Chemistry:Arsenide nitride

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Cubic Mg3AsN, orthorhombic Ca3AsN Sr3AsN and Ba3AsN showing increased distortion as alkaline earth metal increases in size.

Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.

Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.

List

name formula crystal

system

space group unit cell Å volume density comment ref
Mg3AsN cubic Pm3m a =4.2148 Z=1 74.88 3.589 orange [2]
Ca3AsN orthorhombic Pbnm a=6.725 b=6.7198 c=9.5335 Z=4 430.8 3.237 red; moisture sensitive [3]
Ca14As6C0.445N1.135H4.915 P4/mbm a = 15.749 c = 9.1062 red; band gap 1.6 eV [4]
Cr3AsN tetragonal I4/mcm a=5.360 c=8.066 [5][6]
gallium arsenide nitride Ga(As,N)
indium gallium arsenide nitride (In,Ga)(As,N)
aluminium gallium arsenide nitride (Al,Ga)(As,N)
Sr3AsN orthorhombic Pbnm a=7.1856 b=10.1446 c=7.1464 Z=4 520.93 4.486 dark grey [2]
Ba3AsN orthorhombic Pbnm a=7.6741 b=10.7573 c=7.5387 Z=4 622.33 5.347 black [2]
LaFe2AsN orthorhombic Cmcm a =3.79932 b =11.11461 c =7.18656 303.474 [7]
LaCo2AsN orthorhombic Cmcm a =3.75993 b =11.1674 c =7.0185 294699 [7]
LaNi2AsN orthorhombic Cmcm a =3.71584 b =11.4147 c =6.9786 296.004 [7]
Th2ONAs P3m1 a=4.041 c=6.979 [8]
ThCrAsN metallic [9]
ThMnAsN tetragonal P4/nmm a =4.0818 b =4.0818 c =8.947 metallic [10]
ThFeAsN tetragonal P4/nmm a = 4.0367 c = 8.5262 superconductor Tc 30 K [11]
ThFe1-xCoxAsN superconductivity lost for x>0.05 [12]
ThNiAsN tetragonal P4/nmm a=4,0804 c=7.9888 superconductor at 4.3K [13]
BaTh2Fe4As4(N0.7O0.3)2 a=3.9886 c=29.853 Tc 22K [14]
U2N2As P3m1 a=3.833 c=6.737 [8]

References

  1. ↑ Toivonen, J.; Oila, J.; Saarinen, K.; Hakkarainen, T.; Sopanen, M.; Lipsanen, H. (2002). "Vacancy-type defects in GaAsN grown by metalorganic vapor phase epitaxy". Conference Proceedings. 14th Indium Phosphide and Related Materials Conference (Cat. No.02CH37307). Stockholm, Sweden: IEEE. pp. 245–248. doi:10.1109/ICIPRM.2002.1014345. ISBN 978-0-7803-7320-4. https://ieeexplore.ieee.org/document/1014345. 
  2. ↑ 2.0 2.1 2.2 Stoiber, Dominik; Niewa, Rainer (2019-02-15). "Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba)" (in en). Zeitschrift für anorganische und allgemeine Chemie 645 (3): 329–334. doi:10.1002/zaac.201800295. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201800295. 
  3. ↑ Chern, Ming Y.; Disalvo, F.J.; Parise, J.B.; Goldstone, Joyce A. (February 1992). "The structural distortion of the anti-perovskite nitride Ca3AsN" (in en). Journal of Solid State Chemistry 96 (2): 426–435. doi:10.1016/S0022-4596(05)80277-4. Bibcode: 1992JSSCh..96..426C. https://linkinghub.elsevier.com/retrieve/pii/S0022459605802774. 
  4. ↑ Blankenship, Trevor V.; Wang, Xiaoping; Hoffmann, Christina; Latturner, Susan E. (2014-10-06). "LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux" (in en). Inorganic Chemistry 53 (19): 10620–10626. doi:10.1021/ic501722d. ISSN 0020-1669. PMID 25222291. https://pubs.acs.org/doi/10.1021/ic501722d. 
  5. ↑ Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu; Ohta, Hiroto; Yajima, Takeshi; Hiroi, Zenji; Nakamura, Hiroyuki (15 October 2017). "Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan 86 (10): 104706. doi:10.7566/JPSJ.86.104706. Bibcode: 2017JPSJ...86j4706W. 
  6. ↑ Boller, H. (1968). "Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ". Monatshefte für Chemie 99 (6): 2444–2449. doi:10.1007/BF01154362. 
  7. ↑ 7.0 7.1 7.2 Jeong, Sehoon; Matsuishi, Satoru; Bang, Joonho; Hosono, Hideo (2015-04-01). "Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN ( TM = Fe, Co, and Ni)" (in en). APL Materials 3 (4): 041509. doi:10.1063/1.4913395. ISSN 2166-532X. Bibcode: 2015APLM....3d1509J. https://pubs.aip.org/apm/article/3/4/041509/121652/Crystal-structure-and-physical-properties-of-new. 
  8. ↑ 8.0 8.1 Benz, R.; Zachariasen, W. H. (1969-02-15). "Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 25 (2): 294–296. doi:10.1107/S0567740869002135. https://scripts.iucr.org/cgi-bin/paper?S0567740869002135. 
  9. ↑ Wang, Zhi-Cheng; Shao, Ye-Ting; Lin, Yi-Qiang; Song, Shi-Jie; Li, Bai-Zhuo; Cheng, Er-Jian; Li, Shi-Yan; Zhu, Qin-Qing et al. (2023-08-09). "Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x" (in en). Physical Review B 108 (6): 064503. doi:10.1103/PhysRevB.108.064503. ISSN 2469-9950. Bibcode: 2023PhRvB.108f4503W. https://link.aps.org/doi/10.1103/PhysRevB.108.064503. 
  10. ↑ Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong; Mao, Huican; Xia, Yuanhua; Hu, Bingfeng; Liu, Zichen; Wang, Zhicheng et al. (2020-03-02). "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects" (in en). Inorganic Chemistry 59 (5): 2937–2944. doi:10.1021/acs.inorgchem.9b03294. ISSN 0020-1669. PMID 32064866. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b03294. 
  11. ↑ Wang, Cao; Wang, Zhi-Cheng; Mei, Yu-Xue; Li, Yu-Ke; Li, Lin; Tang, Zhang-Tu; Liu, Yi; Zhang, Pan et al. (2016-02-24). "A New ZrCuSiAs-Type Superconductor: ThFeAsN" (in en). Journal of the American Chemical Society 138 (7): 2170–2173. doi:10.1021/jacs.6b00236. ISSN 0002-7863. PMID 26853632. https://pubs.acs.org/doi/10.1021/jacs.6b00236. 
  12. ↑ Wang, Jingfeng; Jiao, Fei; Wang, Xianyu; Zhu, Shu; Cai, Lingbo; Yang, Chunhui; Song, Pengwei; Zhang, Fuxiang et al. (2020-07-21). "The phase transition of ThFe 1-x Co x AsN from superconductor to metallic paramagnet". EPL (Europhysics Letters) 130 (6): 67003. doi:10.1209/0295-5075/130/67003. ISSN 1286-4854. Bibcode: 2020EL....13067003W. https://iopscience.iop.org/article/10.1209/0295-5075/130/67003. 
  13. ↑ Wang, Zhi-Cheng; Shao, Ye-Ting; Wang, Cao; Wang, Zhen; Xu, Zhu-An; Cao, Guang-Han (2017-06-01). "Enhanced superconductivity in ThNiAsN". EPL (Europhysics Letters) 118 (5): 57004. doi:10.1209/0295-5075/118/57004. ISSN 0295-5075. Bibcode: 2017EL....11857004W. https://iopscience.iop.org/article/10.1209/0295-5075/118/57004. 
  14. ↑ Shao, Ye-Ting; Wang, Zhi-Cheng; Li, Bai-Zhuo; Wu, Si-Qi; Wu, Ji-Feng; Ren, Zhi; Qiu, Su-Wen; Rao, Can et al. (September 2019). "BaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer". Science China Materials 62 (9): 1357–1362. doi:10.1007/s40843-019-9438-7. ISSN 2095-8226. 
Salts and covalent derivatives of the nitride ion
NH3 He(N2)11
Li3N Be3N2 BN β-C3N4
g-C3N4 		N2 NxOy NF3 Ne
Na3N Mg3N2 AlN Si3N4 PN
P3N5 		SxNy
SN
S4N4 		NCl3 Ar
K3N Ca3N2 ScN TiN VN CrN
Cr2N 		MnxNy FexNy CoN Ni3N CuN Zn3N2 GaN Ge3N4 As Se NBr3 Kr
Rb3N Sr3N2 YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N CdN InN Sn Sb Te NI3 Xe
Cs3N Ba3N2   Hf3N4 TaN WN Re Os Ir Pt Au Hg3N2 TlN Pb BiN Po At Rn
Fr3N Ra3N   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La CeN Pr Nd Pm Sm Eu GdN Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UN Np Pu Am Cm Bk Cf Es Fm Md No Lr



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