02)01307-5. Retrieved 2021-11-20. 
  53. ↑ Ares, Jose R.; Aguey-Zinsou, Kondo-Francois; Leardini, Fabrice; Ferrer, Isabel Jímenez; Fernandez, Jose-Francisco; Guo, Zheng-Xiao; Sánchez, Carlos (2009-03-26). "Hydrogen Absorption/Desorption Mechanism in Potassium Alanate (KAlH4) and Enhancement by TiCl3 Doping". The Journal of Physical Chemistry C 113 (16): 6845–6851. doi:10.1021/jp807184v. ISSN 1932-7447. http://dx.doi.org/10.1021/jp807184v. 
  54. ↑ Müller, Benjamin (2011). "Energiespeicherung mittels Methan und energietragenden Stoffen - ein thermodynamischer Vergleich" (in de). Chemie Ingenieur Technik 83 (11): 2002–2013. doi:10.1002/cite.201100113. 
  55. ↑ 55.0 55.1 55.2 55.3 55.4 He, Teng; Pei, Qijun; Chen, Ping (2015-09-01). "Liquid organic hydrogen carriers". Journal of Energy Chemistry 24 (5): 587–594. doi:10.1016/j.jechem.2015.08.007. https://zenodo.org/record/895538. Retrieved 2019-11-29. 
  56. ↑ Teichmann, Daniel; Arlt, Wolfgang; Wasserscheid, Peter; Freymann, Raymond (2011). "A future energy supply based on Liquid Organic Hydrogen Carriers (LOHC)". Energy & Environmental Science 4 (8): 2767–2773. doi:10.1039/C1EE01454D. 
  57. ↑ "Hydrogen storage by reversible hydrogenation of pi-conjugated substrates" US patent 7351395
  58. ↑ Brückner, Nicole (2013). "Evaluation of Industrially Applied Heat-Transfer Fluids as Liquid Organic Hydrogen Carrier Systems". ChemSusChem 7 (1): 229–235. doi:10.1002/cssc.201300426. PMID 23956191. 
  59. ↑ Grasemann, Martin; Laurenczy, Gábor (2012-07-18). "Formic acid as a hydrogen source – recent developments and future trends". Energy & Environmental Science 5 (8): 8171–8181. doi:10.1039/C2EE21928J. 
  60. ↑ Wang, Bo; Goodman, D. Wayne; Froment, Gilbert F. (2008-01-25). "Kinetic modeling of pure hydrogen production from decalin". Journal of Catalysis 253 (2): 229–238. doi:10.1016/j.jcat.2007.11.012. 
  61. ↑ Kariya, Nobuko; Fukuoka, Atsushi; Ichikawa, Masaru (2002-07-10). "Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under "wet–dry multiphase conditions"". Applied Catalysis A: General 233 (1–2): 91–102. doi:10.1016/S0926-860X(02)00139-4. 
  62. ↑ Yolcular, Sevim; Olgun, Özden (2008-11-01). "Ni/Al2O3 catalysts and their activity in dehydrogenation of methylcyclohexane for hydrogen production". Catalysis Today. Selected papers from the EUROPACAT VIII Hydrogen Society Session, Turku, Finland, 26–31 August 2007 138 (3–4): 198–202. doi:10.1016/j.cattod.2008.07.020. 
  63. ↑ Clot, Eric; Eisenstein, Odile; Crabtree, Robert H. (2007-05-30). "Computational structure–activity relationships in H2 storage: how placement of N atoms affects release temperatures in organic liquid storage materials". Chemical Communications (22): 2231–2233. doi:10.1039/B705037B. PMID 17534500. 
  64. ↑ Eblagon, Katarzyna Morawa; Tam, Kin; Tsang, Shik Chi Edman (2012). "Comparison of catalytic performance of supported ruthenium and rhodium for hydrogenation of 9-ethylcarbazole for hydrogen storage applications". Energy & Environmental Science 5 (9): 8621. doi:10.1039/C2EE22066K. 
  65. ↑ Stracke, Marcelo P.; Ebeling, Günter; Cataluña, Renato; Dupont, Jairton (2007). "Hydrogen-Storage Materials Based on Imidazolium Ionic Liquids". Energy & Fuels 21 (3): 1695–1698. doi:10.1021/ef060481t. 
  66. ↑ Fellay, C; Dyson, PJ; Laurenczy, G (2008). "A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst". Angewandte Chemie International Edition in English 47 (21): 3966–8. doi:10.1002/anie.200800320. PMID 18393267. 
  67. ↑ F. Joó (2008). "Breakthroughs in Hydrogen Storage – Formic Acid as a Sustainable Storage Material for Hydrogen". ChemSusChem 1 (10): 805–8. doi:10.1002/cssc.200800133. PMID 18781551. Bibcode: 2008ChSCh...1..805J. 
  68. ↑ P. G. Jessop, in Handbook of Homogeneous Hydrogenation (Eds.: J. G. de Vries, C. J. Elsevier), Wiley-VCH, Weinheim, Germany, 2007, pp. 489–511.
  69. ↑ P. G. Jessop; F. Joó; C.-C. Tai (2004). "Recent advances in the homogeneous hydrogenation of carbon dioxide". Coordination Chemistry Reviews 248 (21–24): 2425. doi:10.1016/j.ccr.2004.05.019. 
  70. ↑ AVERY, W (1988). "A role for ammonia in the hydrogen economy". International Journal of Hydrogen Energy 13 (12): 761–773. doi:10.1016/0360-3199(88)90037-7. ISSN 0360-3199. 
  71. ↑ The ammonia economy . Memagazine.org (2003-07-10). Retrieved on 2012-01-08.
  72. ↑ Lamb, Krystina E.; Dolan, Michael D.; Kennedy, Danielle F. (2019-02-05). "Ammonia for hydrogen storage; A review of catalytic ammonia decomposition and hydrogen separation and purification" (in en). International Journal of Hydrogen Energy 44 (7): 3580–3593. doi:10.1016/j.ijhydene.2018.12.024. ISSN 0360-3199. http://www.sciencedirect.com/science/article/pii/S0360319918339272. 
  73. ↑ Bligaard, T.; Nørskov, J. K.; Dahl, S.; Matthiesen, J.; Christensen, C. H.; Sehested, J. (2004-05-15). "The Brønsted–Evans–Polanyi relation and the volcano curve in heterogeneous catalysis" (in en). Journal of Catalysis 224 (1): 206–217. doi:10.1016/j.jcat.2004.02.034. ISSN 0021-9517. http://www.sciencedirect.com/science/article/pii/S0021951704001010. Retrieved 2020-11-18. 
  74. ↑ Dolan, Michael D.; Viano, David M.; Langley, Matthew J.; Lamb, Krystina E. (2018-03-01). "Tubular vanadium membranes for hydrogen purification" (in en). Journal of Membrane Science 549: 306–311. doi:10.1016/j.memsci.2017.12.031. ISSN 0376-7388. http://www.sciencedirect.com/science/article/pii/S037673881733185X. 
  75. ↑ Park, Soo-Jin; Kim, Byung-Joo (2005-11-15). "Ammonia removal of activated carbon fibers produced by oxyfluorination" (in en). Journal of Colloid and Interface Science 291 (2): 597–599. doi:10.1016/j.jcis.2005.05.012. ISSN 0021-9797. PMID 15975585. Bibcode: 2005JCIS..291..597P. http://www.sciencedirect.com/science/article/pii/S0021979705005291. 
  76. ↑ Focus Denmark . Netpublikationer.dk (2006-06-13). Retrieved on 2012-01-08.
  77. ↑ "Liquid asset". The Engineer. 2008-01-15. http://www.theengineer.co.uk/Articles/303939/Liquid+asset.htm. 
  78. ↑ Zong, J., J. T. Mague, and R. A. Pascal, Jr., Exceptional Steric Congestion in an in,in-Bis(hydrosilane), J. Am. Chem. Soc. 2013, 135, 13235-13237.
  79. ↑ Echeverría, Jorge; Aullón, Gabriel; Alvarez, Santiago (2017). "Intermolecular interactions in group 14 hydrides: Beyond C-H··· H-C contacts". International Journal of Quantum Chemistry 117 (21): e25432. doi:10.1002/qua.25432. 
  80. ↑ Compendium of Hydrogen Energy.Volume 2:hydrogen Storage, Transportation and Infrastructure. A volume in Woodhead Publishing Series in Energy 2016, Chapter 8 – Other methods for the physical storage of hydrogen doi:10.1016/B978-1-78242-362-1.00008-0
  81. ↑ Bjørnæs, Christian. "Global warming potential of hydrogen estimated", Centre for International Climate and Environmental Research, June 7, 2023. Retrieved June 15, 2023
  82. ↑ 82.0 82.1 Dong, Jinxiang; Wang, Xiaoyan; Xu, Hong; Zhao, Qiang; Li, Jinping (2007-12-01). "Hydrogen storage in several microporous zeolites" (in en). International Journal of Hydrogen Energy 32 (18): 4998–5004. doi:10.1016/j.ijhydene.2007.08.009. ISSN 0360-3199. https://www.sciencedirect.com/science/article/pii/S0360319907004843. 
  83. ↑ Ren, Jianwei; Musyoka, Nicholas M.; Langmi, Henrietta W.; Mathe, Mkhulu; Liao, Shijun (2017-01-05). "Current research trends and perspectives on materials-based hydrogen storage solutions: A critical review" (in en). International Journal of Hydrogen Energy 42 (1): 289–311. doi:10.1016/j.ijhydene.2016.11.195. ISSN 0360-3199. https://www.sciencedirect.com/science/article/pii/S0360319916335285. 
  84. ↑ Li, Yingwei; Yang, Ralph T. (2006-08-01). "Hydrogen Storage in Low Silica Type X Zeolites" (in en). The Journal of Physical Chemistry B 110 (34): 17175–17181. doi:10.1021/jp0634508. ISSN 1520-6106. PMID 16928014. https://pubs.acs.org/doi/10.1021/jp0634508. 
  85. ↑ Sevilla, Marta; Mokaya, Robert (2014-03-21). "Energy storage applications of activated carbons: supercapacitors and hydrogen storage" (in en). Energy Environ. Sci. 7 (4): 1250–1280. doi:10.1039/c3ee43525c. ISSN 1754-5706. 
  86. ↑ Blankenship II, Troy Scott; Balahmar, Norah; Mokaya, Robert (2017-11-16). "Oxygen-rich microporous carbons with exceptional hydrogen storage capacity" (in En). Nature Communications 8 (1): 1545. doi:10.1038/s41467-017-01633-x. ISSN 2041-1723. PMID 29146978. Bibcode: 2017NatCo...8.1545B. 
  87. ↑ Blankenship, Troy Scott; Mokaya, Robert (2017-12-06). "Cigarette butt-derived carbons have ultra-high surface area and unprecedented hydrogen storage capacity" (in en). Energy & Environmental Science 10 (12): 2552–2562. doi:10.1039/c7ee02616a. ISSN 1754-5706. http://eprints.nottingham.ac.uk/47622/1/RMokaya%20Cigarette%20butt-derived%20carbons.pdf. Retrieved 2019-06-27. 
  88. ↑ Graphene as suitable hydrogen storage substance . Physicsworld.com. Retrieved on 2012-01-08.
  89. ↑ Graphene to graphane . Rsc.org. January 2009. Retrieved on 2012-01-08.
  90. ↑ 90.0 90.1 90.2 Shet, Sachin P.; Shanmuga Priya, S.; Sudhakar, K.; Tahir, Muhammad (March 2021). "A review on current trends in potential use of metal-organic framework for hydrogen storage". International Journal of Hydrogen Energy 46 (21): 11782–11803. doi:10.1016/j.ijhydene.2021.01.020. ISSN 0360-3199. http://dx.doi.org/10.1016/j.ijhydene.2021.01.020. Retrieved 2021-11-21. 
  91. ↑ Xia, Liangzhi; Liu, Qing (January 2017). "Adsorption of H2 on aluminum-based metal-organic frameworks: A computational study". Computational Materials Science 126: 176–181. doi:10.1016/j.commatsci.2016.09.039. ISSN 0927-0256. http://dx.doi.org/10.1016/j.commatsci.2016.09.039. Retrieved 2021-11-21. 
  92. ↑ Ahmed, Alauddin; Seth, Saona; Purewal, Justin; Wong-Foy, Antek G.; Veenstra, Mike; Matzger, Adam J.; Siegel, Donald J. (2019-04-05). "Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks". Nature Communications 10 (1): 1568. doi:10.1038/s41467-019-09365-w. ISSN 2041-1723. PMID 30952862. PMC 6450936. Bibcode: 2019NatCo..10.1568A. http://dx.doi.org/10.1038/s41467-019-09365-w. Retrieved 2021-11-21. 
  93. ↑ Liu, Jia; Zou, Ruqiang; Zhao, Yanli (November 2016). "Recent developments in porous materials for H2 and CH4 storage". Tetrahedron Letters 57 (44): 4873–4881. doi:10.1016/j.tetlet.2016.09.085. ISSN 0040-4039. http://dx.doi.org/10.1016/j.tetlet.2016.09.085. Retrieved 2021-11-21. 
  94. ↑ Rochat, Sébastien; Polak-Kraśna, Katarzyna; Tian, Mi; Holyfield, Leighton T.; Mays, Timothy J.; Bowen, Christopher R.; Burrows, Andrew D. (2017). "Hydrogen storage in polymer-based processable microporous composites". Journal of Materials Chemistry A 5 (35): 18752–18761. doi:10.1039/c7ta05232d. ISSN 2050-7488. 
  95. ↑ MOF-74 – A Potential Hydrogen-Storage Compound . Nist.gov. Retrieved on 2012-01-08.
  96. ↑ Researchers Demonstrate 7.5 wt% Hydrogen Storage in MOFs . Green Car Congress (2006-03-06). Retrieved on 2012-01-08.
  97. ↑ New MOF Material With hydrogen Uptake Of Up To 10 wt% . 22 February 2009
  98. ↑ "Climate change: 'Bath sponge' breakthrough could boost cleaner cars". 18 April 2020. https://www.bbc.co.uk/news/science-environment-52328786. 
  99. ↑ Zhijie Chen (2020). "Balancing volumetric and gravimetric uptake in highly porous materials for clean energy". Science 368 (6488): 297–303. doi:10.1126/science.aaz8881. PMID 32299950. Bibcode: 2020Sci...368..297C. https://www.science.org/doi/10.1126/science.aaz8881. Retrieved 19 April 2020. 
  100. ↑ 100.0 100.1 R. K. Ahluwalia, T. Q. Hua, J. K. Peng and R. Kumar System Level Analysis of Hydrogen Storage Options . 2010 DOE Hydrogen Program Review, Washington, DC, June 8–11, 2010
  101. ↑ Stephen Lasher Analyses of Hydrogen Storage Materials and On-Board Systems . DOE Annual Merit Review June 7–11, 2010
  102. ↑ S&TR | Setting a World Driving Record with Hydrogen . Llnl.gov (2007-06-12). Retrieved on 2012-01-08.
  103. ↑ Compact (L)H2 Storage with Extended Dormancy in Cryogenic Pressure Vessels . Lawrence Livermore National Laboratory June 8, 2010
  104. ↑ Technical Sessions . FISITA 2010. Retrieved on 2012-01-08.
  105. ↑ Hassanpouryouzband, Aliakbar; Joonaki, Edris; Vasheghani Farahani, Mehrdad; Takeya, Satoshi; Ruppel, Carolyn; Yang, Jinhai; J. English, Niall; M. Schicks, Judith et al. (2020). "Gas hydrates in sustainable chemistry". Chemical Society Reviews 49 (15): 5225–5309. doi:10.1039/C8CS00989A. PMID 32567615. 
  106. ↑ Florusse, L. J.; Peters, CJ; Schoonman, J; Hester, KC; Koh, CA; Dec, SF; Marsh, KN; Sloan, ED (2004). "Stable Low-Pressure Hydrogen Clusters Stored in a Binary Clathrate Hydrate". Science 306 (5695): 469–71. doi:10.1126/science.1102076. PMID 15486295. Bibcode: 2004Sci...306..469F. 
  107. ↑ Zhevago, N.K.; Glebov, V.I. (2007). "Hydrogen storage in capillary arrays". Energy Conversion and Management 48 (5): 1554–1559. doi:10.1016/j.enconman.2006.11.017. 
  108. ↑ Zhevago, N.K.; Denisov, E.I.; Glebov, V.I. (2010). "Experimental investigation of hydrogen storage in capillary arrays". International Journal of Hydrogen Energy 35: 169–175. doi:10.1016/j.ijhydene.2009.10.011. 
  109. ↑ Dan Eliezer et al. A New Technology for Hydrogen Storage in Capillary Arrays. C.En & BAM
  110. ↑ Zhevago, N. K.; Chabak, A. F.; Denisov, E. I.; Glebov, V. I.; Korobtsev, S. V. (2013). "Storage of cryo-compressed hydrogen in flexible glass capillaries". International Journal of Hydrogen Energy 38 (16): 6694–6703. doi:10.1016/j.ijhydene.2013.03.107. 
  111. ↑ 111.0 111.1 Dalai, Sridhar; Savithri, Vijayalakshmi (26 October 2017). "Investigating the effect of cobalt loading on thermal conductivity and hydrogen storage capacity of hollow glass microspheres (HGMs)". MaterialsToday: Proceedings 4 (11): 11608–11616. doi:10.1016/j.matpr.2017.09.072. https://www.sciencedirect.com/science/article/pii/S2214785317318059. Retrieved 16 November 2020. 
  112. ↑ Qi, Xiaobo; Gao, Cong; Zhang, Zhanwen; Chen, Sufen; Li, Bo; Wei, Sheng (January 2012). "Production and characterization of hollow glass microspheres with high diffusivity for hydrogen storage". International Journal of Hydrogen Energy 37 (2): 1518–1530. doi:10.1016/j.ijhydene.2011.10.034. https://www.sciencedirect.com/science/article/pii/S0360319911023937. Retrieved 16 November 2020. 
  113. ↑ Rapp, Douglas; Shelby, James (1 December 2004). "Photo-induced hydrogen outgassing of glass". Journal of Non-Crystalline Solids 349: 254–259. doi:10.1016/j.jnoncrysol.2004.08.151. Bibcode: 2004JNCS..349..254R. https://www.sciencedirect.com/science/article/pii/S0022309304007549. Retrieved 16 November 2020. 
  114. ↑ Zarezadeh Mehrizi, Majid; Abdi, Jafar; Rezakazemi, Mashallah; Salehi, Ehsan (10 July 2020). "A review on recent advances in hollow spheres for hydrogen storage". International Journal of Hydrogen Energy 45 (35): 17583–17604. doi:10.1016/j.ijhydene.2020.04.201. https://www.sciencedirect.com/science/article/pii/S0360319920316104. Retrieved 16 November 2020. 
  115. ↑ "R&D of large stationary hydrogen/CNG/HCNG storage vessels". http://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/ihfpv_zheng2.pdf. 
  116. ↑ 116.0 116.1 "COMMISSION STAFF WORKING DOCUMENT: Energy storage – the role of electricity". European Commission. 1 Feb 2017. https://ec.europa.eu/energy/sites/ener/files/documents/swd2017_61_document_travail_service_part1_v6.pdf. 
  117. ↑ Hassanpouryouzband, Aliakbar; Joonaki, Edris; Edlmann, Katriona; Haszeldine, R. Stuart (2021). "Offshore Geological Storage of Hydrogen: Is This Our Best Option to Achieve Net-Zero?". ACS Energy Lett. 6 (6): 2181–2186. doi:10.1021/acsenergylett.1c00845. https://www.research.ed.ac.uk/en/publications/4de280c0-20f2-40be-bdeb-31ef68929826. Retrieved 2022-06-27. 
  118. ↑ 1994 – ECN abstract . Hyweb.de. Retrieved on 2012-01-08.
  119. ↑ "European Renewable Energy Network Study". Brussels: European Union. January 2012. pp. 86, 188. http://www.europarl.europa.eu/document/activities/cont/201202/20120208ATT37544/20120208ATT37544EN.pdf. 
  120. ↑ "Why storing large scale intermittent renewable energies with hydrogen?". http://www.hyunder.eu/. 
  121. ↑ "Storing renewable energy: Is hydrogen a viable solution?". http://www.hyunder.eu/images/Presentations%20EUSEW/2%20HyUnder%20EUSEW%20workshop%20Luis%20Correas.pdf. [yes|permanent dead link|dead link}}]
  122. ↑ "Bringing North Sea Energy Ashore Efficiently". World Energy Council Netherlands. https://www.worldenergy.org/wp-content/uploads/2018/01/WEC-brochure_Online-offshore.pdf. 
  123. ↑ Gerdes, Justin (2018-04-10). "Enlisting Abandoned Oil and Gas Wells as 'Electron Reserves'". https://www.greentechmedia.com/articles/read/enlisting-abandoned-oil-and-gas-wells-as-electron-reserves#gs.ByNEEjY. 
  124. ↑ Rathi, Akshat (11 December 2017). "Batteries can't solve the world's biggest energy-storage problem. One startup has a solution.". Quartz. https://qz.com/1133123/batteries-cant-solve-the-worlds-biggest-energy-storage-problem-one-startup-has-a-solution/. 
  125. ↑ "Munich-based clean-tech startup Electrochaea and Hungarian utility MVM establish power-to-gas joint venture". MVM Group. 24 October 2016. http://mvm.hu/uncategorized/munich-based-clean-tech-startup-electrochaea-hungarian-utility-mvm-establish-power-gas-joint-venture/?lang=en. 
  126. ↑ "SoCalGas and Opus 12 Successfully Demonstrate Technology That Simplifies Conversion of Carbon Dioxide into Storable Renewable Energy". prnewswire. https://www.prnewswire.com/news-releases/socalgas-and-opus-12-successfully-demonstrate-technology-that-simplifies-conversion-of-carbon-dioxide-into-storable-renewable-energy-300633313.html. 
  127. ↑ Ambrose, Jillian (2018-01-06). "Energy networks prepare to blend hydrogen into the gas grid for the first time". The Telegraph. https://www.telegraph.co.uk/business/2018/01/06/hydrogen/. 
  128. ↑ Anscombe, Nadya (4 June 2012). "Energy storage: Could hydrogen be the answer?". Solar Novus Today. http://www.solarnovus.com/energy-storage-could-hydrogen-be-the-answer_N5028.html. 
  129. ↑ "naturalhy.net". Archived from the original on January 18, 2012. https://web.archive.org/web/20120118102741/http://www.naturalhy.net/docs/Naturalhy_Brochure.pdf. 
  130. ↑ Mike Millikin (2014-11-18). "Toyota FCV Mirai launches in LA; initial TFCS specs; $57,500 or $499 lease; leaning on Prius analogy". Green Car Congress. http://www.greencarcongress.com/2014/11/20141118-mirai.html. 
  131. ↑ "DOE Technical Targets for Onboard Hydrogen Storage for Light-Duty Vehicles". https://www.energy.gov/eere/fuelcells/doe-technical-targets-onboard-hydrogen-storage-light-duty-vehicles. 
  132. ↑ Hydrogen Storage Technologies Roadmap . uscar.org. November 2005
  133. ↑ Yang, Jun; Sudik, A; Wolverton, C; Siegel, DJ (2010). "High capacity hydrogen storage materials: attributes for automotive applications and techniques for materials discovery". Chemical Society Reviews 39 (2): 656–675. doi:10.1039/b802882f. PMID 20111786. 
  134. ↑ FCT Hydrogen Storage: Current Technology. Office of Energy Efficiency & Renewable Energy|access
  135. ↑ "DOE National Center for Carbon-Based Hydrogen Storage". National Renewable Energy Laboratory (NREL). https://www.nrel.gov/basic_sciences/carbon_based_hydrogen_center.cfm. . See also "Targets for On-Board Hydrogen Storage Systems". Office of Energy Efficiency & Renewable Energy. http://www1.eere.energy.gov/hydrogenandfuelcells/storage/pdfs/targets_onboard_hydro_storage.pdf. 
  136. ↑ "Hydrogen Storage". https://www.energy.gov/eere/fuelcells/hydrogen-storage. 
  137. ↑ 137.0 137.1 Hussein, A.K. (2015). "Applications of nanotechnology in renewable energies—A comprehensive overview and understanding". Renewable and Sustainable Energy Reviews 42: 460–476. doi:10.1016/j.rser.2014.10.027. 
  138. ↑ Evans, Scarlett (August 20, 2018). "Researchers to create hydrogen energy source using nanotechnology". United Kingdom. https://www.power-technology.com/news/researchers-create-hydrogen-energy-source-using-nanotechnology/. 
  139. ↑ Chanchetti, Lucas Faccioni (2014-09-18). Cientometria aplicada a materiais para armazenamento de hidrogênio. https://repositorio.ufscar.br/handle/ufscar/935. Retrieved 2021-11-19. 
  140. ↑ 140.0 140.1 Chanchetti, Lucas Faccioni; Leiva, Daniel Rodrigo; Lopes de Faria, Leandro Innocentini; Ishikawa, Tomaz Toshimi (2020-02-14). "A scientometric review of research in hydrogen storage materials" (in en). International Journal of Hydrogen Energy. 22nd World Hydrogen Energy Conference 45 (8): 5356–5366. doi:10.1016/j.ijhydene.2019.06.093. ISSN 0360-3199. https://www.sciencedirect.com/science/article/pii/S0360319919323432. 
  141. ↑ Jain, Ankur; Ichikawa, Takayuki; Ichikawa, Takayuki; Agarwal, Shivani (2018-08-06), "Nitrogen-Based Hydrogen Storage Systems: A Detailed Overview", Hydrogen Storage Technologies (Hoboken, NJ, USA: John Wiley & Sons, Inc.): pp. 39–88, doi:10.1002/9781119460572.ch2, ISBN 9781119460572, http://dx.doi.org/10.1002/9781119460572.ch2, retrieved 2021-11-19 
  142. ↑ Teichmann, Daniel; Arlt, Wolfgang; Wasserscheid, Peter; Freymann, Raymond (2011). "A future energy supply based on Liquid Organic Hydrogen Carriers (LOHC)". Energy & Environmental Science 4 (8): 2767. doi:10.1039/c1ee01454d. ISSN 1754-5692. http://dx.doi.org/10.1039/c1ee01454d. Retrieved 2021-11-19. 

External links



Retrieved from "https://handwiki.org/wiki/index.php?title=Physics:Hydrogen_storage&oldid=3417685"