Chemistry:Arsenide nitride
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Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.
Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.
List
name | formula | crystal
system |
space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|---|
Mg3AsN | cubic | Pm3m | a =4.2148 Z=1 | 74.88 | 3.589 | orange | [2] | |
Ca3AsN | orthorhombic | Pbnm | a=6.725 b=6.7198 c=9.5335 Z=4 | 430.8 | 3.237 | red; moisture sensitive | [3] | |
Ca14As6C0.445N1.135H4.915 | P4/mbm | a = 15.749 c = 9.1062 | red; band gap 1.6 eV | [4] | ||||
Cr3AsN | tetragonal | I4/mcm | a=5.360 c=8.066 | [5][6] | ||||
gallium arsenide nitride | Ga(As,N) | |||||||
indium gallium arsenide nitride | (In,Ga)(As,N) | |||||||
aluminium gallium arsenide nitride | (Al,Ga)(As,N) | |||||||
Sr3AsN | orthorhombic | Pbnm | a=7.1856 b=10.1446 c=7.1464 Z=4 | 520.93 | 4.486 | dark grey | [2] | |
Ba3AsN | orthorhombic | Pbnm | a=7.6741 b=10.7573 c=7.5387 Z=4 | 622.33 | 5.347 | black | [2] | |
LaFe2AsN | orthorhombic | Cmcm | a =3.79932 b =11.11461 c =7.18656 | 303.474 | [7] | |||
LaCo2AsN | orthorhombic | Cmcm | a =3.75993 b =11.1674 c =7.0185 | 294699 | [7] | |||
LaNi2AsN | orthorhombic | Cmcm | a =3.71584 b =11.4147 c =6.9786 | 296.004 | [7] | |||
Th2ONAs | P3m1 | a=4.041 c=6.979 | [8] | |||||
ThCrAsN | metallic | [9] | ||||||
ThMnAsN | tetragonal | P4/nmm | a =4.0818 b =4.0818 c =8.947 | metallic | [10] | |||
ThFeAsN | tetragonal | P4/nmm | a = 4.0367 c = 8.5262 | superconductor Tc 30 K | [11] | |||
ThFe1-xCoxAsN | superconductivity lost for x>0.05 | [12] | ||||||
ThNiAsN | tetragonal | P4/nmm | a=4,0804 c=7.9888 | superconductor at 4.3K | [13] | |||
BaTh2Fe4As4(N0.7O0.3)2 | a=3.9886 c=29.853 | Tc 22K | [14] | |||||
U2N2As | P3m1 | a=3.833 c=6.737 | [8] |
References
- ↑ Toivonen, J.; Oila, J.; Saarinen, K.; Hakkarainen, T.; Sopanen, M.; Lipsanen, H. (2002). "Vacancy-type defects in GaAsN grown by metalorganic vapor phase epitaxy". Conference Proceedings. 14th Indium Phosphide and Related Materials Conference (Cat. No.02CH37307). Stockholm, Sweden: IEEE. pp. 245–248. doi:10.1109/ICIPRM.2002.1014345. ISBN 978-0-7803-7320-4. https://ieeexplore.ieee.org/document/1014345.
- ↑ 2.0 2.1 2.2 Stoiber, Dominik; Niewa, Rainer (2019-02-15). "Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba)" (in en). Zeitschrift für anorganische und allgemeine Chemie 645 (3): 329–334. doi:10.1002/zaac.201800295. https://onlinelibrary.wiley.com/doi/10.1002/zaac.201800295.
- ↑ Chern, Ming Y.; Disalvo, F.J.; Parise, J.B.; Goldstone, Joyce A. (February 1992). "The structural distortion of the anti-perovskite nitride Ca3AsN" (in en). Journal of Solid State Chemistry 96 (2): 426–435. doi:10.1016/S0022-4596(05)80277-4. Bibcode: 1992JSSCh..96..426C. https://linkinghub.elsevier.com/retrieve/pii/S0022459605802774.
- ↑ Blankenship, Trevor V.; Wang, Xiaoping; Hoffmann, Christina; Latturner, Susan E. (2014-10-06). "LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux" (in en). Inorganic Chemistry 53 (19): 10620–10626. doi:10.1021/ic501722d. ISSN 0020-1669. PMID 25222291. https://pubs.acs.org/doi/10.1021/ic501722d.
- ↑ Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu; Ohta, Hiroto; Yajima, Takeshi; Hiroi, Zenji; Nakamura, Hiroyuki (15 October 2017). "Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan 86 (10): 104706. doi:10.7566/JPSJ.86.104706. Bibcode: 2017JPSJ...86j4706W.
- ↑ Boller, H. (1968). "Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ". Monatshefte für Chemie 99 (6): 2444–2449. doi:10.1007/BF01154362.
- ↑ 7.0 7.1 7.2 Jeong, Sehoon; Matsuishi, Satoru; Bang, Joonho; Hosono, Hideo (2015-04-01). "Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN ( TM = Fe, Co, and Ni)" (in en). APL Materials 3 (4): 041509. doi:10.1063/1.4913395. ISSN 2166-532X. Bibcode: 2015APLM....3d1509J. https://pubs.aip.org/apm/article/3/4/041509/121652/Crystal-structure-and-physical-properties-of-new.
- ↑ 8.0 8.1 Benz, R.; Zachariasen, W. H. (1969-02-15). "Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 25 (2): 294–296. doi:10.1107/S0567740869002135. https://scripts.iucr.org/cgi-bin/paper?S0567740869002135.
- ↑ Wang, Zhi-Cheng; Shao, Ye-Ting; Lin, Yi-Qiang; Song, Shi-Jie; Li, Bai-Zhuo; Cheng, Er-Jian; Li, Shi-Yan; Zhu, Qin-Qing et al. (2023-08-09). "Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x" (in en). Physical Review B 108 (6): 064503. doi:10.1103/PhysRevB.108.064503. ISSN 2469-9950. Bibcode: 2023PhRvB.108f4503W. https://link.aps.org/doi/10.1103/PhysRevB.108.064503.
- ↑ Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong; Mao, Huican; Xia, Yuanhua; Hu, Bingfeng; Liu, Zichen; Wang, Zhicheng et al. (2020-03-02). "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects" (in en). Inorganic Chemistry 59 (5): 2937–2944. doi:10.1021/acs.inorgchem.9b03294. ISSN 0020-1669. PMID 32064866. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b03294.
- ↑ Wang, Cao; Wang, Zhi-Cheng; Mei, Yu-Xue; Li, Yu-Ke; Li, Lin; Tang, Zhang-Tu; Liu, Yi; Zhang, Pan et al. (2016-02-24). "A New ZrCuSiAs-Type Superconductor: ThFeAsN" (in en). Journal of the American Chemical Society 138 (7): 2170–2173. doi:10.1021/jacs.6b00236. ISSN 0002-7863. PMID 26853632. https://pubs.acs.org/doi/10.1021/jacs.6b00236.
- ↑ Wang, Jingfeng; Jiao, Fei; Wang, Xianyu; Zhu, Shu; Cai, Lingbo; Yang, Chunhui; Song, Pengwei; Zhang, Fuxiang et al. (2020-07-21). "The phase transition of ThFe 1-x Co x AsN from superconductor to metallic paramagnet". EPL (Europhysics Letters) 130 (6): 67003. doi:10.1209/0295-5075/130/67003. ISSN 1286-4854. Bibcode: 2020EL....13067003W. https://iopscience.iop.org/article/10.1209/0295-5075/130/67003.
- ↑ Wang, Zhi-Cheng; Shao, Ye-Ting; Wang, Cao; Wang, Zhen; Xu, Zhu-An; Cao, Guang-Han (2017-06-01). "Enhanced superconductivity in ThNiAsN". EPL (Europhysics Letters) 118 (5): 57004. doi:10.1209/0295-5075/118/57004. ISSN 0295-5075. Bibcode: 2017EL....11857004W. https://iopscience.iop.org/article/10.1209/0295-5075/118/57004.
- ↑ Shao, Ye-Ting; Wang, Zhi-Cheng; Li, Bai-Zhuo; Wu, Si-Qi; Wu, Ji-Feng; Ren, Zhi; Qiu, Su-Wen; Rao, Can et al. (September 2019). "BaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer". Science China Materials 62 (9): 1357–1362. doi:10.1007/s40843-019-9438-7. ISSN 2095-8226.
Salts and covalent derivatives of the nitride ion
NH3 | He(N2)11 | ||||||||||||||||
Li3N | Be3N2 | BN | β-C3N4 g-C3N4 |
N2 | NxOy | NF3 | Ne | ||||||||||
Na3N | Mg3N2 | AlN | Si3N4 | PN P3N5 |
SxNy SN S4N4 |
NCl3 | Ar | ||||||||||
K3N | Ca3N2 | ScN | TiN | VN | CrN Cr2N |
MnxNy | FexNy | CoN | Ni3N | CuN | Zn3N2 | GaN | Ge3N4 | As | Se | NBr3 | Kr |
Rb3N | Sr3N2 | YN | ZrN | NbN | β-Mo2N | Tc | Ru | Rh | PdN | Ag3N | CdN | InN | Sn | Sb | Te | NI3 | Xe |
Cs3N | Ba3N2 | Hf3N4 | TaN | WN | Re | Os | Ir | Pt | Au | Hg3N2 | TlN | Pb | BiN | Po | At | Rn | |
Fr3N | Ra3N | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
↓ | |||||||||||||||||
La | CeN | Pr | Nd | Pm | Sm | Eu | GdN | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||
Ac | Th | Pa | UN | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr |
![]() | Original source: https://en.wikipedia.org/wiki/Arsenide nitride.
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