Chemistry:Palladium tetrafluoride
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3D model (JSmol)
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PubChem CID
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| Properties | |
| F4Pd | |
| Molar mass | 182.41 g·mol−1 |
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Other cations
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Platinum(IV) fluoride |
Related compounds
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Palladium(II) fluoride Palladium(II,IV) fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Palladium (IV) fluoride, also known as palladium tetrafluoride, is the chemical compound of palladium and fluorine with the chemical formula PdF4. The palladium atoms in PdF4 are in the +4 oxidation state.[1][2]
Synthesis
Palladium tetrafluoride has been prepared by reacting palladium(II,IV) fluoride with fluorine gas at pressures around 7 atm and at 300 °C for several days.[3]
Structure
Crystals are composed of octahedral PdF6 units, with four fluorides from each octahedron shared (bridging between octahedra).[4]
Reactivity
PdF4 is a strong oxidising agent and undergoes rapid hydrolysis in moist air.[3]
See also
References
- ↑ Cite error: Invalid
<ref>tag; no text was provided for refs namedG&E-1152-1153 - ↑ Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. pp. 788–789. ISBN 978-0-13-175553-6.
- ↑ 3.0 3.1 Cite error: Invalid
<ref>tag; no text was provided for refs namedRao - ↑ Wright, Albert F.; Fender, B. E. F.; Bartlett, N.; Leary, K. (1978-03-01). "A neutron powder diffraction study of palladium tetrafluoride" (in en). Inorganic Chemistry 17 (3): 748–749. doi:10.1021/ic50181a049. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic50181a049.
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