Chemistry:Gallium palladide
From HandWiki
| Names | |
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| Preferred IUPAC name
Gallium palladide | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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| Properties | |
| GaPd | |
| Molar mass | 176.14 g·mol−1 |
| Structure[1] | |
| Iron monosilicide (cubic) | |
| P213 (No. 198) | |
a = 489.695 pm
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Gallium palladide (GaPd or PdGa)[2] is an intermetallic combination of gallium and palladium. It has the iron monosilicide crystal structure.[3] The compound has been suggested as an improved catalyst for hydrogenation reactions.[4][5] In principle, gallium palladide can be a more selective catalyst since unlike substituted compounds, the palladium atoms are spaced out in a regular crystal structure rather than randomly.[6][7]
References
- ↑ Armbrüster, Marc; Borrmann, Horst; Wedel, Michael; Prots, Yurii; Giedigkeit, Rainer; Gille, Peter (2010). "Refinement of the crystal structure of palladium gallium (1:1), PdGa". Zeitschrift für Kristallographie - New Crystal Structures (Walter de Gruyter GmbH) 225 (4): 617–618. doi:10.1524/ncrs.2010.0269. ISSN 2197-4578. https://epub.ub.uni-muenchen.de/18779/1/10.1524_ncrs.2010.0269.pdf.
- ↑ Grin, Yu.; Armbrüster, M.; Baranov, A. I.; Finzel, K.; Kohout, M.; Ormeci, A.; Rosner, H.; Wagner, F. R. (2015-10-27). "Atomic interactions in the intermetallic catalyst GaPd". Molecular Physics (Informa UK Limited) 114 (7–8): 1250–1259. doi:10.1080/00268976.2015.1093664. ISSN 0026-8976.
- ↑ Bhargava, M.K; Gadalla, A.A; Schubert, K (1975). "Koexistente phasen vom FeSi-Typ in den mischungen Ni-Pd-Ga und Ni-Pt-Ga" (in de). Journal of the Less Common Metals (Elsevier BV) 42 (1): 69–76. doi:10.1016/0022-5088(75)90021-1. ISSN 0022-5088.
- ↑ OSSWALD, J; GIEDIGKEIT, R; JENTOFT, R; ARMBRUSTER, M; GIRGSDIES, F; KOVNIR, K; RESSLER, T; GRIN, Y et al. (2008-08-15). "Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart I: Preparation and structural investigation under reaction conditions". Journal of Catalysis (Elsevier BV) 258 (1): 210–218. doi:10.1016/j.jcat.2008.06.013. ISSN 0021-9517.
- ↑ OSSWALD, J; KOVNIR, K; ARMBRUSTER, M; GIEDIGKEIT, R; JENTOFT, R; WILD, U; GRIN, Y; SCHLOGL, R (2008-08-15). "Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart II: Surface characterization and catalytic performance". Journal of Catalysis (Elsevier BV) 258 (1): 219–227. doi:10.1016/j.jcat.2008.06.014. ISSN 0021-9517.
- ↑ Armbrüster, Marc; Schlögl, Robert; Grin, Yuri (2014). "Intermetallic compounds in heterogeneous catalysis—a quickly developing field". Science and Technology of Advanced Materials (Informa UK Limited) 15 (3): 034803. doi:10.1088/1468-6996/15/3/034803. ISSN 1468-6996. PMID 27877674. Bibcode: 2014STAdM..15c4803A.
- ↑ Krajčı´, M.; Hafner, J. (2012). "The (210) surface of intermetallic B20 compound GaPd as a selective hydrogenation catalyst: A DFT study". Journal of Catalysis (Elsevier BV) 295: 70–80. doi:10.1016/j.jcat.2012.07.025. ISSN 0021-9517.
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