Chemistry:Trimolybdenum phosphide
From HandWiki
| Identifiers | |
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3D model (JSmol)
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| Properties | |
| Mo3P | |
| Molar mass | 318.82 g·mol−1 |
| Appearance | grey crystals |
| insoluble | |
| Related compounds | |
Related compounds
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Molybdenum monophosphide, Molybdenum diphosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Trimolybdenum phosphide is a binary inorganic compound of molybdenum metal and phosphorus with the chemical formula Mo
3P.[1][2]
Preparation
Trimolybdenum phosphide can be obtained via electrolysis of a melt mixture of molybdenum hexametaphosphate with molybdenum(VI) oxide and sodium chloride.
Properties
Trimolybdenum phosphide forms grey crystals of tetragonal crystal system with space group I4.[3] It is insoluble in water. Trimolybdenum phosphide becomes superconducting at 7 K.[4]
Uses
Trimolybdenum phosphide can be used as a catalyst for electrocatalytic processes.[5][6] It can also be used in accumulators.[7][8]
References
- ↑ Kondori, Alireza; Esmaeilirad, Mohammadreza; Baskin, Artem; Song, Boao; Wei, Jialiang; Chen, Wei; Segre, Carlo U.; Shahbazian-Yassar, Reza et al. (June 2019). "Identifying Catalytic Active Sites of Trimolybdenum Phosphide (Mo 3 P) for Electrochemical Hydrogen Evolution" (in en). Advanced Energy Materials 9 (22). doi:10.1002/aenm.201900516. ISSN 1614-6832. Bibcode: 2019AdEnM...900516K. https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.201900516. Retrieved 9 March 2024.
- ↑ Muchharla, Baleeswaraiah; Malali, Praveen; Daniel, Brenna; Kondori, Alireza; Asadi, Mohammad; Cao, Wei; Elsayed-Ali, Hani E.; Castro, Mickaël et al. (13 September 2021). "Tri-molybdenum phosphide (Mo3P) and multi-walled carbon nanotube junctions for volatile organic compounds (VOCs) detection". Applied Physics Letters 119 (11). doi:10.1063/5.0059378. https://pubs.aip.org/aip/apl/article/119/11/113101/39954/Tri-molybdenum-phosphide-Mo3P-and-multi-walled.
- ↑ Donnay, Joseph Désiré Hubert (1973) (in en). Crystal Data: Inorganic compounds. National Bureau of Standards. p. 16. https://books.google.com/books?id=5lVCBwmZsLYC&dq=%22Molybdenum+phosphide+Mo3P%22&pg=RA4-PA16. Retrieved 9 March 2024.
- ↑ Mellor, Joseph William (1971) (in en). Supplement to Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry: suppl. 1, pt. 1. N. Longmans, Green and Company. p. 337. https://books.google.com/books?id=BBhGAQAAMAAJ&q=Tri+Molybdenum+phosphide. Retrieved 9 March 2024.
- ↑ Kondori, Alireza; Esmaeilirad, Mohammadreza; Baskin, Artem; Song, Boao; Wei, Jialiang; Chen, Wei; Segre, Carlo U.; Shahbazian-Yassar, Reza et al. (June 2019). "Identifying Catalytic Active Sites of Trimolybdenum Phosphide (Mo 3 P) for Electrochemical Hydrogen Evolution". Advanced Energy Materials 9 (22). doi:10.1002/aenm.201900516. Bibcode: 2019AdEnM...900516K. https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.201900516. Retrieved 9 March 2024.
- ↑ Kuei, Brooke (August 27, 2019). "Uncovering the Origin of High Performance in a New Water Splitting Catalyst". foundry.lbl.gov. https://foundry.lbl.gov/2019/08/27/uncovering-the-origin-of-high-performance-in-a-new-water-splitting-catalyst/.
- ↑ Timmer, John (6 February 2023). "New battery seems to offer it all: Lithium-metal/lithium-air electrodes" (in en-us). https://arstechnica.com/science/2023/02/new-battery-seems-to-offer-it-all-lithium-metal-lithium-air-electrodes/.
- ↑ "(201d) First-Principles Study of Lithium-Air Batteries Based on Tri-Molybdenum Phosphide (Mo3P) Nanoparticles | AIChE". aiche.org. https://www.aiche.org/academy/conferences/aiche-annual-meeting/2020/proceeding/paper/201d-first-principles-study-lithium-air-batteries-based-on-tri-molybdenum-phosphide-mo3p.
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