A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
The first fuel cells were invented by Sir William Grove in 1838. The first commercial use of fuel cells came more than a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932. The alkaline fuel cell, also known as the Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for satellites and space capsules. Since then, fuel cells have been used in many other applications. Fuel cells are used for primary and backup power for commercial, industrial and residential buildings and in remote or inaccessible areas. They are also used to power fuel cell vehicles, including forklifts, automobiles, buses, trains, boats, motorcycles and submarines.
There are many types of fuel cells, but they all consist of an anode, a cathode, and an electrolyte that allows ions, often positively charged hydrogen ions (protons), to move between the two sides of the fuel cell. At the anode a catalyst causes the fuel to undergo oxidation reactions that generate ions (often positively charged hydrogen ions) and electrons. The ions move from the anode to the cathode through the electrolyte. At the same time, electrons flow from the anode to the cathode through an external circuit, producing direct current electricity. At the cathode, another catalyst causes ions, electrons, and oxygen to react, forming water and possibly other products. Fuel cells are classified by the type of electrolyte they use and by the difference in startup time ranging from 1 second for proton-exchange membrane fuel cells (PEM fuel cells, or PEMFC) to 10 minutes for solid oxide fuel cells (SOFC). A related technology is flow batteries, in which the fuel can be regenerated by recharging. Individual fuel cells produce relatively small electrical potentials, about 0.7 volts, so cells are "stacked", or placed in series, to create sufficient voltage to meet an application's requirements. In addition to electricity, fuel cells produce water, heat and, depending on the fuel source, very small amounts of nitrogen dioxide and other emissions. The energy efficiency of a fuel cell is generally between 40 and 60%; however, if waste heat is captured in a cogeneration scheme, efficiencies of up to 85% can be obtained.
The first references to hydrogen fuel cells appeared in 1838. In a letter dated October 1838 but published in the December 1838 edition of The London and Edinburgh Philosophical Magazine and Journal of Science, Welsh physicist and barrister Sir William Grove wrote about the development of his first crude fuel cells. He used a combination of sheet iron, copper and porcelain plates, and a solution of sulphate of copper and dilute acid. In a letter to the same publication written in December 1838 but published in June 1839, German physicist Christian Friedrich Schönbein discussed the first crude fuel cell that he had invented. His letter discussed current generated from hydrogen and oxygen dissolved in water. Grove later sketched his design, in 1842, in the same journal. The fuel cell he made used similar materials to today's phosphoric acid fuel cell.
In 1932, English engineer Francis Thomas Bacon successfully developed a 5 kW stationary fuel cell. The alkaline fuel cell (AFC), also known as the Bacon fuel cell after its inventor, is one of the most developed fuel cell technologies, which NASA has used since the mid-1960s.
In 1955, W. Thomas Grubb, a chemist working for the General Electric Company (GE), further modified the original fuel cell design by using a sulphonated polystyrene ion-exchange membrane as the electrolyte. Three years later another GE chemist, Leonard Niedrach, devised a way of depositing platinum onto the membrane, which served as catalyst for the necessary hydrogen oxidation and oxygen reduction reactions. This became known as the "Grubb-Niedrach fuel cell". GE went on to develop this technology with NASA and McDonnell Aircraft, leading to its use during Project Gemini. This was the first commercial use of a fuel cell. In 1959, a team led by Harry Ihrig built a 15 kW fuel cell tractor for Allis-Chalmers, which was demonstrated across the U.S. at state fairs. This system used potassium hydroxide as the electrolyte and compressed hydrogen and oxygen as the reactants. Later in 1959, Bacon and his colleagues demonstrated a practical five-kilowatt unit capable of powering a welding machine. In the 1960s, Pratt & Whitney licensed Bacon's U.S. patents for use in the U.S. space program to supply electricity and drinking water (hydrogen and oxygen being readily available from the spacecraft tanks). In 1991, the first hydrogen fuel cell automobile was developed by Roger E. Billings.
In recognition of the fuel cell industry and America's role in fuel cell development, the United States Senate recognized 8 October 2015 as National Hydrogen and Fuel Cell Day, passing S. RES 217. The date was chosen in recognition of the atomic weight of hydrogen (1.008).
Types of fuel cells; design
Fuel cells come in many varieties; however, they all work in the same general manner. They are made up of three adjacent segments: the anode, the electrolyte, and the cathode. Two chemical reactions occur at the interfaces of the three different segments. The net result of the two reactions is that fuel is consumed, water or carbon dioxide is created, and an electric current is created, which can be used to power electrical devices, normally referred to as the load.
At the anode a catalyst oxidizes the fuel, usually hydrogen, turning the fuel into a positively charged ion and a negatively charged electron. The electrolyte is a substance specifically designed so ions can pass through it, but the electrons cannot. The freed electrons travel through a wire creating the electric current. The ions travel through the electrolyte to the cathode. Once reaching the cathode, the ions are reunited with the electrons and the two react with a third chemical, usually oxygen, to create water or carbon dioxide.
Design features in a fuel cell include:
- The electrolyte substance, which usually defines the type of fuel cell, and can be made from a number of substances like potassium hydroxide, salt carbonates, and phosphoric acid.
- The fuel that is used. The most common fuel is hydrogen.
- The anode catalyst, usually fine platinum powder, breaks down the fuel into electrons and ions.
- The cathode catalyst, often nickel, converts ions into waste chemicals, with water being the most common type of waste.
- Gas diffusion layers that are designed to resist oxidization.
A typical fuel cell produces a voltage from 0.6 to 0.7 V at full rated load. Voltage decreases as current increases, due to several factors:
- Activation loss
- Ohmic loss (voltage drop due to resistance of the cell components and interconnections)
- Mass transport loss (depletion of reactants at catalyst sites under high loads, causing rapid loss of voltage).
To deliver the desired amount of energy, the fuel cells can be combined in series to yield higher voltage, and in parallel to allow a higher current to be supplied. Such a design is called a fuel cell stack. The cell surface area can also be increased, to allow higher current from each cell.
Proton-exchange membrane fuel cells
In the archetypical hydrogen–oxide proton-exchange membrane fuel cell (PEMFC) design, a proton-conducting polymer membrane (typically nafion) contains the electrolyte solution that separates the anode and cathode sides. This was called a solid polymer electrolyte fuel cell (SPEFC) in the early 1970s, before the proton-exchange mechanism was well understood. (Notice that the synonyms polymer electrolyte membrane and proton-exchange mechanism result in the same acronym.)
On the anode side, hydrogen diffuses to the anode catalyst where it later dissociates into protons and electrons. These protons often react with oxidants causing them to become what are commonly referred to as multi-facilitated proton membranes. The protons are conducted through the membrane to the cathode, but the electrons are forced to travel in an external circuit (supplying power) because the membrane is electrically insulating. On the cathode catalyst, oxygen molecules react with the electrons (which have traveled through the external circuit) and protons to form water.
In addition to this pure hydrogen type, there are hydrocarbon fuels for fuel cells, including diesel, methanol (see: direct-methanol fuel cells and indirect methanol fuel cells) and chemical hydrides. The waste products with these types of fuel are carbon dioxide and water. When hydrogen is used, the CO2 is released when methane from natural gas is combined with steam, in a process called steam methane reforming, to produce the hydrogen. This can take place in a different location to the fuel cell, potentially allowing the hydrogen fuel cell to be used indoors—for example, in fork lifts.
The different components of a PEMFC are
- bipolar plates,
- membrane, and
- the necessary hardware such as current collectors and gaskets.
The materials used for different parts of the fuel cells differ by type. The bipolar plates may be made of different types of materials, such as, metal, coated metal, graphite, flexible graphite, C–C composite, carbon–polymer composites etc. The membrane electrode assembly (MEA) is referred to as the heart of the PEMFC and is usually made of a proton-exchange membrane sandwiched between two catalyst-coated carbon papers. Platinum and/or similar type of noble metals are usually used as the catalyst for PEMFC, and these can be contaminated by carbon monoxide, necessitating a relatively pure hydrogen fuel. The electrolyte could be a polymer membrane.
Proton-exchange membrane fuel cell design issues
- In 2013, the Department of Energy estimated that 80-kW automotive fuel cell system costs of US$67 per kilowatt could be achieved, assuming volume production of 100,000 automotive units per year and US$55 per kilowatt could be achieved, assuming volume production of 500,000 units per year. Many companies are working on techniques to reduce cost in a variety of ways including reducing the amount of platinum needed in each individual cell. Ballard Power Systems has experimented with a catalyst enhanced with carbon silk, which allows a 30% reduction (1.0–0.7 mg/cm2) in platinum usage without reduction in performance. Monash University, Melbourne uses PEDOT as a cathode. A 2011-published study documented the first metal-free electrocatalyst using relatively inexpensive doped carbon nanotubes, which are less than 1% the cost of platinum and are of equal or superior performance. A recently published article demonstrated how the environmental burdens change when using carbon nanotubes as carbon substrate for platinum.
- Water and air management (in PEMFCs)
- In this type of fuel cell, the membrane must be hydrated, requiring water to be evaporated at precisely the same rate that it is produced. If water is evaporated too quickly, the membrane dries, resistance across it increases, and eventually it will crack, creating a gas "short circuit" where hydrogen and oxygen combine directly, generating heat that will damage the fuel cell. If the water is evaporated too slowly, the electrodes will flood, preventing the reactants from reaching the catalyst and stopping the reaction. Methods to manage water in cells are being developed like electroosmotic pumps focusing on flow control. Just as in a combustion engine, a steady ratio between the reactant and oxygen is necessary to keep the fuel cell operating efficiently.
- Temperature management
- The same temperature must be maintained throughout the cell in order to prevent destruction of the cell through thermal loading. This is particularly challenging as the 2H2 + O2 → 2H2O reaction is highly exothermic, so a large quantity of heat is generated within the fuel cell.
- Durability, service life, and special requirements for some type of cells
- Stationary fuel cell applications typically require more than 40,000 hours of reliable operation at a temperature of −35 °C to 40 °C (−31 °F to 104 °F), while automotive fuel cells require a 5,000-hour lifespan (the equivalent of 240,000 km (150,000 mi)) under extreme temperatures. Current service life is 2,500 hours (about 75,000 miles). Automotive engines must also be able to start reliably at −30 °C (−22 °F) and have a high power-to-volume ratio (typically 2.5 kW/L).
- Limited carbon monoxide tolerance of some (non-PEDOT) cathodes.
Phosphoric acid fuel cell
Phosphoric acid fuel cells (PAFCs) were first designed and introduced in 1961 by G. V. Elmore and H. A. Tanner. In these cells, phosphoric acid is used as a non-conductive electrolyte to pass protons from the anode to the cathode and to force electrons to travel from anode to cathode through an external electrical circuit. These cells commonly work in temperatures of 150 to 200°C. This high temperature will cause heat and energy loss if the heat is not removed and used properly. This heat can be used to produce steam for air conditioning systems or any other thermal energy consuming system. Using this heat in cogeneration can enhance the efficiency of phosphoric acid fuel cells from 40 to 50% to about 80%. Since the proton production rate on the anode is small, platinum is used as catalyst to increase this ionization rate. A key disadvantage of these cells is the use of an acidic electrolyte. This increases the corrosion or oxidation of components exposed to phosphoric acid.
Solid acid fuel cell
Solid acid fuel cells (SAFCs) are characterized by the use of a solid acid material as the electrolyte. At low temperatures, solid acids have an ordered molecular structure like most salts. At warmer temperatures (between 140 and 150 °C for CsHSO4), some solid acids undergo a phase transition to become highly disordered "superprotonic" structures, which increases conductivity by several orders of magnitude. The first proof-of-concept SAFCs were developed in 2000 using cesium hydrogen sulfate (CsHSO4). Current SAFC systems use cesium dihydrogen phosphate (CsH2PO4) and have demonstrated lifetimes in the thousands of hours.
Alkaline fuel cell
The alkaline fuel cell (AFC) or hydrogen-oxygen fuel cell was designed and first demonstrated publicly by Francis Thomas Bacon in 1959. It was used as a primary source of electrical energy in the Apollo space program. The cell consists of two porous carbon electrodes impregnated with a suitable catalyst such as Pt, Ag, CoO, etc. The space between the two electrodes is filled with a concentrated solution of KOH or NaOH which serves as an electrolyte. H2 gas and O2 gas are bubbled into the electrolyte through the porous carbon electrodes. Thus the overall reaction involves the combination of hydrogen gas and oxygen gas to form water. The cell runs continuously until the reactant's supply is exhausted. This type of cell operates efficiently in the temperature range 343–413 K and provides a potential of about 0.9 V. Alkaline anion exchange membrane fuel cell (AAEMFC) is a type of AFC which employs a solid polymer electrolyte instead of aqueous potassium hydroxide (KOH) and it is superior to aqueous AFC.
High-temperature fuel cells
Solid oxide fuel cell
Solid oxide fuel cells (SOFCs) use a solid material, most commonly a ceramic material called yttria-stabilized zirconia (YSZ), as the electrolyte. Because SOFCs are made entirely of solid materials, they are not limited to the flat plane configuration of other types of fuel cells and are often designed as rolled tubes. They require high operating temperatures (800–1000 °C) and can be run on a variety of fuels including natural gas.
SOFCs are unique because negatively charged oxygen ions travel from the cathode (positive side of the fuel cell) to the anode (negative side of the fuel cell) instead of protons travelling vice versa (i.e., from the anode to the cathode), as is the case in all other types of fuel cells. Oxygen gas is fed through the cathode, where it absorbs electrons to create oxygen ions. The oxygen ions then travel through the electrolyte to react with hydrogen gas at the anode. The reaction at the anode produces electricity and water as by-products. Carbon dioxide may also be a by-product depending on the fuel, but the carbon emissions from an SOFC system are less than those from a fossil fuel combustion plant. The chemical reactions for the SOFC system can be expressed as follows:
- Anode reaction: 2H2 + 2O2− → 2H2O + 4e−
- Cathode reaction: O2 + 4e− → 2O2−
- Overall cell reaction: 2H2 + O2 → 2H2O
SOFC systems can run on fuels other than pure hydrogen gas. However, since hydrogen is necessary for the reactions listed above, the fuel selected must contain hydrogen atoms. For the fuel cell to operate, the fuel must be converted into pure hydrogen gas. SOFCs are capable of internally reforming light hydrocarbons such as methane (natural gas), propane and butane. These fuel cells are at an early stage of development.
Challenges exist in SOFC systems due to their high operating temperatures. One such challenge is the potential for carbon dust to build up on the anode, which slows down the internal reforming process. Research to address this "carbon coking" issue at the University of Pennsylvania has shown that the use of copper-based cermet (heat-resistant materials made of ceramic and metal) can reduce coking and the loss of performance. Another disadvantage of SOFC systems is the long start-up, making SOFCs less useful for mobile applications. Despite these disadvantages, a high operating temperature provides an advantage by removing the need for a precious metal catalyst like platinum, thereby reducing cost. Additionally, waste heat from SOFC systems may be captured and reused, increasing the theoretical overall efficiency to as high as 80–85%.
The high operating temperature is largely due to the physical properties of the YSZ electrolyte. As temperature decreases, so does the ionic conductivity of YSZ. Therefore, to obtain optimum performance of the fuel cell, a high operating temperature is required. According to their website, Ceres Power, a UK SOFC fuel cell manufacturer, has developed a method of reducing the operating temperature of their SOFC system to 500–600 degrees Celsius. They replaced the commonly used YSZ electrolyte with a CGO (cerium gadolinium oxide) electrolyte. The lower operating temperature allows them to use stainless steel instead of ceramic as the cell substrate, which reduces cost and start-up time of the system.
Molten-carbonate fuel cell
Molten carbonate fuel cells (MCFCs) require a high operating temperature, 650 °C (1,200 °F), similar to SOFCs. MCFCs use lithium potassium carbonate salt as an electrolyte, and this salt liquefies at high temperatures, allowing for the movement of charge within the cell – in this case, negative carbonate ions.
Like SOFCs, MCFCs are capable of converting fossil fuel to a hydrogen-rich gas in the anode, eliminating the need to produce hydrogen externally. The reforming process creates CO
2 emissions. MCFC-compatible fuels include natural gas, biogas and gas produced from coal. The hydrogen in the gas reacts with carbonate ions from the electrolyte to produce water, carbon dioxide, electrons and small amounts of other chemicals. The electrons travel through an external circuit creating electricity and return to the cathode. There, oxygen from the air and carbon dioxide recycled from the anode react with the electrons to form carbonate ions that replenish the electrolyte, completing the circuit. The chemical reactions for an MCFC system can be expressed as follows:
- Anode reaction: CO32− + H2 → H2O + CO2 + 2e−
- Cathode reaction: CO2 + ½O2 + 2e− → CO32−
- Overall cell reaction: H2 + ½O2 → H2O
As with SOFCs, MCFC disadvantages include slow start-up times because of their high operating temperature. This makes MCFC systems not suitable for mobile applications, and this technology will most likely be used for stationary fuel cell purposes. The main challenge of MCFC technology is the cells' short life span. The high-temperature and carbonate electrolyte lead to corrosion of the anode and cathode. These factors accelerate the degradation of MCFC components, decreasing the durability and cell life. Researchers are addressing this problem by exploring corrosion-resistant materials for components as well as fuel cell designs that may increase cell life without decreasing performance.
MCFCs hold several advantages over other fuel cell technologies, including their resistance to impurities. They are not prone to "carbon coking", which refers to carbon build-up on the anode that results in reduced performance by slowing down the internal fuel reforming process. Therefore, carbon-rich fuels like gases made from coal are compatible with the system. The United States Department of Energy claims that coal, itself, might even be a fuel option in the future, assuming the system can be made resistant to impurities such as sulfur and particulates that result from converting coal into hydrogen. MCFCs also have relatively high efficiencies. They can reach a fuel-to-electricity efficiency of 50%, considerably higher than the 37–42% efficiency of a phosphoric acid fuel cell plant. Efficiencies can be as high as 65% when the fuel cell is paired with a turbine, and 85% if heat is captured and used in a combined heat and power (CHP) system.
FuelCell Energy, a Connecticut-based fuel cell manufacturer, develops and sells MCFC fuel cells. The company says that their MCFC products range from 300 kW to 2.8 MW systems that achieve 47% electrical efficiency and can utilize CHP technology to obtain higher overall efficiencies. One product, the DFC-ERG, is combined with a gas turbine and, according to the company, it achieves an electrical efficiency of 65%.
Electric storage fuel cell
The electric storage fuel cell is a conventional battery chargeable by electric power input, using the conventional electro-chemical effect. However, the battery further includes hydrogen (and oxygen) inputs for alternatively charging the battery chemically.
Comparison of fuel cell types
|Fuel cell name||Electrolyte||Qualified power (W)||Working temperature (°C)||Efficiency||Status||Cost (USD/W)|
|Metal hydride fuel cell||Aqueous alkaline solution||0 > −20
(50% Ppeak @ 0 °C)
|Commercial / Research|
|Electro-galvanic fuel cell||Aqueous alkaline solution||39 < 40
||Commercial / Research|
|Direct formic acid fuel cell (DFAFC)||Polymer membrane (ionomer)||49 < 50 W
||39 < 40
||Commercial / Research|
|Zinc–air battery||Aqueous alkaline solution||39 < 40||Mass production|
|Microbial fuel cell||Polymer membrane or humic acid||39 < 40
|Upflow microbial fuel cell (UMFC)||39 < 40
|Regenerative fuel cell||Polymer membrane (ionomer)||49 < 50
||Commercial / Research|
|Direct borohydride fuel cell||Aqueous alkaline solution||70||Commercial|
|Alkaline fuel cell||Aqueous alkaline solution||10000 10–200 kW
||79 < 80
||65% 60–70%||style="background: #bfd; color: black; vertical-align: middle; text-align: center; " class="yes2 table-yes2"| 62%||Commercial / Research|
|Direct methanol fuel cell||Polymer membrane (ionomer)||0.1 100 mW – 1 kW
||25% 20–30%||style="background:#F99;vertical-align:middle;text-align:center;" class="table-no"|15% 10–25%
||Commercial / Research||125|
|Reformed methanol fuel cell||Polymer membrane (ionomer)||5 5 W – 100 kW
||200 250–300 (reformer)
|55% 50–60%||style="background:#F99;vertical-align:middle;text-align:center;" class="table-no"|33% 25–40%
||Commercial / Research|
|Direct-ethanol fuel cell||Polymer membrane (ionomer)||0 < 140 mW/cm²
||26 > 25
|Proton-exchange membrane fuel cell||Polymer membrane (ionomer)||100 1 W – 500 kW
||125 50–100 (Nafion)
|60% 50–70%||style="background: #FFD; color: black; vertical-align: middle; text-align: center; " class="partial table-partial"| 40% 30–50%
||Commercial / Research||50–100|
|Redox fuel cell (RFC)||Liquid electrolytes with redox shuttle and polymer membrane (ionomer)||1000 1 kW – 10 MW
|Phosphoric acid fuel cell||Molten phosphoric acid (H3PO4)||999999 < 10 MW
|Commercial / Research||4.00–4.50|
|Solid acid fuel cell||H+-conducting oxyanion salt (solid acid)||505 10 W – 1 kW
||Commercial / Research|
|Molten carbonate fuel cell||Molten alkaline carbonate||100000000 100 MW
||55%||45–55%||Commercial / Research|
|Tubular solid oxide fuel cell (TSOFC)||O2−-conducting ceramic oxide||99999999 < 100 MW
||63% 60–65%||style="background: #bfd; color: black; vertical-align: middle; text-align: center; " class="yes2 table-yes2"| 57% 55–60%
||Commercial / Research|
|Protonic ceramic fuel cell||H+-conducting ceramic oxide||700||Research|
|Direct carbon fuel cell||Several different||775 700–850
||80%||70%||Commercial / Research|
|Planar solid oxide fuel cell||O2−-conducting ceramic oxide||99999999 < 100 MW
||63% 60–65%||style="background: #bfd; color: black; vertical-align: middle; text-align: center; " class="yes2 table-yes2"| 57% 55–60%
||Commercial / Research|
|Enzymatic biofuel cells||Any that will not denature the enzyme||39 < 40
|Magnesium-air fuel cell||Salt water||−20 −20 to 55
||90% 90%||Commercial / Research|
Glossary of terms in table:
- The electrode at which oxidation (a loss of electrons) takes place. For fuel cells and other galvanic cells, the anode is the negative terminal; for electrolytic cells (where electrolysis occurs), the anode is the positive terminal.
- Aqueous solution
- Of, relating to, or resembling water
- Made from, with, or by water.
- A chemical substance that increases the rate of a reaction without being consumed; after the reaction, it can potentially be recovered from the reaction mixture and is chemically unchanged. The catalyst lowers the activation energy required, allowing the reaction to proceed more quickly or at a lower temperature. In a fuel cell, the catalyst facilitates the reaction of oxygen and hydrogen. It is usually made of platinum powder very thinly coated onto carbon paper or cloth. The catalyst is rough and porous so the maximum surface area of the platinum can be exposed to the hydrogen or oxygen. The platinum-coated side of the catalyst faces the membrane in the fuel cell.
- The electrode at which reduction (a gain of electrons) occurs. For fuel cells and other galvanic cells, the cathode is the positive terminal; for electrolytic cells (where electrolysis occurs), the cathode is the negative terminal.
- A substance that conducts charged ions from one electrode to the other in a fuel cell, battery, or electrolyzer.
- Fuel cell stack
- Individual fuel cells connected in a series. Fuel cells are stacked to increase voltage.
- something within or from which something else originates, develops, or takes form.
- The separating layer in a fuel cell that acts as electrolyte (an ion-exchanger) as well as a barrier film separating the gases in the anode and cathode compartments of the fuel cell.
- Molten carbonate fuel cell (MCFC)
- A type of fuel cell that contains a molten carbonate electrolyte. Carbonate ions (CO32−) are transported from the cathode to the anode. Operating temperatures are typically near 650 °C.
- Phosphoric acid fuel cell (PAFC)
- A type of fuel cell in which the electrolyte consists of concentrated phosphoric acid (H3PO4). Protons (H+) are transported from the anode to the cathode. The operating temperature range is generally 160–220 °C.
- Proton-exchange membrane fuel cell (PEM)
- A fuel cell incorporating a solid polymer membrane used as its electrolyte. Protons (H+) are transported from the anode to the cathode. The operating temperature range is generally 60–100 °C for Low Temperature Proton-exchange membrane fuel cell (LT-PEMFC). PEM fuel cell with operating temperature of 120-200 °C is called High Temperature Proton-exchange membrane fuel cell (HT-PEMFC).
- Solid oxide fuel cell (SOFC)
- A type of fuel cell in which the electrolyte is a solid, nonporous metal oxide, typically zirconium oxide (ZrO2) treated with Y2O3, and O2− is transported from the cathode to the anode. Any CO in the reformate gas is oxidized to CO2 at the anode. Temperatures of operation are typically 800–1,000 °C.
- An act or the process by which a solid, liquid, or gaseous substance is homogeneously mixed with a liquid or sometimes a gas or solid.
- A homogeneous mixture formed by this process; especially : a single-phase liquid system.
- The condition of being dissolved.
Efficiency of leading fuel cell types
Theoretical maximum efficiency
The energy efficiency of a system or device that converts energy is measured by the ratio of the amount of useful energy put out by the system ("output energy") to the total amount of energy that is put in ("input energy") or by useful output energy as a percentage of the total input energy. In the case of fuel cells, useful output energy is measured in electrical energy produced by the system. Input energy is the energy stored in the fuel. According to the U.S. Department of Energy, fuel cells are generally between 40 and 60% energy efficient. This is higher than some other systems for energy generation. For example, the typical internal combustion engine of a car is about 25% energy efficient. Steam power plants usually achieve efficiencies of 30-40% while combined cycle gas turbine and steam plants can achieve efficiencies as high as 60%. In combined heat and power (CHP) systems, the waste heat produced by the primary power cycle - whether fuel cell, nuclear fission or combustion - is captured and put to use, increasing the efficiency of the system to up to 85–90%.
The theoretical maximum efficiency of any type of power generation system is never reached in practice, and it does not consider other steps in power generation, such as production, transportation and storage of fuel and conversion of the electricity into mechanical power. However, this calculation allows the comparison of different types of power generation. The theoretical maximum efficiency of a fuel cell approaches 100%, while the theoretical maximum efficiency of internal combustion engines is approximately 58%.
In a fuel cell vehicle the tank-to-wheel efficiency is greater than 45% at low loads and shows average values of about 36% when a driving cycle like the NEDC (New European Driving Cycle) is used as test procedure. The comparable NEDC value for a Diesel vehicle is 22%. In 2008 Honda released a demonstration fuel cell electric vehicle (the Honda FCX Clarity) with fuel stack claiming a 60% tank-to-wheel efficiency.
It is also important to take losses due to fuel production, transportation, and storage into account. Fuel cell vehicles running on compressed hydrogen may have a power-plant-to-wheel efficiency of 22% if the hydrogen is stored as high-pressure gas, and 17% if it is stored as liquid hydrogen. Fuel cells cannot store energy like a battery, except as hydrogen, but in some applications, such as stand-alone power plants based on discontinuous sources such as solar or wind power, they are combined with electrolyzers and storage systems to form an energy storage system. As of 2019, 90% of hydrogen was used for oil refining, chemicals and fertilizer production (where hydrogen is required for the Haber-Bosch process), and 98% of hydrogen is produced by steam methane reforming, which emits carbon dioxide. The overall efficiency (electricity to hydrogen and back to electricity) of such plants (known as round-trip efficiency), using pure hydrogen and pure oxygen can be "from 35 up to 50 percent", depending on gas density and other conditions. The electrolyzer/fuel cell system can store indefinite quantities of hydrogen, and is therefore suited for long-term storage.
Solid-oxide fuel cells produce heat from the recombination of the oxygen and hydrogen. The ceramic can run as hot as 800 degrees Celsius. This heat can be captured and used to heat water in a micro combined heat and power (m-CHP) application. When the heat is captured, total efficiency can reach 80–90% at the unit, but does not consider production and distribution losses. CHP units are being developed today for the European home market.
Professor Jeremy P. Meyers, in the Electrochemical Society journal Interface in 2008, wrote, "While fuel cells are efficient relative to combustion engines, they are not as efficient as batteries, primarily due to the inefficiency of the oxygen reduction reaction (and ... the oxygen evolution reaction, should the hydrogen be formed by electrolysis of water).... [T]hey make the most sense for operation disconnected from the grid, or when fuel can be provided continuously. For applications that require frequent and relatively rapid start-ups ... where zero emissions are a requirement, as in enclosed spaces such as warehouses, and where hydrogen is considered an acceptable reactant, a [PEM fuel cell] is becoming an increasingly attractive choice [if exchanging batteries is inconvenient]". In 2013 military organizations were evaluating fuel cells to determine if they could significantly reduce the battery weight carried by soldiers.
Stationary fuel cells are used for commercial, industrial and residential primary and backup power generation. Fuel cells are very useful as power sources in remote locations, such as spacecraft, remote weather stations, large parks, communications centers, rural locations including research stations, and in certain military applications. A fuel cell system running on hydrogen can be compact and lightweight, and have no major moving parts. Because fuel cells have no moving parts and do not involve combustion, in ideal conditions they can achieve up to 99.9999% reliability. This equates to less than one minute of downtime in a six-year period.
Since fuel cell electrolyzer systems do not store fuel in themselves, but rather rely on external storage units, they can be successfully applied in large-scale energy storage, rural areas being one example. There are many different types of stationary fuel cells so efficiencies vary, but most are between 40% and 60% energy efficient. However, when the fuel cell's waste heat is used to heat a building in a cogeneration system this efficiency can increase to 85%. This is significantly more efficient than traditional coal power plants, which are only about one third energy efficient. Assuming production at scale, fuel cells could save 20–40% on energy costs when used in cogeneration systems. Fuel cells are also much cleaner than traditional power generation; a fuel cell power plant using natural gas as a hydrogen source would create less than one ounce of pollution (other than CO
2) for every 1,000 kW·h produced, compared to 25 pounds of pollutants generated by conventional combustion systems. Fuel Cells also produce 97% less nitrogen oxide emissions than conventional coal-fired power plants.
One such pilot program is operating on Stuart Island in Washington State. There the Stuart Island Energy Initiative has built a complete, closed-loop system: Solar panels power an electrolyzer, which makes hydrogen. The hydrogen is stored in a 500-U.S.-gallon (1,900 L) tank at 200 pounds per square inch (1,400 kPa), and runs a ReliOn fuel cell to provide full electric back-up to the off-the-grid residence. Another closed system loop was unveiled in late 2011 in Hempstead, NY.
Fuel cells can be used with low-quality gas from landfills or waste-water treatment plants to generate power and lower methane emissions. A 2.8 MW fuel cell plant in California is said to be the largest of the type. Small-scale (sub-5kWhr) fuel cells are being developed for use in residential off-grid deployment.
Combined heat and power (CHP) fuel cell systems, including micro combined heat and power (MicroCHP) systems are used to generate both electricity and heat for homes (see home fuel cell), office building and factories. The system generates constant electric power (selling excess power back to the grid when it is not consumed), and at the same time produces hot air and water from the waste heat. As the result CHP systems have the potential to save primary energy as they can make use of waste heat which is generally rejected by thermal energy conversion systems. A typical capacity range of home fuel cell is 1–3 kWel, 4–8 kWth. CHP systems linked to absorption chillers use their waste heat for refrigeration.
The waste heat from fuel cells can be diverted during the summer directly into the ground providing further cooling while the waste heat during winter can be pumped directly into the building. The University of Minnesota owns the patent rights to this type of system
Co-generation systems can reach 85% efficiency (40–60% electric and the remainder as thermal). Phosphoric-acid fuel cells (PAFC) comprise the largest segment of existing CHP products worldwide and can provide combined efficiencies close to 90%. Molten carbonate (MCFC) and solid-oxide fuel cells (SOFC) are also used for combined heat and power generation and have electrical energy efficiencies around 60%. Disadvantages of co-generation systems include slow ramping up and down rates, high cost and short lifetime. Also their need to have a hot water storage tank to smooth out the thermal heat production was a serious disadvantage in the domestic market place where space in domestic properties is at a great premium.
Delta-ee consultants stated in 2013 that with 64% of global sales the fuel cell micro-combined heat and power passed the conventional systems in sales in 2012. The Japanese ENE FARM project stated that 34.213 PEMFC and 2.224 SOFC were installed in the period 2012–2014, 30,000 units on LNG and 6,000 on LPG.
Fuel cell electric vehicles (FCEVs)
By year-end 2019, about 18,000 FCEVs had been leased or sold worldwide. Three fuel cell electric vehicles have been introduced for commercial lease and sale: the Honda Clarity, Toyota Mirai and the Hyundai ix35 FCEV. Additional demonstration models include the Honda FCX Clarity, and Mercedes-Benz F-Cell. As of June 2011 demonstration FCEVs had driven more than 4,800,000 km (3,000,000 mi), with more than 27,000 refuelings. Fuel cell electric vehicles feature an average range of 314 miles between refuelings. They can be refueled in less than 5 minutes. The U.S. Department of Energy's Fuel Cell Technology Program states that, as of 2011, fuel cells achieved 53–59% efficiency at one-quarter power and 42–53% vehicle efficiency at full power, and a durability of over 120,000 km (75,000 mi) with less than 10% degradation. In a 2017 Well-to-Wheels simulation analysis that "did not address the economics and market constraints", General Motors and its partners estimated that per mile traveled, a fuel cell electric vehicle running on compressed gaseous hydrogen produced from natural gas could use about 40% less energy and emit 45% less greenhouse gasses than an internal combustion vehicle.
In 2015, Toyota introduced its first fuel cell vehicle, the Mirai, at a price of $57,000. Hyundai introduced the limited production Hyundai ix35 FCEV under a lease agreement. In 2016, Honda started leasing the Honda Clarity Fuel Cell. In 2020, Toyota introduced the second generation of its Mirai brand, improving fuel efficiency and expanding range compared to the original Sedan 2014 model.
Some commentators believe that hydrogen fuel cell cars will never become economically competitive with other technologies or that it will take decades for them to become profitable. Elon Musk, CEO of battery-electric vehicle maker Tesla Motors, stated in 2015 that fuel cells for use in cars will never be commercially viable because of the inefficiency of producing, transporting and storing hydrogen and the flammability of the gas, among other reasons.
In 2012, Lux Research, Inc. issued a report that stated: "The dream of a hydrogen economy ... is no nearer". It concluded that "Capital cost ... will limit adoption to a mere 5.9 GW" by 2030, providing "a nearly insurmountable barrier to adoption, except in niche applications". The analysis concluded that, by 2030, PEM stationary market will reach $1 billion, while the vehicle market, including forklifts, will reach a total of $2 billion. Other analyses cite the lack of an extensive hydrogen infrastructure in the U.S. as an ongoing challenge to Fuel Cell Electric Vehicle commercialization.
In 2014, Joseph Romm, the author of The Hype About Hydrogen (2005), said that FCVs still had not overcome the high fueling cost, lack of fuel-delivery infrastructure, and pollution caused by producing hydrogen. "It would take several miracles to overcome all of those problems simultaneously in the coming decades." He concluded that renewable energy cannot economically be used to make hydrogen for an FCV fleet "either now or in the future." Greentech Media's analyst reached similar conclusions in 2014. In 2015, Clean Technica listed some of the disadvantages of hydrogen fuel cell vehicles. So did Car Throttle.
A 2019 video by Real Engineering noted that, notwithstanding the introduction of vehicles that run on hydrogen, using hydrogen as a fuel for cars does not help to reduce carbon emissions from transportation. The 95% of hydrogen still produced from fossil fuels releases carbon dioxide, and producing hydrogen from water is an energy-consuming process. Storing hydrogen requires more energy either to cool it down to the liquid state or to put it into tanks under high pressure, and delivering the hydrogen to fueling stations requires more energy and may release more carbon. The hydrogen needed to move a FCV a kilometer costs approximately 8 times as much as the electricity needed to move a BEV the same distance. A 2020 assessment concluded that hydrogen vehicles are still only 38% efficient, while battery EVs are 80% efficient.
(As of August 2011), there were about 100 fuel cell buses in service around the world. Most of these were manufactured by UTC Power, Toyota, Ballard, Hydrogenics, and Proton Motor. UTC buses had driven more than 970,000 km (600,000 mi) by 2011. Fuel cell buses have from 39% to 141% higher fuel economy than diesel buses and natural gas buses.
In 2018, the first fuel cell-powered trains, the Alstom Coradia iLint multiple units, began running on the Buxtehude–Bremervörde–Bremerhaven–Cuxhaven line in Germany. These trains offer the advantages of electric trains over Diesel locomotives and DMU’s in eliminating smokestack emissions from the trains themselves without the use of electrification by overhead catenerary infrastructure. Such trains have been ordered or are being tested in Sweden and the UK.
In December 2020, Toyota and Hino Motors, together with Seven-Eleven (Japan), FamilyMart and Lawson announced that they have agreed to jointly consider introducing light-duty fuel cell electric trucks (light-duty FCETs). Lawson started testing for low temperature delivery at the end of July 2021 in Tokyo, using a Hino Dutro in which the Toyota Mirai fuel cell is implemented. FamilyMart started testing in Okazaki city.
In August 2021, Toyota announced their plan to make fuel cell modules at its Kentucky auto-assembly plant for use in zero-emission big rigs and heavy-duty commercial vehicles. They plan to begin assembling the electrochemical devices in 2023.
In October 2021, Daimler Truck's fuel cell based truck received approval from German authorities for use on public roads.
A fuel cell forklift (also called a fuel cell lift truck) is a fuel cell-powered industrial forklift truck used to lift and transport materials. In 2013 there were over 4,000 fuel cell forklifts used in material handling in the US, of which 500 received funding from DOE (2012). Fuel cell fleets are operated by various companies, including Sysco Foods, FedEx Freight, GENCO (at Wegmans, Coca-Cola, Kimberly Clark, and Whole Foods), and H-E-B Grocers. Europe demonstrated 30 fuel cell forklifts with Hylift and extended it with HyLIFT-EUROPE to 200 units, with other projects in France and Austria. Pike Research projected in 2011 that fuel cell-powered forklifts would be the largest driver of hydrogen fuel demand by 2020.
Most companies in Europe and the US do not use petroleum-powered forklifts, as these vehicles work indoors where emissions must be controlled and instead use electric forklifts. Fuel cell-powered forklifts can provide benefits over battery-powered forklifts as they can be refueled in 3 minutes and they can be used in refrigerated warehouses, where their performance is not degraded by lower temperatures. The FC units are often designed as drop-in replacements.
Motorcycles and bicycles
In 2005, a British manufacturer of hydrogen-powered fuel cells, Intelligent Energy (IE), produced the first working hydrogen-run motorcycle called the ENV (Emission Neutral Vehicle). The motorcycle holds enough fuel to run for four hours, and to travel 160 km (100 mi) in an urban area, at a top speed of 80 km/h (50 mph). In 2004 Honda developed a fuel cell motorcycle that utilized the Honda FC Stack.
Other examples of motorbikes and bicycles that use hydrogen fuel cells include the Taiwanese company APFCT's scooter using the fueling system from Italy's Acta SpA and the Suzuki Burgman scooter with an IE fuel cell that received EU Whole Vehicle Type Approval in 2011. Suzuki Motor Corp. and IE have announced a joint venture to accelerate the commercialization of zero-emission vehicles.
In 2003, the world's first propeller-driven airplane to be powered entirely by a fuel cell was flown. The fuel cell was a stack design that allowed the fuel cell to be integrated with the plane's aerodynamic surfaces. Fuel cell-powered unmanned aerial vehicles (UAV) include a Horizon fuel cell UAV that set the record distance flown for a small UAV in 2007. Boeing researchers and industry partners throughout Europe conducted experimental flight tests in February 2008 of a manned airplane powered only by a fuel cell and lightweight batteries. The fuel cell demonstrator airplane, as it was called, used a proton-exchange membrane (PEM) fuel cell/lithium-ion battery hybrid system to power an electric motor, which was coupled to a conventional propeller.
In 2009, the Naval Research Laboratory's (NRL's) Ion Tiger utilized a hydrogen-powered fuel cell and flew for 23 hours and 17 minutes. Fuel cells are also being tested and considered to provide auxiliary power in aircraft, replacing fossil fuel generators that were previously used to start the engines and power on board electrical needs, while reducing carbon emissions. In 2016 a Raptor E1 drone made a successful test flight using a fuel cell that was lighter than the lithium-ion battery it replaced. The flight lasted 10 minutes at an altitude of 80 metres (260 ft), although the fuel cell reportedly had enough fuel to fly for two hours. The fuel was contained in approximately 100 solid 1 square centimetre (0.16 sq in) pellets composed of a proprietary chemical within an unpressurized cartridge. The pellets are physically robust and operate at temperatures as warm as 50 °C (122 °F). The cell was from Arcola Energy.
Lockheed Martin Skunk Works Stalker is an electric UAV powered by solid oxide fuel cell.
The world's first fuel cell boat HYDRA used an AFC system with 6.5 kW net output. Amsterdam introduced fuel cell-powered boats that ferry people around the city's canals.
The Type 212 submarines of the German and Italian navies use fuel cells to remain submerged for weeks without the need to surface.
The U212A is a non-nuclear submarine developed by German naval shipyard Howaldtswerke Deutsche Werft. The system consists of nine PEM fuel cells, providing between 30 kW and 50 kW each. The ship is silent, giving it an advantage in the detection of other submarines. A naval paper has theorized about the possibility of a nuclear-fuel cell hybrid whereby the fuel cell is used when silent operations are required and then replenished from the Nuclear reactor (and water).
Portable power systems
Portable fuel cell systems are generally classified as weighing under 10 kg and providing power of less than 5 kW. The potential market size for smaller fuel cells is quite large with an up to 40% per annum potential growth rate and a market size of around $10 billion, leading a great deal of research to be devoted to the development of portable power cells. Within this market two groups have been identified. The first is the microfuel cell market, in the 1-50 W range for power smaller electronic devices. The second is the 1-5 kW range of generators for larger scale power generation (e.g. military outposts, remote oil fields).
Microfuel cells are primarily aimed at penetrating the market for phones and laptops. This can be primarily attributed to the advantageous energy density provided by fuel cells over a lithium-ion battery, for the entire system. For a battery, this system includes the charger as well as the battery itself. For the fuel cell this system would include the cell, the necessary fuel and peripheral attachments. Taking the full system into consideration, fuel cells have been shown to provide 530Wh/kg compared to 44 Wh/kg for lithium ion batteries. However, while the weight of fuel cell systems offer a distinct advantage the current costs are not in their favor. while a battery system will generally cost around $1.20 per Wh, fuel cell systems cost around $5 per Wh, putting them at a significant disadvantage.
As power demands for cell phones increase, fuel cells could become much more attractive options for larger power generation. The demand for longer on time on phones and computers is something often demanded by consumers so fuel cells could start to make strides into laptop and cell phone markets. The price will continue to go down as developments in fuel cells continues to accelerate. Current strategies for improving micro fuel cells is through the use of carbon nanotubes. It was shown by Girishkumar et al. that depositing nanotubes on electrode surfaces allows for substantially greater surface area increasing the oxygen reduction rate.
Fuel cells for use in larger scale operations also show much promise. Portable power systems that use fuel cells can be used in the leisure sector (i.e. RVs, cabins, marine), the industrial sector (i.e. power for remote locations including gas/oil wellsites, communication towers, security, weather stations), and in the military sector. SFC Energy is a German manufacturer of direct methanol fuel cells for a variety of portable power systems. Ensol Systems Inc. is an integrator of portable power systems, using the SFC Energy DMFC. The key advantage of fuel cells in this market is the great power generation per weight. While fuel cells can be expensive, for remote locations that require dependable energy fuel cells hold great power. For a 72-h excursion the comparison in weight is substantial, with a fuel cell only weighing 15 pounds compared to 29 pounds of batteries needed for the same energy.
- Providing power for base stations or cell sites
- Distributed generation
- Emergency power systems are a type of fuel cell system, which may include lighting, generators and other apparatus, to provide backup resources in a crisis or when regular systems fail. They find uses in a wide variety of settings from residential homes to hospitals, scientific laboratories, data centers,
- Telecommunication equipment and modern naval ships.
- An uninterrupted power supply (UPS) provides emergency power and, depending on the topology, provide line regulation as well to connected equipment by supplying power from a separate source when utility power is not available. Unlike a standby generator, it can provide instant protection from a momentary power interruption.
- Base load power plants
- Hybrid vehicles, pairing the fuel cell with either an ICE or a battery.
- Notebook computers for applications where AC charging may not be readily available.
- Portable charging docks for small electronics (e.g. a belt clip that charges a cell phone or PDA).
- Smartphones, laptops and tablets.
- Small heating appliances
- Food preservation, achieved by exhausting the oxygen and automatically maintaining oxygen exhaustion in a shipping container, containing, for example, fresh fish.
- Breathalyzers, where the amount of voltage generated by a fuel cell is used to determine the concentration of fuel (alcohol) in the sample.
- Carbon monoxide detector, electrochemical sensor.
According to FuelCellsWorks, an industry group, at the end of 2019, 330 hydrogen refueling stations were open to the public worldwide. As of June 2020, there were 178 publicly available hydrogen stations in operation in Asia. 114 of these were in Japan. There were at least 177 stations in Europe, and about half of these were in Germany. There were 44 publicly accessible stations in the US, 42 of which were located in California.
A hydrogen fueling station costs between $1 million and $4 million to build.
Markets and economics
In 2012, fuel cell industry revenues exceeded $1 billion market value worldwide, with Asian pacific countries shipping more than 3/4 of the fuel cell systems worldwide. However, as of January 2014, no public company in the industry had yet become profitable. There were 140,000 fuel cell stacks shipped globally in 2010, up from 11,000 shipments in 2007, and from 2011 to 2012 worldwide fuel cell shipments had an annual growth rate of 85%. Tanaka Kikinzoku expanded its manufacturing facilities in 2011. Approximately 50% of fuel cell shipments in 2010 were stationary fuel cells, up from about a third in 2009, and the four dominant producers in the Fuel Cell Industry were the United States, Germany, Japan and South Korea. The Department of Energy Solid State Energy Conversion Alliance found that, as of January 2011, stationary fuel cells generated power at approximately $724 to $775 per kilowatt installed. In 2011, Bloom Energy, a major fuel cell supplier, said that its fuel cells generated power at 9–11 cents per kilowatt-hour, including the price of fuel, maintenance, and hardware.
Industry groups predict that there are sufficient platinum resources for future demand, and in 2007, research at Brookhaven National Laboratory suggested that platinum could be replaced by a gold-palladium coating, which may be less susceptible to poisoning and thereby improve fuel cell lifetime. Another method would use iron and sulphur instead of platinum. This would lower the cost of a fuel cell (as the platinum in a regular fuel cell costs around US$1,500, and the same amount of iron costs only around US$1.50). The concept was being developed by a coalition of the John Innes Centre and the University of Milan-Bicocca. PEDOT cathodes are immune to monoxide poisoning.
Research and development
- 2005: Georgia Institute of Technology researchers used triazole to raise the operating temperature of PEM fuel cells from below 100 °C to over 125 °C, claiming this will require less carbon-monoxide purification of the hydrogen fuel.
- 2008: Monash University, Melbourne used PEDOT as a cathode.
- 2009: Researchers at the University of Dayton, in Ohio, showed that arrays of vertically grown carbon nanotubes could be used as the catalyst in fuel cells. The same year, a nickel bisdiphosphine-based catalyst for fuel cells was demonstrated.
- 2013: British firm ACAL Energy developed a fuel cell that it said can run for 10,000 hours in simulated driving conditions. It asserted that the cost of fuel cell construction can be reduced to $40/kW (roughly $9,000 for 300 HP).
- 2014: Researchers in Imperial College London developed a new method for regeneration of hydrogen sulfide contaminated PEFCs. They recovered 95–100% of the original performance of a hydrogen sulfide contaminated PEFC. They were successful in rejuvenating a SO2 contaminated PEFC too. This regeneration method is applicable to multiple cell stacks.
- Bio-nano generator
- Fuel Cell Development Information Center
- Fuel Cells and Hydrogen Joint Technology Initiative (in Europe)
- Grid energy storage
- Hydrogen reformer
- Hydrogen storage
- Hydrogen technologies
- List of fuel cell manufacturers
- Methanol reformer
- PEM electrolysis
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