Physics:Energy density
Energy density | |
---|---|
SI unit | J/m3 |
Other units | J/L, W⋅h/L |
In SI base units | m−1⋅kg⋅s−2 |
Derivations from other quantities | U = E/V |
In physics, energy density or volumic energy is the amount of energy stored in a given system or region of space per unit volume. It is sometimes confused with energy per unit mass which is properly called massic energy or gravimetric energy density.
Often only the useful or extractable energy is measured, which is to say that inaccessible energy (such as rest mass energy) is ignored.[1] In cosmological and other general relativistic contexts, however, the energy densities considered are those that correspond to the elements of the stress-energy tensor and therefore do include mass energy as well as energy densities associated with pressure.
Energy per unit volume has the same physical units as pressure and in many situations is synonymous. For example, the energy density of a magnetic field may be expressed as and behaves like a physical pressure. Likewise, the energy required to compress a gas to a certain volume may be determined by multiplying the difference between the gas pressure and the external pressure by the change in volume. A pressure gradient describes the potential to perform work on the surroundings by converting internal energy to work until equilibrium is reached.
Overview
There are different types of energy stored in materials, and it takes a particular type of reaction to release each type of energy. In order of the typical magnitude of the energy released, these types of reactions are: nuclear, chemical, electrochemical, and electrical.
Nuclear reactions take place in stars and nuclear power plants, both of which derive energy from the binding energy of nuclei. Chemical reactions are used by organisms to derive energy from food and by automobiles to derive energy from gasoline. Liquid hydrocarbons (fuels such as gasoline, diesel and kerosene) are today the densest way known to economically store and transport chemical energy at a large scale (1 kg of diesel fuel burns with the oxygen contained in ≈15 kg of air). Electrochemical reactions are used by most mobile devices such as laptop computers and mobile phones to release energy from batteries.
Types of energy content
There are several different types of energy content. One is the theoretical total amount of thermodynamic work that can be derived from a system, at a given temperature and pressure imposed by the surroundings. This is called exergy. Another is the theoretical amount of electrical energy that can be derived from reactants that are at room temperature and atmospheric pressure. This is given by the change in standard Gibbs free energy. But as a source of heat or for use in a heat engine, the relevant quantity is the change in standard enthalpy or the heat of combustion.
There are two kinds of heat of combustion:
- The higher value (HHV), or gross heat of combustion, includes all the heat released as the products cool to room temperature and whatever water vapor is present condenses.
- The lower value (LHV), or net heat of combustion, does not include the heat which could be released by condensing water vapor, and may not include the heat released on cooling all the way down to room temperature.
A convenient table of HHV and LHV of some fuels can be found in the references.[2]
In energy storage and fuels
In energy storage applications the energy density relates the energy in an energy store to the volume of the storage facility, e.g. the fuel tank. The higher the energy density of the fuel, the more energy may be stored or transported for the same amount of volume. Given the high energy density of gasoline, the exploration of alternative media to store the energy of powering a car, such as hydrogen or battery, is strongly limited by the energy density of the alternative medium. The same mass of lithium-ion storage, for example, would result in a car with only 2% the range of its gasoline counterpart. If sacrificing the range is undesirable, it becomes necessary to carry that much more fuel.
The energy density of a fuel per unit mass is called the specific energy of that fuel. In general an engine using that fuel will generate less kinetic energy due to inefficiencies and thermodynamic considerations—hence the specific fuel consumption of an engine will always be greater than its rate of production of the kinetic energy of motion.
Energy density differs from energy conversion efficiency (net output per input) or embodied energy (the energy output costs to provide, as harvesting, refining, distributing, and dealing with pollution all use energy). Large scale, intensive energy use impacts and is impacted by climate, waste storage, and environmental consequences.
No single energy storage method boasts the best in specific power, specific energy, and energy density. Peukert's law describes how the amount of useful energy that can be obtained (for a lead-acid cell) depends on how quickly it is pulled out.
Alternative options are discussed for energy storage to increase energy density and decrease charging time.[10][11][12][13]
The figure above shows the gravimetric and volumetric energy density of some fuels and storage technologies (modified from the Gasoline article).
Some values may not be precise because of isomers or other irregularities. See Heating value for a comprehensive table of specific energies of important fuels.
Generally the density values for chemical fuels do not include the weight of the oxygen required for combustion. The atomic weights of carbon and oxygen are similar, while hydrogen is much lighter. Figures are presented in this way for those fuels where in practice air would only be drawn in locally to the burner. This explains the apparently lower energy density of materials that contain their own oxidizer (such as gunpowder and TNT), where the mass of the oxidizer in effect adds weight, and absorbs some of the energy of combustion to dissociate and liberate oxygen to continue the reaction. This also explains some apparent anomalies, such as the energy density of a sandwich appearing to be higher than that of a stick of dynamite.
List of material energy densities
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The following unit conversions may be helpful when considering the data in the tables: 3.6 MJ = 1 kW⋅h ≈ 1.34 hp⋅h. Since 1 J = 10−6 MJ and 1 m3 = 103 L, divide joule/m3 by 109 to get MJ/L = GJ/m3. Divide MJ/L by 3.6 to get kW⋅h/L.
In chemical reactions (oxidation)
Unless otherwise stated, the values in the following table are lower heating values for perfect combustion, not counting oxidizer mass or volume. When used to produce electricity in a fuel cell or to do work, it is the Gibbs free energy of reaction (ΔG) that sets the theoretical upper limit. If the produced H
2O is vapor, this is generally greater than the lower heat of combustion, whereas if the produced H2O is liquid, it is generally less than the higher heat of combustion. But in the most relevant case of hydrogen, ΔG is 113 MJ/kg if water vapor is produced, and 118 MJ/kg if liquid water is produced, both being less than the lower heat of combustion (120 MJ/kg).[14]
Material | Specific energy (MJ/kg) |
Energy density (MJ/L) |
Specific energy (W⋅h/kg) |
Energy density (W⋅h/L) |
Comment |
---|---|---|---|---|---|
Hydrogen, liquid | 141.86 (HHV) 119.93 (LHV) |
10.044 (HHV) 8.491 (LHV) |
33,313.9 (LHV) |
39,405.6 (HHV)2,790.0 (HHV) 2,358.6 (LHV) |
Energy figures apply after reheating to 25 °C.[15]
See note above about use in fuel cells. |
Hydrogen, gas (681 atm, 69 MPa, 25 °C) | 141.86 (HHV) 119.93 (LHV) |
5.323 (HHV) 4.500 (LHV) |
33,313.9 (LHV) |
39,405.6 (HHV)1,478.6 (HHV) 1,250.0 (LHV) |
Date from same reference as for liquid hydrogen.[15]
High-pressure tanks weigh much more than the hydrogen they can hold. The hydrogen may be around 5.7% of the total mass,[16] giving just 6.8 MJ per kg total mass for the LHV. See note above about use in fuel cells. |
Hydrogen, gas (1 atm or 101.3 kPa, 25 °C) | 141.86 (HHV) 119.93 (LHV) |
0.01188 (HHV) 0.01005 (LHV) |
33,313.9 (LHV) |
39,405.6 (HHV)3.3 (HHV) 2.8 (LHV) |
[15] |
Diborane | 78.2 | 88.4 | 21,722.2 | 24,600 | [17] |
Beryllium | 67.6 | 125.1 | 18,777.8 | 34,750.0 | |
Lithium borohydride | 65.2 | 43.4 | 18,111.1 | 12,055.6 | |
Boron | 58.9 | 137.8 | 16,361.1 | 38,277.8 | |
Methane (101.3 kPa, 15 °C) | 55.6 | 0.0378 | 15,444.5 | 10.5 | |
LNG (NG at −160 °C) | 53.6[18] | 22.2 | 14,888.9 | 6,166.7 | |
CNG (NG compressed to 247 atm, 25 MPa ≈ 3,600 psi) | 53.6[18] | 9 | 14,888.9 | 2,500.0 | |
Natural gas | 53.6[18] | 0.0364 | 14,888.9 | 10.1 | |
LPG propane | 49.6 | 25.3 | 13,777.8 | 7,027.8 | [19] |
LPG butane | 49.1 | 27.7 | 13,638.9 | 7,694.5 | [19] |
Gasoline (petrol) | 46.4 | 34.2 | 12,888.9 | 9,500.0 | [19] |
Polypropylene plastic | 46.4[20] | 41.7 | 12,888.9 | 11,583.3 | |
Polyethylene plastic | 46.3[20] | 42.6 | 12,861.1 | 11,833.3 | |
Residential heating oil | 46.2 | 37.3 | 12,833.3 | 10,361.1 | [19] |
Diesel fuel | 45.6 | 38.6 | 12,666.7 | 10,722.2 | [19] |
100LL Avgas | 44.0[21] | 31.59 | 12,222.2 | 8,775.0 | |
Jet fuel (e.g. kerosene) | 43[22][23][24] | 35 | 11,944.4 | 9,722.2 | Aircraft engine |
Gasohol E10 (10% ethanol 90% gasoline by volume) | 43.54 | 33.18 | 12,094.5 | 9,216.7 | |
Lithium | 43.1 | 23.0 | 11,972.2 | 6,388.9 | |
Biodiesel oil (vegetable oil) | 42.20 | 33 | 11,722.2 | 9,166.7 | |
DMF (2,5-dimethylfuran) | 42[25] | 37.8 | 11,666.7 | 10,500.0 | |
Paraffin wax | 42[26] | 37.8 | 11,700 | 10,500 | |
Crude oil (tonne of oil equivalent) | 41.868 | 37[18] | 11,630 | 10,278 | |
Polystyrene plastic | 41.4[20] | 43.5 | 11,500.0 | 12,083.3 | |
Body fat | 38 | 35 | 10,555.6 | 9,722.2 | Metabolism in human body (22% efficiency[27]) |
Butanol | 36.6 | 29.2 | 10,166.7 | 8,111.1 | |
Gasohol E85 (85% ethanol 15% gasoline by volume) | 33.1 | 25.65[citation needed] | 9,194.5 | 7,125.0 | |
Graphite | 32.7 | 72.9 | 9,083.3 | 20,250.0 | |
Coal, anthracite | 26–33 | 34–43 | 7,222.2–9,166.7 | 9,444.5–11,944.5 | Figures represent perfect combustion not counting oxidizer, but efficiency of conversion to electricity is ≈36%[6] |
Silicon | 32.6 | 75.9 | 9,056 | 21,080 | See Table 1 [28] |
Aluminium | 31.0 | 83.8 | 8,611.1 | 23,277.8 | |
Ethanol | 30 | 24 | 8,333.3 | 6,666.7 | |
DME | 31.7 (HHV) 28.4 (LHV) |
21.24 (HHV) 19.03 (LHV) |
7,888.9 (LHV) |
8,805.6 (HHV)5,900.0 (HHV) 5,286.1 (LHV) |
[29][30] |
Polyester plastic | 26.0[20] | 35.6 | 7,222.2 | 9,888.9 | |
Magnesium | 24.7 | 43.0 | 6,861.1 | 11,944.5 | |
Phosphorus (white) | 24.30 | 44.30 | 6,750 | 12,310 | [31] |
Coal, bituminous | 24–35 | 26–49 | 6,666.7–9,722.2 | 7,222.2–13,611.1 | [6] |
PET plastic (impure) | 23.5[32] | < ~32.4 | 6,527.8 | < ~9000 | |
Methanol | 19.7 | 15.6 | 5,472.2 | 4,333.3 | |
Titanium | 19.74 | 88.93 | 5,480 | 24,700 | burned to titanium dioxide |
Hydrazine (combusted to N2+H2O) | 19.5 | 19.3 | 5,416.7 | 5,361.1 | |
Liquid ammonia (combusted to N2+H2O) | 18.6 | 11.5 | 5,166.7 | 3,194.5 | |
Potassium | 18.6 | 16.5 | 5,160 | 4,600 | burned to dry potassium oxide |
PVC plastic (improper combustion toxic) | 18.0[20] | 25.2 | 5,000.0 | 7,000.0 | |
Wood | 18.0 | 5,000.0 | [33] | ||
Peat briquette | 17.7 | 4,916.7 | [34] | ||
Sugars, carbohydrates, and protein | 17 | 26.2 (dextrose) | 4,722.2 | 7,277.8 | Metabolism in human body (22% efficiency[35])[citation needed] |
Calcium | 15.9 | 24.6 | 4,416.7 | 6,833.3 | |
Glucose | 15.55 | 23.9 | 4,319.5 | 6,638.9 | |
Dry cow dung and camel dung | 15.5[36] | 4,305.6 | |||
Coal, lignite | 10–20 | 2,777.8–5,555.6 | |||
Sodium | 13.3 | 12.8 | 3,694.5 | 3,555.6 | burned to wet sodium hydroxide |
Peat | 12.8 | 3,555.6 | |||
Nitromethane | 11.3 | 12.85 | 3,138.9 | 3,570 | |
Manganese | 9.46 | 68.2 | 2,630 | 18,900 | burned to manganese dioxide |
Sulfur | 9.23 | 19.11 | 2,563.9 | 5,308.3 | burned to sulfur dioxide[37] |
Sodium | 9.1 | 8.8 | 2,527.8 | 2,444.5 | burned to dry sodium oxide |
Battery, lithium-air rechargeable | 2,500.0 | Controlled electric discharge | |||
Household waste | 8.0[38] | 2,222.2 | |||
Zinc | 5.3 | 38.0 | 1,472.2 | 10,555.6 | |
Iron | 5.2 | 40.68 | 1,444.5 | 11,300.0 | burned to iron(III) oxide |
Teflon plastic | 5.1 | 11.2 | 1,416.7 | 3,111.1 | combustion toxic, but flame retardant |
Iron | 4.9 | 38.2 | 1,361.1 | 10,611.1 | burned to iron(II) oxide |
Gunpowder | 4.7–11.3[39] | 5.9–12.9 | 1,600–3,580 | ||
TNT | 4.184 | 6.92 | 1,162 | 1,920 | |
Barium | 3.99 | 14.0 | 1,110 | 3,890 | burned to barium dioxide |
ANFO | 3.7 | 1,027.8 |
In nuclear reactions
Material | Specific energy (MJ/kg) |
Energy density (MJ/L) |
Specific energy (W⋅h/kg) |
Energy density (W⋅h/L) |
Comment |
---|---|---|---|---|---|
Antimatter | 89,875,517,874 ≈ 90 PJ/kg | Depends on the density of the antimatter's form | 24,965,421,631,578 ≈ 25 TW⋅h/kg | Depends on the density of the antimatter's form | Annihilation, counting both the consumed antimatter mass and ordinary matter mass |
Hydrogen (fusion) | 639,780,320[40] but at least 2% of this is lost to neutrinos. | Depends on conditions | 177,716,755,600 | Depends on conditions | Reaction 4H→4He |
Deuterium (fusion) |
571,182,758[41] | Depends on conditions | 158,661,876,600 | Depends on conditions | Proposed fusion scheme for D+D→4He, by combining D+D→T+H, T+D→4He+n, n+H→D and D+D→3He+n, 3He+D→4He+H, n+H→D |
Deuterium+tritium (fusion) | 337,387,388[40] | Depends on conditions | 93,718,718,800 | Depends on conditions | D + T → 4He + n Being developed. |
Lithium-6 deuteride (fusion) | 268,848,415[40] | Depends on conditions | 74,680,115,100 | Depends on conditions | 6LiD → 24He Used in weapons. |
Plutonium-239 | 83,610,000 | 1,300,000,000–1,700,000,000 (Depends on crystallographic phase) | 23,222,915,000 | 370,000,000,000–460,000,000,000 (Depends on crystallographic phase) | Heat produced in Fission reactor |
Plutonium-239 | 31,000,000 | 490,000,000–620,000,000 (Depends on crystallographic phase) | 8,700,000,000 | 140,000,000,000–170,000,000,000 (Depends on crystallographic phase) | Electricity produced in Fission reactor |
Uranium | 80,620,000[42] | 1,539,842,000 | 22,394,000,000 | Heat produced in breeder reactor | |
Thorium | 79,420,000[42] | 929,214,000 | 22,061,000,000 | Heat produced in breeder reactor (Experimental) | |
Plutonium-238 | 2,239,000 | 43,277,631 | 621,900,000 | Radioisotope thermoelectric generator. The heat is only produced at a rate of 0.57 W/g. |
Other release mechanisms
Material | Specific energy (MJ/kg) |
Energy density (MJ/L) |
Specific energy (W⋅h/kg) |
Energy density (W⋅h/L) |
Comment |
---|---|---|---|---|---|
Battery, zinc-air | 1.59 | 6.02 | 441.7 | 1,672.2 | Controlled electric discharge[43] |
Silicon (phase change) | 1.790 | 4.5 | 500 | 1,285 | Energy stored through solid to liquid phase change of silicon[44] |
Strontium bromide hydrate | 0.814 [45] | 1.93 | 628 | Thermal energy of phase change at 88.6 °C (361.8 K) | |
Liquid nitrogen | 0.77[46] | 0.62 | 213.9 | 172.2 | Maximum reversible work at 77.4 K with 300 K reservoir |
Sodium sulfur battery | 0.54–0.86 | 150–240 | |||
Compressed air at 30 MPa | 0.5 | 0.2 | 138.9 | 55.6 | Potential energy |
Latent heat of fusion of ice (thermal) | 0.334 | 0.334 | 93.1 | 93.1 | |
Lithium metal battery | 1.8 | 4.32 | 500 | 1,200 | Controlled electric discharge |
Lithium-ion battery | 0.36–0.875[49] | 0.9–2.63 | 100.00–243.06 | 250.00–730.56 | Controlled electric discharge |
Lithium-ion battery with silicon nanowire anodes | 1.566 | 4.32 | 435[50] | 1,200[50] | Controlled electric discharge |
Flywheel | 0.36–0.5 | 5.3 | Kinetic energy | ||
Alkaline battery | 0.48[51] | 1.3[52] | Controlled electric discharge | ||
Nickel-metal hydride battery | 0.41[53] | 0.504–1.46[53] | Controlled electric discharge | ||
Lead-acid battery | 0.17 | 0.56 | 47.2 | 156 | Controlled electric discharge |
Supercapacitor (EDLC) | 0.01–0.030[54][55][56][57][58][59][60] | 0.006–0.06[54][55][56][57][58][59] | up to 8.57[60] | Controlled electric discharge | |
Water at 100 m dam height | 0.000981 | 0.000978 | 0.272 | 0.272 | Figures represent potential energy, but efficiency of conversion to electricity is 85–90%[61][62] |
Electrolytic capacitor | 0.00001–0.0002[63] | 0.00001–0.001[63][64][65] | Controlled electric discharge |
In material deformation
The mechanical energy storage capacity, or resilience, of a Hookean material when it is deformed to the point of failure can be computed by calculating tensile strength times the maximum elongation dividing by two. The maximum elongation of a Hookean material can be computed by dividing stiffness of that material by its ultimate tensile strength. The following table lists these values computed using the Young's modulus as measure of stiffness:
Material | Energy density by mass
(J/kg) |
Resilience: Energy density by volume
(J/L) |
Density
(kg/L) |
Young's modulus
(GPa) |
Tensile yield strength
(MPa) |
---|---|---|---|---|---|
Rubber band | 1,651–6,605[66] | 2,200–8,900[66] | 1.35[66] | ||
Steel, ASTM A228 (yield, 1 mm diameter) | 1,440–1,770 | 11,200–13,800 | 7.80[67] | 210[67] | 2,170–2,410[67] |
Acetals | 908 | 754 | 0.831[68] | 2.8[69] | 65 (ultimate)[69] |
Nylon-6 | 233–1,870 | 253–2,030 | 1.084 | 2–4[69] | 45–90 (ultimate)[69] |
Copper Beryllium 25-1/2 HT (yield) | 684 | 5,720[70] | 8.36[71] | 131[70] | 1,224[70] |
Polycarbonates | 433–615 | 520–740 | 1.2[72] | 2.6[69] | 52–62 (ultimate)[69] |
ABS plastics | 241–534 | 258–571 | 1.07 | 1.4–3.1[69] | 40 (ultimate)[69] |
Acrylic | 1,530 | 3.2[69] | 70 (ultimate)[69] | ||
Aluminium 7077-T8 (yield) | 399 | 1,120[70] | 2.81[73] | 71.0[70] | 400[70] |
Steel, stainless, 301-H (yield) | 301 | 2,410[70] | 8.0[74] | 193[70] | 965[70] |
Aluminium 6061-T6 (yield @ 24 °C) | 205 | 553 | 2.70[75] | 68.9[75] | 276[75] |
Epoxy resins | 113–1,810 | 2–3[69] | 26–85 (ultimate)[69] | ||
Douglas fir Wood | 158–200 | 96 | .481–.609[76] | 13[69] | 50 (compression)[69] |
Steel, Mild AISI 1018 | 42.4 | 334 | 7.87[77] | 205[77] | 370 (440 Ultimate)[77] |
Aluminium (not alloyed) | 32.5 | 87.7 | 2.70[78] | 69[69] | 110 (ultimate)[69] |
Pine (American Eastern White, flexural) | 31.8–32.8 | 11.1–11.5 | .350[79] | 8.30–8.56 (flexural)[79] | 41.4 (flexural)[79] |
Brass | 28.6–36.5 | 250–306 | 8.4–8.73[80] | 102–125[69] | 250 (ultimate)[69] |
Copper | 23.1 | 207 | 8.93[80] | 117[69] | 220 (ultimate)[69] |
Glass | 5.56–10.0 | 13.9–25.0 | 2.5[81] | 50–90[69] | 50 (compression)[69] |
In batteries
Storage device | Energy content (Joule) |
Energy content (W⋅h) |
Energy type | Typical mass (g) |
Typical dimensions (diameter × height in mm) |
Typical volume (mL) | Energy density by volume (MJ/L) |
Energy density by mass (MJ/kg) |
---|---|---|---|---|---|---|---|---|
Alkaline AA battery[82] | 9,360 | 2.6 | Electrochemical | 24 | 14.2 × 50 | 7.92 | 1.18 | 0.39 |
Alkaline C battery[82] | 34,416 | 9.5 | Electrochemical | 65 | 26 × 46 | 24.42 | 1.41 | 0.53 |
NiMH AA battery | 9,072 | 2.5 | Electrochemical | 26 | 14.2 × 50 | 7.92 | 1.15 | 0.35 |
NiMH C battery | 19,440 | 5.4 | Electrochemical | 82 | 26 × 46 | 24.42 | 0.80 | 0.24 |
Lithium-ion 18650 battery | 28,800–46,800 | 8–13 | Electrochemical | 44–49[83] | 18 × 65 | 16.54 | 1.74–2.83 | 0.59–1.06 |
Nuclear energy sources
The greatest energy source by far is matter itself. This energy, E = mc2, where m = ρV, ρ is the mass per unit volume, V is the volume of the mass itself and c is the speed of light. This energy, however, can be released only by the processes of nuclear fission (0.1%), nuclear fusion (1%), or the annihilation of some or all of the matter in the volume V by matter-antimatter collisions (100%).[citation needed] Nuclear reactions cannot be realized by chemical reactions such as combustion. Although greater matter densities can be achieved, the density of a neutron star would approximate the most dense system capable of matter-antimatter annihilation possible. A black hole, although denser than a neutron star, does not have an equivalent anti-particle form, but would offer the same 100% conversion rate of mass to energy in the form of Hawking radiation. In the case of relatively small black holes (smaller than astronomical objects) the power output would be tremendous.
The highest density sources of energy aside from antimatter are fusion and fission. Fusion includes energy from the sun which will be available for billions of years (in the form of sunlight) but so far (2021), sustained fusion power production continues to be elusive.
Power from fission of uranium and thorium in nuclear power plants will be available for many decades or even centuries because of the plentiful supply of the elements on earth,[84] though the full potential of this source can only be realized through breeder reactors, which are, apart from the BN-600 reactor, not yet used commercially.[85] Coal, gas, and petroleum are the current primary energy sources in the U.S.[86] but have a much lower energy density. Burning local biomass fuels supplies household energy needs (cooking fires, oil lamps, etc.) worldwide.
Thermal power of nuclear fission reactors
The density of thermal energy contained in the core of a light water reactor (PWR or BWR) of typically 1 GWe (1,000 MW electrical corresponding to ≈3,000 MW thermal) is in the range of 10 to 100 MW of thermal energy per cubic meter of cooling water depending on the location considered in the system (the core itself (≈30 m3), the reactor pressure vessel (≈50 m3), or the whole primary circuit (≈300 m3)). This represents a considerable density of energy which requires under all circumstances a continuous water flow at high velocity in order to be able to remove the heat from the core, even after an emergency shutdown of the reactor. The incapacity to cool the cores of three boiling water reactors (BWR) at Fukushima in 2011 after the tsunami and the resulting loss of the external electrical power and of the cold source was the cause of the meltdown of the three cores in only a few hours, even though the three reactors were correctly shut down just after the Tōhoku earthquake. This extremely high power density distinguishes nuclear power plants (NPP's) from any thermal power plants (burning coal, fuel or gas) or any chemical plants and explains the large redundancy required to permanently control the neutron reactivity and to remove the residual heat from the core of NPP's.
Energy density of electric and magnetic fields
Electric and magnetic fields store energy. The (volumetric) energy density is given by
- [math]\displaystyle{ u = \frac{\varepsilon}{2} \mathbf{E}^2 + \frac{1}{2\mu} \mathbf{B}^2 }[/math]
where E is the electric field, B is the magnetic field, and ε and µ are the permittivity and permeability of the surroundings respectively. The solution will be (in SI units) in joules per cubic metre. In the context of magnetohydrodynamics, the physics of conductive fluids, the magnetic energy density behaves like an additional pressure that adds to the gas pressure of a plasma.
In ideal (linear and nondispersive) substances, the energy density (in SI units) is
- [math]\displaystyle{ u = \frac{1}{2} ( \mathbf{E} \cdot \mathbf{D} + \mathbf{H} \cdot \mathbf{B} ) }[/math]
where D is the electric displacement field and H is the magnetizing field.
In the case of absence of magnetic fields, by exploiting Fröhlich's relationships it is also possible to extend these equations to anisotropic and nonlinear dielectrics, as well as to calculate the correlated Helmholtz free energy and entropy densities.[87]
When a pulsed laser impacts a surface, the radiant exposure, i.e. the energy deposited per unit of surface, may be called energy density or fluence.[88]
See also
- Energy content of biofuel
- Energy density Extended Reference Table
- Figure of merit
- Food energy
- Heat of combustion
- High-energy-density matter
- Power density and specifically
- Power-to-weight ratio
- Rechargeable battery
- Solid-state battery
- Specific energy
- Specific impulse
Footnotes
- ↑ "The Two Classes of SI Units and the SI Prefixes". NIST Guide to the SI. 2009-07-02. http://physics.nist.gov/Pubs/SP811/sec04.html. Retrieved 2012-01-25.
- ↑ "Fossil and Alternative Fuels - Energy Content (2008).". Engineering ToolBox. https://www.engineeringtoolbox.com/fossil-fuels-energy-content-d_1298.html.
- ↑ Jeong, Goojin; Kim, Hansu; Park, Jong Hwan; Jeon, Jaehwan; Jin, Xing; Song, Juhye; Kim, Bo-Ram; Park, Min-Sik et al. (2015). "Nanotechnology enabled rechargeable Li–SO2 batteries: Another approach towards post-lithium-ion battery systems". Energy & Environmental Science 8 (11): 3173–3180. doi:10.1039/C5EE01659B.
- ↑ "Panasonic Develops New Higher-Capacity 18650 Li-Ion Cells." Green Car Congress. N.p., 25 Dec. 2009. Web.
- ↑ Stura, Enrico; Nicolini, Claudio (2006). "New nanomaterials for light weight lithium batteries". Analytica Chimica Acta 568 (1–2): 57–64. doi:10.1016/j.aca.2005.11.025. PMID 17761246. Bibcode: 2006AcAC..568...57S.
- ↑ 6.0 6.1 6.2 Fisher, Julia (2003). "Energy density of coal". in Elert, Glenn. https://hypertextbook.com/facts/2003/JuliyaFisher.shtml. Retrieved 2019-07-28.
- ↑ "Heat Values of Various Fuels - World Nuclear Association." World Nuclear Association. N.p., Sept. 2016. Web.
- ↑ "Overview of Storage Development DOE Hydrogen Program." Office of Energy Efficiency & Renewable Energy. N.p., May 2000. Web.
- ↑ Wong, Kaufui; Dia, Sarah (2017). "Nanotechnology in Batteries". Journal of Energy Resources Technology 139. doi:10.1115/1.4034860.
- ↑ Ionescu-Zanetti, C.; et., al. (2005). "Nanogap capacitors: Sensitivity to sample permittivity changes". Journal of Applied Physics 99 (2): 024305–024305–5. doi:10.1063/1.2161818. Bibcode: 2006JAP....99b4305I.
- ↑ Naoi, K.; et., al. (2013). "New generation "nanohybrid supercapacitor".". Accounts of Chemical Research 46 (5): 1075–1083. doi:10.1021/ar200308h. PMID 22433167.
- ↑ Hubler, A.; Osuagwu, O. (2010). "Digital quantum batteries: Energy and information storage in nanovacuum tube arrays". Complexity 15 (5): NA. doi:10.1002/cplx.20306.
- ↑ Lyon, D.; et., al. (2013). "Gap size dependence of the dielectric strength in nano vacuum gaps". IEEE Transactions on Dielectrics and Electrical Insulation 2 (4): 1467–1471. doi:10.1109/TDEI.2013.6571470.
- ↑ CRC Handbook of Chemistry and Physics, 49th Edition, page D-42.
- ↑ 15.0 15.1 15.2 College of the Desert, “Module 1, Hydrogen Properties”, Revision 0, December 2001 Hydrogen Properties. Retrieved 2014-06-08.
- ↑ Mike Millikin (2014-11-18). "Toyota FCV Mirai launches in LA; initial TFCS specs; $57,500 or $499 lease; leaning on Prius analogy". Green Car Congress. http://www.greencarcongress.com/2014/11/20141118-mirai.html.
- ↑ Greenwood, Norman N.; Earnshaw, Alan (1997), Chemistry of the Elements (2nd ed) (page 164)
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- ↑ 20.0 20.1 20.2 20.3 20.4 Paul A. Kittle, Ph.D.. "ALTERNATE DAILY COVER MATERIALS AND SUBTITLE D - THE SELECTION TECHNIQUE". http://www.aquafoam.com/papers/selection.pdf.
- ↑ "537.PDF". June 1993. http://www-static.shell.com/static/aus/downloads/aviation/avgas_100ll_pds.pdf.
- ↑ Gofman, Evelyn (2003). "Energy density of aviation fuel". in Elert, Glenn. https://hypertextbook.com/facts/2003/EvelynGofman.shtml.
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- ↑ Characteristics of Petroleum Products Stored and Dispensed, Petroleum Products Division - GN, p. 132, http://ftp.nirb.ca/01-SCREENINGS/COMPLETED%20SCREENINGS/2016/16XN003-GN-CGS-Tank%20Farm%20Expansion/01-APPLICATION/160204-16XN003-Petroleum%20Products%20Strored%20and%20Dispensed-IA2E.pdf, retrieved 15 January 2017
- ↑ Román-Leshkov, Yuriy; Barrett, Christopher J.; Liu, Zhen Y.; Dumesic, James A. (21 June 2007). "Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates". Nature 447 (7147): 982–985. doi:10.1038/nature05923. PMID 17581580. Bibcode: 2007Natur.447..982R.
- ↑ Wiener, Harry (January 1947). "Structural Determination of Paraffin Boiling Points". Journal of the American Chemical Society 69 (1): 17–20. doi:10.1021/ja01193a005. ISSN 0002-7863. PMID 20291038. https://pubs.acs.org/doi/pdf/10.1021/ja01193a005.
- ↑ Justin Lemire-Elmore (2004-04-13). "The Energy Cost of Electric and Human-Powered Bicycles". p. 5. http://www.ebikes.ca/documents/Ebike_Energy.pdf. "properly trained athlete will have efficiencies of 22 to 26%"
- ↑ "Silicon as an intermediary between renewable energy and hydrogen". Deutsche Bank Research. pp. 5. https://www.dbresearch.com/PROD/DBR_INTERNET_EN-PROD/PROD0000000000079095.pdf.
- ↑ Bossel, Ulf (July 2003). "The Physics of the Hydrogen Economy". European Fuel Cell News. https://www.efcf.com/reports/E05.pdf. "The Higher Heating Values are 22.7, 29.7 or 31.7 MJ/kg for methanol, ethanol and DME, respectively, while gasoline contains about 45 MJ per kg."
- ↑ "Dimethyl Ether (DME)". 2013-11-18. http://www.etipbioenergy.eu/images/dme-fact-sheet.pdf. DME density and lower heating value were obtained from the table on the first page.
- ↑ Green Don; Perry Robert (2008). Perry's chemical engineers' handbook (8th ed.). New York: McGraw-Hill. ISBN 9780071422949.
- ↑ "Elite_bloc.indd". http://www.payne-worldwide.com/documents/cms/Elite_bloc_msds.pdf.
- ↑ "Biomass Energy Foundation: Fuel Densities". Woodgas.com. http://www.woodgas.com/fuel_densities.htm.
- ↑ "Bord na Mona, Peat for Energy". Bnm.ie. http://www.bnm.ie/files/20061124040716_peat_for_energy.pdf.
- ↑ Justin Lemire-elmore (April 13, 2004). "The Energy Cost of Electric and Human-Powered Bicycle". http://www.ebikes.ca/documents/Ebike_Energy.pdf.
- ↑ "energy buffers". Home.hccnet.nl. http://www.davdata.nl/math/energy.html.
- ↑ Anne Wignall and Terry Wales. Chemistry 12 Workbook, page 138 . Pearson Education NZ ISBN:978-0-582-54974-6
- ↑ David E. Dirkse. energy buffers. "household waste 8..11 MJ/kg"
- ↑ Lu, Gui-e; Chang, Wen-ping; Jiang, Jin-yong; Du, Shi-guo (May 2011). "Study on the energy density of gunpowder heat source". 2011 International Conference on Materials for Renewable Energy & Environment. IEEE. pp. 1185–1187. doi:10.1109/ICMREE.2011.5930549. ISBN 978-1-61284-749-8.
- ↑ 40.0 40.1 40.2 Calculated from fractional mass loss times c squared.
- ↑ Calculated from fractional mass loss times c squared. Ball, Justin (2019). "Maximizing specific energy by breeding deuterium". Nuclear Fusion 59 (10): 106043. doi:10.1088/1741-4326/ab394c. Bibcode: 2019NucFu..59j6043B.
- ↑ 42.0 42.1 "Computing the energy density of nuclear fuel". whatisnuclear.com. http://www.whatisnuclear.com/physics/energy_density_of_nuclear.html.
- ↑ "Technical bulletin on Zinc-air batteries". Duracell. http://www.duracell.com/oem/primary/Zinc/zinc_air_tech.asp.
- ↑ Meroueh, Laureen (2020). Thermal energy storage in Silicon. doi:10.1016/j.renene.2019.06.036.
- ↑ A. Fopah-Lele, J. G. Tamba "A review on the use of SrBr
2 · 6H2O as a potential material for low temperature energy storage systems and building applications", Solar Energy Materials and Solar Cells 164 175-84 (2017). - ↑ C. Knowlen, A.T. Mattick, A.P. Bruckner and A. Hertzberg, "High Efficiency Conversion Systems for Liquid Nitrogen Automobiles", Society of Automotive Engineers Inc, 1988.
- ↑ "Overview of lithium ion batteries". Panasonic. Jan 2007. http://www.panasonic.com/industrial/includes/pdf/Panasonic_LiIon_Overview.pdf.
- ↑ "Panasonic NCR18650B". http://industrial.panasonic.com/lecs/www-data/pdf2/ACA4000/ACA4000CE417.pdf.
- ↑ [47][48]
- ↑ 50.0 50.1 "Amprius' silicon nanowire Li-ion batteries power Airbus Zephyr S HAPS solar aircraft". https://www.greencarcongress.com/2018/12/20181205-amprius.html.
- ↑ "Test of Duracell Ultra Power AA". https://lygte-info.dk/review/batteries2012/Duracell%20Ultra%20Power%20AA%20UK.html.
- ↑ "Energizer EN91 AA alkaline battery datasheet". http://data.energizer.com/PDFs/EN91.pdf.
- ↑ 53.0 53.1 "Test of GP ReCyko+ AA 2700mAh (Green)". https://lygte-info.dk/review/batteries2012/GP%20ReCyko+%20AA%202700mAh%20(Green)%20UK.html.
- ↑ 54.0 54.1 "Maxwell supercapacitor comparison". http://www.maxwell.com/images/documents/Product_Comparison_Matrix_3000489_2.pdf.
- ↑ 55.0 55.1 "Nesscap ESHSP series supercapacitor datasheet". http://www.nesscap.com/common/download.jsp?dir=product&sfn=MSCWSMXHBBOMXOZ.pdf.
- ↑ 56.0 56.1 "Cooper PowerStor XL60 series supercapacitor datasheet". http://www.cooperindustries.com/content/dam/public/bussmann/Electronics/Resources/product-datasheets/bus-elx-ds-10339-xl.pdf.
- ↑ 57.0 57.1 "Kemet S301 series supercapacitor datasheet". http://www.kemet.com/Lists/ProductCatalog/Attachments/504/KEM_S6001_S301.pdf.
- ↑ 58.0 58.1 "Nichicon JJD series supercapatcitor datasheet". http://www.nichicon-us.com/english/products/pdfs/e-jjd.pdf.
- ↑ 59.0 59.1 "skelcap High Energy Ultracapacitor". http://skeletontech.com/datasheets/skelcap-energy-en.pdf.
- ↑ 60.0 60.1 "3.0V 3400F ULTRACAPACITOR CELL DATASHEET BCAP3400 P300 K04/05". https://www.maxwell.com/images/documents/3V_3400F_datasheet.pdf.
- ↑ "Hydroelectric Power Generation". Woodbank Communications Ltd. http://www.mpoweruk.com/hydro_power.htm.
- ↑ "2.1 Power, discharge, head relationship | River Engineering & Restoration at OSU | Oregon State University" (in en). http://rivers.bee.oregonstate.edu/elevation-discharge-power-relationship. "Let ε = 0.85, signifying an 85% efficiency rating, typical of an older powerplant."
- ↑ 63.0 63.1 "Vishay STE series tantalum capacitors datasheet". http://www.vishay.com/docs/43009/ste.pdf.
- ↑ "nichicon TVX aluminum electrolytic capacitors datasheet". http://www.nichicon-us.com/english/products/pdfs/e-tvx.pdf.
- ↑ "nichicon LGU aluminum electrolytic capacitors datasheet". http://www.nichicon-us.com/english/products/pdfs/e-lgu.pdf.
- ↑ 66.0 66.1 66.2 "How Much Energy Can You Store in a Rubber Band?" (in en). Wired. ISSN 1059-1028. https://www.wired.com/story/how-much-energy-can-you-store-in-a-rubber-band/. Retrieved 2020-01-21.
- ↑ 67.0 67.1 67.2 "MatWeb - The Online Materials Information Resource". http://www.matweb.com/search/datasheettext.aspx?matid=14072.
- ↑ PubChem. "Acetal" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/7765.
- ↑ 69.00 69.01 69.02 69.03 69.04 69.05 69.06 69.07 69.08 69.09 69.10 69.11 69.12 69.13 69.14 69.15 69.16 69.17 69.18 69.19 69.20 69.21 "Young's Modulus - Tensile and Yield Strength for common Materials". https://www.engineeringtoolbox.com/young-modulus-d_417.html.
- ↑ 70.0 70.1 70.2 70.3 70.4 70.5 70.6 70.7 70.8 Brush Wellman Alloy Products. "Elastic Resilience". https://materion.com/-/media/files/alloy/newsletters/technical-tidbits/issue-no-22--elastic-resilience.pdf.
- ↑ "C17200 Alloy Specifications | E. Jordan Brookes Company". https://www.ejbmetals.com/p/25/C17200.
- ↑ "polycarbonate information and properties". http://www.polymerprocessing.com/polymers/PC.html.
- ↑ "ASM Material Data Sheet". http://asm.matweb.com/search/SpecificMaterial.asp?bassnum=MA7075T6.
- ↑ Sutherland, Karen; Martin, Monica (2004). "Density of steel". in Elert, Glenn. https://hypertextbook.com/facts/2004/KarenSutherland.shtml.
- ↑ 75.0 75.1 75.2 "Aluminum 6061-T6; 6061-T651". http://www.matweb.com/search/datasheet_print.aspx?matguid=1b8c06d0ca7c456694c7777d9e10be5b.
- ↑ "Wood Species - Moisture Content and Weight". https://www.engineeringtoolbox.com/weigt-wood-d_821.html.
- ↑ 77.0 77.1 77.2 "AISI 1018 Mild/Low Carbon Steel" (in en). 2012-06-28. https://www.azom.com/article.aspx?ArticleID=6115.
- ↑ "ASM Material Data Sheet". http://asm.matweb.com/search/SpecificMaterial.asp?bassnum=MA6061T6.
- ↑ 79.0 79.1 79.2 "American Eastern White Pine Wood". http://www.matweb.com/search/datasheetText.aspx?bassnum=PTSAH.
- ↑ 80.0 80.1 "Mass, Weight, Density or Specific Gravity of Different Metals". https://www.simetric.co.uk/si_metals.htm.
- ↑ "Physical properties of glass | Saint Gobain Building Glass UK". https://uk.saint-gobain-building-glass.com/en-gb/architects/physical-properties.
- ↑ 82.0 82.1 "Battery Energy Tables". http://www.allaboutbatteries.com/Energy-tables.html.
- ↑ "18650 Battery capacities". http://www.best18650battery.com/.
- ↑ "Supply of Uranium". world-nuclear.org. 2014-10-08. http://www.world-nuclear.org/info/Nuclear-Fuel-Cycle/Uranium-Resources/Supply-of-Uranium/.
- ↑ "Facts from Cohen". Formal.stanford.edu. 2007-01-26. http://www-formal.stanford.edu/jmc/progress/cohen.html.
- ↑ "U.S. Energy Information Administration (EIA) - Annual Energy Review". Eia.doe.gov. 2009-06-26. http://www.eia.doe.gov/emeu/aer/pecss_diagram.html.
- ↑ Parravicini, J. (2018). "Thermodynamic potentials in anisotropic and nonlinear dielectrics". Physica B 541: 54–60. doi:10.1016/j.physb.2018.04.029. Bibcode: 2018PhyB..541...54P.
- ↑ "Terminology" (in en). https://www.rltvet.com/terminology.html.
Further reading
- The Inflationary Universe: The Quest for a New Theory of Cosmic Origins by Alan H. Guth (1998) ISBN:0-201-32840-2
- Cosmological Inflation and Large-Scale Structure by Andrew R. Liddle, David H. Lyth (2000) ISBN:0-521-57598-2
- Richard Becker, "Electromagnetic Fields and Interactions", Dover Publications Inc., 1964
External links
- ^ "Aircraft Fuels." Energy, Technology and the Environment Ed. Attilio Bisio. Vol. 1. New York: John Wiley and Sons, Inc., 1995. 257–259
- "Fuels of the Future for Cars and Trucks" – Dr. James J. Eberhardt – Energy Efficiency and Renewable Energy, U.S. Department of Energy – 2002 Diesel Engine Emissions Reduction (DEER) Workshop San Diego, California - August 25–29, 2002
- "Heat values of various fuels – World Nuclear Association". www.world-nuclear.org. http://www.world-nuclear.org/information-library/facts-and-figures/heat-values-of-various-fuels.aspx.
- "Energy and Energy Types – Springer". https://www.springer.com/cda/content/document/cda_downloaddocument/9781447123712-c2.pdf?SGWID=0-0-45-1293540-p174262962.
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